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    • 1. 发明授权
    • Catalyzed alkaline hydrogen peroxide bleaching of dye-containing
cellulose textiles
    • 催化碱性过氧化氢漂白含染料的纤维素纺织品
    • US6120554A
    • 2000-09-19
    • US017064
    • 1998-02-02
    • Robert T. PattonDavid Hall
    • Robert T. PattonDavid Hall
    • D06L3/02
    • D06L3/02
    • A process for decolorizing a cellulose textile bearing oxidized vat dye comprising contacting the cellulose textile with an aqueous solution of hydrogen peroxide containing an amount of a hydrogen peroxide catalyst sufficient to oxidize vat dye in the fabric until the dye is decolorized by oxidation. Then the cellulose textile is separated from the aqueous solution. The hydrogen peroxide catalyst can be a water-soluble lower alkyl quaternary amine salt such as a dihydroxypropyltrimethylammonium halide, chlorohydroxypropyltrimethylammonium halide or epoxypropyltrimethylammonium halide, or it can be a transition metal ion such as a cupric or stannous metal ion present in an amount of from 0.1 to 2 ppm. The process is suitable for decolorizing denim bearing vat dyes such as indigo, and is particularly suitable for decolorizing denim scrap.
    • 一种使含有氧化瓮染料的纤维素纺织品脱色的方法,包括使纤维素纺织物与含有足以氧化织物中的瓮染料的量的过氧化氢催化剂的过氧化氢水溶液接触,直到染料通过氧化脱色。 然后将纤维素纺织物与水溶液分离。 过氧化氢催化剂可以是水溶性低级烷基季铵盐,例如二羟丙基三甲基卤化铵,氯羟丙基三甲基卤化铵或环氧丙基三甲基卤化铵,或者它可以是过量金属离子,例如以0.1的量存在的二价或二价金属离子 至2ppm。 该方法适用于靛蓝脱色牛仔布承载瓮染料,特别适用于脱色牛仔布废料。
    • 2. 发明授权
    • Solvent process for recovering indigo dye from textile scrap
    • 从纺织废料回收靛蓝染料的溶剂工艺
    • US5989296A
    • 1999-11-23
    • US17063
    • 1998-02-02
    • Robert T. PattonDavid Hall
    • Robert T. PattonDavid Hall
    • C09B67/30C09B67/54C09B67/34D09P1/22D09P3/58
    • C09B67/0078C09B67/0096D06P5/137Y10S8/918
    • A process for recovering a vat dye from a textile using a heated organic solvent. The textile is contacted with a heated organic solvent in which the dye is soluble until dye is extracted from the textile into the solvent to produce a dye-containing solvent solution. The dye is then recovered from the organic solvent by evaporation of the solvent leaving a dye residue, cooling and precipitation of the dye, or extraction of the dye by contacting the dye-containing solvent solution with an aqueous solution containing a reducing agent for the dye. When dye is extracted from the dye-containing solvent solution by contacting it with an aqueous solution containing a reducing agent, the dye is subsequently insolubilized by oxidation, and the dye is recovered from the aqueous dye solution. This process is particularly advantageous for recovering indigo dye from denim scrap.
    • 使用加热的有机溶剂从纺织品中回收含水染料的方法。 织物与加热的有机溶剂接触,其中染料可溶,直到染料从织物中提取到溶剂中以产生含染料的溶剂溶液。 然后通过蒸发溶剂蒸发染料残留物,染料冷却和沉淀,或通过使含染料的溶剂溶液与含有染料的还原剂的水溶液接触来提取染料,从有机溶剂中回收染料 。 当通过使其与含有还原剂的水溶液接触从含染料的溶剂溶液中提取染料时,染料随后通过氧化而不溶解,并且染料从染料溶液中回收。 该方法对于从牛仔布废料中回收靛蓝染料是特别有利的。
    • 9. 发明授权
    • Viscosity-modifiers for aqueous-based dye-depletion products
    • 用于水性染料消耗产物的粘度调节剂
    • US4999025A
    • 1991-03-12
    • US212403
    • 1988-06-27
    • Robert T. Patton
    • Robert T. Patton
    • C09K3/00C11D3/12C11D3/39C11D3/395D06L3/00D06L3/06D06P1/673D06P5/00D06P5/02D06P5/15
    • D06P5/001C09K3/00C11D3/1213C11D3/3947C11D3/3956D06L3/06D06P1/6735D06P5/15
    • Aqueous-based dye-depletion formulations such as bleaches, oxidizing agents or reducing agents are thickened or viscosity-modified by the addition of at least a small, but effective, amount of at least one crystalline mixed metal hydroxide conforming substantially to the formulaLi.sub.m D.sub.d T(OH)(m+2d+3+n.multidot.a)(A.sup.n).sub.a .multidot.xH.sub.2 Owhere m is zero to one, D is a divalent metal, d is from zero to 4, T is a trivalent metal, A represents at least one anion or negative-valence radical of valence n, where n is 1 or more, (m+2d+3+n.multidot.a) is equal to or greater than 3, (m+d) is greater than zero, and xH.sub.2 O represents excess waters of hydration.The dye-depletion formulations have highly beneficial gel-thinning and gel-setting properties which render it capable of being used in pattern-dying, pattern-bleaching, and the like.
    • 通过添加具有阳离子表面电荷的合成层状结晶混合金属氢氧化物,特别是通式为LimDdT(OH)(m + 2d),通过添加水性染料消耗剂如漂白剂,氧化剂或还原剂来增稠或粘度改性 + 3 + na)(A n)a.xH 2 O其中m为0至1,D为二价金属,d为0至4,T为三价金属,A为至少一个阴离子或负数 (m + 2d + 3 + na)等于或大于3,(m + d)大于零,xH 2 O表示多余的水合水合物,其中n为1以上。 本发明的染料消耗制剂具有非常有益的凝胶稀释和凝胶凝固性质,使得它们能够用于图案染色,图案漂白等。