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1. 发明授权

US07494574B2 Methods for natural gas and heavy hydrocarbon co-conversion 有权
标题翻译：天然气和重质烃共转化方法
公开(公告)号：US07494574B2
公开(公告)日：2009-02-24
申请号：US11051682
申请日：2005-02-03
申请人： Peter C. Kong , Lee O. Nelson , Brent A. Detering
发明人： Peter C. Kong , Lee O. Nelson , Brent A. Detering
IPC分类号： B01J19/08
CPC分类号： B01J19/2415 , B01J19/088 , B01J19/123 , B01J2208/025 , B01J2219/00135 , B01J2219/0809 , B01J2219/083 , B01J2219/0841 , B01J2219/0843 , B01J2219/0869 , B01J2219/0871 , B01J2219/0875 , B01J2219/0884 , B01J2219/0892 , B01J2219/0894 , C01B3/342 , C01B2203/0861 , C07C27/12 , C07C29/50 , C10G15/08 , C10G32/02 , C10G45/04 , C10G47/12 , C10G65/12 , C10G69/02 , H05H1/2406 , H05H2001/2412 , H05H2001/245 , H05H2001/2462 , H05H2240/20 , H05H2245/1215
摘要： A reactor for reactive co-conversion of heavy hydrocarbons and hydrocarbon gases and includes a dielectric barrier discharge plasma cell having a pair of electrodes separated by a dielectric material and passageway therebetween. An inlet is provided for feeding heavy hydrocarbons and other reactive materials to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a variety of light sources for providing ultraviolet light within the discharge plasma cell. Methods for upgrading heavy hydrocarbons are also disclosed.
摘要翻译：一种用于重质烃和烃类气体的反应性共转化反应器，包括具有由电介质材料隔开的一对电极和介于其间的通路的电介质势垒放电等离子体单元。提供入口用于将重质烃和其它反应性材料供给到放电等离子体电池的通道，并且提供用于从反应器中排出反应产物的出口。可以任选地在反应器中使用填充床催化剂以提高转化效率。反应器可以被修改以允许使用各种光源来在放电等离子体电池内提供紫外光。还公开了重质烃的改质方法。

2. 发明授权

US06896854B2 Nonthermal plasma systems and methods for natural gas and heavy hydrocarbon co-conversion 有权
标题翻译：非等离子体系统和天然气和重质烃共转化方法
公开(公告)号：US06896854B2
公开(公告)日：2005-05-24
申请号：US10059669
申请日：2002-01-29
申请人： Peter C. Kong , Lee O. Nelson , Brent A. Detering
发明人： Peter C. Kong , Lee O. Nelson , Brent A. Detering
IPC分类号： B01J19/08 , B01J19/12 , B01J19/24 , C01B3/34 , C07C27/12 , C07C29/50 , C10G15/08 , C10G32/02 , C10G45/04 , C10G47/12 , C10G65/12 , C10G69/02 , H05H1/24
CPC分类号： B01J19/2415 , B01J19/088 , B01J19/123 , B01J2208/025 , B01J2219/00135 , B01J2219/0809 , B01J2219/083 , B01J2219/0841 , B01J2219/0843 , B01J2219/0869 , B01J2219/0871 , B01J2219/0875 , B01J2219/0884 , B01J2219/0892 , B01J2219/0894 , C01B3/342 , C01B2203/0861 , C07C27/12 , C07C29/50 , C10G15/08 , C10G32/02 , C10G45/04 , C10G47/12 , C10G65/12 , C10G69/02 , H05H1/2406 , H05H2001/2412 , H05H2001/245 , H05H2001/2462 , H05H2240/20 , H05H2245/1215
摘要： A reactor for reactive co-conversion of heavy hydrocarbons and hydrocarbon gases and includes a dielectric barrier discharge plasma cell having a pair of electrodes separated by a dielectric material and passageway therebetween. An inlet is provided for feeding heavy hydrocarbons and other reactive materials to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a variety of light sources for providing ultraviolet light within the discharge plasma cell. Methods for upgrading heavy hydrocarbons are also disclosed.
摘要翻译：一种用于重质烃和烃类气体的反应性共转化反应器，包括具有由电介质材料隔开的一对电极和介于其间的通路的电介质势垒放电等离子体单元。提供入口用于将重质烃和其它反应性材料供给到放电等离子体电池的通道，并且提供用于从反应器中排出反应产物的出口。可以任选地在反应器中使用填充床催化剂以提高转化效率。反应器可以被修改以允许使用各种光源来在放电等离子体电池内提供紫外光。还公开了重质烃的改质方法。

