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1. 发明授权

US08142530B2 Methods and apparatus for producing syngas and alcohols 失效
标题翻译：用于生产合成气和醇的方法和设备
公开(公告)号：US08142530B2
公开(公告)日：2012-03-27
申请号：US12166183
申请日：2008-07-01
申请人： Robert E. Klepper , Arie Geertsema , Shakeel H. Tirmizi , Heinz Juergen Robota , Francis M. Ferraro , Ronald C. Stites
发明人： Robert E. Klepper , Arie Geertsema , Shakeel H. Tirmizi , Heinz Juergen Robota , Francis M. Ferraro , Ronald C. Stites
IPC分类号： C01B3/36 , C07C31/08 , C07C31/10 , C07C31/12 , C10J3/46
CPC分类号： C01B3/16 , B01J2219/00006 , C07C29/1518 , C07C29/32 , C10B47/44 , C10J3/66 , C10J2300/0916 , C10J2300/0959 , C10J2300/0973 , C10J2300/0986 , C10J2300/1665 , C10K1/04 , C10K1/101 , C10K1/32 , C10K3/04 , Y02E50/18 , Y02P20/145 , C07C31/08 , C07C31/04 , C07C31/10 , C07C31/12
摘要： This invention features methods and apparatus for producing syngas from any carbon-containing feed material. In some embodiments, a substoichiometric amount of oxygen is used to enhance the formation of syngas. In various embodiments, both oxygen and steam are added during the conversion of the feed material into syngas. The syngas can be converted to alcohols, such as ethanol, or to other products.
摘要翻译：本发明的特征在于用于从任何含碳原料生产合成气的方法和装置。在一些实施方案中，使用亚化学计量的氧来增强合成气的形成。在各种实施方案中，在将进料转化为合成气期间，加入氧气和蒸汽。合成气可以转化为醇类，如乙醇，或其他产品。

2. 发明申请

US20090018221A1 METHODS AND APPARATUS FOR PRODUCING SYNGAS AND ALCOHOLS 失效
标题翻译：用于生产正气和酒精的方法和装置
公开(公告)号：US20090018221A1
公开(公告)日：2009-01-15
申请号：US12166183
申请日：2008-07-01
申请人： Robert E. KLEPPER , Arie Geertsema , Shakeel H. Tirmizi , Heinz Juergen Robota , Francis M. Ferraro , Ronald C. Stites
发明人： Robert E. KLEPPER , Arie Geertsema , Shakeel H. Tirmizi , Heinz Juergen Robota , Francis M. Ferraro , Ronald C. Stites
IPC分类号： C07C27/00
CPC分类号： C01B3/16 , B01J2219/00006 , C07C29/1518 , C07C29/32 , C10B47/44 , C10J3/66 , C10J2300/0916 , C10J2300/0959 , C10J2300/0973 , C10J2300/0986 , C10J2300/1665 , C10K1/04 , C10K1/101 , C10K1/32 , C10K3/04 , Y02E50/18 , Y02P20/145 , C07C31/08 , C07C31/04 , C07C31/10 , C07C31/12
摘要： This invention features methods and apparatus for producing syngas from any carbon-containing feed material. In some embodiments, a substoichiometric amount of oxygen is used to enhance the formation of syngas. In various embodiments, both oxygen and steam are added during the conversion of the feed material into syngas. The syngas can be converted to alcohols, such as ethanol, or to other products.
摘要翻译：本发明的特征在于用于从任何含碳原料生产合成气的方法和装置。在一些实施方案中，使用亚化学计量的氧来增强合成气的形成。在各种实施方案中，在将进料转化为合成气期间，加入氧气和蒸汽。合成气可以转化为醇类，如乙醇，或其他产品。

3. 发明申请

US20090014689A1 METHODS AND APPARATUS FOR PRODUCING SYNGAS AND ALCOHOLS 审中-公开
标题翻译：用于生产正气和酒精的方法和装置
公开(公告)号：US20090014689A1
公开(公告)日：2009-01-15
申请号：US12166194
申请日：2008-07-01
申请人： Robert E. Klepper , Francis M. Ferraro , Shakeel H. Tirmizi , Arie Geertsema , Jerrod Hohman , Ronald C. Stites
发明人： Robert E. Klepper , Francis M. Ferraro , Shakeel H. Tirmizi , Arie Geertsema , Jerrod Hohman , Ronald C. Stites
IPC分类号： C01B3/38 , B01J19/00 , B01D1/00
CPC分类号： C01B3/16 , B01J2219/00006 , C07C29/1518 , C10B47/44 , C10J3/66 , C10J2300/0916 , C10J2300/0959 , C10J2300/0973 , C10J2300/0986 , C10J2300/1665 , C10K1/005 , C10K1/101 , C10K1/32 , C10K3/04 , Y02E50/18 , Y02P20/145 , C07C31/04 , C07C31/08 , C07C31/10 , C07C31/12 , C07C31/125
摘要： This invention features methods and apparatus for producing syngas from any carbon-containing feed material. In some embodiments, a substoichiometric amount of oxygen is used to enhance the formation of syngas. In various embodiments, both oxygen and steam are added during the conversion of the feed material into syngas. Some variations employ eductors for facilitating flow of solid and gas phases in the processes of the invention. The syngas can be converted to alcohols, such as ethanol, or to other products.
摘要翻译：本发明的特征在于用于从任何含碳原料生产合成气的方法和装置。在一些实施方案中，使用亚化学计量的氧来增强合成气的形成。在各种实施方案中，在将进料转化为合成气期间，加入氧气和蒸汽。在本发明的方法中，一些变型使用喷射器促进固相和气相的流动。合成气可以转化为醇类，如乙醇，或其他产品。

