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1. 发明授权

US5661199A Hydroxyl group containing binder, a process for its preparation, and its use 失效
标题翻译：含羟基的粘合剂，其制备方法及其用途
公开(公告)号：US5661199A
公开(公告)日：1997-08-26
申请号：US657005
申请日：1996-05-28
申请人： Klaus Bederke , Hermann Kerber , Ralf Dahm , Friedrich Herrmann , Horst Voss
发明人： Klaus Bederke , Hermann Kerber , Ralf Dahm , Friedrich Herrmann , Horst Voss
IPC分类号： C09D5/00 , B05D7/16 , C08F265/06 , C08F283/02 , C09D4/00 , C09D5/02 , C09D133/10 , C09D151/00 , C09D167/00 , C09D167/02 , C08L33/14 , C08L67/00
CPC分类号： C09D151/00 , C08F265/06 , C08F283/02 , Y10S524/923
摘要： A non-aqueous dispersion containing, in addition to organic solvents,A) from 15-85% by weight of a dissolved film-forming component of hydroxyl group- and carboxyl-group containing polyesters, (meth)acrylic copolymers or mixtures thereof in which up to half the molecules may be esterified with 1 molecule of maleic acid each, andB) from 15-85% by weight of a disperse phase of uncross-linked (meth)acrylic copolymers having a hydroxyl number of at least 300, obtainable by the radical polymerization ofa) from 80-100% by weight of hydroxyalkyl (meth)acrylates andb) from 0-20% by weight of other .alpha.,.beta.-monounsaturated monomers in the dissolved film-forming component.
摘要翻译：除了有机溶剂之外，还包含A）15-85重量％的含羟基和含羧基的聚酯，（甲基）丙烯酸共聚物或其混合物的溶解成膜组分的非水分散体，其中最多一半的分子可以用1分子马来酸各自酯化，B）15-85重量％的羟基数为至少300的未交联的（甲基）丙烯酸共聚物的分散相，可通过 a）从80-100重量％的（甲基）丙烯酸羟烷基酯和b）0-20重量％的其它α，β-单元不饱和单体在溶解的成膜组分中的自由基聚合。

2. 发明授权

US5614590A Coating agents, process for their preparation and their use for the preparation of transparent top layers on multilayer coatings 失效
标题翻译：涂层剂，其制备方法及其在多层涂料上制备透明顶层的用途
公开(公告)号：US5614590A
公开(公告)日：1997-03-25
申请号：US119289
申请日：1993-09-09
申请人： Klaus Bederke , Friedrich Herrmann , Hermann Kerber , Hans-Martin Schonrock
发明人： Klaus Bederke , Friedrich Herrmann , Hermann Kerber , Hans-Martin Schonrock
IPC分类号： C09D175/04 , C08G18/62 , C09D133/14 , C09D175/06 , C08F8/30
CPC分类号： C08G18/6229
摘要： A transparent coating agent which is free of heavy metal catalysts and which contains a hydroxy functional (meth)acrylic copolymer based binder, an aliphatic or cycloaliphatic polyisocyanate crosslinking agent, a solvent, and lacquer adjuvant.
摘要翻译：一种不含重金属催化剂且含有羟基官能（甲基）丙烯酸共聚物的粘合剂，脂族或脂环族多异氰酸酯交联剂，溶剂和漆佐剂的透明涂料。

3. 发明授权

US5391620A Composition suitable as a rheology-influencing agent, a method for its preparation and its use in coating media 失效
标题翻译：适用于流变影响剂的组合物，其制备方法及其在涂布介质中的应用
公开(公告)号：US5391620A
公开(公告)日：1995-02-21
申请号：US139918
申请日：1993-10-20
申请人： Klaus Bederke , Ralf Dahm , Hermann Kerber , Walter Schubert , Friedrich Hermann , Heinz-Walter Reifferscheidt
发明人： Klaus Bederke , Ralf Dahm , Hermann Kerber , Walter Schubert , Friedrich Hermann , Heinz-Walter Reifferscheidt
IPC分类号： C08G18/28 , C08G18/40 , C08G18/42 , C08G18/62 , C08G18/63 , C09D7/12 , C09D133/04 , C09D133/14 , C09D167/00 , C09D175/04 , C09D175/06 , C08L75/00
CPC分类号： C09D7/125 , C08G18/282 , C08G18/2865 , C08G18/4063 , C08G18/4072 , C08G18/633 , C08G18/635
摘要： A rheology-influencing agent for coating media, containing a mixture of a (meth)acrylic copolymer containing hydroxyl groups and/or one or more polyesters containing hydroxyl groups, a hydroxy functional microdispersion obtainable by preparing a solution of one or more film-forming polyesters containing hydroxyl and/or carboxyl groups and/or (meth)acrylic copolymers containing hydroxyl and/or carboxyl groups, the foregoing mixture being reacted with a diisocyanate, and an aliphatic primary monoamine.
摘要翻译：包含含有羟基的（甲基）丙烯酸共聚物和/或一种或多种含羟基的聚酯的混合物的涂料介质的流变影响剂，通过制备一种或多种成膜聚酯的溶液可获得的羟基官能微分散体含有羟基和/或羧基和/或含有羟基和/或羧基的（甲基）丙烯酸共聚物，前述混合物与二异氰酸酯和脂族伯单胺反应。