3. 发明授权

US06804950B2 Plasma reforming and partial oxidation of hydrocarbon fuel vapor to produce synthesis gas and/or hydrogen gas 失效
标题翻译：烃燃料蒸汽的等离子体重整和部分氧化产生合成气和/或氢气
公开(公告)号：US06804950B2
公开(公告)日：2004-10-19
申请号：US10447565
申请日：2003-05-28
申请人： Peter C. Kong , Brent A. Detering
发明人： Peter C. Kong , Brent A. Detering
IPC分类号： F01N300
CPC分类号： F02M25/089 , B01D53/32 , B01D53/92 , C01B3/342 , C01B2203/0211 , C01B2203/0255 , C01B2203/0861 , C10J2300/1238 , F01N3/0892 , F01N5/02 , F01N2240/02 , F01N2240/28 , F01N2240/30 , F02B43/10 , F02D19/0644 , F02D19/0671 , F02M21/06 , F02M25/12 , F02M27/042 , F02M31/12 , Y02T10/121 , Y02T10/16 , Y02T10/32 , Y02T10/36 , Y10S123/12
摘要： Methods and systems are disclosed for treating vapors from fuels such as gasoline or diesel fuel in an internal combustion engine, to form hydrogen gas or synthesis gas, which can then be burned in the engine to produce more power. Fuel vapor, or a mixture of fuel vapor and exhaust gas and/or air, is contacted with a plasma, to promote reforming reactions between the fuel vapor and exhaust gas to produce carbon monoxide and hydrogen gas, partial oxidation reactions between the fuel vapor and air to produce carbon monoxide and hydrogen gas, or direct hydrogen and carbon particle production from the fuel vapor. The plasma can be a thermal plasma or a non-thermal plasma. The plasma can be produced in a plasma generating device which can be preheated by contact with at least a portion of the hot exhaust gas stream, thereby decreasing the power requirements of the plasma generating device.
摘要翻译：公开了用于处理来自内燃机中的燃料（例如汽油或柴油）的蒸汽的方法和系统，以形成氢气或合成气，然后可以在发动机中燃烧产生更多的动力。燃料蒸气或燃料蒸气与废气和/或空气的混合物与等离子体接触，以促进燃料蒸汽与废气之间的重整反应，产生一氧化碳和氢气，燃料蒸气和空气产生一氧化碳和氢气，或直接由燃料蒸汽产生的氢和碳颗粒。等离子体可以是热等离子体或非热等离子体。等离子体可以在等离子体产生装置中制造，其可以通过与热废气流的至少一部分接触而被预热，从而降低等离子体产生装置的功率需求。

4. 再颁专利

USRE37853E1 Fast quench reactor and method 有权
标题翻译：快速骤冷反应器及方法
公开(公告)号：USRE37853E1
公开(公告)日：2002-09-24
申请号：US09569146
申请日：2000-05-11
申请人： Brent A. Detering , Alan D. Donaldson , James R. Fincke , Peter C. Kong
发明人： Brent A. Detering , Alan D. Donaldson , James R. Fincke , Peter C. Kong
IPC分类号： C22B406
CPC分类号： B82Y30/00 , B01J19/088 , B01J19/26 , B01J2219/00094 , B01J2219/00119 , B01J2219/00155 , B01J2219/00159 , B01J2219/00162 , B01J2219/00166 , B01J2219/00245 , B01J2219/0809 , B01J2219/0871 , B01J2219/0875 , B01J2219/0886 , B01J2219/0898 , C01B3/342 , C01B7/035 , C01G1/02 , C01P2004/64 , C07C2/76 , C22B4/005 , C22B4/08 , C22B34/12 , C22B34/1286 , C22B34/129 , H05H1/34 , H05H2001/3484 , Y02P20/582 , Y10S977/777 , C07C11/24
摘要： A fast quench reaction includes a reactor chamber having a high temperature heating means such as a plasma torch at its inlet and a restrictive convergent-divergent nozzle at its outlet end. Reactants are injected into the reactor chamber. The resulting heated gaseous stream is then rapidly cooled by passage through the nozzle. This “freezes” the desired end product(s) in the heated equilibrium reaction stage.
摘要翻译：快速淬火反应包括具有高温加热装置的反应室，例如其入口处的等离子体焰炬和在其出口端处的限制性会聚发散喷嘴。将反应物注入反应器室。然后通过通过喷嘴快速冷却所得加热的气流。这在“加热的平衡反应阶段”冻结了所需的最终产物。