4. 发明授权

US08153027B2 Methods for producing syngas 失效
标题翻译：生产合成气的方法
公开(公告)号：US08153027B2
公开(公告)日：2012-04-10
申请号：US12166167
申请日：2008-07-01
申请人： Robert E. Klepper , Arie Geertsema , Shakeel H. Tirmizi , Francis M. Ferraro
发明人： Robert E. Klepper , Arie Geertsema , Shakeel H. Tirmizi , Francis M. Ferraro
IPC分类号： C01B3/22
CPC分类号： C01B3/16 , B01J2219/00006 , C10B47/44 , C10J3/66 , C10J2300/0916 , C10J2300/0959 , C10J2300/0973 , C10J2300/0986 , C10J2300/1665 , C10K1/101 , Y02E50/18 , Y02E50/32 , Y02P20/145
摘要： This invention features methods and apparatus for producing syngas from any carbon-containing feed material. In some embodiments, a substoichiometric amount of oxygen is used to enhance the formation of syngas. In various embodiments, both oxygen and steam are added during the conversion of the feed material into syngas. The syngas can be converted to alcohols, such as ethanol, or to other products.
摘要翻译：本发明的特征在于用于从任何含碳原料生产合成气的方法和装置。在一些实施方案中，使用亚化学计量的氧来增强合成气的形成。在各种实施方案中，在将进料转化为合成气期间，加入氧气和蒸汽。合成气可以转化为醇类，如乙醇，或其他产品。

5. 发明申请

US20090018222A1 METHODS AND APPARATUS FOR PRODUCING SYNGAS 失效
标题翻译：用于生产SYNGAS的方法和装置
公开(公告)号：US20090018222A1
公开(公告)日：2009-01-15
申请号：US12166167
申请日：2008-07-01
申请人： Robert E. KLEPPER , Arie Geertsema , Shakeel H. Tirmizi , Francis M. Ferraro
发明人： Robert E. KLEPPER , Arie Geertsema , Shakeel H. Tirmizi , Francis M. Ferraro
IPC分类号： C07C27/00
CPC分类号： C01B3/16 , B01J2219/00006 , C10B47/44 , C10J3/66 , C10J2300/0916 , C10J2300/0959 , C10J2300/0973 , C10J2300/0986 , C10J2300/1665 , C10K1/101 , Y02E50/18 , Y02E50/32 , Y02P20/145
摘要： This invention features methods and apparatus for producing syngas from any carbon-containing feed material. In some embodiments, a substoichiometric amount of oxygen is used to enhance the formation of syngas. In various embodiments, both oxygen and steam are added during the conversion of the feed material into syngas. The syngas can be converted to alcohols, such as ethanol, or to other products.
摘要翻译：本发明的特征在于用于从任何含碳原料生产合成气的方法和装置。在一些实施方案中，使用亚化学计量的氧来增强合成气的形成。在各种实施方案中，在将进料转化为合成气期间，加入氧气和蒸汽。合成气可以转化为醇类，如乙醇，或其他产品。

6. 发明申请

US20090018372A1 METHODS AND APPARATUS FOR PRODUCING ALCOHOLS FROM SYNGAS 有权
标题翻译：从SYNGAS生产酒精的方法和装置
公开(公告)号：US20090018372A1
公开(公告)日：2009-01-15
申请号：US12166212
申请日：2008-07-01
申请人： Shakeel H. TIRMIZI , Robert E. Klepper , Francis M. Ferraro
发明人： Shakeel H. TIRMIZI , Robert E. Klepper , Francis M. Ferraro
IPC分类号： C07C29/74 , B01J19/00
CPC分类号： C07C29/1518 , C07C29/76 , C07C31/04 , C07C31/08 , C07C31/10 , C07C31/12
摘要： Methods and apparatus for producing alcohols from syngas are disclosed herein. In some variations, syngas is catalytically converted to alcohols. The alcohols can be subjected to drying to produce an intermediate alcohol product, followed by distilling the intermediate product to produce a purified ethanol product for use in liquid fuels.
摘要翻译：本文公开了从合成气生产醇的方法和装置。在一些变化中，合成气被催化转化成醇。可以将醇干燥以产生中间体醇产物，然后蒸馏中间产物以产生用于液体燃料的纯化乙醇产物。