4. 发明授权

US4855342A Coating material and its use as primer and extender 失效
标题翻译：涂料及其用作底漆和增量剂
公开(公告)号：US4855342A
公开(公告)日：1989-08-08
申请号：US122903
申请日：1987-11-19
申请人： Heinz D. Becker , Klaus Bederke , Ralf Dahm , Hermann Kerber , Fritz Sadowski , Werner Stephan
发明人： Heinz D. Becker , Klaus Bederke , Ralf Dahm , Hermann Kerber , Fritz Sadowski , Werner Stephan
IPC分类号： C08G18/40 , C08G18/62
CPC分类号： C08G18/4081 , C08G18/6204 , C08G18/6229
摘要： Previous coating materials lead to the formation of bubbles at high layer thickness and when drying by heating. The new coating materials are intended to be bubble-free when dried at higher layer thicknesses.Aside from pigments and/or extenders, the coating material contains solvents and, if necessary, conventional paint auxiliaries in a vehicle mixture, comprising essentially 60-75% by weight of a hydroxy-functional copolymer, 1-5% by weight of an ester-soluble nitrocellulose and 25-35% by weight of difunctional or multifunctional polyisocyanate. It can be cured without forming bubbles even when applied in thick layers.Use as primer and filler.
摘要翻译：以前的涂层材料导致在高层厚度下形成气泡，并且通过加热干燥。当在较高层厚度下干燥时，新的涂层材料旨在是无气泡的。除了颜料和/或增量剂之外，涂料含有溶剂，如果需要的话，在车辆混合物中含有基本上为60-75重量％的羟基官能共聚物的常规涂料助剂，1-5重量％的酯 - 可溶性硝酸纤维素和25-35％重量的双官能或多官能多异氰酸酯。即使施加在厚层上也可以固化而不形成气泡。用作底漆和填料。

5. 发明授权

US5663233A Coating agents and the use thereof in processes for the production of multi-layer coatings 失效
标题翻译：涂层剂及其在多层涂料生产方法中的应用
公开(公告)号：US5663233A
公开(公告)日：1997-09-02
申请号：US492291
申请日：1995-06-19
申请人： Klaus Bederke , Friedrich Herrmann , Hermann Kerber , Thomas Kutzner , Hans-Martin Schonrock
发明人： Klaus Bederke , Friedrich Herrmann , Hermann Kerber , Thomas Kutzner , Hans-Martin Schonrock
IPC分类号： C08G18/40 , C09D167/00 , C09D175/04 , C08L67/02 , C08L33/02 , C08L61/28 , C08L67/04
CPC分类号： C09D167/00 , C08G18/4063 , C09D175/04
摘要： A solvent based coating composition containing a binding agent, the binding agent comprising: (a) 10 to 80 wt.% of at least one hydroxyfunctional polyester formed by reacting a mixture comprising: (i) 10 to 40 mol.% of a 2,2-dialkylalkanediol with two primary OH groups; (ii) 10 to 30 mol.% of a polyol with at least one secondary OH group; (iii) 20 to 50 mol.% of an aliphatic or cycloaliphatic dicarboxylic acid with fewer than 16 C atoms or anhydrides thereof; (iv) 5 to 30 mol.% of a compound selected from the group consisting of dimeric fatty acids, dimeric diols, epsilon-caprolactone, and mixtures thereof; (v) 1 to 15 mol.% of a hydroxycarboxylic acid with at least one hydroxy group and at least one carboxyl group; and (b) 10 to 80 wt.% of a (meth)acrylic copolymer containing a hydroxyl group; and (c) 10 to 60 wt.% of a crosslinking agent; wherein the sum of the wt.% of components (a)-(c) is 100% of the binding agent.
摘要翻译：一种含有粘合剂的溶剂型涂料组合物，所述粘合剂包含：（a）10至80重量％的至少一种羟基官能聚酯，所述羟基官能聚酯是通过使混合物反应形成的，所述混合物包含：（i）10至40摩尔％具有两个伯OH基的2-二烷基二醇; （ii）10至30mol％具有至少一个仲OH基团的多元醇; （iii）20-50mol％具有少于16个C原子的脂族或脂环族二羧酸或其酸酐; （iv）5至30mol％的选自二聚脂肪酸，二聚二醇，ε-己内酯及其混合物的化合物; （v）1至15mol％具有至少一个羟基和至少一个羧基的羟基羧酸; 和（b）10〜80重量％的含有羟基的（甲基）丙烯酸共聚物; 和（c）10〜60重量％的交联剂; 其中组分（a） - （c）的重量％的总和为粘合剂的100％。