5. 发明授权

US06606855B1 Plasma reforming and partial oxidation of hydrocarbon fuel vapor to produce synthesis gas and/or hydrogen gas 失效
公开(公告)号：US06606855B1
公开(公告)日：2003-08-19
申请号：US09590537
申请日：2000-06-08
申请人： Peter C. Kong , Brent A. Detering
发明人： Peter C. Kong , Brent A. Detering
IPC分类号： F01N300
CPC分类号： F02M25/089 , B01D53/32 , B01D53/92 , C01B3/342 , C01B2203/0211 , C01B2203/0255 , C01B2203/0861 , C10J2300/1238 , F01N3/0892 , F01N5/02 , F01N2240/02 , F01N2240/28 , F01N2240/30 , F02B43/10 , F02D19/0644 , F02D19/0671 , F02M21/06 , F02M25/12 , F02M27/042 , F02M31/12 , Y02T10/121 , Y02T10/16 , Y02T10/32 , Y02T10/36 , Y10S123/12
摘要： Methods and systems for treating vapors from fuels such as gasoline or diesel fuel in an internal combustion engine, to form hydrogen gas or synthesis gas, which can then be burned in the engine to produce more power. Fuel vapor, or a mixture of fuel vapor and exhaust gas and/or air, is contacted with a plasma, to promote reforming reactions between the fuel vapor and exhaust gas to produce carbon monoxide and hydrogen gas, partial oxidation reactions between the fuel vapor and air to produce carbon monoxide and hydrogen gas, or direct hydrogen and carbon particle production from the fuel vapor. The plasma can be a thermal plasma or a non-thermal plasma. The plasma can be produced in a plasma generating device which can be preheated by contact with at least a portion of the hot exhaust gas stream, thereby decreasing the power requirements of the plasma generating device.

6. 发明授权

US06187226B1 Thermal device and method for production of carbon monoxide and hydrogen by thermal dissociation of hydrocarbon gases 失效
标题翻译：通过碳氢化合物气体的热解解生产一氧化碳和氢气的热装置和方法
公开(公告)号：US06187226B1
公开(公告)日：2001-02-13
申请号：US09320784
申请日：1999-05-27
申请人： Brent A. Detering , Peter C. Kong
发明人： Brent A. Detering , Peter C. Kong
IPC分类号： C07C102
CPC分类号： C01B7/035 , B01J19/088 , B01J19/26 , B01J2219/00094 , B01J2219/00119 , B01J2219/00155 , B01J2219/00159 , B01J2219/00162 , B01J2219/00166 , B01J2219/00245 , B01J2219/0809 , B01J2219/0828 , B01J2219/0869 , B01J2219/0871 , B01J2219/0875 , B01J2219/0883 , B01J2219/0886 , B01J2219/0898 , C01B3/24 , C01B3/342 , C01B32/40 , C01G1/02 , C07C2/76 , C22B4/005 , C22B4/08 , C22B34/1286 , C22B34/129 , H05H1/34 , H05H1/42 , H05H2001/3484 , C07C11/24
摘要： Carbon monoxide is produced in a fast quench reactor. The production of carbon monoxide includes injecting carbon dioxide and some air into a reactor chamber having a high temperature at its inlet and a rapidly expanding a reactant stream, such as a restrictive convergent-divergent nozzle at its outlet end. Carbon dioxide and other reactants such as methane and other low molecular weight hydrocarbons are injected into the reactor chamber. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The resulting heated gaseous stream is then rapidly cooled by expansion of the gaseous stream.
摘要翻译：一氧化碳在快速骤冷反应器中产生。一氧化碳的生产包括将二氧化碳和一些空气注入到其入口处具有高温的反应器室中，并且在其出口端快速膨胀反应物流，例如限制性会聚发散喷嘴。将二氧化碳和其它反应物如甲烷和其他低分子量烃注入反应器室中。可以在该过程的不同阶段加入其它气体以形成期望的最终产物并防止反应。然后通过气流的膨胀迅速冷却所得加热的气流。

