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1. 发明授权

US06613270B1 Method of forming superconducting composite article 失效
标题翻译：形成超导复合制品的方法
公开(公告)号：US06613270B1
公开(公告)日：2003-09-02
申请号：US09583304
申请日：2000-05-30
申请人： Qi Li , Gilbert N. Riley, Jr. , Lawrence J. Masur , Eric R. Podtburg , Ronald D. Parella , Martin W. Rupich , Donald R. Parker , William L. Carter , William J. Rosati , Mark D. Teplitsky
发明人： Qi Li , Gilbert N. Riley, Jr. , Lawrence J. Masur , Eric R. Podtburg , Ronald D. Parella , Martin W. Rupich , Donald R. Parker , William L. Carter , William J. Rosati , Mark D. Teplitsky
IPC分类号： H01L3900
CPC分类号： H01L39/248 , Y10T29/49014
摘要： A novel process of the production and processing of high quality, high Tc BSCCO or (Bi,Pb)SCCO superconductors starts with fabrication of a forming a bundle including a plurality of billets, each billet containing at least one filament comprising a dominant amount of an tetragonal BSCCO phase with selected intermediate phases, and substantially surrounded by a constraining metal. The bundle is thermomechanically consolidated to form a multifilamentary precursor article by applying pressure and heat to the bundle under conditions cooperatively selected to cause interdiffusion of said constraining metal at the interfaces between said metal and said filaments and substantially complete elimination of voids in said bundle, and the consolidation step is completed before any high strain longitudinal deformation is performed on the bundle. The precursor article is then heated at a second selected processing temperature in an inert atmosphere with a second selected oxygen partial pressure for a second selected time period, the second processing temperature, the second time period and the second oxygen partial pressure being cooperatively selected to form a dominant amount of an orthorhombic BSCCO phase in the reacted mixture. It may then be deformed to form an elongated precursor article of a desired texture; and thereafter heated at a third selected processing temperature in an inert atmosphere with a third selected oxygen partial pressure for a third selected time period, all cooperatively selected to convert at least a portion of the orthorhombic BSCCO phase to the final superconducting BSCCO material.
摘要翻译：高品质，高Tc BSCCO或（Bi，Pb）SCCO超导体的生产和加工的新工艺首先制造形成包括多个坯料的束，每个坯料含有至少一根细丝，其包含显着量的具有选定的中间相的四边形BSCCO相，并且基本上被约束金属包围。通过热力学机械固结所述束以通过在协同选择的条件下对所述束施加压力和热量以在所述金属和所述长丝之间的界面处引起所述约束金属的相互扩散并且基本上完全消除所述束中的空隙而形成多丝前体制品，以及在对束进行任何高应变纵向变形之前完成固结步骤。然后将前体制品在具有第二选择的氧分压的惰性气氛中的第二选定处理温度下加热第二选定的时间段，第二处理温度，第二时间段和第二氧分压协同选择以形成反应混合物中正交的BSCCO相的显着量。然后可以将其变形以形成具有所需纹理的细长的前体制品; 然后在具有第三选择的氧分压的惰性气氛中在第三选定的处理温度下加热第三选定的时间段，全部协同选择以将至少一部分正交BSCCO相转化为最终超导BSCCO材料。

