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    • 1. 发明授权
    • Alkyl vinyl ether polymers containing a lactam functionality
    • 含有内酰胺官能团的烷基乙烯基醚聚合物
    • US5322898A
    • 1994-06-21
    • US114127
    • 1993-08-30
    • Ratan K. ChaudhuriJenn S. Shih
    • Ratan K. ChaudhuriJenn S. Shih
    • C08F8/14C08F8/12C08F8/30C08F16/16C08F20/02C08F22/36C08F216/16C08F222/02C08F222/04C08F222/38
    • C08J5/18C08F8/44C08F8/48C08F2810/50C08J2371/12Y10T428/31739
    • The invention relates to polymers containing units of the structure ##STR1## or mixtures of A with more than one of B, B-1 and B-2; wherein R and R.sup.1 are each independently C.sub.1 to C.sub.18 alkyl;R.sup.2 is oxygen, sulfur or --NR.sup.5 --;R.sup.5 is hydrogen or lower alkyl;R.sup.3 is alkylene having from 3 to 6 carbon atoms, optionally mono- or di- substituted with lower alkyl;W is hydrogen, --NH.sub.4, an alkali metal or an alkaline earth metal;Y is alkylene;Z is hydrogen, --NH.sub.4, an alkali metal or an alkaline earth metal or mixtures thereof;X is lower alkyl, a hydroxy phenyl radical or mixtures thereof;t has a value of from 2 to 8 andm, m', m" and n independently have a value of from 30 to 3,500 and n represents at least 5 mole percent of the polymeric product. The invention is also releated to the synthesis of the above polymers and to their use as superior adhesives which have significantly improved bond strength.
    • 本发明涉及含有结构单元A,B,B-1的聚合物。 或 B-2。 或A与B,B-1和B-2中的一种以上的混合物; 其中R和R 1各自独立地为C 1至C 18烷基; R2是氧,硫或-NR5-; R5是氢或低级烷基; R3是具有3至6个碳原子的亚烷基,任选被低级烷基单取代或二取代; W是氢,-NH4,碱金属或碱土金属; Y是亚烷基; Z是氢,-NH4,碱金属或碱土金属或其混合物; X是低级烷基,羟基苯基或其混合物; t的值为2至8,m,m',m“和n独立地具有30至3,500的值,n表示聚合物的至少5摩尔%。 本发明还涉及上述聚合物的合成以及它们作为具有明显改善的粘结强度的优异粘合剂的用途。
    • 2. 发明授权
    • Alkyl vinyl ether polymers containing a lactam functionality
    • 含有内酰胺官能团的烷基乙烯基醚聚合物
    • US5244974A
    • 1993-09-14
    • US763020
    • 1991-09-20
    • Ratan K. ChaudhuriJenn S. Shih
    • Ratan K. ChaudhuriJenn S. Shih
    • C08F8/12C08F8/30
    • C08F8/30C08J5/18C08F2810/50
    • The invention relates to polymers containing units of the structure ##STR1## or mixtures of A with more than one of B, B-1 and B-2; wherein R and R.sup.1 are each independently C.sub.1 to C.sub.18 alkyl;R.sup.2 is oxygen, sulfur or --NR.sup.5 --;R.sup.5 is hydrogen or lower alkyl;R.sup.3 is alkylene having from 3 to 6 carbon atoms, optionally mono- or di- substituted with lower alkyl;W is hydrogen --NH.sub.4, an alkali metal or an alkaline earth metal;Y is alkylene;Z is hydrogen, --NH.sub.4, an alkali metal or an alkaline earth metal or mixtures thereof;X is lower alkyl, a hydroxy phenyl radical or mixtures thereof;t has a value of from 2 to 8 andm, m', m" and n independently have a value of from 30 to 3,500 and n represents at least 5 mole percent of the polymeric product. The invention is also related to the synthesis of the above polymers and to their use as superior adhesives which have significantly improved bond strength.