6. 发明授权

US5698330A Coating compositions for transparent topcoat lacquer layers and the use thereof in processes for the production of multi-layer lacquer coatings 失效
标题翻译：用于透明顶涂漆层的涂料组合物及其在生产多层漆涂料的方法中的用途
公开(公告)号：US5698330A
公开(公告)日：1997-12-16
申请号：US591485
申请日：1996-01-22
申请人： Klaus Bederke , Friedrich Herrmann , Hermann Kerber , Thomas Kutzner , Heinz Walter Reifferscheidt
发明人： Klaus Bederke , Friedrich Herrmann , Hermann Kerber , Thomas Kutzner , Heinz Walter Reifferscheidt
IPC分类号： C08G18/10 , C08G18/40 , C08G18/62 , C08G18/80 , C09D175/04 , B32B15/08 , B32B27/08 , C08F216/04 , C08F220/26
CPC分类号： C08G18/10 , C08G18/4063 , C08G18/6229 , C08G18/6254 , C08G18/8048 , C09D175/04 , Y10T428/31551 , Y10T428/31554 , Y10T428/31565 , Y10T428/31576
摘要： The present invention is directed to a coating composition for use as topcoat lacquer on a multi-layer lacquer coating for substrates such as automobile bodies and parts. The coating composition is based upon a combination of hydroxyl-functional methacrylic copolymers, carboxy-functional blocked urethane prepolymers, crosslinking agents and optional hydroxyl-functional polyesters. The carboxy-functional polyurethane prepolymer is formed from a combination of organic diols, polycarboxylic acids, polyols, hydroxyl-carboxylic acids, aliphatic or aryl polyisocyanates and monofunctional isocyanate blocking agents. The lacquer coating according to the invention has a high sulfuric acid resistance and has a high solids content.
摘要翻译： PCT No.PCT / EP95 / 01095 Sec。 371日期1996年1月22日 102（e）日期1996年1月22日PCT 1995年3月23日PCT公布。 WO95 / 26375 PCT公开日期1995年10月5日本发明涉及一种用作多层漆涂层的涂料组合物，用于诸如汽车车身和部件的基材。涂料组合物基于羟基官能的甲基丙烯酸共聚物，羧基官能的封端的氨基甲酸酯预聚物，交联剂和任选的羟基官能的聚酯的组合。羧基官能聚氨酯预聚物由有机二醇，多元羧酸，多元醇，羟基羧酸，脂族或芳基多异氰酸酯和单官能异氰酸酯封端剂的组合形成。根据本发明的漆涂层具有高耐硫酸性并且具有高的固体含量。

