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1. 发明申请

US20080221285A1 Solvent-Stable Metal Complexes Having Slightly Coordinating Counter Anions as Polymerisation Catalysts 审中-公开
标题翻译：具有轻微配位计数阴离子作为聚合催化剂的溶剂稳定金属络合物
公开(公告)号：US20080221285A1
公开(公告)日：2008-09-11
申请号：US11997912
申请日：2006-08-11
申请人： Hans-Michael Walter , Mirjam Herrlich-Loos , Fritz Elmar Kuehn , Yanmei Zhang , Brigitte Voit , Radha Krishnan Narayanan
发明人： Hans-Michael Walter , Mirjam Herrlich-Loos , Fritz Elmar Kuehn , Yanmei Zhang , Brigitte Voit , Radha Krishnan Narayanan
IPC分类号： C08F4/06 , C07F11/00
CPC分类号： B01J31/1805 , B01J2231/12 , B01J2531/64
摘要： The invention relates to a solvent-stable metal catalyst having slightly coordinating counter anions of formula I [M(L)a(Z)b]m+m(A−)(I), wherein M represents a transition metal of groups 3-12 of the periodic system, a lanthanide or a metal of groups 2 or 13 of the periodic system; L represents a solvent molecule; Z represents a mono or polycharged ligand; A− represents a slightly or non coordinated anion; a represents a whole number which is greater than or equal to 1; b represents a whole number which is greater than or equal to 1, whereby the total from a and b is between 4 and 8, and m represents a whole number from 1 6. The invention also relates to a method for polymerising olefinically unsaturated compounds in the presence of said catalyst and copolymers which are made of monomers comprising isobutene and at least one vinylaromatic compound which is obtained according to said inventive method.
摘要翻译：本发明涉及一种溶剂稳定的金属催化剂，其具有式I的轻微配位的反阴离子[M（L）a（Z）b + m + （I），其中M表示周期系统的基团3-12的过渡金属，镧系元素或周期性体系的基团2或13的金属; L表示溶剂分子; Z表示单或多电荷配体; A 表示轻度或非配位的阴离子; a表示大于或等于1的整数; b表示大于或等于1的整数，其中a和b的总数在4和8之间，m表示从1 6起的整数。本发明还涉及一种聚合烯属不饱和化合物的方法，所述催化剂和共聚物的存在由根据本发明方法获得的包含异丁烯和至少一种乙烯基芳族化合物的单体制成。

2. 发明申请

US20080249267A1 Method for Producing Highly Reactive Isobutylene Homo-or Copolymers Using Boron-Containing Catalyst Complexes 审中-公开
标题翻译：使用含硼催化剂配合物生产高反应异丁烯均聚物或共聚物的方法
公开(公告)号：US20080249267A1
公开(公告)日：2008-10-09
申请号：US12092910
申请日：2006-11-15
申请人： Phillip Hanefeld , Volker Bohm , Marcus Sigl , Nina Challand , Michael Roper , Hans-Michael Walter , Brigitte Voit , Fritz Elmar Kuehn , Ahmed Hijazi , Radha Krishnan Narayanan
发明人： Phillip Hanefeld , Volker Bohm , Marcus Sigl , Nina Challand , Michael Roper , Hans-Michael Walter , Brigitte Voit , Fritz Elmar Kuehn , Ahmed Hijazi , Radha Krishnan Narayanan
IPC分类号： C08F10/10
CPC分类号： C07F5/027 , C08F10/10 , C08F110/10 , C08F4/52 , C08F2500/04
摘要： Preparation of highly reactive isobutene homo- or copolymers having Mn=from 500 to 45 000 by polymerizing isobutene in the liquid phase in the presence of a dissolved, dispersed or supported boron-containing catalyst complex, by using, as the catalyst complex, a protic acid compound I [H+]m+1[R1R2R3B—(-Am+—BR5R6—)n—R4](m+1)−.Lx (I) R1 to R6 each independently aliphatic, heterocyclic or aromatic, fluorinated hydrocarbon radicals having in each case from 1 to 18 carbon atoms, or silyl groups comprising C1 to C18 hydrocarbon radicals, A nitrogen-containing bridging member which forms covalent bonds to the boron atoms via its nitrogen atoms, L neutral solvent molecules, n=0 or 1, m=0 or 1 and x is ≧0.
摘要翻译：通过在溶解，分散或负载的含硼催化剂络合物的存在下，通过在液相中聚合异丁烯，通过使用以下方法制备具有M + n = 500至45000的高活性异丁烯均聚物或共聚物作为催化剂络合物，质子化合物I <βin-line-formula description =“In-line Formulas”end =“lead”→> [H +] + + [R 1] R 2 - - - - （3）B 3 - （ - A m + （m + 1）-L （I）<？in-line-formula description =“In-line Formulas”end =“tail”？> R＆lt; 1＆gt;至R 6＆lt; 各自独立地为具有1至18个碳原子的脂族，杂环或芳族氟化烃基，或包含C 1至C 18烃基的甲硅烷基，含氮桥连构件，其通过其氮原子与硼原子形成共价键，L中性溶剂分子，n = 0或1，m = 0 或1并且x是> = 0。