2. 发明授权

US6069116A Method of forming BSCCO superconducting composite articles 失效
标题翻译：形成BSCCO超导复合材料制品的方法
公开(公告)号：US6069116A
公开(公告)日：2000-05-30
申请号：US927006
申请日：1997-09-10
申请人： Qi Li , Gilbert N. Riley, Jr. , Lawrence J. Masur , Eric R. Podtburg , Ronald D. Parrella , Martin W. Rupich , Donald R. Parker , William L. Carter , William J. Rosati , Mark D. Teplitsky
发明人： Qi Li , Gilbert N. Riley, Jr. , Lawrence J. Masur , Eric R. Podtburg , Ronald D. Parrella , Martin W. Rupich , Donald R. Parker , William L. Carter , William J. Rosati , Mark D. Teplitsky
IPC分类号： H01L39/24
CPC分类号： H01L39/248 , Y10T29/49014
摘要： A novel process of the production and processing of high quality, high T.sub.c BSCCO or (Bi,Pb)SCCO superconductors starts with fabrication of a forming a bundle including a plurality of billets, each billet containing at least one filament comprising a dominant amount of an tetragonal BSCCO phase with selected intermediate phases, and substantially surrounded by a constraining metal. The bundle is thermomechanically consolidated to form a multifilamentary precursor article by applying pressure and heat to the bundle under conditions cooperatively selected to cause interdiffusion of said constraining metal at the interfaces between said metal and said filaments and substantially complete elimination of voids in said bundle, and the consolidation step is completed before any high strain longitudinal deformation is performed on the bundle. The precursor article is then heated at a second selected processing temperature in an inert atmosphere with a second selected oxygen partial pressure for a second selected time period, the second processing temperature, the second time period and the second oxygen partial pressure being cooperatively selected to form a dominant amount of an orthorhombic BSCCO phase in the reacted mixture. It may then be deformed to form an elongated precursor article of a desired texture; and thereafter heated at a third selected processing temperature in an inert atmosphere with a third selected oxygen partial pressure for a third selected time period, all cooperatively selected to convert at least a portion of the orthorhombic BSCCO phase to the final superconducting BSCCO material.
摘要翻译：高品质，高Tc BSCCO或（Bi，Pb）SCCO超导体的生产和加工的新工艺首先制造形成包括多个坯料的束，每个坯料含有至少一根细丝，其包含显着量的具有选定的中间相的四边形BSCCO相，并且基本上被约束金属包围。通过热力学机械固结所述束以通过在协同选择的条件下对所述束施加压力和热量以在所述金属和所述长丝之间的界面处引起所述约束金属的相互扩散并且基本上完全消除所述束中的空隙而形成多丝前体制品，以及在对束进行任何高应变纵向变形之前完成固结步骤。然后将前体制品在具有第二选择的氧分压的惰性气氛中的第二选定处理温度下加热第二选定的时间段，第二处理温度，第二时间段和第二氧分压协同选择以形成反应混合物中正交的BSCCO相的显着量。然后可以将其变形以形成具有所需纹理的细长的前体制品; 然后在具有第三选择的氧分压的惰性气氛中在第三选定的处理温度下加热第三选定的时间段，全部协同选择以将至少一部分正交BSCCO相转化为最终超导BSCCO材料。

3. 发明授权

US06205645B1 Tensioning process for manufacture of superconducting ceramic composite conductors 失效
标题翻译：用于制造超导陶瓷复合导体的张紧工艺
公开(公告)号：US06205645B1
公开(公告)日：2001-03-27
申请号：US08652624
申请日：1996-05-21
申请人： Qi Li , Craig J. Christopherson , Gilbert N. Riley, Jr. , William L. Carter , William J. Michels , Eric R. Podtburg , Lawrence J. Masur
发明人： Qi Li , Craig J. Christopherson , Gilbert N. Riley, Jr. , William L. Carter , William J. Michels , Eric R. Podtburg , Lawrence J. Masur
IPC分类号： H01L3924
CPC分类号： H01L39/248 , Y10T29/49014
摘要： The combination of one or more high reduction drafts with controlled, low back tensions increases the range of deformation conditions over which dimensional tolerances and Je may be optimized. The method comprises the steps of: first, providing a precursor article comprising a metal matrix surrounding a plurality of filaments extending along the length of the article and comprising precursors to a desired superconducting ceramic; next, roll working the precursor article during a breakdown stage at a back tension less than the elastic to plastic transition threshold of the composite during at least one high reduction roll working draft, and, then, sintering the rolled article to obtain the desired superconducting ceramic. In a preferred embodiment, the rolling step further comprises rolling the article at a front tension less than the elastic to plastic transition threshold of the rolled, unsintered article.
摘要翻译：一个或多个高减速牵引力与受控的低回力张力的组合增加了尺寸公差和Je可能被优化的变形条件的范围。该方法包括以下步骤：首先，提供包含金属基体的前体制品，所述金属基质围绕沿着所述制品的长度延伸的多根长丝，并且包括所需超导陶瓷的前体; 接下来，在至少一个高还原辊工作牵伸期间，以小于复合材料的弹性 - 塑性转变阈值的后拉力在击穿阶段期间辊加工前体制品，然后烧结轧制制品以获得所需的超导陶瓷。在优选实施例中，轧制步骤还包括以低于轧制未烧结制品的弹性 - 塑性转变阈值的前拉力滚动制品。

