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1. 发明申请

US20080293900A1 Method for Producing Highly Reactive Isobutylene Homo-or Copolymers Using Metal-Containing Catalyst Complexes 审中-公开
标题翻译：使用含金属催化剂配合物生产高反应异丁烯均聚物或共聚物的方法
公开(公告)号：US20080293900A1
公开(公告)日：2008-11-27
申请号：US12092588
申请日：2006-11-15
申请人： Phillip Hanefeld , Marcus Sigl , Volker Bohm , Michael Roper , Hans-Michael Walter , Ingo Krossing
发明人： Phillip Hanefeld , Marcus Sigl , Volker Bohm , Michael Roper , Hans-Michael Walter , Ingo Krossing
IPC分类号： C08F2/04
CPC分类号： C07F5/062 , C08F10/10 , C08F110/10 , C08F4/12 , C08F4/14 , C08F2500/03
摘要： Preparation of highly reactive isobutene homo- or copolymers having Mn=from 500 to 1 000 000 by polymerizing isobutene in the liquid phase in the presence of a dissolved, dispersed or supported metal-containing catalyst complex by using, as the catalyst complex, a compound I Zn+[MXa(OR)b]n−·Lx (I) M metal atom from the group of boron, aluminum, gallium, indium and thallium, R each independently aliphatic, heterocyclic or aromatic hydrocarbon radicals which have in each case from 1 to 18 carbon atoms and may comprise fluorine atoms, or silyl groups comprising C1 to C18 hydrocarbon radicals, X halogen atoms, Z proton (n=1), optionally substituted ammonium (n=1) or n-valent metal cation, L neutral solvent molecules, a integer from 0 to 3, b integer from 1 to 4, where a+b=4, and x≧0.
摘要翻译：通过使用作为催化剂配合物的化合物，在溶解的，分散的或负载的含金属的催化剂配合物的存在下，通过在液相中聚合异丁烯来制备具有Mn = 500至1000000的高活性异丁烯均聚物或共聚物 I <？in-line-formula description =“In-line Formulas”end =“lead”？> Zn + [MXa（OR）b] n -.Lx（I）<？in-line-formula description = 来自硼，铝，镓，铟和铊的组中的“式”末端=“尾”→M金属原子，R各自独立地为具有1至18个碳原子的脂族，杂环或芳族烃基，并且可以包含氟原子或甲硅烷基，包括C1至C18烃基，X卤素原子，Z质子（n = 1），任选取代的铵（n = 1）或n价金属阳离子，L中性溶剂分子，到3，b从1到4的整数，其中a + b = 4，x> = 0。

2. 发明申请

US20080249267A1 Method for Producing Highly Reactive Isobutylene Homo-or Copolymers Using Boron-Containing Catalyst Complexes 审中-公开
标题翻译：使用含硼催化剂配合物生产高反应异丁烯均聚物或共聚物的方法
公开(公告)号：US20080249267A1
公开(公告)日：2008-10-09
申请号：US12092910
申请日：2006-11-15
申请人： Phillip Hanefeld , Volker Bohm , Marcus Sigl , Nina Challand , Michael Roper , Hans-Michael Walter , Brigitte Voit , Fritz Elmar Kuehn , Ahmed Hijazi , Radha Krishnan Narayanan
发明人： Phillip Hanefeld , Volker Bohm , Marcus Sigl , Nina Challand , Michael Roper , Hans-Michael Walter , Brigitte Voit , Fritz Elmar Kuehn , Ahmed Hijazi , Radha Krishnan Narayanan
IPC分类号： C08F10/10
CPC分类号： C07F5/027 , C08F10/10 , C08F110/10 , C08F4/52 , C08F2500/04
摘要： Preparation of highly reactive isobutene homo- or copolymers having Mn=from 500 to 45 000 by polymerizing isobutene in the liquid phase in the presence of a dissolved, dispersed or supported boron-containing catalyst complex, by using, as the catalyst complex, a protic acid compound I [H+]m+1[R1R2R3B—(-Am+—BR5R6—)n—R4](m+1)−.Lx (I) R1 to R6 each independently aliphatic, heterocyclic or aromatic, fluorinated hydrocarbon radicals having in each case from 1 to 18 carbon atoms, or silyl groups comprising C1 to C18 hydrocarbon radicals, A nitrogen-containing bridging member which forms covalent bonds to the boron atoms via its nitrogen atoms, L neutral solvent molecules, n=0 or 1, m=0 or 1 and x is ≧0.
摘要翻译：通过在溶解，分散或负载的含硼催化剂络合物的存在下，通过在液相中聚合异丁烯，通过使用以下方法制备具有M + n = 500至45000的高活性异丁烯均聚物或共聚物作为催化剂络合物，质子化合物I <βin-line-formula description =“In-line Formulas”end =“lead”→> [H +] + + [R 1] R 2 - - - - （3）B 3 - （ - A m + （m + 1）-L （I）<？in-line-formula description =“In-line Formulas”end =“tail”？> R＆lt; 1＆gt;至R 6＆lt; 各自独立地为具有1至18个碳原子的脂族，杂环或芳族氟化烃基，或包含C 1至C 18烃基的甲硅烷基，含氮桥连构件，其通过其氮原子与硼原子形成共价键，L中性溶剂分子，n = 0或1，m = 0 或1并且x是> = 0。

