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    • 1. 发明授权
    • Rheology-influencing composition for coating media
    • 用于涂料介质的流变学影响组合物
    • US6037404A
    • 2000-03-14
    • US089754
    • 1998-06-02
    • Ralf DahmCarmen FlosbachHermann KerberSandra KirchgasslerDieter LerchFrank SchnodewindWalter Schubert
    • Ralf DahmCarmen FlosbachHermann KerberSandra KirchgasslerDieter LerchFrank SchnodewindWalter Schubert
    • C09K3/00C08G18/40C08G18/42C08G18/62C08G18/63C08G18/80C09D5/04C09D7/12C08J3/00C08F8/30C08G18/08C08K3/20C08L75/00
    • C08G18/631C08G18/4072C08G18/8074C09D5/04
    • This invention relates to a composition, and to the preparation and use of thereof said composition being suitable as a rheology influencer for coating media and comprising the reaction product formed by reaction of a mixture of components A, B and C with components D, E and F. Components A, B and C form a mixture wherein component A is one or more (meth)acrylic copolymers and/or one or more polyesters which contain hydroxyl groups. Component B is a copolymer of ethylhexyl (meth)acrylate and one or more hydroxyalkyl (meth)acrylates, as well as .alpha.,.beta.-unsaturated monomers which are different therefrom. Component C is a hydroxy--functional microdispersion which is produced by polymerizing hydroxylalkyl (meth)acrylates in combination with unsaturated monomers in a mixture of polyesters or polyacrylates containing carboxyl and/or hydroxyl groups. Component D is one or more aliphatic polyisocyantes and component E is .epsilon.-caprolactam. The caprolactam partially blocks the polyisocyanate. The component F is one or more primary amines. These ingredients are combined in certain specified amounts. The invention also relates to coating media and to the production of these coating media, which contain said composition as a rheology influencer.
    • 本发明涉及一种组合物及其制备和用途,所述组合物适合用作涂料介质的流变学影响剂,并且包含通过组分A,B和C的混合物与组分D,E反应形成的反应产物和 F.组分A,B和C形成混合物,其中组分A是一种或多种(甲基)丙烯酸共聚物和/或一种或多种含有羟基的聚酯。 组分B是(甲基)丙烯酸乙基己酯和一种或多种(甲基)丙烯酸羟烷基酯以及与其不同的α,β-不饱和单体的共聚物。 组分C是通过在含有羧基和/或羟基的聚酯或聚丙烯酸酯的混合物中聚合(甲基)丙烯酸羟烷基酯与不饱和单体组合制备的羟基官能微分散体。 组分D是一种或多种脂肪族聚异氰酸酯,组分E是ε-己内酰胺。 己内酰胺部分阻断多异氰酸酯。 组分F是一种或多种伯胺。 这些成分以特定的量组合。 本发明还涉及涂料介质和这些包含所述组合物作为流变学影响剂的涂料介质的生产。
    • 2. 发明授权
    • Sag stabilized coating compositions containing epoxy-functional crosslinking components
    • 含有环氧官能交联组分的凹凸稳定的涂料组合物
    • US06555176B1
    • 2003-04-29
    • US09914219
    • 2001-08-22
    • Ralf DahmCarmen FlosbachHans-Jürgen GawinHermann KerberApostolos ManassisVolker PaschmannWalter Schubert
    • Ralf DahmCarmen FlosbachHans-Jürgen GawinHermann KerberApostolos ManassisVolker PaschmannWalter Schubert
    • C08J500
    • C09D163/00C08L2666/04C08L2666/18
    • Coating composition containing a binder/crosslinking agent system, organic solvents, optionally together with pigments and/or extenders and conventional lacquer additives, wherein the binder/crosslinking agent system contains A) 20 to 80 wt. % of carboxy-functional (meth)acrylic copolymers and/or polyesters which are dissolved in the continuous phase of the coating composition, with an acid value of 15 to 300 mg of KOH/g, B) 80 to 20 wt. % of epoxy-functional crosslinking agents, wherein the numerical ratio between the component A) carboxyl groups and the component B) epoxy groups is between 1:1 and 1:3, and the epoxy-functional crosslinking agent B) comprises at least one epoxy-functional crosslinking component B1) which is dissolved in the continuous phase of the coating composition and at least one epoxy-functional component B2) dispersed in the continuous phase of the coating composition, wherein the numerical ratio of the epoxy groups of the crosslinking components B1) and B2) is 10:1 to 1:5 and wherein the organic solvents comprise 0 to 35 wt. % of one or more conventional organic lacquer solvents containing oxygen and 65 to 100 wt. % of one or more conventional lacquer hydrocarbons.
