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1. 发明授权

US08394862B1 Catalytic process for the direct production of hydrocarbon fuels from syngas 有权
标题翻译：从合成气直接生产烃类燃料的催化过程
公开(公告)号：US08394862B1
公开(公告)日：2013-03-12
申请号：US12927242
申请日：2010-11-10
申请人： Robert Schuetzle , Dennis Schuetzle , David De Villiers
发明人： Robert Schuetzle , Dennis Schuetzle , David De Villiers
IPC分类号： C07C27/00
CPC分类号： C10G2/332 , B01J21/04 , B01J23/745 , B01J23/75 , B01J23/755 , B01J23/8896 , B01J23/8906 , B01J23/8913 , B01J23/892 , B01J35/023 , B01J35/1019 , B01J35/1061 , B01J37/0201 , B01J37/18 , C10G2/333 , C10G45/62 , C10L1/1963 , C10L1/1966 , C10L1/1973 , C10L10/14
摘要： A unique process and catalyst is described that operates efficiently at low pressures for the direct production of a high cetane diesel type fuel or diesel type blending stock from stoichiometric mixtures of hydrogen and carbon monoxide. This invention allows for, but is not limited to, the economical and efficient production high quality diesel type fuels from small or distributed fuel production plants that have an annual production capacity of less than 100 million gallons per year by eliminating traditional hydrocracking and other costly upgrading processes. This catalytic process is ideal for distributed diesel fuel production plants such as biomass to fuel production plants and stranded natural gas to diesel fuel production plants, and other applications that require optimized economics based on supporting distributed feedstock resources.
摘要翻译：描述了一种独特的方法和催化剂，其在低压下有效地运行，用于从氢和一氧化碳的化学计量混合物直接生产高十六烷值柴油型燃料或柴油型混合原料。本发明允许但不限于通过消除传统的加氢裂化和其他昂贵的升级，年生产能力低于每年1亿加仑的小型或分布式燃料生产设备的经济高效的生产优质柴油型燃料过程。这种催化过程对于分布式柴油发电厂如生物质燃料生产设备和滞留的天然气到柴油发电厂以及其他需要基于支持分布的原料资源优化经济性的应用是理想的。

2. 发明公开

US20230150823A1 CO2 hydrogenation catalysts for the commercial production of syngas 审中-公开
公开(公告)号：US20230150823A1
公开(公告)日：2023-05-18
申请号：US17300820
申请日：2021-11-16
申请人： Dennis Schuetzle , Robert Schuetzle , Anja Rumplecker Galloway , Orion Hanbury
发明人： Dennis Schuetzle , Robert Schuetzle , Anja Rumplecker Galloway , Orion Hanbury
IPC分类号： C01B32/40 , B01J21/00 , B01J21/04 , B01J21/10 , B01J37/08 , B01J37/02 , B01J35/10 , B01J23/78 , B01J23/755
CPC分类号： C01B32/40 , B01J21/005 , B01J21/04 , B01J21/10 , B01J37/082 , B01J37/0207 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J37/0225 , B01J23/78 , B01J23/755 , C01B2203/0283 , C01B2203/061 , C01B2203/062 , C25B1/04
摘要： The present invention is generally directed to the production of low-carbon syngas from captured CO2 and renewable H2. The H2 is generated from water using an electrolyzer powered by renewable electricity, or from any other method of low-carbon H2 production. The improved catalysts use low-cost metals, they can be produced economically in commercial quantities, and they are chemically and physically stable up to 2,100° F. CO2 conversion is between 80% and 100% with CO selectivity of greater than 99%. The catalysts don't sinter or form coke when converting H2:CO2 mixtures to syngas in the operating ranges of 1,300-1,800° F., pressures of 75-450 psi, and space velocities of 2,000-100,000 hr−1. The catalysts are stable, exhibiting between 0 and 1% CO2 conversion decline per 1,000 hrs. The syngas can be used for the synthesis of low-carbon fuels and chemicals, or for the production of purified H2. The H2 can be used at the production site for the synthesis of low-carbon chemical products or compressed for transportation use.

