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    • 9. 发明授权
    • Mixtures of phosphorus-containing compounds used as polymer stabilizers
    • 用作聚合物稳定剂的含磷化合物的混合物
    • US07067569B2
    • 2006-06-27
    • US10332479
    • 2001-07-13
    • Peter Staniek
    • Peter Staniek
    • C08K5/50C08K5/524
    • C08K5/51C08K5/50C09K15/322C09K15/324
    • The invention relates to a synergistic mixture comprising a) at least one compound selected from the group consisting of the phosphites of the formula (I) to (V), of the phosphonites of the formulae (VI) to (IX) and (XV), of the di/oligophosphonites of the formulae (X) and (XI) and of the phosphinites of the formulae (XII) to (XIV), and b) at least one compound selected from the group consisting of the phosphanes of the formula (XVI), the di/oligophosphanes of the formulae (XVII) and (XVIII), and of the cyclophosphanes of the formula (XIX), and also to a process for stabilizing polymers with respect to thermooxidative degradation by addition and incorporation of a synergistic mixture of this type.
    • 本发明涉及一种协同混合物,其包含a)至少一种选自式(I)至(V)的亚磷酸酯的化合物,式(VI)至(IX)和(XV)的亚膦酸酯的化合物, 的式(X)和(XI)的二亚膦酸酯和式(XII)至(XIV)的亚磷酸酯的二膦酸酯,和b)至少一种选自下列的化合物的化合物:式 XVI),式(XVII)和(XVIII)的二低聚膦和式(XIX)的环磷烷的方法,还涉及通过加入和加入协同混合物来稳定聚合物的热氧化降解方法 这种类型的
    • 10. 发明申请
    • Salt-like reaction products of hals derivatives and phosphor-cntaining organic acids for the stabilisation of polymeric materials
    • 用于稳定聚合物材料的海藻衍生物和磷酸化有机酸的盐状反应产物
    • US20060079610A1
    • 2006-04-13
    • US10546503
    • 2004-02-19
    • Peter Staniek
    • Peter Staniek
    • C08K5/34
    • C08K5/3435C08K5/09C08K5/353
    • This invention relates to salt reaction products resp. premanufactured mixtures of compounds, which contain one or more groups of formula (Ia) to (Ic), reaction products of and organophosphorus acids resp. their derivatives, which contain one or more groups of formula (II), wherin the symbols have the meanings as given in claim 1 of the application. The invention further relates to a process for the preparation of saltlike reaction products and premanufactured mixtures. The saltlike reaction products and premanufactured mixtures can be used for stabilisation of polymers, in particularly polar polymers such as polyamides and polyesters, and for the improvement of the processing properties, heat stability, colour, gloss, surface and mechanical properties of these polymers.
    • 本发明涉及盐反应产物, 化合物的预制混合物,其含有一个或多个式(Ia)至(Ic)的基团,反应产物和有机磷酸的反应产物。 它们的衍生物含有一个或多个式(II)的基团,所述符号具有本申请的权利要求1中给出的含义。 本发明还涉及一种制备盐状反应产物和预制混合物的方法。 盐类反应产物和预制混合物可用于稳定聚合物,特别是极性聚合物如聚酰胺和聚酯,以及改善这些聚合物的加工性能,热稳定性,颜色,光泽度,表面和机械性能。