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1. 发明授权

US5854362A Supported biscyclopentadienyl metal complexes 失效
标题翻译：负载双环戊二烯基金属配合物
公开(公告)号：US5854362A
公开(公告)日：1998-12-29
申请号：US570261
申请日：1995-12-11
申请人： Peter N. Nickias , Lee Spencer
发明人： Peter N. Nickias , Lee Spencer
IPC分类号： C07F17/00 , C08F4/645 , C08F4/659 , C08F10/00 , C08F210/16
CPC分类号： C07F17/00 , C08F10/00 , C08F210/16 , C08F4/65908 , C08F4/65916 , Y10S526/943
摘要： Metal complexes corresponding to the formula: ##STR1## wherein: L independently each occurrence is a delocalized, .pi.-bonded group that is bound to M, containing up to 50 nonhydrogen atoms; M is a metal of Group 3, 4 or the Lanthanide series of the Periodic Table of the Elements; Z is a covalently bound, divalent substituent of up to 50 non-hydrogen atoms having the formula, --(ER.sub.2).sub.m --, wherein E independently each occurrence is carbon, silicon or germanium, R independently each occurrence is selected from the group consisting of C.sub.1-20 hydrocarbyl, and C.sub.1-20 hydrocarbyloxy, with the proviso that in at least one occurrence R is C.sub.1-20 hydrocarbyloxy, and m is an integer from 1 to 3; X' is a neutral Lewis base ligand having up to 20 non-hydrogen atoms; X" independently each occurrence is a monovalent, anionic moiety selected from hydride, halo, hydrocarbyl, silyl, germyl, hydrocarbyloxy, amide, siloxy, halohydrocarbyl, halosilyl, silylhydrocarbyl, and aminohydrocarbyl having up to 20 non-hydrogen atoms, or two X" groups together form a divalent hydrocarbadiyl or neutral hydrocarbon group; n is a number from 0 to 3; and p is an integer from 0 to 2.
摘要翻译：对应于下式的金属络合物：其中：L独立地每次发生是与Mg结合的离域的π键合基团，其含有至多50个非氢原子; M是元素周期表第3,4族金属或镧系元素; Z是具有式 - （ER 2）m - 的多达50个非氢原子的共价结合的二价取代基，其中E独立地每次出现为碳，硅或锗，R各自独立地选自 C 1-20烃基和C 1-20烃氧基，条件是在至少一个出现中R是C 1-20烃氧基，m是1至3的整数; X'是具有至多20个非氢原子的中性路易斯碱配体; X“独立地是选自氢化物，卤素，烃基，甲硅烷基，甲硅烷基，烃氧基，酰胺，甲硅烷氧基，卤代烃基，卤代甲硅烷基，甲硅烷基烃基和具有至多20个非氢原子的氨基烃基的一价阴离子部分，或两个X “一起形成二价烃基或中性烃基; n是从0到3的数字; p为0〜2的整数。