3. 发明授权

US5037961A Polymerizable aryldiazosulphonates diazosulphonate groups and ethylenically unsaturated groups bound to aromatic radicals 失效
标题翻译：可聚合的芳基重氮磺酸盐，重氮磺酸盐基团和与烯基结合的烯属不饱和基团
公开(公告)号：US5037961A
公开(公告)日：1991-08-06
申请号：US336877
申请日：1989-04-12
申请人： Oskar Nuyken , Thomas Knepper , Brigitte Voit , Stephen D. Pask
发明人： Oskar Nuyken , Thomas Knepper , Brigitte Voit , Stephen D. Pask
IPC分类号： C07C381/00 , C08F12/00 , C08F12/30 , C08F246/00 , G03F7/029
CPC分类号： C08F12/30 , C07C381/00 , C08F246/00 , G03F7/029 , Y10S534/03
摘要： Aryldiazosulphonates having polymerizable ethylenically unsaturated groups are excellent starting materials for water-soluble homopolymers and copolymers, which can be converted to water-soluble polymers by irradiation. Thus, the polymers can be utilized for the preparation of aqueous coating compositions.
摘要翻译：具有可聚合烯键式不饱和基团的芳基二磺酸盐是水溶性均聚物和共聚物的优异原料，可通过照射转化成水溶性聚合物。因此，聚合物可用于制备水性涂料组合物。

4. 发明授权

US5506085A Thermal imaging element 失效
标题翻译：热成像元件
公开(公告)号：US5506085A
公开(公告)日：1996-04-09
申请号：US442828
申请日：1995-05-17
申请人： Marc Van Damme , Joan Vermeersch , Johan Lamotte , Oskar Nuyken , Brigitte Voit , Armin Lang , Cliff Scherer , Andreas Baindl , Jurgen Stebani , Alexander Wokaun , Andrej Stasko
发明人： Marc Van Damme , Joan Vermeersch , Johan Lamotte , Oskar Nuyken , Brigitte Voit , Armin Lang , Cliff Scherer , Andreas Baindl , Jurgen Stebani , Alexander Wokaun , Andrej Stasko
IPC分类号： B41C1/10 , B41M5/24 , B41M5/36 , C08G69/00 , G03F7/039 , G03C1/76
CPC分类号： G03F7/039 , B41C1/1033 , B41M5/24 , B41M5/368 , C08G69/00
摘要： A new type of thermal imaging element containing a thermally degradable polymer and a radiation to heat converting substance is disclosed. The invention further comprises several methods for the formation of a heat mode image after image-wise exposure of the thermal imaging element to intense laser radiation.
摘要翻译：公开了一种新型的含有可热降解聚合物和辐射至热转化物质的热成像元件。本发明还包括几种用于在热成像元件对强激光辐射进行成像曝光之后形成加热模式图像的方法。