    • 本发明涉及含有结构单元A,B,B-1的聚合物。 或 B-2。 或A与B,B-1和B-2中的一种以上的混合物; 其中R和R 1各自独立地为C 1至C 18烷基; R2是氧,硫或-NR5-; R5是氢或低级烷基; R3是具有3至6个碳原子的亚烷基,任选被低级烷基单取代或二取代; W是氢-NH4,碱金属或碱土金属; Y是亚烷基; Z是氢,-NH4,碱金属或碱土金属或其混合物; X是低级烷基,羟基苯基或其混合物; t的值为2至8,m,m',m“和n独立地具有30至3,500的值,n表示聚合物的至少5摩尔%。 本发明还涉及上述聚合物的合成及其作为具有明显改善的粘合强度的优异粘合剂的用途。
    • 3. 发明申请
    • POLYMER-BOUND UV ABSORBERS IN PERSONAL CARE COMPOSITIONS
    • 聚合物紫外吸收剂在个人护理组合物中的应用
    • US20100189661A1
    • 2010-07-29
    • US12694647
    • 2010-01-27
    • Osama M. MusaJenn S. Shih
    • Osama M. MusaJenn S. Shih
    • A61K8/30A61K9/72A61Q17/04C08G67/04
    • A61Q17/04A61K8/8164A61K2800/57C08F8/30C08F222/06
    • Personal care compositions comprising a polymer-bound UV absorber are described that provide enhanced properties, including customizable UV spectrum protection, broad-spectrum UV spectrum protection, water resistance, and labile UV stabilization. The polymer comprises anhydride functionality, such as maleic anhydride or a derivative thereof, and the UV absorber contains at least one hydroxyl, primary amine, or secondary amine group.The personal care compositions may be used to treat and/or protect against burns, cancers, erythema, lentigo (“liver spots”), keratotic lesions, wrinkles, and cellular changes of the skin; and/or color changes, embrittlement, lack of luster, tangles, split ends, and/or unmanageability of the hair.
    • 描述了包含聚合物结合的UV吸收剂的个人护理组合物,其提供增强的性质,包括可定制的UV光谱保护,广谱紫外光谱保护,耐水性和不稳定的UV稳定性。 聚合物包含酸酐官能团,如马来酸酐或其衍生物,UV吸收剂含有至少一个羟基,伯胺或仲胺基团。 个人护理组合物可用于治疗和/或保护免受灼伤,癌症,红斑,雀斑(“肝斑”),角化病变,皱纹和皮肤的细胞变化; 和/或颜色变化,脆化,缺乏光泽,缠结,分裂末端和/或头发的不可操纵性。
    • 9. 发明授权
    • Polymerization of vinylpyrrolidone
    • 乙烯基吡咯烷酮的聚合
    • US5306795A
    • 1994-04-26
    • US648261
    • 1991-01-31
    • Jenn S. ShihTerry E. Smith
    • Jenn S. ShihTerry E. Smith
    • C08F2/12C08F26/10C08F126/10
    • C08F26/10
    • What is provided herein is a process for making homopolymers of polyvinylpyrrolidone polymer in the form of fine powders at a polymer solids level of at least about 17%, preferably 30% or more, and in a yield of at least about 95%, which comprises precharging a reactor with a predetermined amount of a solvent selected from a C.sub.3 -C.sub.20 alkane, preferably heptane, or a C.sub.3 -C.sub.20 cycloalkane, preferably cyclohexane, and a free radical polymerization initiator, and feeding vinylpyrrolidone monomer into the precharged reactor at a selected rate, preferably about 0.1 to 1.8 g vinylpyrrolidone/min/1000 g of solvent, and most preferably, about 1 g/min/1000 g of cyclohexane and 0.5 g/min/1000 g of heptane, which rates preclude build-up of monomer during the polymerization, and for a feed period which provides the desired level of polymer solids in the reaction product, preferably at least about 200 minutes. The polymer product may be isolated from the reaction mixture by filtration and drying, or by direct drying.
    • 本文提供的是以至少约17%,优选30%或更高,至少约95%的聚合物固体含量制备细粉末形式的聚乙烯吡咯烷酮聚合物的均聚物的方法,其包含 用预定量的选自C 3 -C 20烷烃,优选庚烷或C 3 -C 20环烷烃,优选环己烷的溶剂和自由基聚合引发剂预反应器,并以选定的速率将乙烯基吡咯烷酮单体进料到预充电反应器中 ,优选约0.1至1.8g乙烯基吡咯烷酮/ min / 1000g溶剂,最优选约1g / min / 1000g环己烷和0.5g / min / 1000g庚烷,其速率阻止单体累积 聚合反应,以及在反应产物中提供所需水平的聚合物固体的进料周期,优选至少约200分钟。 聚合物产物可以通过过滤和干燥或通过直接干燥从反应混合物中分离出来。