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    • 5. 发明授权
    • Pigment formulations
    • 颜料配方
    • US4720304A
    • 1988-01-19
    • US777494
    • 1985-09-19
    • Wolfgang RuffEgon LiedekGerhard BergerHans W. Sonneborn
    • Wolfgang RuffEgon LiedekGerhard BergerHans W. Sonneborn
    • C09D11/00C09B67/20C09B67/22C09D11/02C08K5/18
    • C09B67/0041
    • Novel formulations which contain (a) one or more azo pigments based on coupling products of aromatic monoamines or 4,4'-diaminodiphenyls with acetoacetarylides, 1-arylpyrazolones, 3-hydroxy-2-naphthoic acid derivatives or .beta.-naphthol and (b) one or more dyes of the formulaQ--(X).sub.nwhere F is an n-valent radical of a monoazo dye, of a disazo dye or of a quinophthalone, n is 1, 2, 3 or 4 and X is a group of the formula ##STR1## where R.sup.1 and R.sup.2 are each hydrogen or C.sub.1 -C.sub.4 -alkyl, R.sup.3 is C.sub.1 -C.sub.4 -alkyl or hydroxy-C.sub.2 -C.sub.4 -alkyl and A.sup..crclbar. is one equivalent of an anion.The pigments present in the formulations exhibit improved tinctorial, rheological and printing properties when the formulations are used in printing inks.
    • 基于芳族单胺或4,4'-二氨基二苯基与乙酰乙酰芳烃,1-芳基吡唑酮,3-羟基-2-萘甲酸衍生物或β-萘酚的偶联产物的一种或多种偶氮颜料的新型配方,和(b) 一种或多种式Q-(X)n的染料,其中F是单偶氮染料,双偶氮染料或喹酞酮的n价基团,n是1,2,3或4,X是 其中R 1和R 2各自为氢或C 1 -C 4 - 烷基,R 3为C 1 -C 4 - 烷基或羟基-C 2 - C 4 - 烷基且A( - )为1当量阴离子。 当制剂用于印刷油墨时,配方中存在的颜料表现出改进的着色,流变和印刷性能。
    • 7. 发明授权
    • Disazo compounds and formulations containing same
    • 双偶氮化合物和含有相同的配方
    • US4894094A
    • 1990-01-16
    • US86780
    • 1987-08-19
    • Wolfgang RuffEgon LiedekGerhard BergerHans W. Sonneborn
    • Wolfgang RuffEgon LiedekGerhard BergerHans W. Sonneborn
    • C09B67/36C07C67/00C07C241/00C07C245/08C07C301/00C07C309/51C07D231/48C09B35/08C09B67/20C09B67/22C09D11/02
    • C09B35/08C09B67/0055Y10S534/01
    • Disazo compounds based on 4,4'-diaminodiphenyl compounds contain not less than 50% by weight of a disazo compound of the general formulaA--N.dbd.N--Z--N.dbd.N--B (I)where Z is a radical of an unsubstituted of symmetrically substituted diphenylene, A is a radical of a coupling component of a 1-phenylpyrazolone or of an acetoacetarylide, where the phenyl and the aryl radical is substituted by sulfo or carboxyl groups, and B is a radical of a coupling component based on 1-phenylpyrazolone or acetoacetarylide, which are free of sulfo and/or carboxyl groups.The disazo compounds can be obtained by coupling the tetrazotized diamine H.sub.2 N--Z--NH.sub.2 to the coupling component AH containing an acidic group in a medium containing a mineral acid, and then coupling the product to BH in a buffered medium (pH about 4).The novel disazo compounds are suitable as additives to pigments, in particular azo and disazo pigments, for improving the transparency and heat stability of the pigment particles, and the flow behavior.
    • 基于4,4'-二氨基二苯基化合物的双偶氮化合物含有不少于50重量%的通式AN = NZN = NB(I)的双偶氮化合物,其中Z是未取代的对称取代的亚二苯基的基团,A是 苯基和芳基被磺基或羧基取代的1-苯基吡唑啉酮或乙酰乙酰芳胺的偶联组分的基团,B是基于1-苯基吡唑酮或乙酰乙酰芳胺的偶联组分的基团,它们是 没有磺基和/或羧基。 双偶氮化合物可以通过将四唑二胺H 2 N -Z-NH 2偶联到含有无机酸的介质中的含有酸性基团的偶联组分AH,然后在缓冲介质(pH约为4)中将该产物偶联到BH上来获得。 新型双偶氮化合物适用于颜料,特别是偶氮和双偶氮颜料的添加剂,用于改善颜料颗粒的透明度和热稳定性以及流动行为。