4. 发明授权

US06305070B1 Performance of oxide dispersion strengthened superconductor composites 失效
标题翻译：氧化物分散强化超导体复合材料的性能
公开(公告)号：US06305070B1
公开(公告)日：2001-10-23
申请号：US08731302
申请日：1996-10-15
申请人： Lawrence J. Masur , Donald R. Parker , Eric R. Podtburg , Peter R. Roberts , Ronald D. Parrella , Gilbert N. Riley, Jr. , Steven Hancock
发明人： Lawrence J. Masur , Donald R. Parker , Eric R. Podtburg , Peter R. Roberts , Ronald D. Parrella , Gilbert N. Riley, Jr. , Steven Hancock
IPC分类号： H01L3924
CPC分类号： H01L39/248 , Y10S505/742 , Y10T29/49014
摘要： The invention features high performing composite superconducting oxide articles that can be produced from OPIT precursors substantially without poisoning the superconductor. In general, the superconducting oxide is substantially surrounded by a matrix material. The matrix material contains a first constraining material including a noble metal and a second metal. The second metal is a relatively reducing metal which lowers the overall oxygen activity of the matrix material and the article at a precursor process point prior to oxidation of the second metal. The second metal is substantially converted to a metal oxide dispersed in the matrix during or prior to a first phase conversion heat treatment but after formation of the composite, creating an ODS matrix.
摘要翻译：本发明的特征在于高性能复合超导氧化物制品，其可以从OPIT前体生产，而不会使超导体中毒。通常，超导氧化物基本上被基质材料包围。基质材料含有包含贵金属和第二金属的第一约束材料。第二种金属是相对还原的金属，其降低了在第二金属氧化之前的前体工艺点处的基质材料和制品的整体氧活性。在第一相转化热处理期间或之前，第二金属基本上转化为分散在基质中的金属氧化物，但是在形成复合材料之后，形成ODS基体。

5. 发明授权

US06436875B2 Performance of oxide dispersion strengthened superconductor composites 失效
标题翻译：氧化物分散强化超导体复合材料的性能
公开(公告)号：US06436875B2
公开(公告)日：2002-08-20
申请号：US09815063
申请日：2001-03-22
申请人： Lawrence J. Masur , Donald R. Parker , Eric R. Podtburg , Peter R. Roberts , Ronald D. Parrella , Gilbert N. Riley, Jr. , Steven Hancock
发明人： Lawrence J. Masur , Donald R. Parker , Eric R. Podtburg , Peter R. Roberts , Ronald D. Parrella , Gilbert N. Riley, Jr. , Steven Hancock
IPC分类号： C04B3564
CPC分类号： H01L39/248 , Y10S505/742 , Y10T29/49014
摘要： The invention features high performing composite superconducting oxide articles that can be produced from OPIT precursors substantially without poisoning the superconductor. In general, the superconducting oxide is substantially surrounded by a matrix material. The matrix material contains a first constraining material including a noble metal and a second metal. The second metal is a relatively reducing metal which lowers the overall oxygen activity of the matrix material and the article at a precursor process point prior to oxidation of the second metal. The second metal is substantially converted to a metal oxide dispersed in the matrix during or prior to a first phase conversion heat treatment but after formation of the composite, creating an ODS matrix.
摘要翻译：本发明的特征在于高性能复合超导氧化物制品，其可以从OPIT前体生产，而不会使超导体中毒。通常，超导氧化物基本上被基质材料包围。基质材料含有包含贵金属和第二金属的第一约束材料。第二种金属是相对还原的金属，其降低了在第二金属氧化之前的前体工艺点处的基质材料和制品的整体氧活性。在第一相转化热处理期间或之前，第二金属基本上转化为分散在基质中的金属氧化物，但是在形成复合材料之后，形成ODS基体。