2. 发明授权

US5688880A Readily supportable metal complexes 失效
标题翻译：易于支持的金属配合物
公开(公告)号：US5688880A
公开(公告)日：1997-11-18
申请号：US570262
申请日：1995-12-11
申请人： Lee Spencer , Peter N. Nickias
发明人： Lee Spencer , Peter N. Nickias
IPC分类号： C07F17/00 , C08F4/619 , C08F4/6192 , C08F4/643 , C08F10/00
CPC分类号： C07F17/00 , C08F10/00 , C08F4/61908 , C08F4/61916 , C08F4/6192 , Y10S526/943
摘要： Metal complexes useful as olefin polymerization catalysts corresponding to the formula: ##STR1## wherein: L is a delocalized, .pi.-bonded group that is bound to M, containing up to 50 nonhydrogen atoms; M is a metal of Group 3, 4 or the Lanthanide series of the Periodic Table of the Elements; Z is a covalently bound, divalent substituent of up to 50 non-hydrogen atoms having the formula, --(ER.sub.2).sub.m --, wherein E independently each occurrence is carbon, silicon or germanium, R independently each occurrence is selected from the group consisting of C.sub.1-20 hydrocarbyl, and C.sub.1-20 hydrocarbyloxy, with the proviso that in at least one occurrence R is C.sub.1-20 hydrocarbyloxy, and m is an integer from 1 to 3; Y is a divalent ligand group comprising nitrogen, phosphorus, oxygen or sulfur, said Y containing up to 20 nonhydrogen atoms; X' is a neutral Lewis base ligand having up to 20 non-hydrogen atoms; X" independently each occurrence is a monovalent, anionic moiety selected from hydride, halo, hydrocarbyl, silyl, germyl, hydrocarbyloxy, amide, siloxy, halohydrocarbyl, halosilyl, silylhydrocarbyl, and aminohydrocarbyl having up to 20 non-hydrogen atoms, or two X" groups together form a divalent hydrocarbadiyl group; n is a number from 0 to 3; and p is an integer from 0 to 2.
摘要翻译：可用作对应于下式的烯烃聚合催化剂的金属络合物：其中：L是与M结合的离域的π键合基，其含有至多50个非氢原子; M是元素周期表第3,4族金属或镧系元素; Z是具有式 - （ER 2）m - 的多达50个非氢原子的共价结合的二价取代基，其中E独立地每次出现为碳，硅或锗，R各自独立地选自 C 1-20烃基和C 1-20烃氧基，条件是在至少一个出现中R是C 1-20烃氧基，m是1至3的整数; Y是包含氮，磷，氧或硫的二价配体基团，所述Y含有至多20个非氢原子; X'是具有至多20个非氢原子的中性路易斯碱配体; X“独立地是选自氢化物，卤素，烃基，甲硅烷基，甲硅烷基，烃氧基，酰胺，甲硅烷氧基，卤代烃基，卤代甲硅烷基，甲硅烷基烃基和具有至多20个非氢原子的氨基烃基的一价阴离子部分，或两个X 一起形成二价烃基; n是从0到3的数字; p为0〜2的整数。

3. 发明授权

US6087293A Supported catalyst containing tethered cation forming activator 失效
标题翻译：负载催化剂含有束缚阳离子形成活化剂
公开(公告)号：US6087293A
公开(公告)日：2000-07-11
申请号：US117470
申请日：1998-03-02
申请人： Edmund M. Carnahan , Michael J. Carney , David R. Neithamer , Peter N. Nickias , Keng-Yu Shih , Lee Spencer
发明人： Edmund M. Carnahan , Michael J. Carney , David R. Neithamer , Peter N. Nickias , Keng-Yu Shih , Lee Spencer
IPC分类号： C08F4/02 , C08F4/603 , C08F4/619 , C08F4/6192 , C08F4/643 , C08F4/645 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , B01J31/00 , C08F4/06 , C08F4/44
CPC分类号： C08F10/00 , C08F10/02 , C08F4/025 , C08F110/02 , C08F210/16 , C08F4/61908 , C08F4/61912 , C08F4/61916 , C08F4/6192 , C08F4/65912 , C08F4/6592 , C08F4/65925 , Y10S526/943
摘要： A support for use in preparing supported catalysts for addition polymerizations comprising the reaction product of: (A) an inorganic oxide material comprising reactive surface hydroxyl groups, at least some of said hydroxyl groups optionally having been functionalized an converted to a reactive silano moiety corresponding to the formula: --OSiR.sub.2 H, wherein R, independently each occurrence, is hydrogen C.sub.1-20 hydrocarbyl, or C.sub.1-20 hydrocarbyloxy, said inorganic oxide or functionalized derivative thereof comprising less than 1.0 mmol of reactive surface hydroxyl functionality per gram, and (B) an activator compound comprising: b.sub.1) a cation which is capable of reacting with a transition metal compound to form a catalytically active transition metal complex, and b.sub.2) a compatible anion containing at least one substituent able to react with the inorgnaic oxide, with residual hydroxyl functionality of the inorganic oxide, or with the reactive silane moiety, hereby covalently bonding the compatible anion to the support, catalysts formed therefrom, process of manufacture and the method to use.
摘要翻译： PCT No.PCT / US96 / 17140 Sec。 371日期1998年3月2日 102（e）1998年3月2日PCT PCT 1996年10月25日PCT公布。公开号WO97 / 19959 日期1997年6月5日，用于制备用于加成聚合的载体催化剂的载体，其包括以下反应产物：（A）包含反应性表面羟基的无机氧化物材料，至少一些所述羟基任选已被官能化转化为对应于式-OSiR 2 H的反应性硅烷基部分，其中R各自独立地为氢C 1-20烃基或C 1-20烃氧基，所述无机氧化物或其官能化衍生物包含小于1.0mmol反应性表面羟基官能度/克和（B）活化剂化合物，其包含：b1）能够与过渡金属化合物反应形成催化活性过渡金属络合物的阳离子，和b2）含有至少一个能够与无规性反应的取代基的相容阴离子氧化物，具有无机氧化物的残余羟基官能团，或与反应性硅烷部分共价共轭将相容的阴离子与载体，由其形成的催化剂，制备方法和使用方法相结合。

