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1. 发明申请

US20110245489A1 METHOD OF INCREASING ANHYDROSUGARS, PYROLIGNEOUS FRACTIONS AND ESTERIFIED BIO-OIL 有权
标题翻译：增加非糖基化合物的方法，分离纯化的生物油
公开(公告)号：US20110245489A1
公开(公告)日：2011-10-06
申请号：US12896797
申请日：2010-10-01
申请人： Philip H. Steele , Fei Yu , Qi Li , Brian Mitchell
发明人： Philip H. Steele , Fei Yu , Qi Li , Brian Mitchell
IPC分类号： C07H1/06 , B01J19/00
CPC分类号： C10L1/02 , B01J21/12 , B01J23/755 , C10C5/00 , C10G2300/1011 , C10K1/04 , Y02E50/13 , Y02E50/14 , Y02E50/32 , Y02P30/20
摘要： The device and method of this invention provides a means to increase anhydrosugars yield during pyrolysis of biomass. This increase is achieved by injection of a liquid or gas into the vapor stream of any pyrolysis reactor prior to the reactor condensers. A second novel feature of our technology is the utilization of sonication, microwave excitation or shear mixing of the biomass to increase the acid catalyst rate for demineralization or removal of hemicellulose prior to pyrolysis. The increased reactivity of these treatments reduces reaction time as well as the required amount of catalyst to less than half of that otherwise required. A fractional condensation system employed by our pyrolysis reactor is also a novel element of our technology. This system condenses bio-oil pyrolysis vapors to various desired fractions by differential temperature manipulation of individual condensers comprising a condenser chain.
摘要翻译：本发明的装置和方法提供了在生物质热解过程中增加脱氢蔗糖产量的方法。这种增加通过在反应器冷凝器之前将液体或气体注入任何热解反应器的蒸汽流中来实现。我们的技术的第二个新特征是利用超声波，微波激发或剪切混合生物质，以提高酸解催化剂的速率，以便在热解之前脱盐或除去半纤维素。这些处理的反应性增加将反应时间以及所需量的催化剂减少到少于另外所需催化剂的一半。我们的热解反应器采用的分级冷凝系统也是我们技术的一个新颖元素。该系统通过对包括冷凝器链的各个冷凝器的差温控制将生物油热解蒸汽冷凝成各种所需馏分。

2. 发明授权

US08920609B2 Method of increasing anhydrosugars, pyroligneous fractions and esterified bio-oil 有权
$Method of increasing anhydrosugars, pyroligneous fractions and esterified bio-oil$
标题翻译：增加脱水糖，木酚馏分和酯化生物油的方法
公开(公告)号：US08920609B2
公开(公告)日：2014-12-30
申请号：US12896797
申请日：2010-10-01
申请人： Philip H. Steele , Fei Yu , Qi Li , Brian Mitchell
发明人： Philip H. Steele , Fei Yu , Qi Li , Brian Mitchell
IPC分类号： B01D3/14 , C10K1/04 , C10L1/02 , C10C5/00 , B01J21/12 , B01J23/755
CPC分类号： C10L1/02 , B01J21/12 , B01J23/755 , C10C5/00 , C10G2300/1011 , C10K1/04 , Y02E50/13 , Y02E50/14 , Y02E50/32 , Y02P30/20
摘要： The device and method are provided to increase anhydrosugars yield during pyrolysis of biomass. This increase is achieved by injection of a liquid or gas into the vapor stream of any pyrolysis reactor prior to the reactor condensers. A second feature of our technology is the utilization of sonication, microwave excitation, or shear mixing of the biomass to increase the acid catalyst rate for demineralization or removal of hemicellulose prior to pyrolysis. The increased reactivity of these treatments reduces reaction time as well as the required amount of catalyst to less than half of that otherwise required. A fractional condensation system employed by our pyrolysis reactor is another feature of our technology. This system condenses bio-oil pyrolysis vapors to various desired fractions by differential temperature manipulation of individual condensers comprising a condenser chain.
摘要翻译：提供该装置和方法以增加生物质热解过程中的脱氢糖产量。这种增加通过在反应器冷凝器之前将液体或气体注入任何热解反应器的蒸汽流中来实现。我们的技术的第二个特点是利用超声处理，微波激发或剪切混合生物质，以提高酸解催化剂的速率，以便在热解前脱盐或除去半纤维素。这些处理的反应性增加将反应时间以及所需量的催化剂减少到少于另外所需催化剂的一半。我们的热解反应器采用的分级冷凝系统是我们技术的另一个特点。该系统通过对包括冷凝器链的各个冷凝器的差温控制将生物油热解蒸汽冷凝成各种所需馏分。