6. 发明授权

US06310297B1 Strongly-linked oxide superconductor and a method of its manufacture 失效
标题翻译：强连接氧化物超导体及其制造方法
公开(公告)号：US06310297B1
公开(公告)日：2001-10-30
申请号：US08477456
申请日：1995-06-07
申请人： Lawrence J. Masur , Eric R. Podtburg
发明人： Lawrence J. Masur , Eric R. Podtburg
IPC分类号： H01B1200
CPC分类号： C04B35/65 , C04B35/45 , H01L39/2419 , H01L39/2477 , Y10S505/704 , Y10S505/736 , Y10S505/74 , Y10S505/742 , Y10S505/776 , Y10S505/78 , Y10S505/813 , Y10T29/49014
摘要： A strongly-linked polycrystalline oxide superconductor article includes an oxide superconductor selected from the group consisting 124-type and 247-type oxide superconductors having fine, highly aligned oxide superconductor grains less than &mgr;m long a longest dimension. The oxide superconductor article has at least a 25% retention of critical current density in a 0.1 Tesla field. A method for preparing a strongly-linked oxide superconductor includes shaping a finely divided metallic precursor of an oxide superconductor; oxidizing the finely divided metallic precursor to produce a finely divided sub-oxide species while avoiding conversion of an appreciable amount of the sub-oxide species into the oxide superconductor, annealing and deforming the article, in either order, the annealing carried out at a temperature and for a time sufficient to convert some of the sub-oxide species into fine grains of the oxide superconductor thereby forming a mixture of sub-oxide species and oxide superconductor and the deformation carried out such that the fine grains of oxide superconductor are rotated into alignment parallel to an intended current carrying direction of the article without fracturing or pulverization of the oxide superconductor grains; alternating annealing and deformation of the article until no further improvement in alignment is observed; and subjecting the aligned grains to a final anneal in order to react any remaining sub-oxide species and maximize the growth and sintering of existing aligned grains.
摘要翻译：强连接的多晶氧化物超导体制品包括选自124型和247型氧化物超导体的氧化物超导体，其具有小于长度最长尺寸的妈妈的精细高度排列的氧化物超导体晶粒。氧化物超导体制品在0.1特斯拉场中具有至少25％的临界电流密度保留。一种制备强连接的氧化物超导体的方法包括使细分的氧化物超导体的金属前体成形; 氧化细碎的金属前体以产生细碎的亚氧化物物质，同时避免将大量的次氧化物物质转化为氧化物超导体，退火和使制品变形，以任何顺序，在温度下进行退火并且足以将一些氧化物物质转化为氧化物超导体的细晶粒的时间，从而形成次氧化物种类和氧化物超导体的混合物，并进行变形，使得氧化物超导体的细晶粒旋转成对准平行于制品的预期电流输送方向，而不会破坏或粉碎氧化物超导体晶粒; 交替退火和变形，直到观察不到进一步改善; 并使对准的晶粒进行最终退火，以使任何剩余的亚氧化物物质反应并使现有对准晶粒的生长和烧结最大化。

