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1. 发明授权

US5181045A Bleed alleviation using pH-sensitive dyes 失效
标题翻译：使用pH敏感染料排泄缓解
公开(公告)号：US5181045A
公开(公告)日：1993-01-19
申请号：US764014
申请日：1991-09-23
申请人： James P. Shields , Raymond J. Adamic
发明人： James P. Shields , Raymond J. Adamic
IPC分类号： B41J2/21 , B41J2/01 , B41M5/00 , B41M7/00 , C09D11/00 , C09D11/02
CPC分类号： C09D11/328 , B41M7/00
摘要： Certain dyes become insoluble under specific and well-defined pH conditions. By forcing a dye to become insoluble on the page, migration of the dye is inhibited, thereby helping to reduce bleed between inks of different colors. The dye is forced out of solution from the ink by contact with another ink having the appropriate pH (either higher or lower than that of the first ink).

2. 发明授权

US5431724A Low water content inks for minimizing wet cockle in thermal ink-jet inks 失效
标题翻译：低含水量油墨，用于最大限度地减少热喷墨油墨中的湿cock
公开(公告)号：US5431724A
公开(公告)日：1995-07-11
申请号：US221230
申请日：1994-03-30
申请人： Raymond J. Adamic , Garold E. Radke
发明人： Raymond J. Adamic , Garold E. Radke
IPC分类号： C09D11/00 , C09D11/02
CPC分类号： C09D11/30 , C09D11/38
摘要： Wet cockle is minimized in aqueous-based, thermal ink-jet inks by adding to the ink at least one water-soluble substance, such as a solvent or salt, having a molecular weight of less than 200 grams/mole in an amount sufficient to reduce the mole fraction of water to a maximum value of about 0.5. Addition of the substance reduces wet paper cockle to a value that is less than the distance between the thermal ink-jet pen and the paper, thereby preventing a crash condition between the paper and the pen.
摘要翻译：通过向油墨中加入至少一种分子量小于200克/摩尔的水溶性物质，例如溶剂或盐，使水性基础的热喷墨油墨最小化，其量足以将水的摩尔分数降低到最大值约0.5。添加该物质可以将湿纸烟囱减小到小于热喷墨笔和纸之间距离的值，从而防止纸和纸笔之间的碰撞状况。

3. 发明授权

US5062893A Ink formulations by mixing anionic waterfast dyes containing two or more carboxyl groups 失效
标题翻译：通过混合含有两个或更多个羧基的阴离子防水染料来制备油墨
公开(公告)号：US5062893A
公开(公告)日：1991-11-05
申请号：US542862
申请日：1990-06-22
申请人： Raymond J. Adamic , Palitha Wickramanayake , Suraj L. Hindagolla , Garold E. Radke , David J. Halko
发明人： Raymond J. Adamic , Palitha Wickramanayake , Suraj L. Hindagolla , Garold E. Radke , David J. Halko
IPC分类号： C09B67/22 , C09D11/00 , C09D11/02
CPC分类号： C09D11/328
摘要： Inks are provided comprising (a) at least two dyes corresponding to the formula ##STR1## wherein W is COOH,X is H, or COOH,Y is H, COOH, or SO.sub.3 H,Z is H, COOH, or SO.sub.3 H, andR is H, CH.sub.2 COOH, or CH.sub.2 CH.sub.2 COOH;with the proviso that there are at least two COOH groups and that the number of COOH groups is equal to or greater than the number of SO.sub.3 H groups, and (b) a solvent which may be water or a mixture of water and a water-soluble organic solvent provide excellent waterfast prints on paper. The inks preferably have a pH from about 7 to about 9.5. Also preferably, a phosphate is added to reduce kogation and a metal chelating agent is added to further reduce nozzle clogging.

4. 发明授权

US5006862A Fixation of reactive dyes to paper by ink-jet printing 失效
标题翻译：通过喷墨打印将活性染料固定在纸上
公开(公告)号：US5006862A
公开(公告)日：1991-04-09
申请号：US429251
申请日：1989-10-27
申请人： Raymond J. Adamic
发明人： Raymond J. Adamic
IPC分类号： B41J2/01 , B41M5/00 , B41M5/50 , B41M5/52 , B41M7/00 , C09D11/00
CPC分类号： B41M7/00
摘要： The water-fastness and smear resistance of prints from inks in which a reactive moiety is attached to a chromophore are improved if the prints are treated with a strong base solution. Preferably, the paper is first treated with the base solution and then printed with the ink.