3. 发明申请

US20140073827A1 UPGRADING OF BIO-OIL USING SYNTHESIS GAS 审中-公开
标题翻译：使用合成气升级生物油
公开(公告)号：US20140073827A1
公开(公告)日：2014-03-13
申请号：US14022077
申请日：2013-09-09
申请人： Philip H. Steele , Sanjeev K. Gajjela , Todd Mlsna , Charles U. Pittman, JR. , Fei Yu
发明人： Philip H. Steele , Sanjeev K. Gajjela , Todd Mlsna , Charles U. Pittman, JR. , Fei Yu
IPC分类号： C10G3/00
CPC分类号： C10G3/52 , C10G3/45 , C10G3/46 , C10G2300/1014 , Y02P30/20
摘要： A method for producing biofuel and other hydrocarbons from bio-oil is disclosed. The method does not require the use of hydrogen derived from fossil fuel.
摘要翻译：公开了一种从生物油生产生物燃料和其他烃的方法。该方法不需要使用源自化石燃料的氢。

4. 发明申请

US20120228112A1 THERMAL TRANSFER MECHANISMS FOR AN AUGER PYROLYSIS REACTOR 审中-公开
标题翻译：高温热解反应器的热转移机理
公开(公告)号：US20120228112A1
公开(公告)日：2012-09-13
申请号：US13043340
申请日：2011-03-08
申请人： Philip H. Steele , Brian Mitchell
发明人： Philip H. Steele , Brian Mitchell
IPC分类号： C10B51/00
CPC分类号： C10B53/02 , C10B7/10 , C10B47/44 , C10B51/00 , C10B57/06 , C10C5/00 , C10L9/083 , Y02E50/14 , Y02E50/15 , Y02P30/20
摘要： An improved method of providing heat to a pyrolysis reactor is disclosed. A solid heat carrier produces fast pyrolysis vapors during transport of the solid heat carrier/feedstock mixture down the shell of the main reactor tube by the reactor tube auger. These vapors are drawn from the main reactor tube by a slight vacuum pressure and are condensed in a multiple condenser train comprised of shell and tube condensers cooled by water or other means.
摘要翻译：公开了一种向热解反应器提供热量的改进方法。在固体热载体/原料混合物通过反应器管螺旋钻运送主反应器管的壳体之前，固体热载体产生快速的热解蒸汽。这些蒸气通过轻微的真空压力从主反应器管中抽出，并在由冷凝水或其它装置的壳和冷凝器组成的多个冷凝器列中冷凝。

5. 发明授权

US09133341B2 Methods for producing binders and combustible composite materials and compositions produced therefrom 有权
标题翻译：用于生产粘合剂和可燃复合材料的方法及由其制备的组合物
公开(公告)号：US09133341B2
公开(公告)日：2015-09-15
申请号：US13367138
申请日：2012-02-06
申请人： Philip H. Steele , Venkata K. Penmetsa
发明人： Philip H. Steele , Venkata K. Penmetsa
IPC分类号： C10L1/00 , C08L89/00 , C08L91/00
CPC分类号： C08L89/00 , C08L91/00 , C08L97/005
摘要： Methods and compositions are provided for producing thermoset, water repellent binders particularly effective for forming combustible composite materials. The binders include a mixture of an alkaline protein hydrolyzate and a bio-oil or an acidic protein hydrolyzate and a lignin compound. Desirably, the binders and the resulting combustible composite materials are substantially free of formaldehyde.
摘要翻译：提供了用于生产热固性防水粘合剂的方法和组合物，其特别有效地用于形成可燃复合材料。粘合剂包括碱性蛋白水解物和生物油或酸性蛋白质水解物和木质素化合物的混合物。理想地，粘合剂和所得到的可燃复合材料基本上不含甲醛。