3. 发明申请

US20070083066A1 Method for the production of 1,7-octadiene and use thereof 审中-公开
标题翻译： 1,7-辛二烯的制备方法及其用途
公开(公告)号：US20070083066A1
公开(公告)日：2007-04-12
申请号：US10572077
申请日：2004-09-17
申请人： Volker Bohm , Michael Roper , Jurgen Stephan , Regina Benfer , Markus Schubert , Jorn Karl , Klaus Ebel , Oliver Lober , Martin Volland
发明人： Volker Bohm , Michael Roper , Jurgen Stephan , Regina Benfer , Markus Schubert , Jorn Karl , Klaus Ebel , Oliver Lober , Martin Volland
IPC分类号： C07C45/68 , C07C45/49 , C07C5/08
CPC分类号： C07C49/587 , C07C6/06 , C07C45/50 , C07C45/62 , C07C45/73 , C07C49/385 , C07C2521/04 , C07C2523/20 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2523/74 , C07C11/12 , C07C47/12 , C07C49/12
摘要： The invention relates to a method for the production of 1,7 octadiene by reacting metathesis of cyclohexene with ethylene. The invention also relates to the production of 1,10-decandiol by hydroformulating 1,7 octadiene produced according to said method. The invention further relates to a method for the production of muscone or olefinically unsaturated analogs thereof using 1,10 decandiol which is obtainable in said manner.
摘要翻译：本发明涉及通过使环己烯的复分解与乙烯反应制备1,7辛二烯的方法。本发明还涉及通过根据所述方法制备的1,7辛二烯加氢制备1,10-癸二醇。本发明还涉及使用可以所述方式获得的1,10-癸二醇生产肌醇或其烯属不饱和类似物的方法。

4. 发明申请

US20060052645A1 Method for producing dialdehydes and or ethylenically unsaturated monoaldehydes by hydroformylating ethylenically unsaturated compounds 失效
标题翻译：通过加氢甲酰化烯属不饱和化合物生产二醛和/或烯属不饱和单醛的方法
公开(公告)号：US20060052645A1
公开(公告)日：2006-03-09
申请号：US10527635
申请日：2003-09-12
申请人： Martin Volland , Wolfgang Ahlers , Klaus Ebel , Rocco Paciello , Michael Roper , Thomas Mackewitz , Volker Bohm , Xavier Sava , Oliver Lober , Oliver Bey , Jurgen Stephan , Frank Haese
发明人： Martin Volland , Wolfgang Ahlers , Klaus Ebel , Rocco Paciello , Michael Roper , Thomas Mackewitz , Volker Bohm , Xavier Sava , Oliver Lober , Oliver Bey , Jurgen Stephan , Frank Haese
IPC分类号： C07C45/49
CPC分类号： C07F9/6596 , C07C45/50 , C07F9/572 , C07F9/5728 , C07F9/65522 , C07F9/65586 , C07F9/65842 , C07F9/65848 , C07C47/12 , C07C47/21
摘要： The invention relates to a method for producing dialdehydes and/or ethylenically unsaturated monoaldehydes by reacting at least one compound with at least two ethylenically unsaturated double bonds with carbon monoxide and hydrogen in the presence of a hydroformylating catalyst with at least one complex of a metal of subgroup VIII. The subgroup comprises at least pnicogen chelate ligands.
摘要翻译：本发明涉及通过使至少一种化合物与至少两个烯键式不饱和双键与一氧化碳和氢气在加氢甲酰化催化剂存在下与至少一种金属与不饱和双键的金属络合物第八组。该亚组至少包含pnicogen螯合配体。

