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    • 6. 发明授权
    • Multistage system for conversion of lower olefins with reactor quenching
means
    • 用反应器淬火方法转化低级烯烃的多级体系
    • US4942021A
    • 1990-07-17
    • US137224
    • 1987-12-23
    • William E. GarwoodFrederick J. KrambeckJohn D. KushnerickSamuel A. Tabak
    • William E. GarwoodFrederick J. KrambeckJohn D. KushnerickSamuel A. Tabak
    • C07C2/12C07C11/02C10G50/00
    • C07C11/02C07C2/12C10G50/00
    • A continuous multistage catalytic conversion system for upgrading lower olefins comprisingfirst adaibatic catalytic bed reactor means containing an acidic zeolite solid catalyst;means for feeding light olefinic gas directly to the first reactor without addition of separate diluent or recycle streams;means for operating the first reactor under olefin partial conversion conditions at elevated temperature to control adiabatic temperature increase;interstage quench means for injecting a liquid coolant directly into first stage effluent for reducing the temperature thereof and protecting downstream catalyst;second catalytic bed reactor means for receiving cooled first stage effluent with injected liquid coolant and further converting the olefins over a metallic zeolite catalyst having a metal ethene oligomerization component;means for cooling and recovering heavier liquid hydrocarbon product from the second reactor effluent; andmeans for recovering liquid coolant from the second effluent for recycle to the interstage quench means.
    • 一种用于升级低级烯烃的连续多级催化转化系统,包括含有酸性沸石固体催化剂的第一辅助催化床反应器装置; 用于将轻质烯属气体直接供给到第一反应器而不加入单独的稀释剂或再循环流的装置; 用于在高温下在烯烃部分转化条件下操作第一反应器的装置,以控制绝热温度升高; 级间骤冷装置,用于将液体冷却剂直接注入第一级流出物中以降低其温度并保护下游催化剂​​; 第二催化床反应器装置,用于接收具有注入的液体冷却剂的冷却的第一级流出物,并进一步转化具有金属乙烯低聚组分的金属沸石催化剂的烯烃; 用于从第二反应器流出物冷却和回收较重液体烃产物的装置; 以及用于从第二流出物回收液体冷却剂以再循环到级间骤冷装置的装置。
    • 10. 发明授权
    • Production of lubricant range hydrocarbons from light olefins
    • 从轻质烯烃生产润滑剂范围烃
    • US4568786A
    • 1986-02-04
    • US709143
    • 1985-03-07
    • Catherine S. Hsia ChenSamuel A. Tabak
    • Catherine S. Hsia ChenSamuel A. Tabak
    • B01J29/40B01J29/65B01J29/70C10G50/00C10G50/02C07C2/02
    • C10G50/02B01J29/40B01J29/7007C10G50/00B01J29/65B01J29/70
    • Olefin upgrading in plural reactors can achieve conversion of lower olefinic feedstock, such as propene, butene, etc., to valuable heavy hydrocarbons containing a lubricant fraction of high viscosity index. Other fuel products, such as (C.sub.10 -C.sub.20) distillate, gasoline and LPG may also be recovered as products. In a preferred process for converting lower olefinic feed to heavier hydrocarbons by contacting the feed with a shape selective medium pore acidic zeolite catalyst at elevated temperature and pressure the catalyst surface is rendered relatively inactive by adding to the olefinic feed an inactivating amount of a sterically-hindered organic base, whereby the catalyst is selectively surface-deactivated, to produce substantially linear heavier hydrocarbons rich in C.sub.10.sup.+ olefins. In the preferred multi-stage process the olefinic feed comprises C.sub.2 -C.sub.8 olefins and the catalyst employed in each stage comprises aluminosilicate having a silica-to-alumina mole ratio of at least 12 and a constraint index of about 1 to 12.
    • 在多个反应器中的烯烃升级可以实现将低级烯烃原料如丙烯,丁烯等转化成含有高粘度指数的润滑剂部分的有价值的重烃。 其他燃料产品,如(C10-C20)馏出物,汽油和LPG也可作为产品回收。 在优选的方法中,通过使进料与形状选择性中孔孔酸性沸石催化剂在升高的温度和压力下接触来将低级烯烃进料转化成较重的烃,通过向烯烃进料中加入灭活量的空间位阻,使催化剂表面相对无活性, 受阻的有机碱,其中催化剂被选择性地表面失活,以产生富含C10 +烯烃的基本上线性的较重的烃。 在优选的多级方法中,烯烃进料包含C 2 -C 8烯烃,并且在每个阶段中使用的催化剂包含二氧化硅与氧化铝的摩尔比至少为12,约束指数为约1至12的硅铝酸盐。