会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 2. 发明授权
    • Process for the manufacture of halocarbons and selected compounds and azeotropes with HF
    • 用于制造卤代烃和所选化合物以及与HF共沸的方法
    • US06291730B1
    • 2001-09-18
    • US09011401
    • 1998-01-28
    • Ralph Thomas BakerViacheslav Alexandrovich PetrovVelliyur Nott Mallikarjuna RaoAllen Capron Sievert
    • Ralph Thomas BakerViacheslav Alexandrovich PetrovVelliyur Nott Mallikarjuna RaoAllen Capron Sievert
    • C07C1710
    • C07C19/10C07C17/206C07C17/275C07C17/278C07C17/38C07C17/386C07C19/08Y02P20/582C07C19/01C07C19/16
    • A liquid phase process is disclosed for producing halogenated alkane adducts of the formula: CAR1R2CBR3R4 (where A, B, R1, R2, R3, and R4 are as defined in the specification) which involves contacting a corresponding halogenated alkane, AB, with a corresponding olefin, CR1R2═C3R4 in a dinitrile or cyclic carbonate ester solvent which divides the reaction mixture into two liquid phases and in the presence of a catalyst system containing: (i) at least one catalyst selected from monovalent and divalent copper; and optionally (ii) a promoter selected from aromatic or aliphatic heterocyclic compounds which contain at least one carbon-nitrogen double bond in the heterocyclic ring. When hydrochlorofluorocarbons are formed, the chlorine content may be reduced by reacting the hydrochlorofluorocarbons with HF. New compounds disclosed include CF3CF2CCl2CH2CCl3, CF3CCl2CH2CH2Cl and CF3CCl2CH2CHClF. These compounds are useful as intermediates for producing hydrofluorocarbons. Azeotropes of CClF2CH2CF3 with HF and azeotropes of CF3CH2CHF2 with HF are also disclosed; as are processes for producing such azeotropes. A process for purification of certain hydrofluorocarbons and/or chloroprecursors thereof from mixtures of such compounds with HF is also disclosed.
    • 公开了制备下式的卤化烷烃加成物的液相方法:CAR1R2CBR3R4(其中A,B,R1,R2,R3和R4如说明书中所定义),其涉及使相应的卤代烷烃AB与相应的 烯烃,CR1R2 = C3R4在二腈或环状碳酸酯溶剂中,其将反应混合物分成两个液相,并且在催化剂体系存在下,包含:(i)至少一种选自单价和二价铜的催化剂; 和任选地(ii)选自在杂环中含有至少一个碳 - 氮双键的芳族或脂族杂环化合物的促进剂。 当形成氢氯氟烃时,可以通过氢氯氟烃与HF反应来降低氯含量。 所公开的新化合物包括CF 3 CF 2 CCl 2 CH 2 ClCl 3,CF 3 CCl 2 CH 2 CH 2 Cl和CF 3 CCl 2 CH 2 CHClF。 这些化合物可用作生产氢氟烃的中间体。 还公开了CClF 2 CH 2 CF 3与HF的共沸物和CF 3 CH 2 CHF 2与HF的共沸物质; 生产这种共沸物的方法也是如此。 还公开了从这些化合物与HF的混合物中纯化某些氢氟烃和/或其氯前体的方法。
    • 9. 发明授权
    • Process for the manufacturing of selected halogenated hydrocarbons
containing fluorine and hydrogen and compositions provided therein
    • 用于制造选择的含氟和氢的卤代烃的方法及其中提供的组合物
    • US5670679A
    • 1997-09-23
    • US458784
    • 1995-06-02
    • Ralph Thomas BakerRichard Paul BeattyWilliam Brown FarnhamRobert Lewis Wallace, Jr.
    • Ralph Thomas BakerRichard Paul BeattyWilliam Brown FarnhamRobert Lewis Wallace, Jr.
    • C07B31/00C07B37/02C07B61/00C07C17/00C07C17/281C07C17/354C07C17/361C07C19/08C07C19/10C07C22/08C07C43/12C07C69/63C07C255/10C07F15/04C07F17/00C07F9/02
    • C07F15/04C07B31/00C07B37/02C07B61/00C07C17/281C07C17/361C07C19/08C07C19/10C07C22/08C07C255/10C07C43/123C07C69/63
    • A process is disclosed for the manufacture of product compounds of the formula HC(R.sup.1).sub.2 C(R.sup.1).sub.2 C(R.sup.2).sub.2 C(R.sup.2).sub.2 H wherein each R.sup.1 is independently selected from the group consisting of H, F, Cl, CN, R, OR, CO.sub.2 R, C(O)R, OC(O)R, R.sup.f, OR.sup.f, CO.sub.2 R.sup.f C(O)R.sup.f and OC(O)R.sup.f where R is a hydrocarbyl group and R.sup.f is a C.sub.1 to C.sub.10 polyfluoroalkyl group, provided that at least one R.sup.1 is F, and wherein each R.sup.2 is independently selected from the group consisting of H, F, Cl, CN, R, OR, CO.sub.2 R, C(O)R, OC(O)R, R.sup.f, OR.sup.f, CO.sub.2 R.sup.f, C(O)R.sup.f, OC(O)R.sup.f and difunctional linkages where an R.sup.2 group on each of two adjacent carbon atoms together form a link selected from the group consisting of --CH.sub.2 CH.sub.2 CH.sub.2 --, --CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 --, --CH.sub.2 CH.sub.2 CH(CH.sub.3 --, --CH.sub.2 CH(CH.sub.3)CH.sub.2 --, --C(O)OC(O)--, and norborndiyl. The process involves reacting a metallacycle of the formula L.sub.m M(1,4-C(R.sup.1).sub.2 C(R.sup.1).sub.2 C(R.sup.2).sub.2 C(R.sup.2).sub.2 --) wherein R.sup.1 and R.sup.2 are as defined above, and wherein M is a metal selected from the group consisting of Group 8, Group 9 and Group 10 metals, each L is a ligand selected from the group consisting of Group 14, Group 15 and Group 16 ligands, and m is an integer from 1 to 4, in the liquid phase with hydrogen. Also disclosed are certain compositions comprising product compounds within the above product compound formula and certain metallacycle compounds within the above metallacycle formula.
    • 公开了制备式HC(R1)2C(R1)2C(R2)2C(R2)2H的产物化合物的方法,其中每个R 1独立地选自H,F,Cl,CN,R ,OR,CO 2 R,C(O)R,OC(O)R,R f,OR f,CO 2 R f C(O)R f和OC(O)R f,其中R是烃基,Rf是C1至C10多氟烷基, 至少一个R1是F,并且其中每个R 2独立地选自H,F,Cl,CN,R,OR,CO 2 R,C(O)R,OC(O)R,R f,OR f, CO 2 R f,C(O)R f,OC(O)R f和双官能键,其中两个相邻碳原子上的每一个上的R 2基团一起形成选自-CH 2 CH 2 CH 2 - , - CH 2 CH 2 CH 2 CH 2 - , - CH 2 CH 2 CH 所述方法包括使式LmM(1,4-C(R 1)2 C(R 1)2 C(R 2))的金属环反应, 2C(R2)2-)其中R1和R2如上定义,并且其中M是选自第8族,第9族和第10族金属的金属,每个L是配体 选自第14族,第15族和第16族配体,m为1至4的整数,在液相中为氢。 还公开了包含上述产物化合物式中的产物化合物和上述金属环状配方中的某些金属环化合物的某些组合物。