6. 发明申请

US20110192072A1 METHOD TO UPGRADE BIO-OILS TO FUEL AND BIO-CRUDE 有权
标题翻译：将生物油升级为燃料和生物试剂的方法
公开(公告)号：US20110192072A1
公开(公告)日：2011-08-11
申请号：US12896741
申请日：2010-10-01
申请人： Philip H. Steele , Charles U. Pittman, JR. , Leonard L. Ingram, JR. , Sanjeev Gajjela , Zhijun Zhang , Priyanka Bhattacharya
发明人： Philip H. Steele , Charles U. Pittman, JR. , Leonard L. Ingram, JR. , Sanjeev Gajjela , Zhijun Zhang , Priyanka Bhattacharya
IPC分类号： C10L1/00 , B01J8/00
CPC分类号： C10L1/02 , B01J21/12 , B01J23/755 , C10C5/00 , C10G2300/1011 , C10K1/04 , Y02E50/13 , Y02E50/14 , Y02E50/32 , Y02P30/20
摘要： This invention relates to a method and device to produce esterified, olefinated/esterified, or thermochemolytic reacted bio-oils as fuels. The olefinated/esterified product may be utilized as a biocrude for input to a refinery, either alone or in combination with petroleum crude oils. The bio-oil esterification reaction is catalyzed by addition of alcohol and acid catalyst. The olefination/esterification reaction is catalyzed by addition of resin acid or other heterogeneous catalyst to catalyze olefins added to previously etherified bio-oil; the olefins and alcohol may also be simultaneously combined and catalyzed by addition of resin acid or other heterogeneous catalyst to produce the olefinated/esterified product.
摘要翻译：本发明涉及一种生产酯化，烯化/酯化或热溶解反应的生物油作为燃料的方法和装置。烯化/酯化产物可以单独使用或与石油原油组合用作输入炼油厂的生物重油。通过加入醇和酸催化剂催化生物油酯化反应。烯化/酯化反应通过加入树脂酸或其他非均相催化剂催化加入到先前醚化生物油中的烯烃催化; 烯烃和醇也可以通过加入树脂酸或其它非均相催化剂同时组合和催化，以产生烯化/酯化产物。

7. 发明授权

US08603199B2 Method to upgrade bio-oils to fuel and bio-crude 有权
标题翻译：将生物油升级为燃料和生物原油的方法
公开(公告)号：US08603199B2
公开(公告)日：2013-12-10
申请号：US12896741
申请日：2010-10-01
申请人： Philip H. Steele , Charles U. Pittman, Jr. , Leonard L. Ingram, Jr. , Sanjeev Gajjela , Zhijun Zhang , Priyanka Bhattacharya
发明人： Philip H. Steele , Charles U. Pittman, Jr. , Leonard L. Ingram, Jr. , Sanjeev Gajjela , Zhijun Zhang , Priyanka Bhattacharya
IPC分类号： C10L1/18
CPC分类号： C10L1/02 , B01J21/12 , B01J23/755 , C10C5/00 , C10G2300/1011 , C10K1/04 , Y02E50/13 , Y02E50/14 , Y02E50/32 , Y02P30/20
摘要： This invention relates to a method and device to produce esterified, olefinated/esterified, or thermochemolytic reacted bio-oils as fuels. The olefinated/esterified product may be utilized as a biocrude for input to a refinery, either alone or in combination with petroleum crude oils. The bio-oil esterification reaction is catalyzed by addition of alcohol and acid catalyst. The olefination/esterification reaction is catalyzed by addition of resin acid or other heterogeneous catalyst to catalyze olefins added to previously etherified bio-oil; the olefins and alcohol may also be simultaneously combined and catalyzed by addition of resin acid or other heterogeneous catalyst to produce the olefinated/esterified product.
摘要翻译：本发明涉及一种生产酯化，烯化/酯化或热溶解反应的生物油作为燃料的方法和装置。烯化/酯化产物可以单独使用或与石油原油组合用作输入炼油厂的生物重油。通过加入醇和酸催化剂催化生物油酯化反应。烯化/酯化反应通过加入树脂酸或其他非均相催化剂催化加入到先前醚化生物油中的烯烃催化; 烯烃和醇也可以通过加入树脂酸或其它非均相催化剂同时组合和催化，以产生烯化/酯化产物。

