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1. 发明授权

US5332906A Scintillator assembly for alpha radiation detection and an associated method of making 失效
标题翻译：用于α辐射检测的闪烁体组件和相关的制造方法
公开(公告)号：US5332906A
公开(公告)日：1994-07-26
申请号：US928999
申请日：1992-08-12
申请人： Robert J. Lauf , Stephanie A. McElhaney , John B. Bates
发明人： Robert J. Lauf , Stephanie A. McElhaney , John B. Bates
IPC分类号： G01T1/202
CPC分类号： G01T1/202
摘要： A scintillator assembly for use in conjunction with a photomultiplier or the like in the detection of alpha radiation utilizes a substrate or transparent yttrium aluminum garnet and a relatively thin film of cerium-doped yttrium aluminum garnet coated upon the substrate. The film material is applied to the substrate in a sputtering process, and the applied film and substrate are annealed to effect crystallization of the film upon the substrate. The resultant assembly provides relatively high energy resolution during use in a detection instrument and is sufficiently rugged for use in field environments.
摘要翻译：在α辐射检测中与光电倍增管等结合使用的闪烁体组件利用涂覆在基底上的基底或透明钇铝石榴石和相对薄的铈掺杂的钇铝石榴石膜。在溅射工艺中将薄膜材料施加到基板上，并将涂覆的薄膜和基板退火以使薄膜在基板上结晶。所得组件在检测仪器中的使用期间提供相对较高的能量分辨率，并且足够坚固地用于现场环境中。

2. 发明授权

US07410730B2 Thin film battery and electrolyte therefor 失效
标题翻译：薄膜电池及其电解液
公开(公告)号：US07410730B2
公开(公告)日：2008-08-12
申请号：US10951840
申请日：2004-09-28
申请人： John B. Bates
发明人： John B. Bates
IPC分类号： H01M6/18 , C23C14/34
CPC分类号： C01B21/097 , C01B21/0975 , C01P2002/52 , C23C14/06 , C23C14/3414 , H01M4/66 , H01M6/40 , H01M10/052 , H01M10/0562
摘要： A solid amorphous electrolyte composition for a thin-film battery. The electrolyte composition includes a lithium phosphorus oxynitride material containing an aluminum ion dopant wherein the atomic ratio of aluminum ion to phosphorus ion (Al/P) in the electrolyte ranges greater than zero up to about 0.5. The composition is represented by the formula: LitPxAlyOuNvSw, where 5x+3y=5, 2u+3v+2w=5+t, t ranges from about 2.9 to about 3.3, x ranges from about 0.94 to about 0.85, y ranges from about 0.094 to about 0.26, u ranges from about 3.2 to about 3.8, v ranges from about 0.13 to about 0.46, and w ranges from zero to about 0.2. Thin film batteries containing such electrolyte films have less tendency to fail prematurely.
摘要翻译：一种用于薄膜电池的固体非晶电解质组合物。电解质组合物包括含有铝离子掺杂剂的磷酸锂锂材料，其中电解质中铝离子与磷离子（Al / P）的原子比范围大于零至约0.5。组合物由下式表示：<？in-line-formula description =“In-line Formulas”end =“lead”？> Li ？“”O u u，，，，，，，，，，，，，，，，“”“”“”“”“”“”“”“”“”“”“”“”“”“”“”“”“” end =“tail”？>其中5x + 3y = 5,2u + 3v + 2w = 5 + t，t为约2.9至约3.3，x为约0.94至约0.85，y为约0.094至约0.26 u为约3.2至约3.8，v为约0.13至约0.46，w为0至约0.2。含有这种电解质膜的薄膜电池具有较少的过早失效倾向。