3. 发明申请

US20130217792A1 Catalytic process for the direct production of hydrocarbon fuels from syngas 审中-公开
公开(公告)号：US20130217792A1
公开(公告)日：2013-08-22
申请号：US13815518
申请日：2013-03-08
申请人： Robert Schuetzle , Dennis Schuetzle , David DeVilliers
发明人： Robert Schuetzle , Dennis Schuetzle , David DeVilliers
IPC分类号： C10G2/00
CPC分类号： C10G2/332 , B01J21/04 , B01J23/745 , B01J23/75 , B01J23/755 , B01J23/8896 , B01J23/8906 , B01J23/8913 , B01J23/892 , B01J35/023 , B01J35/1019 , B01J35/1061 , B01J37/0201 , B01J37/18 , C10G2/333 , C10G45/62 , C10L1/1963 , C10L1/1966 , C10L1/1973 , C10L10/14
摘要： A unique process and catalyst is described that operates efficiently at low pressures for the direct production of a high cetane diesel type fuel or diesel type blending stock from stoichiometric mixtures of hydrogen and carbon monoxide. This invention allows for, but is not limited to, the economical and efficient production high quality diesel type fuels from small or distributed fuel production plants that have an annual production capacity of less than 100 million gallons per year by eliminating traditional hydrocracking and other costly upgrading processes. This catalytic process is ideal for distributed diesel fuel production plants such as biomass to fuel production plants and stranded natural gas to diesel fuel production plants, and other applications that require optimized economics based on supporting distributed feedstock resources.

4. 发明授权

US09476005B1 High-performance diesel fuel lubricity additive 有权
标题翻译：高性能柴油燃油润滑添加剂
公开(公告)号：US09476005B1
公开(公告)日：2016-10-25
申请号：US13987133
申请日：2013-07-01
申请人： Robert Schuetzle , Dennis Schuetzle
发明人： Robert Schuetzle , Dennis Schuetzle
IPC分类号： C10L1/18 , C10L10/08
CPC分类号： C10L10/08 , C10L1/18 , C10L1/1824 , C10L1/1881 , C10L1/1883 , C10L1/19 , C10L1/1905 , C10L2200/0446 , C10L2200/0492 , C10L2270/026
摘要： The present teachings are directed toward the invention of high-performance diesel fuel lubricity additives that are comprised of a mixture of one or more C3-C10 di-carboxylic acids with a mixture of one or more C3-C14 carboxylic acids that are blended in one or more C3-C16 hydroxy-alkanes. These additives may be produced by blending one or more C3-C14 carboxylic acids, C3-C10 di-carboxylic acids and C3-C16 hydroxy-alkanes, or by using various chemical synthesis procedures to directly produce mixtures of these classes of oxygenated aliphatic hydrocarbons.
摘要翻译：本发明涉及高性能柴油燃料润滑添加剂的发明，其包括一种或多种C 3 -C 10二羧酸与一种或多种C 3 -C 14羧酸的混合物的混合物，其混合在一种或更多的C 3 -C 16羟基烷烃。这些添加剂可以通过混合一种或多种C 3 -C 14羧酸，C 3 -C 10二羧酸和C 3 -C 16羟基烷烃，或通过使用各种化学合成方法直接产生这些类型的氧化脂族烃的混合物来制备。