5. 发明授权

US5232780A Microcapsules with a polymeric capsule wall 失效
标题翻译：微胶囊与聚合胶囊
公开(公告)号：US5232780A
公开(公告)日：1993-08-03
申请号：US776279
申请日：1991-12-18
申请人： Oskar Nuyken , Brigitte Voit , Jochen Dauth
发明人： Oskar Nuyken , Brigitte Voit , Jochen Dauth
IPC分类号： B01J13/14 , B01J13/16 , B01J13/20 , B41M5/24 , B41M5/26 , C08G69/26
CPC分类号： B01J13/203 , B01J13/16 , Y10T428/2985
摘要： In microcapsules with a polymeric capsule wall, the polymer of the capsule wall comprises thermolabile predetermined breaking points in the form of hexamethylenetetramine or acetaldehyde ammonia derivatives in order to facilitate release of the capsule contents (various active substances, such as example, dyes, medicaments, developers, curing agents, flameproofing agents) in a specific manner by exposure to heat.
摘要翻译：在具有聚合物胶囊壁的微胶囊中，胶囊壁的聚合物包含六亚甲基四胺或乙醛氨衍生物形式的不耐热预定断裂点，以便于胶囊内容物的释放（各种活性物质，例如染料，药物，开发商，固化剂，防火剂）以特定的方式暴露于热。

6. 发明申请

US20100292422A1 METHOD FOR PRODUCING COPOLYMERS MADE FROM ISOBUTENE AND AT LEAST ONE VINYLAROMATIC COMPONENT 审中-公开
标题翻译：从ISOBUTENE和至少一种乙烯基成分制备共聚物的方法
公开(公告)号：US20100292422A1
公开(公告)日：2010-11-18
申请号：US12063034
申请日：2006-08-11
申请人： Hans Peter Rath , Hans-Michael Walter , Oskar Nuyken , Fritz Elmar Kuehn , Yanmei Zhang , Hui Yee Yeong , Brigitte Voit , Radha Krishnan Narayanan
发明人： Hans Peter Rath , Hans-Michael Walter , Oskar Nuyken , Fritz Elmar Kuehn , Yanmei Zhang , Hui Yee Yeong , Brigitte Voit , Radha Krishnan Narayanan
IPC分类号： C08F4/44
CPC分类号： C08F8/00 , C08F210/10 , C08K3/00 , C08L23/22 , C08F10/00 , C08F4/695 , C08F212/08
摘要： The invention relates to a method for producing copolymers made from isobutene and at least one vinylaromatic component. Said method consists of polymerising isobutene or a hydrocarbon mixture containing isobutene with at least one vinylaromatic compound in the presence of a solvent-stable transistion metal complex comprising slightly co-ordinating anions as a polymerisation catalyst. The invention also relates to copolymers made of isobutene and at least one vinylaromatic compound, which can be obtained by means of said inventive method, in addition to specific functionalisation products therefrom.
摘要翻译：本发明涉及一种由异丁烯和至少一种乙烯基芳族成分制备共聚物的方法。所述方法包括将异丁烯或含有异丁烯的烃混合物与至少一种乙烯基芳族化合物在溶剂稳定的转移金属络合物存在下聚合，所述络合物包含稍微配位的阴离子作为聚合催化剂。本发明还涉及由异丁烯和至少一种乙烯基芳族化合物制成的共聚物，其可以通过所述本发明方法获得，除了其中的特定的官能化产物。

7. 发明授权

US07767130B2 Method and device for production of a three-dimensional article 有权
标题翻译：用于生产三维制品的方法和装置
公开(公告)号：US07767130B2
公开(公告)日：2010-08-03
申请号：US11569537
申请日：2005-05-24
申请人： Philip Elsner , Stefan Dreher , Ingo Ederer , Brigitte Voit , Janke Gudrun , Michael Stephan
发明人： Philip Elsner , Stefan Dreher , Ingo Ederer , Brigitte Voit , Janke Gudrun , Michael Stephan
IPC分类号： B28B1/16
CPC分类号： B41M3/16 , B29C64/112 , B29C64/165 , B33Y10/00 , B33Y70/00
摘要： The invention relates to a method and device for production of a three-dimensional article from a material, by means of layered application. According to the invention, a dropwise application is carried out, whereby drops of reaction components are ejected by a nozzle arrangement (3) and applied to a base reaction component (2), arranged on a substrate (1). The material for the three-dimensional article is formed in layers, with reaction of the base reaction component (2) with reaction components on contact, whereby the material is formed on a reaction of the base reaction component with one of the reaction components to give a material with one material property and on another reaction of the base reaction component with another of the reaction components to give a material with another material property. On production of the three-dimensional article, an article section is produced in which a gradual transition between the one material property and the other material property is generated.
摘要翻译：本发明涉及通过分层应用从材料制造三维制品的方法和装置。根据本发明，进行滴液处理，由喷嘴装置（3）喷射反应组分，并将其施加到设置在基板（1）上的基础反应组分（2）上。三维制品的材料是由基础反应组分（2）与反应组分接触反应而形成的，由此在碱反应组分与一种反应组分的反应中形成材料，得到具有一种材料性质的材料，以及碱反应组分与另一种反应组分的另一反应，得到具有另一材料性质的材料。在三维制品的制造中，制造其中产生一种材料性质和另一种材料性质之间的逐渐过渡的制品部分。