3. 发明申请

US20080003493A1 GETTERS FOR THIN FILM BATTERY HERMETIC PACKAGE 失效
标题翻译：薄膜电池电阻封装
公开(公告)号：US20080003493A1
公开(公告)日：2008-01-03
申请号：US11533490
申请日：2006-09-20
申请人： John B. Bates
发明人： John B. Bates
IPC分类号： H01M2/08 , H01M10/04
CPC分类号： H01M2/0207 , H01M2/021 , H01M2/0212 , H01M2/0275 , H01M2/0277 , H01M2/0285 , H01M2/0287 , H01M2/08 , H01M2/1022 , H01M4/382 , H01M4/386 , H01M4/387 , H01M6/40 , H01M10/0436 , H01M10/0525 , H01M10/0562 , H01M10/0585 , H01M2002/0297 , H01M2300/0068 , Y10T29/4911 , Y10T29/49114
摘要： A method for improving the useful life of a thin film lithium-ion battery containing a solid electrolyte and an anode that expands on charging and long life batteries made by the method. The method includes providing a hermetic barrier package for the thin film battery that includes an anode expansion absorbing structure and at least one film getter.
摘要翻译：一种用于提高包含固体电解质和阳极的薄膜锂离子电池的使用寿命的方法，所述固体电解质和阳极在通过该方法制造的充电和长寿命的电池上膨胀。该方法包括为包括阳极膨胀吸收结构和至少一个膜吸气剂的薄膜电池提供密封屏障封装。

4. 发明授权

US07158255B2 Method for printing shingling print data 有权
标题翻译：打印封印打印数据的方法
公开(公告)号：US07158255B2
公开(公告)日：2007-01-02
申请号：US10174351
申请日：2002-06-18
申请人： John B. Bates , Thomas J. Eade , Mark W. Fagan
发明人： John B. Bates , Thomas J. Eade , Mark W. Fagan
IPC分类号： G06F3/12 , G06F15/00 , G06K1/00
CPC分类号： G06F3/122 , G06F3/1237 , G06F3/1284
摘要： A method for printing shingling print data in a shingling print pass of a multi-shingling-pass print swath. One step includes compacting the shingling print data by removing the deterministic voids associated with the shingling print algorithm. Another step includes expanding the compacted shingling print data based on the shingling print algorithm. An additional step includes printing the expanded shingling print data.
摘要翻译：一种打印带状打印数据的方法，该打印数据以多重打印通行打印条带的带状打印通行。一步包括通过去除与嵌入式打印算法相关联的确定性空隙来压缩着色打印数据。另一个步骤包括基于分页打印算法来扩展压缩的分页打印数据。一个额外的步骤包括打印扩展的绑定打印数据。

5. 发明授权

US06168884A Battery with an in-situ activation plated lithium anode 有权
标题翻译：具有原位激活电镀锂阳极的电池
公开(公告)号：US06168884A
公开(公告)日：2001-01-02
申请号：US09285326
申请日：1999-04-02
申请人： Bernd J. Neudecker , Nancy J. Dudney , John B. Bates
发明人： Bernd J. Neudecker , Nancy J. Dudney , John B. Bates
IPC分类号： H01M1000
CPC分类号： H01M10/0436 , H01M4/0447 , H01M4/661 , H01M6/185 , H01M6/188 , H01M6/40 , H01M10/052 , H01M10/056 , H01M2004/027
摘要： A thin-film rechargeable battery includes a cathode film; including a lithium transition metal oxide, an electrolyte film coupled to the cathode film, the electrolyte film being substantially nonreactive with oxidizing materials and with metallic lithium, an anode current collector coupled to the electrolyte film; and an overlying layer coupled to the anode current collector. The thin-film rechargeable battery is activated during an initial charge by electrochemical plating of a metallic lithium anode between the anode current collector and the electrolyte film. The plating of the anode during charging and the stripping of the anode layer during discharging are essentially reversible. Therefore, almost no diminishment of discharge capacity occurs, even after many discharge and charge cycles. Other advantages include no need for special packaging for shipping and handling. The battery eliminates the main drawbacks of the thin-film Li-ion battery (high capacity loss during the initial charge) and of the thin-film lithium battery (high air-sensitivity at all times, temperature limited to ˜100° C., expensive preparation of the lithium anode). The battery survives processing conditions that exceed those of a solder reflow process without any signs of degradation.
摘要翻译：薄膜可充电电池包括阴极膜; 包括锂过渡金属氧化物，与阴极膜耦合的电解质膜，所述电解质膜与氧化材料和金属锂基本上无反应性;阳极集电器耦合到所述电解质膜; 以及耦合到阳极集电器的上覆层。通过在阳极集电器和电解质膜之间的金属锂阳极的电化学电镀，在初始充电期间，薄膜可再充电电池被激活。在充电期间阳极的电镀和在放电期间阳极层的剥离基本上是可逆的。因此，即使在许多放电和充电循环之后，也几乎不会发生放电容量的减小。其他优点包括不需要特殊的包装运输和处理。电池消除了薄膜锂离子电池的主要缺点（初始充电期间的高容量损失）和薄膜锂电池（高度空气敏感性，温度限制在〜100℃，昂贵的锂阳极制备）。电池的处理条件超过了焊料回流工艺，而没有任何退化的迹象。

