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    • 3. 发明授权
    • Method of forming BSCCO superconducting composite articles
    • 形成BSCCO超导复合材料制品的方法
    • US6069116A
    • 2000-05-30
    • US927006
    • 1997-09-10
    • Qi LiGilbert N. Riley, Jr.Lawrence J. MasurEric R. PodtburgRonald D. ParrellaMartin W. RupichDonald R. ParkerWilliam L. CarterWilliam J. RosatiMark D. Teplitsky
    • Qi LiGilbert N. Riley, Jr.Lawrence J. MasurEric R. PodtburgRonald D. ParrellaMartin W. RupichDonald R. ParkerWilliam L. CarterWilliam J. RosatiMark D. Teplitsky
    • H01L39/24
    • H01L39/248Y10T29/49014
    • A novel process of the production and processing of high quality, high T.sub.c BSCCO or (Bi,Pb)SCCO superconductors starts with fabrication of a forming a bundle including a plurality of billets, each billet containing at least one filament comprising a dominant amount of an tetragonal BSCCO phase with selected intermediate phases, and substantially surrounded by a constraining metal. The bundle is thermomechanically consolidated to form a multifilamentary precursor article by applying pressure and heat to the bundle under conditions cooperatively selected to cause interdiffusion of said constraining metal at the interfaces between said metal and said filaments and substantially complete elimination of voids in said bundle, and the consolidation step is completed before any high strain longitudinal deformation is performed on the bundle. The precursor article is then heated at a second selected processing temperature in an inert atmosphere with a second selected oxygen partial pressure for a second selected time period, the second processing temperature, the second time period and the second oxygen partial pressure being cooperatively selected to form a dominant amount of an orthorhombic BSCCO phase in the reacted mixture. It may then be deformed to form an elongated precursor article of a desired texture; and thereafter heated at a third selected processing temperature in an inert atmosphere with a third selected oxygen partial pressure for a third selected time period, all cooperatively selected to convert at least a portion of the orthorhombic BSCCO phase to the final superconducting BSCCO material.
    • 高品质,高Tc BSCCO或(Bi,Pb)SCCO超导体的生产和加工的新工艺首先制造形成包括多个坯料的束,每个坯料含有至少一根细丝,其包含显着量的 具有选定的中间相的四边形BSCCO相,并且基本上被约束金属包围。 通过热力学机械固结所述束以通过在协同选择的条件下对所述束施加压力和热量以在所述金属和所述长丝之间的界面处引起所述约束金属的相互扩散并且基本上完全消除所述束中的空隙而形成多丝前体制品,以及 在对束进行任何高应变纵向变形之前完成固结步骤。 然后将前体制品在具有第二选择的氧分压的惰性气氛中的第二选定处理温度下加热第二选定的时间段,第二处理温度,第二时间段和第二氧分压协同选择以形成 反应混合物中正交的BSCCO相的显着量。 然后可以将其变形以形成具有所需纹理的细长的前体制品; 然后在具有第三选择的氧分压的惰性气氛中在第三选定的处理温度下加热第三选定的时间段,全部协同选择以将至少一部分正交BSCCO相转化为最终超导BSCCO材料。
    • 7. 发明授权
    • Method for forming bismuth-based superconducting ceramics
    • 形成铋基超导陶瓷的方法
    • US06894006B1
    • 2005-05-17
    • US10031525
    • 2000-07-21
    • Victor A. MaroniNazarali N. MerchantRonald D. Parrella
    • Victor A. MaroniNazarali N. MerchantRonald D. Parrella
    • C04B35/45C04B35/64H01B12/00H01L39/24C04B101/00
    • C04B35/4525C04B35/64H01L39/248
    • A method for reducing the concentration of non-superconducting phases during the heat treatment of Pb doped Ag/Bi-2223 composites having Bi-2223 and Bi-2212 superconducting phases is disclosed. A Pb doped Ag/Bi-2223 composite having Bi-2223 and Bi-2212 superconducting phases is heated in an atmosphere having an oxygen partial pressure not less than about 0.04 atmospheres and the temperature is maintained at the lower of a non-superconducting phase take-off temperature and the Bi-2223 superconducting phase grain growth take-off temperature. The oxygen partial pressure is varied and the temperature is varied between about 815° C. and about 835° C. to produce not less than 80 percent conversion to Pb doped Bi-2223 superconducting phase and not greater than about 20 volume percent non-superconducting phases. The oxygen partial pressure is preferably varied between about 0.04 and about 0.21 atmospheres. A product by the method is disclosed.
    • 公开了一种在具有Bi-2223和Bi-2212超导相的掺杂Pb的Ag / Bi-2223复合材料的热处理中降低非超导相浓度的方法。 具有Bi-2223和Bi-2212超导相的Pb掺杂的Ag / Bi-2223复合物在氧分压不小于约0.04大气压的气氛中加热,并且温度保持在非超导相的较低温度 Bi-2223超导相晶粒生长起飞温度。 氧分压变化,温度在约815℃和约835℃之间变化,以产生不少于80%的转化为Pb掺杂的Bi-2223超导相,并且不大于约20体积%的非超导 阶段 氧分压优选在约0.04和约0.21大气压之间变化。 公开了通过该方法的产品。