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    • 4. 发明授权
    • Zeolite catalysis process for conversion of diene-containing olefins to
aromatic hydrocarbons
    • 用于将含二烯烃烯烃转化为芳族烃的沸石催化方法
    • US4751339A
    • 1988-06-14
    • US6089
    • 1987-01-23
    • James H. Beech, Jr.Samuel A. Tabak
    • James H. Beech, Jr.Samuel A. Tabak
    • C07C2/00C07C15/00C10G29/00
    • C07C15/00C07C2/00C07C2529/40Y02P20/584
    • A technique for continuous conversion of diene-containing aliphatic hydrocarbon feedstock to heavier hydrocarbon products wherein the feedstock is contacted at elevated temperature under endothermic high severity reaction conditions with a fluidized bed of acidic zeolite fine catalyst particles, comprising methods and means for:maintaining the fluidized catalyst bed in a vertical reactor having a turbulent reaction zone by passing vapor upwardly through the reaction zone at a velocity greater than dense bed transition velocity to a turbulent regime and less than transport velocity for the average catalyst particle;feeding a continuous stream of feedstock into the reaction zone, said feedstream comprising sufficient C.sub.3.sup.+ alkanes to require net endothermic reaction conditions;withdrawing a portion of coked catalyst from the reaction zone, oxidatively regenerating the withdrawn catalyst, heating the catalyst substantially above process temperature in the fluidized bed reactor, and returning hot regenerated catalyst to the reaction zone at a rate to control catalyst activity and reaction temperature under conditions of reaction severity to effect feedstock conversion to an aromatics-rich hydrocarbon effluent stream; andseparating an aromatics-rich product from the fluidized bed effluent stream.Aromatics yield is increased by recovering a recycle stream comprising C.sub.5.sup.+ aliphatic hydrocarbons from the fluidized bed effluent stream for further conversion in the fluidized bed to increase aromatics product yield.
    • 一种用于将含二烯烃的脂族烃原料连续转化为较重烃产物的技术,其中原料在吸热高度苛刻度的反应条件下在升高的温度下与酸性沸石细催化剂颗粒的流化床接触,包括以下步骤: 催化剂床在具有湍流反应区的立式反应器中,通过使蒸气向上通过反应区,速度大于致密床转变速度至湍流状态且小于平均催化剂颗粒的输送速度; 将连续的原料流送入反应区,所述进料流包含足够的C3 +烷烃以需要净吸热反应条件; 将一部分焦化催化剂从反应区中取出,氧化再生催化剂,在流化床反应器中将催化剂加热至高于工艺温度,并将热再生催化剂返回到反应区,以控制催化剂活性和反应温度 使原料转化成富含芳烃的烃流出物流的反应条件; 以及从流化床流出物流中分离富含芳烃的产物。 通过从流化床流出物流中回收包含C5 +脂族烃的再循环料流以在流化床中进一步转化以提高芳族化合物产物产率来提高芳族化合物产率。