6. 发明授权

US5561004A Packaging material for thin film lithium batteries 失效
标题翻译：薄膜锂电池用包装材料
公开(公告)号：US5561004A
公开(公告)日：1996-10-01
申请号：US202649
申请日：1994-02-25
申请人： John B. Bates , Nancy J. Dudney , Kim A. Weatherspoon
发明人： John B. Bates , Nancy J. Dudney , Kim A. Weatherspoon
IPC分类号： H01M2/02 , H01M6/18 , H01M6/40 , H01M2/08
CPC分类号： H01M2/0275 , H01M6/18 , H01M6/185 , H01M6/40
摘要： A thin film battery including components which are capable of reacting upon exposure to air and water vapor incorporates a packaging system which provides a barrier against the penetration of air and water vapor. The packaging system includes a protective sheath overlying and coating the battery components and can be comprised of an overlayer including metal, ceramic, a ceramic-metal combination, a parylene-metal combination, a parylene-ceramic combination or a parylene-metal-ceramic combination.
摘要翻译：包括能够在暴露于空气和水蒸气中反应的组分的薄膜电池包括提供阻挡空气和水蒸汽渗透的阻隔的包装系统。包装系统包括覆盖和涂覆电池组件的保护套，并且可以由包括金属，陶瓷，陶瓷 - 金属组合，聚对二甲苯 - 金属组合，聚对二甲苯 - 陶瓷组合或聚对二甲苯 - 金属 - 陶瓷组合的覆层。

7. 发明授权

US06994933B1 Long life thin film battery and method therefor 失效
标题翻译：长寿命薄膜电池及其方法
公开(公告)号：US06994933B1
公开(公告)日：2006-02-07
申请号：US10244260
申请日：2002-09-16
申请人： John B. Bates
发明人： John B. Bates
IPC分类号： H01M6/12 , H01M6/46 , H01M2/00
CPC分类号： H01M2/0277 , H01M2/0207 , H01M2/0275 , H01M2/0285 , H01M2/0292 , H01M6/12 , H01M6/40 , H01M2002/0297
摘要： A thin film battery including an anode layer, a cathode layer and a solid electrolyte layer. The battery also includes, a planarization layer applied to the thin film battery. The planarization layer has a surface roughness of no more than about 1.0 nanometers root mean square and a flatness no larger than about 0.005 cm/inch. A barrier layer is applied to the planarization layer. The barrier layer is provided by one or more layers of material selected from the group consisting of polymeric materials, metals and ceramic materials. The planarization layer and barrier layer are sufficient to reduce oxygen flux through the barrier layer to the anode layer to no more than about 1.6 μmol/m2-day, and H2O flux through the barrier layer to the anode layer to less than about 3.3 μmol/m2-day thereby improving the life of the thin film battery.
摘要翻译：一种包括阳极层，阴极层和固体电解质层的薄膜电池。电池还包括施加到薄膜电池的平坦化层。平坦化层的表面粗糙度不超过约1.0纳米的均方根，平坦度不大于约0.005厘米/英寸。将屏障层施加到平坦化层。阻挡层由选自聚合材料，金属和陶瓷材料的一种或多种材料层提供。平坦化层和阻挡层足以将通过阻挡层到氧化层的氧通量减少到不超过约1.6μmol/ m 2·天，而H 2 O 2 - O通过势垒层到阳极层，以小于约3.3μmol/ m 2·天，从而提高薄膜电池的寿命。

8. 发明授权

US5455126A Electra-optical device including a nitrogen containing electrolyte 失效
标题翻译：包括含氮电解质的电光器件
公开(公告)号：US5455126A
公开(公告)日：1995-10-03
申请号：US248935
申请日：1994-05-25
申请人： John B. Bates , Nancy J. Dudney , Greg R. Gruzalski , Christopher F. Luck
发明人： John B. Bates , Nancy J. Dudney , Greg R. Gruzalski , Christopher F. Luck
IPC分类号： H01L23/58 , H01M2/10 , H01M6/18 , H01M6/40 , H01M6/00
CPC分类号： H01M6/18 , H01L23/58 , H01L2924/0002 , H01L2924/12044 , H01M2/1066 , H01M6/40 , Y10T29/49108 , Y10T29/49115
摘要： Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.
摘要翻译：描述了薄膜电池，特别是薄膜微电池，以及用于制造电子器件的备用或一次集成电源的应用的方法。电池包括电化学稳定且不与锂阳极反应的新型电解质和新型氧化钒阴极配置为微电池，电池可以直接制造到半导体芯片上或半导体芯片上，芯片载体。电池可以制造成任何指定的尺寸或形状，以满足特定应用的要求。电池由固体材料制成，能够在-15℃至150℃之间运行。