7. 发明授权

US4839414A Pigment dispersion and its use 失效
标题翻译：颜料分散及其用途
公开(公告)号：US4839414A
公开(公告)日：1989-06-13
申请号：US86931
申请日：1987-08-18
申请人： Klaus Bederke , Thomas Brock , Hermann Kerber , Paul Rupieper
发明人： Klaus Bederke , Thomas Brock , Hermann Kerber , Paul Rupieper
IPC分类号： B01J13/00 , B01F17/00 , B01F17/52 , C08G18/62 , C09B67/46 , C09D17/00
CPC分类号： B01F17/005 , C08G18/6266 , C09B67/009 , C09D17/00
摘要： A pigment dispersion and its use for the preparation of coating compounds are described. The dispersion contains a pigment, solvent and pigment dispersing agent. The pigment dispersing agent is a copolymer containing OH groups, obtainable by the reaction of:(A) 80 to 95% by weight of a copolymer of:(a) 0.5 to 40% by weight of N,N-di-Cl to 4-alkylamino-C.sub.1 to .sub.8 -alkyl(meth)acrylamides and/or a mixture of N,N-di-C to 4-alkylamino-C.sub.1 to 8 -alkyl(meth)acrylates and N-substituted (meth)acrylamides and/or (meth)acrylamide in which the ratio of amino(meth)acrylates to amido(meth)acrylates should be in the range of from 1:2 to 2:1,(b) 10 to 40% by weight of hydroxy-C.sub.2-8 -alkyl (meth)acrylates and(c) 20 to 89.5% by weight of copolymerizable, .alpha., .beta.-olefinically unsaturated compounds with(B) 5 to 20% by weight of a polyisocyanate containing unmasked and optionally also masked isocyanate groups as well as biuret, urethane or isocyanurate groups.
摘要翻译：描述了颜料分散体及其制备涂料化合物的用途。分散体含有颜料，溶剂和颜料分散剂。颜料分散剂是含有OH基团的共聚物，可以通过以下反应获得：（A）80〜95重量％的共聚物，其中：（a）0.5〜40重量％的N，N-2-Cl〜4 - 烷基氨基-C 1-8烷基（甲基）丙烯酰胺和/或N，N-二-C至4-烷基氨基-C 1-8烷基（甲基）丙烯酸酯和N-取代的（甲基）丙烯酰胺和/或（甲基）丙烯酸酯与酰氨基（甲基）丙烯酸酯的比率应在1:2至2:1的范围内的（甲基）丙烯酰胺，（b）10至40重量％的羟基-C 2- （甲基）丙烯酸烷基酯和（c）20至89.5重量％的可共聚的α，β-烯属不饱和化合物与（B）5至20重量％的含有未掩蔽和任选的掩蔽的异氰酸酯基团的多异氰酸酯以及缩二脲，聚氨酯或异氰脲酸酯基。

8. 发明授权

US5399383A Process for priming plastic substrates, coating compositions for this purpose, and the use thereof 失效
标题翻译：用于引发塑料基材，用于该目的的涂料组合物及其用途的方法
公开(公告)号：US5399383A
公开(公告)日：1995-03-21
申请号：US197355
申请日：1994-02-16
申请人： Manfred Mass , Klaus Bederke , Hermann Kerber
发明人： Manfred Mass , Klaus Bederke , Hermann Kerber
IPC分类号： B05D7/02 , B05D7/24 , C08G18/62 , C08J7/04 , C08L63/00 , C09D133/14 , C09D133/26 , C09D163/00 , C09D167/00 , C09D175/04 , C09D175/06
CPC分类号： C09D133/14 , C08G18/6266 , C08J7/04 , C09D133/26 , C08J2323/12 , C08L63/00
摘要： A process for priming of plastic substrates without adverse effects on the mechanical stability by applying to a plastic substrate, particularly a polyolefin substrate, a coating composition which comprises from 10 to 35% by weight of binders having an OH number of from 40 to 150, prepared from (meth)acrylamides, hydroxyalkyl (meth) acrylates and copolymerisable, olefinically unsaturated compounds with subsequent modification by means of polyisocyanates, up to 20% by weight of further binders, from 30 to 70% by weight of organic solvents, from 15 to 45% by weight of pigments and/or fillers, from 0 to 15% by weight of additives and from 1 to 30% by weight of epoxide- or polyisocyanate-based crosslinking agents.
摘要翻译：用于通过施加到塑料基材，特别是聚烯烃基材上的塑料基材的引发而不对机械稳定性产生不利影响的方法，涂料组合物包含10至35重量％的OH值为40至150的粘合剂，由（甲基）丙烯酰胺，（甲基）丙烯酸羟烷基酯和可共聚的烯属不饱和化合物制备，随后通过多异氰酸酯改性，最多20重量％的另外的粘合剂，30-70重量％的有机溶剂，从15至 45重量％的颜料和/或填料，0至15重量％的添加剂和1至30重量％的环氧化物或多异氰酸酯基交联剂。