5. 发明申请

US20050143598A1 Method for producing methyl formate 失效
标题翻译：甲酸甲酯的生产方法
公开(公告)号：US20050143598A1
公开(公告)日：2005-06-30
申请号：US10511088
申请日：2003-04-15
申请人： Christoph Adami , Michael Slany , Jorn Karl , Gerd Kaibel , Martin Schafer , Peter Zehner , Michael Roper
发明人： Christoph Adami , Michael Slany , Jorn Karl , Gerd Kaibel , Martin Schafer , Peter Zehner , Michael Roper
IPC分类号： C07C67/36
CPC分类号： C07C67/36 , C07C69/06
摘要： The invention relates to a process for the preparation of methyl formate by reacting methanol with carbon monoxide at a pressure of from 0.5 to 10 MPa abs. and a temperature of from 50 to 150° C. in the presence of a metal alkoxide as catalyst in a reactor, in which a gas stream is withdrawn from the reactor, entrained methyl formate is removed from this gas stream by condensation, and all or some of the remaining gas stream is returned to the reactor as circulating-gas stream and a mean gas superficial velocity of from 1 to 20 cm/s is set in at least one region of the reactor in which the gas flows essentially in one direction.
摘要翻译：本发明涉及一种通过使甲醇与一氧化碳在0.5至10MPa abs的压力下反应制备甲酸甲酯的方法。在反应器中从作为催化剂的金属醇盐存在下的温度为50-150℃，其中将气流从反应器中排出，夹带的甲酸甲酯通过冷凝从该气流中除去，全部或一些剩余的气流作为循环气体流返回到反应器，并且在反应器的至少一个区域中设置1至20cm / s的平均气体空气速度，其中气体基本上在一个方向上流动。

6. 发明授权

US07606221B2 Network communications having endpoint device with automatic connection to iPBX 有权
标题翻译：具有自动连接到iPBX的端点设备的网络通信
公开(公告)号：US07606221B2
公开(公告)日：2009-10-20
申请号：US10996657
申请日：2004-11-24
申请人： Fredric Artru , Andy Huckridge , Marc Petit-Hugenin , Jean-Hugues Robert , Michael Roper , Philip Bednarz
发明人： Fredric Artru , Andy Huckridge , Marc Petit-Hugenin , Jean-Hugues Robert , Michael Roper , Philip Bednarz
IPC分类号： H04L12/66
CPC分类号： G06F21/10
摘要： A telephony communications approach implements an autodiscover feature that enables an endpoint device to automatically locate and establish communication with a desirable server in a web of interconnected servers. In one specific example implementation, the endpoint device is an internet-type telephone communicating with a remotely-located server in an internet-based private branch exchange. Various packet-communicating endpoint devices are adapted to communicate with the internet-based private branch exchange by adapting each to automatically broadcast its identity and, in response to receiving an assignment for the appropriated iPBX, establish communication with the internet-based private branch exchange from other packet-based servers. Other aspects of the invention are directed to approaches for distinguishing the desired internet-based private branch exchange from the other packet-based servers and implementations for assigning the appropriate iPBX.
摘要翻译：电话通信方法实现自动发现功能，其使端点设备能够自动定位并建立与互连服务器的网络中期望的服务器的通信。在一个具体示例实现中，端点设备是在基于因特网的专用小交换机中与位于远程的服务器通信的互联网型电话。各种分组通信端点设备适于通过适应每个分组通信端点设备来自动广播其身份，并且响应于接收到专用iPBX的分配来建立与基于因特网的专用小交换机的通信其他基于包的服务器。本发明的其它方面涉及用于将期望的基于互联网的私人分支交换与其他基于分组的服务器区分开来的方法以及用于分配适当的iPBX的实施方式。

7. 发明申请

US20050010067A1 Preparation for production of formic acid formates 失效
标题翻译：甲酸甲酸盐的制备
公开(公告)号：US20050010067A1
公开(公告)日：2005-01-13
申请号：US10494701
申请日：2002-10-29
申请人： Michael Slany , Martin Schafer , Jorn Karl , Michael Roper
发明人： Michael Slany , Martin Schafer , Jorn Karl , Michael Roper
IPC分类号： A23K1/16 , C07C27/02 , C07C51/09 , C07C51/41 , C07C53/02 , C07C53/06
CPC分类号： C07C51/09 , C07C53/08
摘要： A process is described for preparing acid formates in which methyl formate is reacted with water and a basic compound having a pKa of the conjugate acid of the corresponding dissociation state of ≧3 measured at 25° C. in aqueous solution, the methanol formed is separated off and, optionally, the desired acid content is set by adding formic acid.
摘要翻译：描述了一种制备酸甲酯的方法，其中甲酸甲酯与水反应，并且在25℃下在水溶液中测定的具有相应解离状态为> = 3的共轭酸的pKa的碱性化合物形成的甲醇为分离出来，任选地，通过加入甲酸来设定所需的酸含量。