9. 发明授权

US5314765A Protective lithium ion conducting ceramic coating for lithium metal anodes and associate method 失效
标题翻译：锂金属阳极保护锂离子导电陶瓷涂层及其相关方法
公开(公告)号：US5314765A
公开(公告)日：1994-05-24
申请号：US137285
申请日：1993-10-14
申请人： John B. Bates
发明人： John B. Bates
IPC分类号： H01M2/16 , H01M4/13 , H01M10/05 , H01M10/40
CPC分类号： H01M10/05 , H01M4/13 , H01M4/38 , H01M2/1646 , H01M2/1673 , H01M2004/028 , Y10T29/49115
摘要： A battery structure including a cathode, a lithium metal anode and an electrolyte disposed between the lithium anode and the cathode utilizes a thin-film layer of lithium phosphorus oxynitride overlying so as to coat the lithium anode and thereby separate the lithium anode from the electrolyte. If desired, a preliminary layer of lithium nitride may be coated upon the lithium anode before the lithium phosphorous oxynitride is, in turn, coated upon the lithium anode so that the separation of the anode and the electrolyte is further enhanced. By coating the lithium anode with this material lay-up, the life of the battery is lengthened and the performance of the battery is enhanced.
摘要翻译：包括阴极，锂金属阳极和设置在锂阳极和阴极之间的电解质的电池结构利用锂磷氮氧化物的薄膜层，以覆盖锂阳极，从而将锂阳极与电解质分离。如果需要，可以在将锂磷氮氧化物再次涂覆在锂阳极上之前，在锂阳极上涂覆预备的氮化锂层，从而进一步提高阳极和电解质的分离。通过用这种材料层叠涂覆锂阳极，延长电池寿命，提高电池的性能。

10. 发明申请

US20080032200A1 Thin film battery and electrolyte therefor 失效
标题翻译：薄膜电池及其电解液
公开(公告)号：US20080032200A1
公开(公告)日：2008-02-07
申请号：US10951840
申请日：2004-09-28
申请人： John B. Bates
发明人： John B. Bates
IPC分类号： H01M6/18 , C23C14/34
CPC分类号： C01B21/097 , C01B21/0975 , C01P2002/52 , C23C14/06 , C23C14/3414 , H01M4/66 , H01M6/40 , H01M10/052 , H01M10/0562
摘要： A solid amorphous electrolyte composition for a thin-film battery. The electrolyte composition includes a lithium phosphorus oxynitride material containing a sulfide ion dopant wherein the atomic ratio of sulfide ion to phosphorus ion (S/P) in the electrolyte ranges greater than 0 up to about 0.2. The composition is represented by the formula: LitPxAlyOuNvSw, where 5x+3y=5, 2u+3v+2w=5+t, t ranges from about 2.9 to about 3.3, x ranges from about 0.94 to about 0.85, y ranges from about 0.094 to about 0.26, u ranges from about 3.2 to about 3.8, v ranges from about 0.13 to about 0.46, and w ranges from zero to about 0.2. Thin film batteries containing such electrolyte films have less tendency to fail prematurely.
摘要翻译：一种用于薄膜电池的固体非晶电解质组合物。电解质组合物包括含有硫化物离子掺杂剂的磷酸锂锂材料，其中电解质中硫化物离子与磷离子的原子比（S / P）大于0至约0.2。组合物由下式表示：<？in-line-formula description =“In-line Formulas”end =“lead”？> Li ？“”O u u，，，，，，，，，，，，，，，，“”“”“”“”“”“”“”“”“”“”“”“”“”“”“”“”“” end =“tail”？>其中5x + 3y = 5,2u + 3v + 2w = 5 + t，t为约2.9至约3.3，x为约0.94至约0.85，y为约0.094至约0.26 u为约3.2至约3.8，v为约0.13至约0.46，w为0至约0.2。含有这种电解质膜的薄膜电池具有较少的过早失效倾向。

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