8. 发明申请

US20080233302A1 Method and Device for Production of a Three-Dimensional Article 有权
标题翻译：三维文章制作方法与装置
公开(公告)号：US20080233302A1
公开(公告)日：2008-09-25
申请号：US11569537
申请日：2005-05-24
申请人： Philip Elsner , Stefan Dreher , Ingo Ederer , Brigitte Voit , Janke Gudrun , Michael Stephan
发明人： Philip Elsner , Stefan Dreher , Ingo Ederer , Brigitte Voit , Janke Gudrun , Michael Stephan
IPC分类号： B05D5/00
CPC分类号： B41M3/16 , B29C64/112 , B29C64/165 , B33Y10/00 , B33Y70/00
摘要： The invention relates to a method and device for production of a three-dimensional article from a material, by means of layered application. According to the invention, a dropwise application is carried out, whereby drops of reaction components are ejected by a nozzle arrangement (3) and applied to a base reaction component (2), arranged on a substrate (1). The material for the three-dimensional article is formed in layers, with reaction of the base reaction component (2) with reaction components on contact, whereby the material is formed on a reaction of the base reaction component with one of the reaction components to give a material with one material property and on another reaction of the base reaction component with another of the reaction components to give a material with another material property. On production of the three-dimensional article, an article section is produced in which a gradual transition between the one material property and the other material property is generated.
摘要翻译：本发明涉及通过分层应用从材料制造三维制品的方法和装置。根据本发明，进行滴液处理，由喷嘴装置（3）喷射反应组分，并将其施加到设置在基板（1）上的基础反应组分（2）上。三维制品的材料是由基础反应组分（2）与反应组分接触反应而形成的，由此在碱反应组分与一种反应组分的反应中形成材料，得到具有一种材料性质的材料，以及碱反应组分与另一种反应组分的另一反应，得到具有另一材料性质的材料。在三维制品的制造中，制造其中产生一种材料性质和另一种材料性质之间的逐渐过渡的制品部分。

9. 发明授权

US5548070A Organosilicon compounds having triazene groups 失效
标题翻译：具有三烯基的有机硅化合物
公开(公告)号：US5548070A
公开(公告)日：1996-08-20
申请号：US276926
申请日：1994-07-19
申请人： Jochen Dauth , Bernward Deubzer , Elfriede Mayer , Oskar Nuyken , Brigitte Voit , Ralf Kollefrath
发明人： Jochen Dauth , Bernward Deubzer , Elfriede Mayer , Oskar Nuyken , Brigitte Voit , Ralf Kollefrath
IPC分类号： C07F7/10 , C07F7/08 , C08F283/12 , C08F293/00 , C08F297/00 , C08G77/26 , C08G77/38 , C08G77/388 , C08G77/398 , C07C245/00
CPC分类号： C07F7/0854 , C08G77/26 , C08G77/388 , C08G77/398
摘要： The organosilicon compounds have at least one Si--C-bonded organic radical which contains at least one triazene group. The organosilicon compounds can be employed as heat- and light-unstable free radical initiators for the preparation of homo-, graft co- and block copolymers from olefinically unsaturated compounds and for crosslinking organosilicon compounds and organic compounds which can be polymerized by free radical polymerization.
摘要翻译：有机硅化合物具有至少一个含有至少一个三烯基的Si-C键合的有机基团。有机硅化合物可用作热和光不稳定的自由基引发剂，用于从烯属不饱和化合物制备均聚物，接枝共聚物和嵌段共聚物，并用于交联可通过自由基聚合聚合的有机硅化合物和有机化合物。

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