7. 发明授权

US5749937A Fast quench reactor and method 失效
公开(公告)号：US5749937A
公开(公告)日：1998-05-12
申请号：US404395
申请日：1995-03-14
申请人： Brent A. Detering , Alan D. Donaldson , James R. Fincke , Peter C. Kong
发明人： Brent A. Detering , Alan D. Donaldson , James R. Fincke , Peter C. Kong
IPC分类号： C01G23/047 , B01J19/08 , B01J19/26 , B22F9/28 , C01B3/34 , C01B7/03 , C01G1/02 , C07C2/76 , C07C2/82 , C07C11/24 , C22B4/00 , C22B4/08 , C22B9/22 , C22B21/00 , C22B34/12 , C22B34/22 , H05H1/24 , C22B4/06
CPC分类号： B82Y30/00 , B01J19/088 , B01J19/26 , C01B3/342 , C01B7/035 , C01G1/02 , C07C2/76 , C22B34/12 , C22B34/1286 , C22B34/129 , C22B4/005 , C22B4/08 , H05H1/34 , B01J2219/00094 , B01J2219/00119 , B01J2219/00155 , B01J2219/00159 , B01J2219/00162 , B01J2219/00166 , B01J2219/00245 , B01J2219/0809 , B01J2219/0871 , B01J2219/0875 , B01J2219/0886 , B01J2219/0898 , C01P2004/64 , H05H2001/3484 , Y02P20/582 , Y10S977/777
摘要： A fast quench reaction includes a reactor chamber having a high temperature heating means such as a plasma torch at its inlet and a restrictive convergent-divergent nozzle at its outlet end. Reactants are injected into the reactor chamber. The resulting heated gaseous stream is then rapidly cooled by passage through the nozzle. This "freezes" the desired end product(s) in the heated equilibrium reaction stage.

8. 发明授权

US07741577B2 Modular hybrid plasma reactor and related systems and methods 有权
标题翻译：模块化混合等离子体反应器及相关系统及方法
公开(公告)号：US07741577B2
公开(公告)日：2010-06-22
申请号：US11392141
申请日：2006-03-28
申请人： Peter C. Kong , Jon D. Grandy , Brent A. Detering
发明人： Peter C. Kong , Jon D. Grandy , Brent A. Detering
IPC分类号： B23K10/00
CPC分类号： H05H1/34 , H05H1/30 , H05H2001/3452
摘要： A device, method and system for generating a plasma is disclosed wherein an electrical arc is established and the movement of the electrical arc is selectively controlled. In one example, modular units are coupled to one another to collectively define a chamber. Each modular unit may include an electrode and a cathode spaced apart and configured to generate an arc therebetween. A device, such as a magnetic or electromagnetic device, may be used to selectively control the movement of the arc about a longitudinal axis of the chamber. The arcs of individual modules may be individually controlled so as to exhibit similar or dissimilar motions about the longitudinal axis of the chamber. In another embodiment, an inlet structure may be used to selectively define the flow path of matter introduced into the chamber such that it travels in a substantially circular or helical path within the chamber.
摘要翻译：公开了一种用于产生等离子体的装置，方法和系统，其中建立电弧并且选择性地控制电弧的移动。在一个示例中，模块化单元彼此耦合以共同限定室。每个模块化单元可以包括间隔开并且被配置成在其间产生电弧的电极和阴极。可以使用诸如磁性或电磁装置的装置来选择性地控制围绕腔室的纵向轴线的电弧运动。单个模块的弧可以单独控制，以便围绕腔室的纵向轴线显示相似或不相似的运动。在另一个实施例中，入口结构可用于选择性地限定引入室中的物质的流动路径，使得其在腔室内以大致圆形或螺旋状的路径行进。