5. 发明授权

US06948801B2 Fluid interconnect with sealant 有权
标题翻译：流体互连密封剂
公开(公告)号：US06948801B2
公开(公告)日：2005-09-27
申请号：US10117648
申请日：2002-04-04
申请人： Zia Rehman , John L. Taylor , Raymond J. Adamic
发明人： Zia Rehman , John L. Taylor , Raymond J. Adamic
IPC分类号： B41J2/175
CPC分类号： B41J2/17523 , B41J2/17509
摘要： A fluid interconnect for a component of a printer is disclosed. The component may, for example, be an inkjet printhead removably attached to a printer and having an ink inlet configured to receive ink from an ink supply. The fluid interconnect has a sealing surface configured to form a seal when contacted against a opposing sealing surface on another component of a printer ink delivery system, and carries a surfactant sealant.
摘要翻译：公开了用于打印机部件的流体互连。组件可以是例如可移除地附接到打印机的喷墨打印头，并且具有被配置为从墨水供应接收墨水的墨水入口。流体互连具有密封表面，其被配置为当与打印机墨水输送系统的另一部件上的相对的密封表面接触时形成密封，并且携带表面活性剂密封剂。

6. 发明授权

US5785743A Bleed alleviation in ink-jet inks using organic acids 失效
标题翻译：使用有机酸在喷墨油墨中排泄缓解
公开(公告)号：US5785743A
公开(公告)日：1998-07-28
申请号：US567974
申请日：1995-12-06
申请人： Raymond J. Adamic , James P. Shields , Mark H. Kowalski
发明人： Raymond J. Adamic , James P. Shields , Mark H. Kowalski
IPC分类号： C09D11/00 , C09D11/02
CPC分类号： C09D11/40
摘要： An organic acid component is employed in a first ink-jet ink composition to reduce the pH differential required to render insoluble the pH-sensitive colorant of a second encroaching ink-jet ink composition. By inducing the precipitation of the pH-sensitive colorant, migration of the colorant is inhibited, thereby substantially reducing bleed between the pH-sensitive ink and the ink containing the organic acid (the "target" ink). The organic acid component is employed at a concentration ranging from about 0.25 to 20 wt % and may be represented by such as acids as polyacrylic, acetic, glycolic, malonic, malic, maleic, ascorbic, succinic, glutaric, fumaric, citric, tartaric, lactic, sulfonic, ortho-phosphoric acid, derivatives thereof. Without the organic acid component, a pH differential on the order of at least 4 and more likely 5 units must exist between the pH-sensitive ink and the target ink to substantially eliminate bleed. By employing an organic acid in the practice of the invention, a pH differential on the order of only 1 to 3 units may be required. Therefore, assuming the pH-sensitive ink has a pH of about 8, the pH of the target ink could be as high as 7 in the practice of the invention as opposed to a pH of about 3 in the absence of an organic acid component.
摘要翻译：在第一喷墨油墨组合物中使用有机酸组分以降低使第二侵入式喷墨油墨组合物的pH敏感着色剂变成不溶性所需的pH差异。通过诱导pH敏感着色剂的沉淀，着色剂的迁移被抑制，从而大大减少了pH敏感性油墨和含有机酸的油墨（“目标”油墨）之间的渗色。有机酸组分的使用浓度范围为约0.25至20重量％，可以由诸如聚丙烯酸，乙酸，乙醇酸，丙二酸，苹果酸，马来酸，抗坏血酸，琥珀酸，戊二酸，富马酸，柠檬酸，酒石酸，乳酸，磺酸，正磷酸，其衍生物。没有有机酸组分时，pH敏感油墨和目标油墨之间必须存在大约至少4个数量级，更可能5个单位的pH差异以基本上消除渗色。通过在本发明的实践中使用有机酸，可能需要大约1至3个单位的pH差。因此，假设pH敏感性墨水的pH值约为8，与实施例1相比，在不存在有机酸成分的情况下，目标油墨的pH值可高达7。

7. 发明授权

US5320668A Bleed alleviation using pH-sensitive agents 失效
标题翻译：使用pH敏感剂进行排泄缓解
公开(公告)号：US5320668A
公开(公告)日：1994-06-14
申请号：US6080
申请日：1993-01-19
申请人： James P. Shields , Raymond J. Adamic
发明人： James P. Shields , Raymond J. Adamic
IPC分类号： B41J2/01 , B41J2/21 , B41M5/00 , B41M7/00 , C09D11/00 , C09D11/02
CPC分类号： B41M7/0027 , C09D11/328 , C09D11/40 , B41M5/0017
摘要： Certain colorants become insoluble under specific and well-defined pH conditions. By forcing a colorant to become insoluble on the page, migration of the colorant is inhibited, thereby helping to reduce bleed between inks of different colors. The colorant is forced out of solution from the ink by contact with another ink having the appropriate pH (either higher or lower than that of the first ink). In particular, an ink containing a colorant comprising a pigment in combination with a pH sensitive dispersant is used in conjunction with an ink of the appropriate pH.
摘要翻译：某些着色剂在特定和明确定义的pH条件下变得不溶。通过强迫着色剂在页面上变得不溶，着色剂的迁移被抑制，从而有助于减少不同颜色的油墨之间的渗色。通过与具有适当pH（高于或低于第一油墨的）的另一种油墨接触，将着色剂从油墨中排出溶液。特别地，将含有颜料的着色剂与pH敏感性分散剂组合的油墨与适当pH的油墨结合使用。