5. 发明授权

US08741001B1 Blends of low carbon and conventional fuels with improved performance characteristics 有权
标题翻译：低碳和常规燃料的混合物具有改进的性能特征
公开(公告)号：US08741001B1
公开(公告)日：2014-06-03
申请号：US12928997
申请日：2010-12-23
申请人： Robert Schuetzle , Dennis Schuetzle
发明人： Robert Schuetzle , Dennis Schuetzle
IPC分类号： C10L1/02 , C10L1/04 , C10L1/19
CPC分类号： C10L1/08 , C01B3/34 , C01B2203/0216 , C01B2203/0233 , C01B2203/0244 , C01B2203/04 , C01B2203/048 , C01B2203/0485 , C01B2203/061 , C01B2203/062 , C10G2/30 , C10G3/00 , C10J3/82 , C10K3/006 , C10L1/02 , C10L1/04 , C10L2200/0492 , C10L2290/04 , C10L2290/24 , C10L2290/42 , Y02E10/00 , Y02E10/20 , Y02E50/00 , Y02E50/10 , Y02E50/13 , Y02E50/16 , Y02E50/30 , Y02E50/32 , Y02E50/34 , Y02E50/343 , Y02E50/346 , Y02E60/00 , Y02E70/00 , Y02P20/145 , Y02P30/10 , Y02P30/20
摘要： The present invention provides a blended fuel and methods for producing the blended fuel, wherein a low carbon fuel derived from a renewable resource such as biomass, is blended with a traditional, petroleum derived fuel. A blended fuel which includes greater than 10% by volume of low carbon fuel has an overall improved lifecycle greenhouse gas content of about 5% or more compared to the petroleum derived fuel. Also, blending of the low carbon fuel to the traditional, petroleum fuel improves various engine performance characteristics of the traditional fuel.
摘要翻译：本发明提供了一种混合燃料和用于生产混合燃料的方法，其中衍生自可再生资源如生物质的低碳燃料与传统的石油衍生燃料混合。包含大于10体积％的低碳燃料的混合燃料与石油衍生燃料相比总体上提高了约5％或更高的生命周期温室气体含量。此外，低碳燃料与传统的石油燃料的混合改进了传统燃料的各种发动机性能特征。

6. 发明授权

US4372155A Methods of monitoring a combustion system 失效
标题翻译：监测燃烧系统的方法
公开(公告)号：US4372155A
公开(公告)日：1983-02-08
申请号：US265316
申请日：1981-05-20
申请人： James W. Butler , Alex D. Colvin , Dennis Schuetzle
发明人： James W. Butler , Alex D. Colvin , Dennis Schuetzle
IPC分类号： G01M15/04 , F02B77/08 , F02D35/00 , G01N27/409 , G01N31/12 , G01N33/00 , G01M15/00
CPC分类号： F02B77/086 , G01N31/12 , G01N33/0013
摘要： This specification teaches a basic method of obtaining on a continuous basis an instantaneous indication of the air to fuel ratio of an air/fuel mixture being fed to a combustion process. The process may take place in an internal combustion engine or, for example, in a power plant. Modifications of the method are taught to obtain such information as the hydrogen to carbon ratio of the fuel being burned in the combustion process, the oxygen equivalence of the air/fuel mixture being burned, the air mass flow through the combustion process, the fuel mass flow through the combustion process, instantaneous fuel economy of a vehicle in which a combustion process is being carried out to propel the vehicle, and the oxygen concentration in the exhaust gases from the combustion process.
摘要翻译：本说明书教导了连续获得供给到燃烧过程的空气/燃料混合物的空燃比的瞬时指示的基本方法。该过程可以在内燃机中或例如在发电厂中进行。教导了该方法的修改以获得诸如在燃烧过程中被燃烧的燃料的氢碳比，燃烧的空气/燃料混合物的氧等价物，通过燃烧过程的空气质量流量，燃料质量流过燃烧过程，其中进行燃烧过程以推动车辆的车辆的瞬时燃料经济性和来自燃烧过程的废气中的氧浓度。