7. 发明授权

US09227895B2 Methods and apparatus for producing alcohols from syngas 有权
标题翻译：从合成气生产醇的方法和设备
公开(公告)号：US09227895B2
公开(公告)日：2016-01-05
申请号：US12166212
申请日：2008-07-01
申请人： Shakeel H. Tirmizi , Robert E. Klepper , Francis M. Ferraro
发明人： Shakeel H. Tirmizi , Robert E. Klepper , Francis M. Ferraro
IPC分类号： C07C29/80 , C07C29/151 , C07C29/76
CPC分类号： C07C29/1518 , C07C29/76 , C07C31/04 , C07C31/08 , C07C31/10 , C07C31/12
摘要： Methods and apparatus for producing alcohols from syngas are disclosed herein. In some variations, syngas is catalytically converted to alcohols. The alcohols can be subjected to drying to produce an intermediate alcohol product, followed by distilling the intermediate product to produce a purified ethanol product for use in liquid fuels.
摘要翻译：本文公开了从合成气生产醇的方法和装置。在一些变化中，合成气被催化转化成醇。可以将醇干燥以产生中间体醇产物，然后蒸馏中间产物以产生用于液体燃料的纯化乙醇产物。

8. 发明授权

US4744909A Method of effecting accelerated oxidation reaction 失效
标题翻译：加速氧化反应的方法
公开(公告)号：US4744909A
公开(公告)日：1988-05-17
申请号：US10060
申请日：1987-02-02
申请人： Francis M. Ferraro , Ronald H. Hall
发明人： Francis M. Ferraro , Ronald H. Hall
IPC分类号： B09B3/00 , B01J3/04 , C02F1/74 , C02F11/08
CPC分类号： C02F11/083 , B01J3/042
摘要： The method of this invention is particularly, although not exclusively, adapted for effecting accelerated oxidation reactions in a downhole or deep well wet oxidation apparatus, including the processing of aqueous organic waste, such as municipal sludge. It includes injecting a multiple-phase composition which contains an oxygen or an oxygen-rich gas which is fully saturated with water vapor and which also contains water in the liquid phase into a wet oxidation reaction apparatus which contains an aqueous stream of combustible waste, preferably at the temperature and pressure of the waste stream at the point of injection. This reduces the likelihood of hazardous spontaneous combustion which may otherwise occur if dry spots are allowed to form in the reaction apparatus. The volume of water in the composition should be equal to at least twice the volume of water necessary to saturate the gas with water vapor to maintain at least 50 percent of the water in the liquid phase.

9. 发明授权

US4721575A Method and apparatus for controlled chemical reactions 失效
标题翻译：受控化学反应的方法和装置
公开(公告)号：US4721575A
公开(公告)日：1988-01-26
申请号：US847965
申请日：1986-04-03
申请人： Jack E. Binning , Francis M. Ferraro , Franklin B. Carlson
发明人： Jack E. Binning , Francis M. Ferraro , Franklin B. Carlson
IPC分类号： B01J10/00 , B01J19/24 , C02F11/08 , C02F1/72
CPC分类号： C02F11/08 , B01J19/243 , B01J2219/00083 , B01J2219/00099 , B01J2219/00121 , B01J2219/00159 , B01J2219/00162 , B01J2219/00182
摘要： A method and apparatus for effecting accelerated chemical reactions at elevated temperatures and pressures including wet oxidation of materials in waste streams. An influent waste stream or first reactant is directed through a long tubular coil within a containment vessel with a second reactant being added to the influent. The waste stream includes gas and liquid components. The flow rates for the reactants of the waste stream are set to cause plug or slug flow of the waste stream through the tubular coil. The curvature of the coil tends to induce a secondary flow in the liquid component such that the liquid component tends to travel in a spiral thereby providing more intimate mixing of the reactants. The containment vessel may be partitioned to form a series of successive compartments to permit different temperature gradients to be applied to successive sections of the tubing coil across its length. Alternatively, a tube in tube construction for the tubular coil permits counter current heat exchange between the waste stream within the inner tube and a returning stream. Multiple injection and extraction points are provided along the path of the tubular coil to permit gas, liquid or solid reactants to be added or extracted as desired. The tubular coil provides an excellent environmental container for the reaction stream and is extremely suitable for temperature control to permit continuous heat input, autogenic operation and continuous heat extraction.
摘要翻译：一种用于在升高的温度和压力下进行加速化学反应的方法和装置，包括废物流中材料的湿氧化。流入的废物流或第一反应物被引导通过容器容器内的长管状线圈，其中第二反应物被添加到流入物中。废物流包括气体和液体组分。废物流的反应物的流速被设定为引起废物流通过管状线圈的塞子或团块流。线圈的曲率倾向于在液体组分中引起二次流动，使得液体组分倾向于以螺旋方式行进，从而提供反应物的更加紧密的混合。容纳容器可以被分隔以形成一系列连续的隔室，以允许将不同的温度梯度施加到管线圈的连续部分的整个长度上。或者，用于管状线圈的管构造管允许内管内的废物流与回流之间的逆流热交换。沿着管状线圈的路径提供多个注入和提取点，以允许根据需要添加或提取气体，液体或固体反应物。管状线圈为反应流提供了极好的环境容器，非常适合于温度控制，以允许连续的热量输入，自动操作和连续的热提取。

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