    • 包含粘合剂/交联剂体系的涂料组合物,有机溶剂,任选地与颜料和/或增量剂和常规漆添加剂一起,其中粘合剂/交联剂体系含有A)20至80wt。 %的羧酸官能(甲基)丙烯酸共聚物和/或聚酯,其溶解在涂料组合物的连续相中,酸值为15至300mg KOH / g,B)80至20wt。 %的环氧官能交联剂,其中组分A)羧基和组分B)环氧基之间的数值比在1:1至1:3之间,并且环氧官能交联剂B)包含至少一种环氧 溶解在涂料组合物的连续相中的功能性交联组分B1)和分散在涂料组合物的连续相中的至少一种环氧官能组分B2),其中交联组分B1的环氧基数 )和B2)为10:1至1:5,并且其中所述有机溶剂包含0至35重量% %的一种或多种常规有机漆溶剂含有氧和65至100wt。 %的一种或多种常规漆油。
    • 3. 发明授权
    • Coating of carboxyl (meth)acrylic copolymer or polyester and urea anti-sag agent prepared in polyepoxide
    • 涂覆在聚环氧化物中制备的羧基(甲基)丙烯酸共聚物或聚酯和尿素防流挂剂
    • US06437056B1
    • 2002-08-20
    • US09622757
    • 2000-12-11
    • Ralf DahmCarmen FlosbachHermann KerberWalter SchubertAstrid Tückmantel
    • Ralf DahmCarmen FlosbachHermann KerberWalter SchubertAstrid Tückmantel
    • C08L3302
    • C09D163/00C09D167/00C08L2666/28C08L2666/04C08L63/00C08L2666/18
    • Coating composition suitable for multilayer lacquering, containing, in addition to organic solvent, anti-sagging agents, optionally pigments, extenders and additives, a binder/crosslinkin agent system containing A) from 20 to 80 wt. % of carboxyl-functional (meth)acrylic copolymers and/or carboxyl-functional polyesters having an acid number of from 20 to 300, B) from 20 to 80 wt. % of epoxy-functional crosslinking agents, the percentages by weight of A) and B) adding up to 100 wt. %. C) from 0 to 30 wt. % of polymer polyol C), based on the sum of the weights of A) and B), E) from 0 to 20 wt. % of further crosslinking agents, based on the sum of the weights of A, B, and C), F) from 0 to 10 wt. % of monoepoxides, based on the sum of the weights of A) and B), and D) as anti-sagging agents, from 0.1 to 3 wt. %, based on the resin solids, of solid, finely divided urea compounds D) which have previously been prepared in the presence of at least a portion of the epoxy-functional crosslinking agent B) and which are insoluble in the coating compositions, all percentages are by weight being based in each case on the solids.
