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    • 4. 发明授权
    • Method of acidizing a subterranean formation with diverting foam or fluid
    • 用转移泡沫或流体酸化地下地层的方法
    • US07510009B2
    • 2009-03-31
    • US11947473
    • 2007-11-29
    • Kay E. CawiezelJeffrey C. Dawson
    • Kay E. CawiezelJeffrey C. Dawson
    • E21B43/16
    • C09K8/72C09K8/74C09K2208/32Y10S507/933
    • A method of acidizing a subterranean formation with a diverting agent composed of a gelled or thickened viscoelastic foam or fluid generated from (i.) an amidoamine oxide gelling agent and (ii.) an acid or foam, water and/or brine. The gelled or thickened foam or fluid may be generated in-situ or introduced directly into the formation by mixing of the amidoamine oxide gelling agent and acid or foam, water and/or brine. As the acid spends, the acidizing fluid thickens. When the acid is further spent, the fluid viscosity declines eventually returning to a low viscosity state, allowing for easy cleanup. The process allows for selective acidizing of less permeable zones of the formation and more uniform stimulation of the hydrocarbon bearing formation.
    • 用由(i。)酰氨基胺氧化物胶凝剂和(ii)酸或泡沫,水和/或盐水产生的胶凝或增稠的粘弹性泡沫或流体组成的转移剂酸化地层的方法。 凝胶或增稠的泡沫或流体可以原位产生或通过混合酰胺胺氧化物胶凝剂和酸或泡沫,水和/或盐水直接引入地层中。 随着酸的消耗,酸化液变稠。 当酸被进一步消耗时,流体粘度下降最终回到低粘度状态,容易清理。 该方法允许选择性酸化地层的较低渗透性区域和对含烃地层的更均匀的刺激。
    • 8. 发明授权
    • Method and composition for delaying the gellation of borated
galactomannans
    • 延缓硼酸半乳甘露聚糖凝胶化的方法和组成
    • US5082579A
    • 1992-01-21
    • US465903
    • 1990-01-16
    • Jeffrey C. Dawson
    • Jeffrey C. Dawson
    • C08B37/00C09K8/68
    • C08B37/0087C09K8/685Y10S507/902Y10S507/903Y10S507/922
    • A complexor and method of use are shown for providing controlled delay of the cross-linking reaction in an aqueous well fracturing fluid. A base fluid is first prepared by blending together an aqueous fluid and a hydratable polymer which is capable of gelling in the presence of borate ions. The complexor is prepared by mixing a cross-linking additive capable of furnishing borate ions in solution with a delay additive, such as glyoxal. The delay additive is effective, within a selected pH range, to chemically bond with both boric acid and the borate ions produced by the cross-linking additive to theeby limit the number of borate ions initially available in solution for subsequent cross-linking of the hydratable polysaccharide. The subsequent rate of cross-linking of the polysaccharide can be controlled by adjusting the pH of the complexor solution.
    • 显示了一种复合剂和使用方法,用于在含水井压裂液中提供交联反应的受控延迟。 首先通过将含水流体和能够在硼酸根离子存在下凝胶化的可水合聚合物共混在一起来制备基础流体。 通过将能够在溶液中提供硼酸根离子的交联添加剂与延迟添加剂如乙二醛混合来制备络合物。 延迟添加剂在选定的pH范围内有效地与硼酸和由交联添加剂产生的硼酸根离子化学键合,以限制最初在溶液中可用的硼酸根离子的数量,以便后续的可水合交联剂的交联 多糖。 可以通过调节复合溶液的pH来控制多糖的随后的交联速率。
    • 10. 发明申请
    • Method of Acidizing a Subterranean Formation with Diverting Foam or Fluid
    • 用分流泡沫或流体酸化地下地层的方法
    • US20080121398A1
    • 2008-05-29
    • US11947473
    • 2007-11-29
    • Kay E. CawiezelJeffrey C. Dawson
    • Kay E. CawiezelJeffrey C. Dawson
    • E21B43/16
    • C09K8/72C09K8/74C09K2208/32Y10S507/933
    • A method of acidizing a subterranean formation with a diverting agent composed of a gelled or thickened viscoelastic foam or fluid generated from (i.) an amidoamine oxide gelling agent and (ii.) an acid or foam, water and/or brine. The gelled or thickened foam or fluid may be generated in-situ or introduced directly into the formation by mixing of the amidoamine oxide gelling agent and acid or foam, water and/or brine. As the acid spends, the acidizing fluid thickens. When the acid is further spent, the fluid viscosity declines eventually returning to a low viscosity state, allowing for easy cleanup. The process allows for selective acidizing of less permeable zones of the formation and more uniform stimulation of the hydrocarbon bearing formation.
    • 用由(i。)酰氨基胺氧化物胶凝剂和(ii)酸或泡沫,水和/或盐水产生的胶凝或增稠的粘弹性泡沫或流体组成的转移剂酸化地层的方法。 凝胶或增稠的泡沫或流体可以原位产生或通过混合酰胺胺氧化物胶凝剂和酸或泡沫,水和/或盐水直接引入地层中。 随着酸的消耗,酸化液变稠。 当酸被进一步消耗时,流体粘度下降最终回到低粘度状态,容易清理。 该方法允许选择性酸化地层的较低渗透性区域和对含烃地层的更均匀的刺激。