8. 发明授权

US5188664A Anti-coalescent ink composition and method for making the same 失效
标题翻译：抗聚结油墨组合物及其制造方法
公开(公告)号：US5188664A
公开(公告)日：1993-02-23
申请号：US798463
申请日：1991-11-26
申请人： Raymond J. Adamic , Theresa A. Gibney
发明人： Raymond J. Adamic , Theresa A. Gibney
IPC分类号： B41J2/01 , B41M5/00 , B41M5/50 , B41M5/52 , C09D11/00
CPC分类号： C09D11/30
摘要： An improved ink composition having an additive therein for reducing the surface tension of the composition and increasing the drip mass per firing. Reduced surface tension and increased drop mass per firing enable the production of graphic images having enhanced clarity and contrast while avoiding problems such as bubble adhesion/longevity and ink mottling/coalescence. The additive basically consists of at least one polyether polyol. The additive is usable in a wide variety of ink compositions. In a preferred embodiment, ink compositions using the additive will include about 0.001-1.0% by weight additive (0.0075%=optimum). The resulting ink formulations are capable of printing high resolution graphic images while avoiding the problems described above.

9. 发明授权

US6139139A Color inkjet printer with pens containing reactive inks 失效
标题翻译：彩色喷墨打印机，含有反应性油墨的笔
公开(公告)号：US6139139A
公开(公告)日：2000-10-31
申请号：US868028
申请日：1997-06-03
申请人： John L. Stoffel , James P. Shields , Mark S. Hickman , Raymond J. Adamic , Mark L. Choy
发明人： John L. Stoffel , James P. Shields , Mark S. Hickman , Raymond J. Adamic , Mark L. Choy
IPC分类号： B41J2/175 , B41J2/21 , C09D11/00 , B41J2/17 , G01D11/00
CPC分类号： C09D11/40 , B41J2/175 , B41J2/2107
摘要： Described is a color inkjet printer for optimum bleed prevention in a printer utilizing multiple black and color pens wherein there is provided one print cartridge for dispensing black ink onto the printing medium and at least one print cartridge for dispensing color ink onto the printing medium. The cartridge for dispensing black ink contains an ink with little or no surface active agent while the cartridge for dispensing color ink contains a sufficient amount of surface active agent to reduce bleed between the colors. Moreover, the cartridge for dispensing black ink contains an ink which reacts with at least one and more preferably all inks contained in the cartridge for dispensing color ink. This reaction reduces bleed on images where the black print is adjacent to the color print to an acceptable level without requiring the black ink to contain surface active agents that would lead to inferior quality black text on the plain paper print medium. The reaction may be initiated by pH changes, reaction between the actual colorants, or reaction between one of the colorants and a component in the other ink.
摘要翻译：描述了一种彩色喷墨打印机，用于利用多个黑色和彩色笔的打印机中的最佳防漏，其中提供一个用于将黑色墨水分配到打印介质上的打印墨盒和用于将彩色墨水分配到打印介质上的至少一个打印墨盒。用于分配黑色墨水的墨盒包含具有很少或没有表面活性剂的墨水，而用于分配彩色墨水的墨盒含有足够量的表面活性剂以减少颜色之间的渗色。此外，用于分配黑色墨水的墨盒包含与至少一种更优选与墨盒中包含的用于分配彩色墨水的所有墨水反应的墨水。该反应减少了黑色印刷品与彩色印刷物相邻的图像上的渗色，使其不会黑色墨水含有表面活性剂，这些表面活性剂将导致普通纸打印介质上的劣质黑色文字。反应可以通过pH变化，实际着色剂之间的反应或其中一种着色剂与另一种油墨中的组分之间的反应引发。

10. 发明授权

US6036759A Black to color bleed control in ink-jet printing inks 失效
标题翻译：喷墨印刷油墨中的黑色渗色控制
公开(公告)号：US6036759A
公开(公告)日：2000-03-14
申请号：US70858
申请日：1998-04-30
申请人： Palitha Wickramanayake , Raymond J. Adamic
发明人： Palitha Wickramanayake , Raymond J. Adamic
IPC分类号： B41J2/01 , B41J29/00 , B41M5/00 , C09D11/00 , C09D11/02
CPC分类号： C09D11/40
摘要： The ink set of this invention comprises an anionic black pigmented ink and at least one color ink containing a dye or pigment colorant. The performance of these ink sets is improved by the addition of specific cationic surfactant or cationic (quaternary) salts which interact with the anionic black pigmented ink to provide improved black to color bleed control.
摘要翻译：本发明的油墨组包括阴离子黑色着色油墨和至少一种含有染料或颜料着色剂的彩色油墨。通过添加与阴离子黑色着色油墨相互作用的特定阳离子表面活性剂或阳离子（四元）盐来提高这些油墨组的性能，以提供改进的黑色到颜色渗色控制。

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