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    • 6. 发明授权
    • Fracturing using gel with ester delayed breaking
    • 使用具有酯延迟断裂的凝胶进行压裂
    • US06793018B2
    • 2004-09-21
    • US10041511
    • 2002-01-08
    • Jeffrey C. DawsonHoang Van Le
    • Jeffrey C. DawsonHoang Van Le
    • E21B4326
    • C09K8/887C09K8/685
    • A well treatment fluid composition comprises a solvent (such as water), a polymer soluble or hydratable in the solvent, a crosslinking agent, an inorganic breaking agent, and an ester compound. Preferably, the hydratable polymer is a polysaccharide, such as galactomannan, cellulose, or derivatives thereof. The crosslinking agent is preferably a borate, titanate, or zirconium-containing compound. The inorganic breaking agent is preferably a metal-based oxidizing agent, such as an alkaline earth metal or transition metal-based oxidizing agent. The ester compound is preferably an ester of polycarboxylic acid, such as an ester of oxalate, citrate, or ethylenediamine tetraacetate. One example of a suitable ester compound is acetyl triethyl citrate.
    • 良好的处理流体组合物包含溶剂(例如水),在溶剂中可溶或可水合的聚合物,交联剂,无机破坏剂和酯化合物。 优选地,可水合聚合物是多糖,例如半乳甘露聚糖,纤维素或其衍生物。 交联剂优选为硼酸盐,钛酸盐或含锆化合物。 无机破坏剂优选为金属类氧化剂,例如碱土金属或过渡金属类氧化剂。 酯化合物优选为多元羧酸的酯,例如草酸酯,柠檬酸酯或乙二胺四乙酸酯。 合适的酯化合物的一个实例是乙酰基柠檬酸三乙酯。
    • 10. 发明授权
    • Surfactant compositions and uses therefor
    • 表面活性剂组合物及其用途
    • US06302209B1
    • 2001-10-16
    • US09151169
    • 1998-09-10
    • Joseph E. Thompson, Sr.Harold D. BrannonGeorge Tso-Chih WooWilliam R. WoodJeffrey C. DawsonMarshall G. Ault
    • Joseph E. Thompson, Sr.Harold D. BrannonGeorge Tso-Chih WooWilliam R. WoodJeffrey C. DawsonMarshall G. Ault
    • E21B4300
    • B01F17/0028B01F17/0042B01F17/0057C09K8/035C09K8/602
    • Solid surfactant suspension compositions are formed by combining solid surfactants, such as alpha-olefin sulfonates, with an organic base fluid, such as diesel. Solid surfactant suspensions may be combined with an aqueous carrier fluid to form surfactant-containing fluids suitable for, among other things, forming foams or for water wetting surfaces. Solid surfactant suspensions may also be combined with additive materials, such as polymer particles, to form a dispersion or emulsion. Polymer-containing solid surfactant suspensions may also be combined with aqueous carrier fluids to form, for example, viscosified, gelled, or foamed fluids. Concentration of solid surfactant materials contained in a solid surfactant suspension may be varied to affect the function the solid surfactant suspension. For example, the solid surfactant material may function as a polymer surface wetting agent, an emulsifier, a dispersant, a viscosifier, and/or a foamer in well completion and remedial and/or workover fluids.
    • 固体表面活性剂悬浮液组合物通过将固体表面活性剂如α-烯烃磺酸盐与有机基础流体如柴油混合而形成。 固体表面活性剂悬浮液可以与含水载体流体组合以形成适于尤其形成泡沫或用于水润湿表面的含表面活性剂的流体。 固体表面活性剂悬浮液也可以与添加剂材料如聚合物颗粒结合以形成分散体或乳液。 含聚合物的固体表面活性剂悬浮液也可以与含水载体流体混合以形成例如粘稠的,胶凝的或发泡的流体。 包含在固体表面活性剂悬浮液中的固体表面活性剂材料的浓度可以变化以影响固体表面活性剂悬浮液的功能。 例如,固体表面活性剂材料可用作完井和补救和/或修井液中的聚合物表面润湿剂,乳化剂,分散剂,增粘剂和/或起泡剂。