9. 发明授权

US07097675B2 Fast-quench reactor for hydrogen and elemental carbon production from natural gas and other hydrocarbons 失效
标题翻译：用于从天然气和其他碳氢化合物生产氢气和元素碳的快速骤冷反应器
公开(公告)号：US07097675B2
公开(公告)日：2006-08-29
申请号：US10109427
申请日：2002-03-27
申请人： Brent A. Detering , Peter C. Kong
发明人： Brent A. Detering , Peter C. Kong
IPC分类号： H05H1/02 , H05H1/00 , B01J19/08
CPC分类号： H01M8/0618 , B01J19/088 , B01J19/26 , B01J2219/00094 , B01J2219/00103 , B01J2219/00108 , B01J2219/00119 , B01J2219/00132 , B01J2219/00159 , B01J2219/00166 , B01J2219/0809 , B01J2219/0826 , B01J2219/083 , B01J2219/0845 , B01J2219/0875 , B01J2219/0879 , B01J2219/0894 , B01J2219/0898 , C01B3/24 , C01B3/34 , C01B32/05 , H01M8/0631 , Y02P20/129
摘要： A fast-quench reactor for production of diatomic hydrogen and unsaturated carbons is provided. During the fast quench in the downstream diverging section of the nozzle, such as in a free expansion chamber, the unsaturated hydrocarbons are further decomposed by reheating the reactor gases. More diatomic hydrogen is produced, along with elemental carbon. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The product is a substantially clean-burning hydrogen fuel that leaves no greenhouse gas emissions, and elemental carbon that may be used in powder form as a commodity for several processes.
摘要翻译：提供了用于生产双原子氢和不饱和碳的快速骤冷反应器。在喷嘴的下游发散部分（例如自由膨胀室）中快速骤冷期间，不饱和烃通过再加热反应器气体进一步分解。产生更多的双原子氢以及元素碳。可以在该过程的不同阶段加入其它气体以形成期望的最终产物并防止反应。该产品是一种基本上清洁燃烧的氢燃料，其不会产生温室气体排放，并且可以以粉末形式使用的元素碳作为几种工艺的商品。

10. 发明授权

US06395197B1 Hydrogen and elemental carbon production from natural gas and other hydrocarbons 失效
标题翻译：从天然气和其他碳氢化合物生产氢和元素碳
公开(公告)号：US06395197B1
公开(公告)日：2002-05-28
申请号：US09732451
申请日：2000-12-06
申请人： Brent A. Detering , Peter C. Kong
发明人： Brent A. Detering , Peter C. Kong
IPC分类号： C07C102
CPC分类号： H01M8/0618 , B01J19/088 , B01J19/26 , B01J2219/00094 , B01J2219/00103 , B01J2219/00108 , B01J2219/00119 , B01J2219/00132 , B01J2219/00159 , B01J2219/00166 , B01J2219/0809 , B01J2219/0826 , B01J2219/083 , B01J2219/0845 , B01J2219/0875 , B01J2219/0879 , B01J2219/0894 , B01J2219/0898 , C01B3/24 , C01B3/34 , C01B32/05 , H01M8/0631 , Y02P20/129
摘要： Diatomic hydrogen and unsaturated hydrocarbons are produced as reactor gases in a fast quench reactor. During the fast quench, the unsaturated hydrocarbons are further decomposed by reheating the reactor gases. More diatomic hydrogen is produced, along with elemental carbon. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The product is a substantially clean-burning hydrogen fuel that leaves no greenhouse gas emissions, and elemental carbon that may be used in powder form as a commodity for several processes.
摘要翻译：双原子氢和不饱和烃在快速骤冷反应器中作为反应器气体生产。在快速淬火期间，不饱和烃通过再加热反应器气体进一步分解。产生更多的双原子氢以及元素碳。可以在该过程的不同阶段加入其它气体以形成期望的最终产物并防止反应。该产品是一种基本上清洁燃烧的氢燃料，其不会产生温室气体排放，并且可以以粉末形式使用的元素碳作为几种工艺的商品。

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