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    • 1. 发明申请
    • Thin film battery and electrolyte therefor
    • 薄膜电池及其电解液
    • US20080032200A1
    • 2008-02-07
    • US10951840
    • 2004-09-28
    • John B. Bates
    • John B. Bates
    • H01M6/18C23C14/34
    • C01B21/097C01B21/0975C01P2002/52C23C14/06C23C14/3414H01M4/66H01M6/40H01M10/052H01M10/0562
    • A solid amorphous electrolyte composition for a thin-film battery. The electrolyte composition includes a lithium phosphorus oxynitride material containing a sulfide ion dopant wherein the atomic ratio of sulfide ion to phosphorus ion (S/P) in the electrolyte ranges greater than 0 up to about 0.2. The composition is represented by the formula: LitPxAlyOuNvSw, where 5x+3y=5, 2u+3v+2w=5+t, t ranges from about 2.9 to about 3.3, x ranges from about 0.94 to about 0.85, y ranges from about 0.094 to about 0.26, u ranges from about 3.2 to about 3.8, v ranges from about 0.13 to about 0.46, and w ranges from zero to about 0.2. Thin film batteries containing such electrolyte films have less tendency to fail prematurely.
    • 一种用于薄膜电池的固体非晶电解质组合物。 电解质组合物包括含有硫化物离子掺杂剂的磷酸锂锂材料,其中电解质中硫化物离子与磷离子的原子比(S / P)大于0至约0.2。 组合物由下式表示:<?in-line-formula description =“In-line Formulas”end =“lead”?> Li ?“”O u u,,,,,,,,,,,,,,,,“”“”“”“”“”“”“”“”“”“”“”“”“”“”“”“”“” end =“tail”?>其中5x + 3y = 5,2u + 3v + 2w = 5 + t,t为约2.9至约3.3,x为约0.94至约0.85,y为约0.094至约0.26 u为约3.2至约3.8,v为约0.13至约0.46,w为0至约0.2。 含有这种电解质膜的薄膜电池具有较少的过早失效倾向。
    • 8. 发明授权
    • Thin film battery and electrolyte therefor
    • 薄膜电池及其电解液
    • US07410730B2
    • 2008-08-12
    • US10951840
    • 2004-09-28
    • John B. Bates
    • John B. Bates
    • H01M6/18C23C14/34
    • C01B21/097C01B21/0975C01P2002/52C23C14/06C23C14/3414H01M4/66H01M6/40H01M10/052H01M10/0562
    • A solid amorphous electrolyte composition for a thin-film battery. The electrolyte composition includes a lithium phosphorus oxynitride material containing an aluminum ion dopant wherein the atomic ratio of aluminum ion to phosphorus ion (Al/P) in the electrolyte ranges greater than zero up to about 0.5. The composition is represented by the formula: LitPxAlyOuNvSw, where 5x+3y=5, 2u+3v+2w=5+t, t ranges from about 2.9 to about 3.3, x ranges from about 0.94 to about 0.85, y ranges from about 0.094 to about 0.26, u ranges from about 3.2 to about 3.8, v ranges from about 0.13 to about 0.46, and w ranges from zero to about 0.2. Thin film batteries containing such electrolyte films have less tendency to fail prematurely.
    • 一种用于薄膜电池的固体非晶电解质组合物。 电解质组合物包括含有铝离子掺杂剂的磷酸锂锂材料,其中电解质中铝离子与磷离子(Al / P)的原子比范围大于零至约0.5。 组合物由下式表示:<?in-line-formula description =“In-line Formulas”end =“lead”?> Li ?“”O u u,,,,,,,,,,,,,,,,“”“”“”“”“”“”“”“”“”“”“”“”“”“”“”“”“” end =“tail”?>其中5x + 3y = 5,2u + 3v + 2w = 5 + t,t为约2.9至约3.3,x为约0.94至约0.85,y为约0.094至约0.26 u为约3.2至约3.8,v为约0.13至约0.46,w为0至约0.2。 含有这种电解质膜的薄膜电池具有较少的过早失效倾向。
    • 9. 发明授权
    • Thin film battery and electrolyte therefor
    • 薄膜电池及其电解液
    • US06818356B1
    • 2004-11-16
    • US10191859
    • 2002-07-09
    • John B Bates
    • John B Bates
    • H01M646
    • H01M10/052C01B21/097C01B21/0975C01P2002/52C23C14/06C23C14/3414H01M4/66H01M6/40H01M10/0562
    • A solid amorphous electrolyte composition for a thin-film battery. The electrolyte composition includes a lithium phosphorus oxynitride material containing a sulfide ion dopant wherein the atomic ratio of sulfide ion to phosphorus ion (S/P) in the electrolyte ranges greater than 0 up to about 0.2. The composition is represented by the formula: LiwPOxNySz, where 2x+3y+2z=5+w, x ranges from about 3.2 to about 3.8, y ranges from about 0.13 to about 0.46, z ranges from greater than zero up to about 0.2, and w ranges from about 2.9 to about 3.3. Thin-film batteries containing the sulfide doped lithium oxynitride electrolyte are capable of delivering more power and energy than thin-film batteries containing electrolytes without sulfide doping.
    • 一种用于薄膜电池的固体非晶电解质组合物。 电解质组合物包括含有硫化物离子掺杂剂的磷酸锂锂材料,其中电解质中硫化物离子与磷离子的原子比(S / P)大于0至约0.2。 组合物由下式表示:其中2x + 3y + 2z = 5 + w,x为约3.2至约3.8,y为约0.13至约0.46,z范围为大于零至约0.2,w 范围从约2.9至约3.3。 含有硫化物掺杂的氧氮化锂电解质的薄膜电池能够比不含硫化物掺杂的含有电解质的薄膜电池输送更多的功率和能量。