7. 发明授权

US5091647A Method and apparatus for measuring the thickness of a layer on a substrate 失效
标题翻译：用于测量衬底上的层的厚度的方法和装置
公开(公告)号：US5091647A
公开(公告)日：1992-02-25
申请号：US632557
申请日：1990-12-24
申请人： Keith R. Carduner , Roscoe O. Carter, III , Dennis Schuetzle , Michael J. Decello
发明人： Keith R. Carduner , Roscoe O. Carter, III , Dennis Schuetzle , Michael J. Decello
IPC分类号： G01B11/06
CPC分类号： G01B11/0625
摘要： A method and an apparatus for simultaneously measuring each constituent film in a multi-layer coating. Near Infrared Reflectance (NIR) measurements are taken at the peak and reference wavelength for a series of calibration samples. Based on these measurements, a relationship is established between the film NIR and thickness. A measuring NIR spectrometer is supplied with the relationship and a target sample is irradiated with near infrared radiation at each peak and reference wavelength. The measuring spectrometer measures the amount of NIR and computes the individual film thicknesses using the relationship supplied to it. Individual film thicknesses can be visually displayed, and/or directed to the film applying apparatus. If the thickness of an individual film layer deviates from a predetermined valve, the film applying apparatus is manipulated to apply the desired thickness of film.
摘要翻译：一种用于同时测量多层涂层中的每个构成膜的方法和装置。对于一系列校准样品，在峰值和参考波长处进行近红外反射（NIR）测量。基于这些测量，在膜NIR和厚度之间建立了关系。提供测量NIR光谱仪的关系，并且在每个峰值和参考波长处用近红外辐射照射目标样品。测量光谱仪测量NIR的量，并使用提供给它的关系来计算各个膜厚度。可以在视觉上显示单独的膜厚度，和/或指向膜施加装置。如果单个膜层的厚度偏离预定的阀，则操作膜施加装置以施加所需的膜厚度。

8. 发明申请

US20100175320A1 ENERGY EFFICIENT SYSTEM AND PROCESS FOR THE CONTINUOUS PRODUCTION OF FUELS AND ENERGY FROM SYNGAS 审中-公开
标题翻译：从SYNCAS连续生产燃料和能源的能源效率系统和工艺
公开(公告)号：US20100175320A1
公开(公告)日：2010-07-15
申请号：US11966788
申请日：2007-12-28
申请人： Dennis Schuetzle , Ronald G. Hurley , Robert W. Schuetzle
发明人： Dennis Schuetzle , Ronald G. Hurley , Robert W. Schuetzle
IPC分类号： C10J3/00
CPC分类号： C10K3/00 , B01J23/10 , B01J23/78 , B01J23/80 , B01J27/051 , C07C29/1518 , C10G2/32 , C10J3/00 , C10J3/723 , C10J2300/0916 , C10J2300/093 , C10J2300/0976 , C10J2300/1609 , C10J2300/1618 , C10J2300/1621 , C10J2300/165 , C10J2300/1659 , C10J2300/1665 , C10J2300/1671 , C10J2300/1684 , C10J2300/1693 , C10J2300/1823 , C10K3/026 , C10K3/06 , F02C3/28 , F05D2220/75 , F05D2260/80 , Y02E50/12 , Y02E50/18 , Y02E50/32 , Y02P20/145 , Y02P20/146 , Y02P20/52 , C07C31/04 , C07C31/08
摘要： A system and apparatus is provided that maximizes mass and energy conversion efficiencies in an integrated thermochemical process for the conversion of fossil fuel or renewable biomass to synthesis gas. The system combines gasification, catalytic conversion of gas to liquid, electricity generation, steam and chilled water generation with a system controller to maximize the conversion efficiency from syngas to merchantable products over the efficiency of syngas alone burned as a fuel. A clean synthesis gas stream is introduced into a catalytic reactor that utilizes specially formulated catalysts to generate liquid fuel from CO and H2 while concentrating CH4 and other combustible, but non-reactive gases in the syngas product stream. The methane rich stream is introduced into an engine for the production of electricity and heat while the unreacted CO and H2 can be recycled to produce additional liquid fuel. Excess heat can be used for other co-located processes and facilities.
摘要翻译：提供了一种系统和装置，其用于将化石燃料或可再生生物质转化为合成气的综合热化学过程中的质量和能量转换效率最大化。该系统将气体，气体与液体的催化转化，发电，蒸汽和冷却水生成与系统控制器相结合，以使合成气转化为可商售产品的转化效率达到单燃烧作为燃料的合成气的效率。将清洁的合成气流引入催化反应器中，该催化反应器利用特殊配制的催化剂从CO和H 2产生液体燃料，同时浓缩合成气产物流中的CH 4和其它可燃但非反应性气体。将富含甲烷的物流引入发动机以产生电和热，同时将未反应的CO和H 2再循环以产生额外的液体燃料。过热可用于其他共同处理和设施。