9. 发明授权

US5136004A Binder, process for its preparation and its use in clear or pigmented coating agents 失效
标题翻译： BINDER，其制备方法及其在清除或掺杂涂料中的用途
公开(公告)号：US5136004A
公开(公告)日：1992-08-04
申请号：US391541
申请日：1990-11-13
申请人： Klaus Bederke , Hermann Kerber , Manfred Krumme , Fritz Sadowski , Werner Stephan
发明人： Klaus Bederke , Hermann Kerber , Manfred Krumme , Fritz Sadowski , Werner Stephan
IPC分类号： C08F220/06 , C08F20/32 , C08F212/00 , C08F212/08 , C08F220/04 , C08F220/10 , C08F220/18 , C08F220/26 , C08F220/28 , C08F220/32 , C08G18/62 , C09D125/00 , C09D125/04 , C09D133/04 , C09D133/06 , C09D175/04
CPC分类号： C08F220/32 , C08F212/08
摘要： The invention concerns a binder suitable for clear or pigmented coating agents. Binders based on copolymers containing hydroxyl groups have hitherto a high solvent content. The solids content of the new binders is improved without affecting the viscosity; gloss, body, flow and processing properties of coatings containing the new binders are improved. The binders consist essentially of a copolymer containing hydroxyl groups, made from specific quantities of styrol, tertbutacrylate, isobutyl methacrylate, 2-ethylhexyl methacrylate, 2-hydroxypropyl methacrylate, butanediol-1, 4-monoacrylate, acrylic acid and glycidyl esters of .alpha.-alkylalkane monocarboxylic acids and/or .alpha.,.alpha.-dialkylalkane monocarboxylic acids.
摘要翻译： PCT No.PCT / EP88 / 01097 Sec。 371日期1990年11月13日 102（e）1990年11月13日日期PCT提交1988年12月2日PCT公布。第WO89 / 05314号公报日期：1989年6月15日。本发明涉及适用于透明或着色涂层剂的粘合剂。基于含有羟基的共聚物的粘合剂迄今为止具有高溶剂含量。新粘合剂的固体含量得到改善而不影响粘度; 提高了含有新粘合剂的涂料的光泽度，体积，流动性和加工性能。粘合剂基本上由含有羟基的共聚物组成，由特定量的苯乙烯，叔丁基丙烯酸酯，甲基丙烯酸异丁酯，甲基丙烯酸2-乙基己酯，甲基丙烯酸2-羟丙酯，丁二醇-1,4-单丙烯酸酯，丙烯酸和α-烷基烷基的缩水甘油酯一元羧酸和/或α，α-二烷基烷烃一元羧酸。

10. 发明授权

US06555176B1 Sag stabilized coating compositions containing epoxy-functional crosslinking components 失效
标题翻译：含有环氧官能交联组分的凹凸稳定的涂料组合物
公开(公告)号：US06555176B1
公开(公告)日：2003-04-29
申请号：US09914219
申请日：2001-08-22
申请人： Ralf Dahm , Carmen Flosbach , Hans-Jürgen Gawin , Hermann Kerber , Apostolos Manassis , Volker Paschmann , Walter Schubert
发明人： Ralf Dahm , Carmen Flosbach , Hans-Jürgen Gawin , Hermann Kerber , Apostolos Manassis , Volker Paschmann , Walter Schubert
IPC分类号： C08J500
CPC分类号： C09D163/00 , C08L2666/04 , C08L2666/18
摘要： Coating composition containing a binder/crosslinking agent system, organic solvents, optionally together with pigments and/or extenders and conventional lacquer additives, wherein the binder/crosslinking agent system contains A) 20 to 80 wt. % of carboxy-functional (meth)acrylic copolymers and/or polyesters which are dissolved in the continuous phase of the coating composition, with an acid value of 15 to 300 mg of KOH/g, B) 80 to 20 wt. % of epoxy-functional crosslinking agents, wherein the numerical ratio between the component A) carboxyl groups and the component B) epoxy groups is between 1:1 and 1:3, and the epoxy-functional crosslinking agent B) comprises at least one epoxy-functional crosslinking component B1) which is dissolved in the continuous phase of the coating composition and at least one epoxy-functional component B2) dispersed in the continuous phase of the coating composition, wherein the numerical ratio of the epoxy groups of the crosslinking components B1) and B2) is 10:1 to 1:5 and wherein the organic solvents comprise 0 to 35 wt. % of one or more conventional organic lacquer solvents containing oxygen and 65 to 100 wt. % of one or more conventional lacquer hydrocarbons.
摘要翻译：包含粘合剂/交联剂体系的涂料组合物，有机溶剂，任选地与颜料和/或增量剂和常规漆添加剂一起，其中粘合剂/交联剂体系含有A）20至80wt。％的羧酸官能（甲基）丙烯酸共聚物和/或聚酯，其溶解在涂料组合物的连续相中，酸值为15至300mg KOH / g，B）80至20wt。％的环氧官能交联剂，其中组分A）羧基和组分B）环氧基之间的数值比在1:1至1:3之间，并且环氧官能交联剂B）包含至少一种环氧溶解在涂料组合物的连续相中的功能性交联组分B1）和分散在涂料组合物的连续相中的至少一种环氧官能组分B2），其中交联组分B1的环氧基数）和B2）为10:1至1:5，并且其中所述有机溶剂包含0至35重量％％的一种或多种常规有机漆溶剂含有氧和65至100wt。％的一种或多种常规漆油。

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