7. 发明授权

US5472527A High pressure oxidation of precursor alloys 失效
标题翻译：前体合金的高压氧化
公开(公告)号：US5472527A
公开(公告)日：1995-12-05
申请号：US82093
申请日：1993-06-24
申请人： Alexander Otto , Lawrence J. Masur , Eric R. Podtburg , Kenneth H. Sandhage
发明人： Alexander Otto , Lawrence J. Masur , Eric R. Podtburg , Kenneth H. Sandhage
IPC分类号： C04B35/45 , C04B35/65 , H01L39/24 , H01B17/00 , H01B1/08
CPC分类号： H01L39/248 , C04B35/45 , C04B35/65 , Y10S148/035 , Y10S428/93 , Y10S505/704 , Y10S505/736 , Y10S505/785
摘要： A method for forming unsegregated metal oxide-silver composites includes preparing a precursor alloy comprising silver and precursor elements of a desired metal oxide and oxidizing the alloy under conditions of high oxygen activity selected to permit diffusion of oxygen into silver while significantly restricting the diffusion of the precursor elements into silver, such that oxidation of the precursor elements to the metal oxide occurs before diffusion of the metallic elements into silver. Further processing of the metal oxide composite affords an oxide superconducting composite with a highly unsegregated microstructure.
摘要翻译：用于形成未分离的金属氧化物 - 银复合物的方法包括制备包含银的前体合金和期望的金属氧化物的前体元素，并在选择高氧活性的条件下氧化合金，以允许氧扩散到银中，同时显着地限制前体元素变成银，使得在将金属元素扩散到银之前，前体元素氧化成金属氧化物。金属氧化物复合物的进一步处理提供具有高度未偏析的微结构的氧化物超导复合材料。

8. 发明授权

US6066599A High pressure oxidation of precursor alloys 失效
标题翻译：前体合金的高压氧化
公开(公告)号：US6066599A
公开(公告)日：2000-05-23
申请号：US469438
申请日：1995-06-06
申请人： Alexander Otto , Lawrence J. Masur , Eric R. Podtburg , Kenneth H. Sandhage
发明人： Alexander Otto , Lawrence J. Masur , Eric R. Podtburg , Kenneth H. Sandhage
IPC分类号： H01L39/14 , H01B12/00 , C04B35/00 , H01B12/10 , H01L39/24
CPC分类号： H01L39/143 , Y10T29/49014
摘要： An unsegregated metal oxide/silver composite wire is provided having a plurality of metal oxide filaments disposed within a matrix comprising silver, wherein the filaments are comprised of at least copper, and an intermediate region comprising copper oxide and silver in contact with and surrounding each of the metal oxide filaments. The intermediate region has a thickness of no greater than three microns. Each of the metal oxide filaments extends continuously for the length of the wire, and each of the metal oxide filaments is separated from adjacent filaments by the matrix.
摘要翻译：提供了一种未分离的金属氧化物/银复合线，其具有设置在包含银的基体内的多个金属氧化物细丝，其中所述长丝至少包含铜，以及包含氧化铜和银的中间区域，其与金属氧化物丝。中间区域的厚度不大于3微米。每个金属氧化物长丝连续延伸线的长度，并且每个金属氧化物细丝通过基体与相邻的长丝分离。