9. 发明授权

US07718832B1 Combination catalytic process for producing ethanol from synthesis gas 有权
标题翻译：从合成气生产乙醇的组合催化方法
公开(公告)号：US07718832B1
公开(公告)日：2010-05-18
申请号：US11966711
申请日：2007-12-28
申请人： Ronald G. Hurley , Dennis Schuetzle , Matthew D. Summers
发明人： Ronald G. Hurley , Dennis Schuetzle , Matthew D. Summers
IPC分类号： C07C29/141
CPC分类号： C07C29/151 , C07C29/32 , Y02P20/52 , C07C31/04 , C07C31/08
摘要： A catalytic process selectively produces ethanol by contacting synthesis gas (syngas), composed primarily of hydrogen and carbon monoxide, with three catalysts within a reactor. The first catalyst is a hydrogenation promoter comprising Cu—Zn, Mo or Fe with an optional alkali metal additive and an optional support of aluminum oxide, silica, zeolite or clay. The second catalyst is a homologation promoter comprising one or more of the Group VIII metals in free or combined form with a co-catalyst metals consisting of Y or lanthanide or actinide series metals with optional additives and support. The third catalyst is a hydrogenation promoter. This series of catalysts improves the selectivity and yield for ethanol from syngas.
摘要翻译：催化过程通过在反应器内接触主要由氢和一氧化碳组成的三种催化剂的合成气（合成气）选择性地产生乙醇。第一催化剂是包含Cu-Zn，Mo或Fe与任选的碱金属添加剂和任选的氧化铝，二氧化硅，沸石或粘土的载体的氢化促进剂。第二种催化剂是包含游离或组合形式的一种或多种第Ⅷ族金属的同系促进剂，其中助催化剂金属由任选的添加剂和载体的Y或镧系元素或锕系金属组成。第三催化剂是氢化促进剂。该系列催化剂改善了合成气中乙醇的选择性和产率。

10. 发明授权

US06245854B1 Fluorocarbon-containing hydrophilic polymer coating composition for heat exchangers 有权
标题翻译：含氟碳的亲水聚合物涂料组合物用于热交换器
公开(公告)号：US06245854B1
公开(公告)日：2001-06-12
申请号：US09209840
申请日：1998-12-11
申请人： Chimere N. Obioha , Riad A. Farah , Dennis Schuetzle , Yun-xiang Zhang
发明人： Chimere N. Obioha , Riad A. Farah , Dennis Schuetzle , Yun-xiang Zhang
IPC分类号： C09D12712
CPC分类号： F28F19/04 , C09D127/12 , F28F13/18 , F28F2245/02 , F28F2265/20 , Y10S165/514 , Y10S525/916
摘要： A hydrophilic coating composition for hydrophilically coating a metallic surface. The coating composition comprises a fluorocarbon-containing hydrophilic polymer comprising units of hydrophilic monomer and fluorocarbon-containing hydrophobic comonomer. The coating composition produces hydrophilic coatings on the metallic surface having a contact angle below about 50°.
摘要翻译：一种用于亲水涂覆金属表面的亲水性涂料组合物。涂料组合物包括含有亲水性单体和含氟烃的疏水性共聚单体的含氟烃亲水性聚合物。涂层组合物在金属表面上产生具有低于约50°的接触角的亲水性涂层。

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