4. 发明授权

US09193487B2 Self assembling polymer membranes in food packaging application 有权
标题翻译：自组装聚合物膜在食品包装中的应用
公开(公告)号：US09193487B2
公开(公告)日：2015-11-24
申请号：US13577603
申请日：2011-02-11
申请人： Scott T. Matteucci , Leonardo C. Lopez , Shawn D. Feist , Peter N. Nickias , Shrikant N. Khot
发明人： Scott T. Matteucci , Leonardo C. Lopez , Shawn D. Feist , Peter N. Nickias , Shrikant N. Khot
IPC分类号： B65B41/00 , B65B31/02 , A23L3/3418 , B65D65/40 , B65D85/36 , B65D85/74 , B65D85/76 , C08G69/40 , C08G69/44 , C08J5/18 , C08L77/06 , C08L77/12 , B65D81/20
CPC分类号： B65B31/024 , A23L3/3418 , B65B41/00 , B65D65/40 , B65D81/2069 , B65D85/36 , B65D85/74 , B65D85/76 , C08G69/40 , C08G69/44 , C08J5/18 , C08J2377/06 , C08J2377/12 , C08L77/06 , C08L77/12
摘要： A method of packaging a food product using a polymer membrane, the polymer being a self assembling polymeric material, and the method including a.) rendering the said polymer into a film; and b.) packaging a food product in an atmosphere with the said polymer film, wherein said film regulates the atmosphere in which the food product is packaged.
摘要翻译：一种使用聚合物膜包装食品的方法，所述聚合物是自组装聚合物材料，并且所述方法包括a）使所述聚合物成膜; 和b。）在所述聚合物膜的大气中包装食品，其中所述膜调节包装食品的气氛。

5. 发明授权

US08304543B2 Blocking agents for organoborane compounds 失效
标题翻译：有机硼烷化合物的封闭剂
公开(公告)号：US08304543B2
公开(公告)日：2012-11-06
申请号：US12603381
申请日：2009-10-21
申请人： Gary Lee Jialanella , Shaoguang Feng , Peter N. Nickias , Toni Ristoski
发明人： Gary Lee Jialanella , Shaoguang Feng , Peter N. Nickias , Toni Ristoski
IPC分类号： C07F5/02
CPC分类号： C07F5/027 , C07F5/00
摘要： An organoborane complex is disclosed. The complex includes a blocking agent comprising a bifunctional Lewis base. The blocking agents include an amine group and a second functional group that has a lower Lewis basicity than the first functional group. The blocking is based on amino alkyl pyridines.
摘要翻译：公开了有机硼烷络合物。络合物包括包含双功能路易斯碱的封闭剂。封端剂包括具有比第一官能团低的路易斯碱度的胺基和第二官能团。封闭基于氨基烷基吡啶。

6. 发明申请

US20120016080A1 INITIATORS FOR POLYMERIZATION OF VINYL MONOMERS BASED ON THE REACTION OF PHENOXYALUMINUM COMPLEXES WITH OXYGEN 审中-公开
标题翻译：基于苯氧基铝复合物与氧的反应聚合乙烯基单体的方法
公开(公告)号：US20120016080A1
公开(公告)日：2012-01-19
申请号：US13179633
申请日：2011-07-11
申请人： Gary L. Jialanella , Peter N. Nickias , Shaoguang Feng , Toni Ristoski , Eric P. Wasserman
发明人： Gary L. Jialanella , Peter N. Nickias , Shaoguang Feng , Toni Ristoski , Eric P. Wasserman
IPC分类号： C09D7/14 , C09J4/02 , B05D1/26 , B05D3/04 , B05D1/02 , B05D1/28 , C09K3/00 , C09D4/02
CPC分类号： C08F220/14 , C08F4/28 , C08F4/52 , C09D7/70
摘要： One exemplary embodiment includes a method comprising polymerizing vinyl monomers with an initiator comprising a phenoxyaluminum alkyl compound in the presence of oxygen.
摘要翻译：一个示例性实施方案包括在氧气存在下使乙烯基单体与包含苯氧基烷基铝化合物的引发剂聚合的方法。