8. 发明申请

US20130031830A1 METHODS FOR PRODUCING BINDERS AND COMBUSTIBLE COMPOSITE MATERIALS AND COMPOSITIONS PRODUCED THEREFROM 有权
标题翻译：生产粘合剂和可燃复合材料的方法及其制备的组合物
公开(公告)号：US20130031830A1
公开(公告)日：2013-02-07
申请号：US13367138
申请日：2012-02-06
申请人： Philip H. Steele , Venkata K. Penmetsa
发明人： Philip H. Steele , Venkata K. Penmetsa
IPC分类号： C10L11/06 , C10L5/14
CPC分类号： C08L89/00 , C08L91/00 , C08L97/005
摘要： Methods and compositions are provided for producing thermoset, water repellent binders particularly effective for forming combustible composite materials. The binders include a mixture of an alkaline protein hydrolyzate and a bio-oil or an acidic protein hydrolyzate and a lignin compound. Desirably, the binders and the resulting combustible composite materials are substantially free of formaldehyde.
摘要翻译：提供了用于生产热固性防水粘合剂的方法和组合物，其特别有效地用于形成可燃复合材料。粘合剂包括碱性蛋白水解物和生物油或酸性蛋白质水解物和木质素化合物的混合物。理想地，粘合剂和所得到的可燃复合材料基本上不含甲醛。

9. 发明授权

US07068050B2 Moisture and density detector (MDD) 失效
标题翻译：水分和密度检测器（MDD）
公开(公告)号：US07068050B2
公开(公告)日：2006-06-27
申请号：US10893494
申请日：2004-07-19
申请人： Philip H. Steele , Jerome E. Cooper
发明人： Philip H. Steele , Jerome E. Cooper
IPC分类号： G01R27/32 , G01R27/26
CPC分类号： G01N9/24 , G01N22/04
摘要： A Moisture and Density Detector (MDD) provides a method and apparatus to determine the moisture content and/or density, as well as presence and location of anomalies, and/or wood type of any dielectric material for various purposes. This device is very useful in detecting the moisture content of wood and wood-based materials, such as that of lumber in a dry kiln prior to, during and/or following drying. The MDD passes a radio frequency signal and/or any other signal between opposed or adjacent capacitance electrodes and measures the signal strength and phase shift of the signal. The addition of phase shift and multiple frequencies improves the accuracy of the results.
摘要翻译：水分和密度检测器（MDD）提供了一种方法和装置，用于确定各种目的的水分含量和/或密度以及异常的存在和位置，和/或任何介电材料的木材类型。该装置在检测木材和木质材料（例如在烘干之前，之中和/或之后的干燥窑中的木材）的水分含量非常有用。 MDD通过相对或相邻电容电极之间的射频信号和/或任何其它信号，并测量信号的信号强度和相移。相移和多个频率的增加提高了结果的准确性。

10. 发明授权

US06784671B2 Moisture and density detector (MDD) 失效
标题翻译：水分和密度检测器（MDD）
公开(公告)号：US06784671B2
公开(公告)日：2004-08-31
申请号：US10061374
申请日：2002-02-04
申请人： Philip H. Steele , Jerome E. Cooper
发明人： Philip H. Steele , Jerome E. Cooper
IPC分类号： G01R2732
CPC分类号： G01N9/24 , G01N22/04
摘要： A Moisture and Density Detector (MDD) that provides a method and apparatus to determine the moisture content and/or density of any dielectric material for various purposes. This device is very useful in detecting the moisture content (MC) of wood and wood-based materials, such as that of lumber in a dry kiln prior to, during and/or following drying. The MDD passes a radio frequency signal between opposed or adjacent capacitance electrodes and measures the signal strength and phase shift of the signal. The addition of phase shift and multiple frequencies improves the accuracy of the results.
摘要翻译：一种水分和密度检测器（MDD），其提供用于确定用于各种目的的任何电介质材料的水分含量和/或密度的方法和装置。该装置在检测木材和木质材料（例如在干燥之前，之中和/或之后的干燥窑中的木材的水分含量（MC））非常有用。 MDD通过相对或相邻电容电极之间的射频信号，并测量信号的信号强度和相移。相移和多个频率的增加提高了结果的准确性。

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