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    • 2. 发明授权
    • Rare earth polymers, optical amplifiers and optical fibers
    • 稀土聚合物,光放大器和光纤
    • US06292292B1
    • 2001-09-18
    • US09507582
    • 2000-02-18
    • Anthony F. GaritoRobert A. NorwoodRenyuan GaoAnna Panackal
    • Anthony F. GaritoRobert A. NorwoodRenyuan GaoAnna Panackal
    • H01S300
    • C03C13/04C08G79/04C08L85/02G02B6/02033H01S3/16H01S3/1698
    • Disclosed are cost-effective, compact, optically pumped, high gain, rare earth polymer materials such as, erbium (Er3+) perfluoro polymers, optical fibers made from the materials and waveguide amplifiers made from the materials having low-loss at telecommunications wavelengths for operation in communications network systems. The polymer amplifier is based on the use of novel high performance rare earth (RE) polymer materials. The new discovered highly transparent RE polymer materials are directly synthesized at high RE ion concentrations (˜1020−1021 rare earth ion/cm3˜10% wt) with each metal ion encapsulated and physically buffered by insulating, covalently bonded, perfluorinated phosphate ligands that then form the high temperature stable, polymer backbone matrix. This is distinctly different from widely studied inorganic glasses and single crystals where RE ion salts are doped directly into the host but only to relatively low levels (
    • 公开了具有成本效益,紧凑,光泵浦,高增益的稀土聚合物材料,例如铒(Er3 +)全氟聚合物,由材料制成的光纤和由用于操作的电信波长的低损耗材料制成的波导放大器 在通信网络系统中。 聚合物放大器基于使用新型高性能稀土(RE)聚合物材料。 新发现的高度透明的RE聚合物材料以高RE离子浓度(〜1020-1021稀土离子/ cm3〜10%wt)直接合成,每个金属离子被封装并通过绝缘,共价键合的全氟化磷酸盐配体进行物理缓冲,然后 形成高温稳定的聚合物骨架基体。 这与广泛研究的无机玻璃和单晶体明显不同,其中RE离子盐直接掺入主体中,但只有相对较低的水平(<0.1%wt)。