    • 适用于多层涂料的涂料组合物,除了有机溶剂之外,还含有抗流挂剂,任选的颜料,增量剂和添加剂,含有A)的粘合剂/交联剂剂系统。20) %羧酸官能(甲基)丙烯酸共聚物和/或酸值为20〜300的羧基官能聚酯,B)20〜80重量% %的环氧官能交联剂,A)的重量百分数和B)加入到100重量% %.C)为0〜30wt。 聚合物多元醇C的%),基于A)和B)的重量之和,E)为0至20wt。 基于A,B和C)的重量之和,F)0至10重量%的其它交联剂的%。 基于作为抗流挂剂的A)和B)和D)的重量之和,单环氧化物的百分比为0.1至3重量%。 基于树脂固体的固体细分尿素化合物D),其在先前在至少一部分环氧官能交联剂B的存在下制备)并且不溶于涂料组合物中,所有百分比 在每种情况下以固体为基准。
    • 5. 发明授权
    • Coating compositions use thereof and process for the production of
multi-layer lacquer coatings
    • 涂料组合物的用途以及生产多层漆层的方法
    • US6013326A
    • 2000-01-11
    • US427
    • 1998-04-17
    • Carmen FlosbachFriedrich HerrmannHermann KerberHeinz-Walter ReifferscheidtCarmen SchloesserWalter Schubert
    • Carmen FlosbachFriedrich HerrmannHermann KerberHeinz-Walter ReifferscheidtCarmen SchloesserWalter Schubert
    • B05D7/14C08G18/62C08G18/80C09D133/14C09D161/20C09D175/04B05D1/36B05D3/02C08F8/30C08F8/32
    • C08G18/6204C08G18/6229
    • Coating compositions suitable for stoved multi-layer coatings containing as binder:A) 20 to 40 wt. % of hydroxy-functional (meth)acrylic copolymer obtainable from styrene and/or styrene derivatives; hydroxyethyl, hydroxypropyl and/or hydroxybutyl (meth)acrylate; non-functionalised (cyclo)alkyl (meth)acrylates having 8 to less than 18 C atoms in the (cyclo)alkyl residue; (meth)acrylic acid and optionally non-functionalised (cyclo)alkyl (meth)acrylates having up to 7 C atoms in the (cyclo)alkyl residue;B) 20 to 40 wt. % of hydroxy-functional (meth)acrylic copolymer obtainable from hydroxyethyl, hydroxypropyl and/or hydroxybutyl (meth)acrylate; non-functionalised (cyclo)alkyl (meth)acrylates having 8 to less than 18 C atoms in the (cyclo)alkyl residue; non-functionalised (cyclo)alkyl (meth)acrylates having up to 7 C atoms in the (cyclo)alkyl residue and (meth)acrylic acid;C) 0 to 40 wt. % of hydroxy-functional binders other than A) and B),D) 10 to 50 wt. % of free or blocked polyisocyanates, andE) 0 to 40 wt. % triazine-based components which crosslink with the hydroxyl groups of components A), B) and optionally C) to form ether and/or ester groups.
    • PCT No.PCT / EP96 / 03402 Sec。 371日期:1998年4月17日 102(e)1998年4月17日PCT PCT 1996年8月2日PCT公布。 出版物WO97 / 06197 日期1997年2月20日涂料组合物适用于含有作为粘合剂的烘烤多层涂料:A)20-40重量% %的由苯乙烯和/或苯乙烯衍生物得到的羟基官能(甲基)丙烯酸共聚物; 羟乙基,羟丙基和/或(甲基)丙烯酸羟丁酯; 在(环)烷基残基中具有8至小于18个碳原子的非官能化(环)烷基(甲基)丙烯酸烷基酯; (环)烷基残基中具有至多7个C原子的(甲基)丙烯酸和任选的非官能化(环)(甲基)丙烯酸烷基酯; B)20〜40重量% 羟乙基,羟丙基和/或羟丁基(甲基)丙烯酸酯得到的羟基官能(甲基)丙烯酸共聚物的% 在(环)烷基残基中具有8至小于18个碳原子的非官能化(环)烷基(甲基)丙烯酸烷基酯; 在(环)烷基残基和(甲基)丙烯酸中具有至多7个C原子的非官能化(环)烷基(甲基)丙烯酸酯; C)0〜40wt。 %的除了A)和B)之外的羟基官能的粘合剂,D)10至50wt。 %的游离或封闭的多异氰酸酯,和E)0-40wt。 与组分A),B)和任选C)的羟基交联的三嗪基组分,以形成醚和/或酯基。