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    • 4. 发明授权
    • Bleed alleviation in ink-jet inks using organic acids
    • 使用有机酸在喷墨油墨中排泄缓解
    • US5785743A
    • 1998-07-28
    • US567974
    • 1995-12-06
    • Raymond J. AdamicJames P. ShieldsMark H. Kowalski
    • Raymond J. AdamicJames P. ShieldsMark H. Kowalski
    • C09D11/00C09D11/02
    • C09D11/40
    • An organic acid component is employed in a first ink-jet ink composition to reduce the pH differential required to render insoluble the pH-sensitive colorant of a second encroaching ink-jet ink composition. By inducing the precipitation of the pH-sensitive colorant, migration of the colorant is inhibited, thereby substantially reducing bleed between the pH-sensitive ink and the ink containing the organic acid (the "target" ink). The organic acid component is employed at a concentration ranging from about 0.25 to 20 wt % and may be represented by such as acids as polyacrylic, acetic, glycolic, malonic, malic, maleic, ascorbic, succinic, glutaric, fumaric, citric, tartaric, lactic, sulfonic, ortho-phosphoric acid, derivatives thereof. Without the organic acid component, a pH differential on the order of at least 4 and more likely 5 units must exist between the pH-sensitive ink and the target ink to substantially eliminate bleed. By employing an organic acid in the practice of the invention, a pH differential on the order of only 1 to 3 units may be required. Therefore, assuming the pH-sensitive ink has a pH of about 8, the pH of the target ink could be as high as 7 in the practice of the invention as opposed to a pH of about 3 in the absence of an organic acid component.
    • 在第一喷墨油墨组合物中使用有机酸组分以降低使第二侵入式喷墨油墨组合物的pH敏感着色剂变成不溶性所需的pH差异。 通过诱导pH敏感着色剂的沉淀,着色剂的迁移被抑制,从而大大减少了pH敏感性油墨和含有机酸的油墨(“目标”油墨)之间的渗色。 有机酸组分的使用浓度范围为约0.25至20重量%,可以由诸如聚丙烯酸,乙酸,乙醇酸,丙二酸,苹果酸,马来酸,抗坏血酸,琥珀酸,戊二酸,富马酸,柠檬酸,酒石酸, 乳酸,磺酸,正磷酸,其衍生物。 没有有机酸组分时,pH敏感油墨和目标油墨之间必须存在大约至少4个数量级,更可能5个单位的pH差异以基本上消除渗色。 通过在本发明的实践中使用有机酸,可能需要大约1至3个单位的pH差。 因此,假设pH敏感性墨水的pH值约为8,与实施例1相比,在不存在有机酸成分的情况下,目标油墨的pH值可高达7。
    • 10. 发明授权
    • Inkjet color ink set
    • 喷墨彩色墨水套装
    • US06540821B2
    • 2003-04-01
    • US09848810
    • 2001-05-04
    • Raymond J AdamicMary E AustinHiang P LauwDennis P ParazakZia Rehman
    • Raymond J AdamicMary E AustinHiang P LauwDennis P ParazakZia Rehman
    • C09D1102
    • C09D11/32C09D11/40
    • Color ink sets for use in printer systems are provided and formulated to provide improved plain paper and special media performance while maintaining good printing characteristics. The inks and ink sets of the present invention exhibit excellent color performance and lightfastness across a range of media, robust K/Y bleed resistance on plain paper at fast print speeds, as well as excellent printability and reliability. A specific dye set for formulating yellow, magenta, and cyan inks comprises a mixture of acid yellow 23 (AY23) and direct yellow 132 (DY132), a mixture of a cyan dye compound having the formula: —(SO3H)2.7 CuPc—(SO2NH2)0.5 —(SO2NH(C2H4OH)0.8 wherein Pc represents a phthalocyanine nucleus and acid blue 9; and a magenta dye compound having formula: wherein Q is a cation.
    • 提供和配制用于打印机系统的彩色油墨组,以提供改进的普通纸和特殊介质性能,同时保持良好的打印特性。 本发明的油墨和油墨组在一系列介质上表现出优异的色彩性能和耐光性,在快速打印速度下在普通纸上表现出强劲的K / Y耐渗色性,以及出色的可印刷性和可靠性。 用于配制黄色,品红色和青色墨水的特定染料组合物包括酸性黄23(AY23)和直接黄132(DY132)的混合物,其具有下式的青色染料化合物的混合物:其中Pc表示酞菁核和酸 蓝色9 和具有下式的品红色染料化合物:其中Q是阳离子。