9. 发明授权

US5683969A Strongly-linked oxide superconductor and a method of its manufacture 失效
标题翻译：强连接氧化物超导体及其制造方法
公开(公告)号：US5683969A
公开(公告)日：1997-11-04
申请号：US881675
申请日：1992-05-12
申请人： Lawrence J. Masur , Eric R. Podtburg
发明人： Lawrence J. Masur , Eric R. Podtburg
IPC分类号： C01G1/00 , C01G3/00 , C04B35/45 , C04B35/65 , H01B13/00 , H01L39/12 , H01L39/24
CPC分类号： C04B35/65 , C04B35/45 , H01L39/2419 , H01L39/2477 , Y10S505/704 , Y10S505/736 , Y10S505/74 , Y10S505/742 , Y10S505/776 , Y10S505/78 , Y10S505/813 , Y10T29/49014
摘要： A strongly-linked polycrystalline oxide superconductor article includes an oxide superconductor selected from the group consisting 124-type and 247-type oxide superconductors having fine, highly aligned oxide superconductor grains less than 50 .mu.m along a longest dimension. The oxide superconductor article has at least a 25% retention of critical current density in a 0.1 Tesla field. A method for preparing a strongly-linked oxide superconductor includes shaping a finely divided metallic precursor of an oxide superconductor; oxidizing the finely divided metallic precursor to produce a finely divided sub-oxide species while avoiding conversion of an appreciable amount of the sub-oxide species into the oxide superconductor; annealing and deforming the article, in either order, the annealing carried out at a temperature and for a time sufficient to convert some of the sub-oxide species into fine grains of the oxide superconductor thereby forming a mixture of sub-oxide species and oxide superconductor and the deformation carried out such that the fine grains of oxide superconductor are rotated into alignment parallel to an intended current carrying direction of the article without fracturing or pulverization of the oxide superconductor grains; alternating annealing and deformation of the article until no further improvement in alignment is observed; and subjecting the aligned grains to a final anneal in order to react any remaining sub-oxide species and maximize the growth and sintering of existing aligned grains.
摘要翻译：强连接的多晶氧化物超导体制品包括选自124型和247型氧化物超导体的氧化物超导体，其具有沿着最长尺寸小于50微米的精细高度排列的氧化物超导体颗粒。氧化物超导体制品在0.1特斯拉场中具有至少25％的临界电流密度保留。一种制备强连接的氧化物超导体的方法包括使细分的氧化物超导体的金属前体成形; 氧化细碎的金属前体以产生细碎的亚氧化物物质，同时避免将相当数量的亚氧化物物质转化成氧化物超导体; 对制品进行退火和变形，以任何顺序进行退火，该退火在足以将一些氧化物物质转化为氧化物超导体的细晶粒的温度和时间进行，从而形成次氧化物物质和氧化物超导体的混合物并且进行变形，使得氧化物超导体的细晶粒在不破坏或粉碎氧化物超导体晶粒的同时使其平行于制品的预期电流方向旋转成对准; 交替退火和变形，直到观察不到进一步改善; 并使对准的晶粒进行最终退火，以使任何剩余的亚氧化物物质反应并使现有对准晶粒的生长和烧结最大化。

10. 发明授权

US06219901B1 Oxide superconductor precursors 失效
标题翻译：氧化物超导体前体
公开(公告)号：US06219901B1
公开(公告)日：2001-04-24
申请号：US08744278
申请日：1996-11-06
申请人： Eric R. Podtburg , Kenneth H. Sandhage , Alexander Otto , Lawrence J. Masur , Christopher A. Craven , Jeffrey D. Schreiber
发明人： Eric R. Podtburg , Kenneth H. Sandhage , Alexander Otto , Lawrence J. Masur , Christopher A. Craven , Jeffrey D. Schreiber
IPC分类号： H01L3924
CPC分类号： C04B35/65 , C04B35/45 , H01L39/2419 , H01L39/2477 , Y10S505/704 , Y10S505/736 , Y10S505/74 , Y10S505/742 , Y10S505/776 , Y10S505/78 , Y10S505/813 , Y10T29/49014
摘要： A composite for preparation of an oxide superconductor includes a primary alloy phase of constituent elements of a desired oxide superconductor; and a secondary phase comprising copper, the secondary phase supported by the primary alloy phase. The composite may additionally include a matrix material for supporting the primary alloy phase and second phase disposed therein. The composite is oxidized to form an oxide superconductor composite.
摘要翻译：用于制备氧化物超导体的复合材料包括期望的氧化物超导体的构成元素的主合金相; 以及包含铜的第二相，第二相由主合金相负载。复合材料还可以包括用于支撑初级合金相的基体材料和设置在其中的第二相。复合材料被氧化形成氧化物超导体复合材料。

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