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    • 6. 发明授权
    • Crosslinked polycyclooctene
    • 交联多环辛烯
    • US07173096B2
    • 2007-02-06
    • US10683559
    • 2003-10-10
    • Patrick T. MatherChangdeng LiuSeung B. ChunE. Bryan Coughlin
    • Patrick T. MatherChangdeng LiuSeung B. ChunE. Bryan Coughlin
    • C08F4/00
    • C08G18/3893C08G61/08C08G2230/00C08L65/00
    • Chemically crosslinked polycyclooctene having excellent shape recovery properties and a method for its synthesis via ring-opening methathesis polymerization of cyclooctene using the dihydroimidazolylidene-modified Grubbs catalyst are disclosed. The polycyclooctene products, following curing with dicumyl peroxide can be shaped, the shape memorized, a new shape imparted with the original shape being recoverable by suitable temperature adjustment. The dependence of shape memory characteristics on degree of crosslinking was established. In addition to polycyclooctene, blends thereof with other materials such as SBR, EVA, polyurethane rubbers, and inorganic fillers can be utilized to provide chemically crosslinked products having excellent and tailored shape memory properties.
    • 公开了具有优异的形状恢复性的化学交联的聚环辛烯和通过使用二氢咪唑基改性的Grubbs催化剂的环辛烯的开环错位聚合合成方法。 多环辛烯产物在用过氧化二异丙苯固化后可以成型,形状记忆,赋予原始形状的新形状可通过适当的温度调节而恢复。 形状记忆特性对交联度的依赖性已被确立。 除了聚环辛烯之外,可以使用其与其它材料如SBR,EVA,聚氨酯橡胶和无机填料的共混物来提供具有优良和定制形状记忆性质的化学交联产物。