7. 发明申请

US20100126341A1 POLYMER PI-BOND-PHILIC FILLER COMPOSITES 失效
标题翻译：聚合物PI-BOND-PHILIC FILLER复合材料
公开(公告)号：US20100126341A1
公开(公告)日：2010-05-27
申请号：US12623355
申请日：2009-11-20
申请人： Scott T. Matteucci , Shawn D. Feist , Peter N. Nickias , Leonardo C. Lopez , Michael S. Paquette , Jeffrey C. Munro
发明人： Scott T. Matteucci , Shawn D. Feist , Peter N. Nickias , Leonardo C. Lopez , Michael S. Paquette , Jeffrey C. Munro
IPC分类号： B01D59/12 , C08J9/36
CPC分类号： C08K3/08 , B01D53/02 , B01D2253/1122 , B01D2253/202 , B01D2257/7022 , C08K2003/0806 , C08L101/00
摘要： The instant invention generally provides polymer pi-bond-philic filler composite comprising a molecularly self-assembling material and a pi-bond-philic filler, and a process of making and an article comprising the polymer pi-bond-philic filler composite. The instant invention also generally provides a process of separating a pi-bond-philic gas from a separable gas mixture comprising the pi-bond-philic gas.
摘要翻译：本发明通常提供包含分子自组装材料和π-亲和填料的聚合物亲合性填料复合材料，以及制备方法和包含聚合物亲环键填料复合材料的制品。本发明还通常提供了一种从包含无亲性气体的可分离气体混合物中分离起始亲气体的方法。

8. 发明授权

US06627711B2 Transition metal donor complexes and olefin polymerization process 失效
标题翻译：过渡金属给体络合物和烯烃聚合过程
公开(公告)号：US06627711B2
公开(公告)日：2003-09-30
申请号：US10104807
申请日：2002-03-22
申请人： Michael J. Mullins , Phillip S. Athey , Peter N. Nickias , Jorge Soto , Harold W. Boone , R. Vernon Snelgrove
发明人： Michael J. Mullins , Phillip S. Athey , Peter N. Nickias , Jorge Soto , Harold W. Boone , R. Vernon Snelgrove
IPC分类号： C08F464
CPC分类号： C08F110/02 , C08F4/64106
摘要： A process for polymerization of addition polymerizable monomers with a catalyst composition comprising a Group 4 or 5 metal bis(silane)amido complex corresponding to the formula: where the various substituents are as defined in claim 1.
摘要翻译：一种用于使催化剂组合物聚合的方法，所述催化剂组合物包含对应于下式的第4或5族金属双（硅烷）酰胺基络合物：其中各种取代基如权利要求1所定义。

9. 发明授权

US06191245B1 &agr;-Olefin/vinylidene aromatic monomer and/or hindered aliphatic or cycloaliphatic vinylidene monomer interpolymers 失效
标题翻译： α-烯烃/亚乙烯基芳族单体和/或受阻的脂族或脂环族亚乙烯基单体互聚物
公开(公告)号：US06191245B1
公开(公告)日：2001-02-20
申请号：US09254251
申请日：1999-03-02
申请人： Richard E. Campbell, Jr. , Mark H. McAdon , Peter N. Nickias , Jasson T. Patton , Oscar D. Redwine , Francis J. Timmers
发明人： Richard E. Campbell, Jr. , Mark H. McAdon , Peter N. Nickias , Jasson T. Patton , Oscar D. Redwine , Francis J. Timmers
IPC分类号： C08F21208
CPC分类号： C08F12/08 , C08F4/65908 , C08F4/65912 , C08F210/02 , C08F2420/02 , C08F2420/04 , Y10S526/943 , C08F4/65927 , C08F4/6592 , C08F212/08 , C08F2500/12 , C08F2500/03
摘要： The present invention relates to &agr;-olefin/vinyl aromatic monomer interpolymers with characteristic signals in their carbon 13 NMR spectra. In particular, ethylene/styrene copolymers of the present invention have peaks in the carbon 13 NMR spectra which appear in the chemical shift range 43.70-44.25 ppm, preferably from 43.75-44.25 ppm and 38.0-38.5 ppm, said peaks being at least three times the peak to peak noise. The interpolymers are prepared by polymerizing the appropriate mixture of monomers in the presence of a catalyst such as racemic-(dimethylsilanediyl(2-methyl-4-phenylindenyl)) zirconium dichloride. The polymers of the present invention posses increased modulus as determined from both tensile stress/strain and dynamic mechanical data at comparable vinyl aromatic monomer levels.
摘要翻译：本发明涉及在其碳13 NMR谱中具有特征信号的α-烯烃/乙烯基芳族单体互聚物。特别地，本发明的乙烯/苯乙烯共聚物在化学位移范围43.70-44.25ppm，优选43.75-44.25ppm和38.0-38.5ppm中出现的碳13 NMR谱中具有峰，所述峰为至少三倍峰值到峰值噪声。通过在催化剂如外消旋 - （二甲基硅烷二基（2-甲基-4-苯基茚基））二氯化锆存在下聚合合适的单体混合物来制备互聚物。本发明的聚合物具有增加的模量，其由相应的乙烯基芳族单体水平下的拉伸应力/应变和动态机械数据两者确定。