8. 发明授权

US5892125A Preparation of n-butyraldehyde and/or n-butanol 失效
标题翻译：正丁醛和/或正丁醇的制备
公开(公告)号：US5892125A
公开(公告)日：1999-04-06
申请号：US793480
申请日：1997-07-23
申请人： Jurgen Kanand , Michael Roper , Rocco Paciello , Alfred Thome
发明人： Jurgen Kanand , Michael Roper , Rocco Paciello , Alfred Thome
IPC分类号： C07C27/00 , C07B61/00 , C07C29/00 , C07C29/09 , C07C29/17 , C07C31/12 , C07C45/51 , C07C45/56 , C07C47/02 , C07D295/023
CPC分类号： C07D295/023 , C07C29/00 , C07C45/516 , C07C45/56 , C07C45/562
摘要： A process for the preparation of n-butyraldehyde and/or n-butanol, in whicha) 1,3-butadiene is caused to react with an amine of the formula IR.sup.1 R.sup.2 NH, I in which R.sup.1 and R.sup.2 independently denote hydrogen, optionally substituted aliphatic or cycloaliphatic radicals, or aryl or aralkyl radicals or are linked to form a bridging member which can contain hetero atoms, at elevated temperature and under superatmospheric pressure in the presence of a compound of a Group VIIIb element and in the presence of an alkali metal amide or a basic metal oxide to form a mixture of the adducts of the formulas II ##STR1## and III ##STR2## b) the adduct III is isomerized to the adduct II, c) the adduct II is isomerized in the presence of a homogeneous or heterogeneous transition metal element catalyst in the liquid phase or in the presence of a heterogeneous catalyst containing a transition metal element in the gaseous phase to form the enamine of the formula IV ##STR3## and d) n-butyraldehyde and/or n-butanol is/are produced from this enamine.
摘要翻译： PCT No.PCT / EP95 / 03358 Sec。 371日期1997年7月23日 102（e）日期1997年7月23日PCT 1995年8月24日PCT PCT。出版物WO96 / 07630 日期：1996年3月14日制备正丁醛和/或正丁醇的方法，其中a）使1,3-丁二烯与式ⅠR1R2NH，Ⅰ的胺反应，其中R1和R2独立地为表示氢，任选取代的脂族或脂环族基团，或芳基或芳烷基，或连接形成可含有杂原子的桥连构件，在高温和超大气压下，在VIIIb族元素的化合物存在下，存在碱金属酰胺或碱性金属氧化物以形成式II II和III III的加合物的混合物b）加合物III异构化为加合物II，c）加合物II为在均相或非均相过渡金属元素催化剂存在下在液相中或在气相中含有过渡金属元素的多相催化剂存在下异构化，形成式IV的烯胺IV和d）n -但从该烯胺产生乙醛和/或正丁醇。

9. 发明申请

US20080176782A1 Production of (Co)Surfactants by Reacting Polyols With Olefins 有权
标题翻译：通过与烯烃反应多元醇制备（Co）表面活性剂
公开(公告)号：US20080176782A1
公开(公告)日：2008-07-24
申请号：US11911028
申请日：2006-04-05
申请人： Jurgen Stephan , Michael Roper , Thomas Heidemann , Michael Triller , Jurgen Tropsch
发明人： Jurgen Stephan , Michael Roper , Thomas Heidemann , Michael Triller , Jurgen Tropsch
IPC分类号： C11D1/66 , C07C41/06 , C07C43/13
CPC分类号： C07C41/06 , C07C43/135 , C08G65/329 , C11D1/72 , C11D1/721 , C11D3/3707 , Y02P20/582
摘要： The present invention relates to a process for preparing polyol alkyl ethers by reacting compounds comprising at least three hydroxyl functionalities with olefins in the presence of acidic catalysts at temperatures of from 20 to 250° C. and pressures of from 0.5 to 10 bar, wherein the olefins correspond to the general formula (I) in which R1 is hydrogen and R2 is a linear or branched carbon radical having from 7 to 28 carbon atoms, or R1 and R2 are each linear or branched carbon radicals having from 1 to 27 carbon atoms, the sum of the carbon number of R1 and R2 being at most 28, to polyol alkyl ethers derived from compounds having at least three hydroxyl functionalities, not more than all but one hydroxyl functionality being replaced by a moiety of the general formula (VIII) to the use of these polyol alkyl ethers as surfactants and to laundry detergents and cleaning compositions comprising these polyol alkyl ethers.
摘要翻译：本发明涉及一种制备多元醇烷基醚的方法，该方法是在20至250℃的温度和0.5至10巴的压力下，在酸性催化剂存在下，使包含至少三个羟基官能团的化合物与烯烃反应，烯烃对应于其中R 1为氢且R 2为具有7至28个碳原子的直链或支链碳基团的通式（I），或R' SUP 1和R 2各自为具有1至27个碳原子的直链或支链碳原子，R 1和R 2的碳数之和至少28个的多元醇烷基醚衍生自具有至少三个羟基官能团的化合物，不超过一个羟基官能团，除了一个羟基官能团被通式（VIII）的部分替代为使用的这些多元醇烷基醚作为表面活性剂和洗涤剂和包含这些多元醇烷基醚的清洁组合物。

