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    • 2. 发明授权
    • Hydrolyzable titanyl sulphate solutions by decomposition of ternary raw
material mixtures
    • 通过三元原料混合物的分解可水解的硫酸氧钛溶液
    • US4304758A
    • 1981-12-08
    • US213540
    • 1980-12-05
    • Hilmar RieckWalter GutschePeter WoditschPeter Panek
    • Hilmar RieckWalter GutschePeter WoditschPeter Panek
    • C01G23/00C22B34/12C01G23/053
    • C22B34/125C01G23/008
    • A process for the preparation of a hydrolyzable titanyl sulphate solution comprising adding sulphuric acid having a concentration greater than about 86% to a ternary mixture of two slags and an ilmenite to bring the proportion by weight of H.sub.2 SO.sub.4 to TiO.sub.2 to from about 1.7:1 to 2.2:1 and adding water, dilute sulphuric acid or oleum in amount sufficient to bring the H.sub.2 SO.sub.4 concentration to from about 86 to 96%, thereby to form the titanyl sulphate solution, the first slag having a TiO.sub.2 content greater than about 80% and a Ti(III) content of about 22 to 40%, the second slag having a TiO.sub.2 content of about 60 to 80% and a Ti(III) content of about 5 to 15%, and the ilmenite having a ratio of Fe(III) to Fe(II) of from about 1:1 to 10:1, the slags and ilmenite being present in such proportions that the ternary mixture of raw materials obtained has a molar ratio of Ti(III) to Fe(III).gtoreq.1.4.
    • 一种制备可水解硫酸氧钛溶液的方法,其包括将浓度大于约86%的硫酸添加到两种炉渣和钛铁矿的三元混合物中,以使H 2 SO 4的重量比例从约1.7:1提高到约1.7:1至 2.2:1,并加入水,稀硫酸或发烟硫酸,其量足以使H 2 SO 4浓度达到约86%至96%,从而形成硫酸氧钛溶液,第一炉渣的TiO 2含量大于约80%,并且 Ti(III)含量为约22〜40%,第二炉渣的TiO 2含量为约60〜80%,Ti(III)含量为5〜15%左右,钛铁矿的Fe(III) 对于Fe(II)为约1:1至10:1,炉渣和钛铁矿以以下比例存在:获得的原料的三元混合物具有Ti(III)与Fe(III)的摩尔比> 1.4。
    • 4. 发明授权
    • Treating hydrolysis residues from preparation of titanium dioxide
    • 处理二氧化钛制备中的水解残留物
    • US4321237A
    • 1982-03-23
    • US213707
    • 1980-12-05
    • Peter PanekPeter WoditschWerner Kannchen
    • Peter PanekPeter WoditschWerner Kannchen
    • C01G23/00B09B3/00C22B34/12
    • C22B34/125Y02P10/212
    • In the process wherein a titanium-containing material is subjected to react with sulphuric acid to form a solid reaction mass from which the titanium values are recovered in solution by digestion with water or dilute sulphuric acid leaving behind a reaction residue and the reaction residue is thereafter treated to recover at least part of the titanium contained therein, the improvement wherein the treatment of the reaction residue is effected by contacting with sulphuric acid of a concentration greater than 86% a mixture by weight comprising about 5 to 95% of the reaction residue and 95 to 5% of a slag having a TiO.sub.2 content 60% by weight and a Ti(III) content of about 5 to 40% by weight, and thereafter eventually adding water, steam or dilute sulphuric acid to the mass to start the reaction.
    • 在使含钛材料与硫酸反应形成固体反应物质的过程中,通过用水或稀硫酸消解在溶液中回收钛值,留下反应残余物,然后反应残余物 处理以回收其中所含的至少一部分钛,其改进在于其中反应残余物的处理通过与浓度大于86%的硫酸与包含约5至95重量%的反应残余物的混合物和 95〜5%的TiO 2含量为60重量%,Ti(III)含量为5〜40重量%左右的炉渣,最后向该物质中加入水,蒸汽或稀硫酸进行反应。