10. 发明授权

US6040401A Saturated tricyclic ligand containing metal complexes and olefin polymerization process 失效
标题翻译：饱和三环配体含有金属络合物和烯烃聚合方法
公开(公告)号：US6040401A
公开(公告)日：2000-03-21
申请号：US904363
申请日：1997-08-01
申请人： Peter N. Nickias , Tobin J. Marks , Yasushi Obora
发明人： Peter N. Nickias , Tobin J. Marks , Yasushi Obora
IPC分类号： C07F7/00 , C07F7/08 , C07F17/00 , C08F4/64 , C08F4/642 , C08F4/645 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F4/44
CPC分类号： C07F17/00 , C08F10/00 , C08F110/06 , C08F4/65908 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： Bridged, group 4 Metal complexes useful as olefin polymerization catalyst components corresponding to the formula: L.sub.1 ZL.sub.2 MX.sub.m X'.sub.nor a dimer, solvated adduct, chelated derivative or mixture thereof, wherein:L.sub.1 is a partially saturated tricyclic group, especially octahydrofluorenyl,L.sub.2 is a substituted cyclopentadienyl group that is bound to M by means of delocalized .pi.-electrons, said cyclopentadienyl group being substituted at one and only one of its two distal positions with a bulky ligand group,Z is divalent bridging substituent,X each occurrence is a monovalent, anionic moiety having up to 40 non-hydrogen atoms, optionally, two X groups may be covalently bound together forming a divalent dianionic moiety having both valences bound to M, or, optionally 2 X groups may be covalently bound together to form a neutral, conjugated or nonconjugated diene that is bonded to M by means of delocalized .pi.-electrons (whereupon M is in the +2 oxidation state), or further optionally one or more X and one or more X' groups may be bonded together thereby forming a moiety that is both covalently bound to M and coordinated thereto;m is 1 or 2 and is equal to two less than the formal oxidation state of M, except when 2 X groups together form a neutral conjugated or non-conjugated diene that is .pi.-bonded to M, in which case m is equal to the formal oxidation state of M;X' is a neutral ligand having up to 20 non-hydrogen atoms, and n is a number from 0 to 3.
摘要翻译：桥接的第4族金属络合物可用作对应于下式的烯烃聚合催化剂组分：L1ZL2MXmX'n或二聚体，溶剂化加合物，螯合衍生物或其混合物，其中：L1是部分饱和的三环基团，特别是八氢芴基，L2是取代的通过离域π电子与M结合的环戊二烯基，所述环戊二烯基在其两个远端位置中的一个且仅一个被取代，具有庞大的配体基团，Z是二价桥接取代基，X每次出现是一价阴离子具有多达40个非氢原子的部分，任选地，两个X基团可以共价键合在一起形成具有与M键合的两价键的二价二阴离子部分，或者任选地，2个X基团可以共价键合在一起以形成中性，共轭或通过离域π电子（因此M处于+2氧化态）与M键合的非共轭二烯，或进一步任选地一个或多个 X和一个或多个X'基团可以键合在一起，从而形成共价键合到M并与之配位的部分; m为1或2，并且等于小于M的形式氧化态的2，除了当两个X基团一起形成与M相连接的中性共轭或非共轭二烯时，其中m等于 M的正式氧化态; X'是具有至多20个非氢原子的中性配体，n是0至3的数。

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