10. 发明申请

US20070142258A1 Method for producing alkylaryl compounds 审中-公开
标题翻译：烷基芳基化合物的制备方法
公开(公告)号：US20070142258A1
公开(公告)日：2007-06-21
申请号：US10583140
申请日：2004-12-17
申请人： Ulrich Steinbrenner , Thomas Heidemann , Michael Roper , Jurgen Stephan , Thomas Narbeshuber , Jurgen Tropsch , Nils Bottke , Regina Benfer
发明人： Ulrich Steinbrenner , Thomas Heidemann , Michael Roper , Jurgen Stephan , Thomas Narbeshuber , Jurgen Tropsch , Nils Bottke , Regina Benfer
IPC分类号： C09D9/00
CPC分类号： C07C6/04 , C07C2/08 , C07C2/66 , C07C5/2506 , C07C303/06 , C11D1/22 , C11D11/04 , C07C309/31 , C07C11/02 , C07C11/10 , C07C15/107
摘要： The preparation of alkylaryl compounds takes place by a) reaction of a C4/C5-olefin mixture over a metathesis catalyst to prepare a C4-8-olefin mixture comprising 2-pentene, and optional removal of the C4-8-olefin mixture, b) removal of from 5 to 100% of the 2-pentene present in stage a) and subsequent reaction over an isomerization catalyst to give a mixture of 2-pentene and 1-pentene which is returned to stage a), c) dimerization of the C4-8-olefin mixture obtained in stage b) following removal in the presence of a dimerization catalyst to give a mixture containing C8-16-olefins, removal of these C8-16-olefins and optional removal of a partial stream thereof, d) reaction of the c8-16-olefin mixtures obtained in stage c) or of the partial stream with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds where, prior to the reaction, 0 to 60% by weight, based on the c8-16-olefin mixtures obtained in stage c), of linear olefins may additionally be added, e) optional sulfonation of the alkyl aromatic compounds obtained in stage d) and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, 0 to 60% by weight, based on the alkyl aromatic compounds obtained in stage d), of linear alkylbenzenes may additionally be added if no admixing has taken place in stage d), f) optional mixing of the alkylarylsulfonates obtained in stage e) with 0 to 60% by weight, based on the alkylarylsulfonates obtained in stage e), of linear alkylarylsulfonate, if no admixing has taken place in stages d) and e).
摘要翻译：烷基芳基化合物的制备通过以下步骤进行：a）在复分解催化剂上使C 4-14 C 5 -C 5 - 烯烃混合物反应以制备C 4-8 - 其包含2-戊烯，任选地除去C 4-18α-烯烃混合物，b）除去在步骤a）中存在的5-100％的2-戊烯，并随后在异构化催化剂上反应，得到2-戊烯和1-戊烯的混合物，将其返回到a）步骤，c）在步骤b中获得的C 4-18α-烯烃混合物的二聚反应），在二聚催化剂存在下除去，得到含有C 8-16 - 烯烃的混合物，除去这些C 8-16 - 烯烃并任选地除去其部分流，d）在烷基化催化剂存在下，将阶段c）或部分流中获得的C 8-16 - α-烯烃混合物与芳族烃反应，形成烷基芳族化合物，其中在反应之前，0至60重量％，b 在阶段c）中得到的C 8-16α-烯烃混合物中，可以另外加入线性烯烃，e）任选的在步骤d）中获得的烷基芳族化合物磺化，中和得到烷基芳基磺酸盐，其中在磺化之前，如果在步骤d）中没有混合，则可以另外加入基于直链烷基苯中得到的直链烷基苯0至60重量％，f）任选混合如果在阶段d）和e）中没有混合，则在阶段e）中获得的烷基芳基磺酸盐以0至60重量％的量计，基于阶段e）中得到的烷基芳基磺酸盐，为直链烷基芳基磺酸盐。

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