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1. 发明授权

US06399171B1 Reactive silicone/alkylenimine barrier laminating adhesives and applications thereof 有权
标题翻译：活性硅酮/亚烷基亚胺屏障层压粘合剂及其应用
公开(公告)号：US06399171B1
公开(公告)日：2002-06-04
申请号：US09341252
申请日：1999-07-15
申请人： Patrick J. Merlin , Daniel Futter , John E. Wyman , Imtiaz Rangwalla , Gary Power , Karen Branch
发明人： Patrick J. Merlin , Daniel Futter , John E. Wyman , Imtiaz Rangwalla , Gary Power , Karen Branch
IPC分类号： B29D2200
CPC分类号： B32B27/08 , B32B7/12 , B32B2305/72 , B32B2310/0887 , B32B2439/00 , C09J4/00 , C09J4/06 , Y10T428/1383 , C08F220/00 , C08F283/00
摘要： The invention relates to a method of laminating two substrates by coating at least one side of a substrate with a laminating adhesive, bringing a coated side of said substrate into contact with a second substrate to form a three layer film, and treating said three layer film with a free radical initiator, wherein said laminating adhesive is formed by mixing an ethylenically unsaturated acid and a polyamine.
摘要翻译：本发明涉及一种通过用层压粘合剂涂覆基板的至少一侧来层压两个基板的方法，使所述基板的涂覆侧与第二基板接触以形成三层膜，并且处理所述三层膜具有自由基引发剂，其中所述层压粘合剂通过混合烯属不饱和酸和多胺而形成。

2. 发明授权

US06794042B1 Barrier coatings 失效
标题翻译：阻隔涂层
公开(公告)号：US06794042B1
公开(公告)日：2004-09-21
申请号：US09341254
申请日：1999-12-17
申请人： Patrick J. Merlin , John E. Wyman , Imtiaz Rangwalla , Daniel Futter , Gary Power , Karen Branch
发明人： Patrick J. Merlin , John E. Wyman , Imtiaz Rangwalla , Daniel Futter , Gary Power , Karen Branch
IPC分类号： B29D2200
CPC分类号： C09D4/00 , C08F290/14 , C08L51/003 , C09D4/06 , Y10T428/31551 , Y10T428/31663 , C08L2666/02 , C08F220/00
摘要： The present invention teaches a composition which provides gas, flavor, and aroma barrier to substrates, where the composition is formed by mixing an ethylenically unsaturated acid and a polyamine, wherein said polyamine optionally has a crosslinker reacted therein, and wherein said polyamine has four or more A, B, or C units, where: A is an —R2—N(R1)2 unit, B is an —R1—N(R2—)2 unit, and C is an (—R2)3N— unit, where: R1 is independently selected from hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and alkylaryl, and R2 is independently selected from the group consisting of: linear or branched alkylene groups or substituted alkylene groups having from 1 to 18 carbon atoms, and arylene groups or substituted arylene groups having from 6 to 18 carbon atoms. The composition is coated on a substrate then optionally treated to initiate a free radical reaction. The invention can be applied as a coating to a variety of substrates used in packaging applications.
摘要翻译：本发明教导了一种通过混合烯键式不饱和酸和多胺形成组合物的方法，其中所述组合物提供气体，风味和香气阻挡物，其中所述多胺任选地具有在其中反应的交联剂，并且其中所述多胺具有四个或更多的A，B或C单元，其中：A是-R 2 -N（R 1）2单元，B是-R 1 -N（R 2 - ）2单元，并且C是（-R 2）3 N-单元，其中：R 1独立地选自氢，烷基，取代的烷基，芳基，取代的芳基，芳烷基和烷芳基，R 2独立地选自由具有1至18个碳原子的直链或支链亚烷基或取代的亚烷基组成的基团，以及具有6至18个碳原子的亚芳基或取代的亚芳基。然后将组合物涂布在基材上，然后任选地处理以引发自由基反应。本发明可以用作包装应用中使用的各种基材的涂层。

3. 发明授权

US06686008B1 Silicone/multifunctional acrylate barrier coatings 有权
标题翻译：硅胶/多功能丙烯酸酯屏障涂料
公开(公告)号：US06686008B1
公开(公告)日：2004-02-03
申请号：US09341253
申请日：1999-12-17
申请人： Patrick J. Merlin , Daniel Futter , John E. Wyman , Imtiaz Rangwalla , Gary Power , Karen Branch
发明人： Patrick J. Merlin , Daniel Futter , John E. Wyman , Imtiaz Rangwalla , Gary Power , Karen Branch
IPC分类号： B32B2708
CPC分类号： C08F290/14 , B65D65/38 , Y10T428/1352 , Y10T428/1393
摘要： The invention is a composition made by mixing a multifunctional acrylate with an aminofunctional silane and an ethylenically unsaturated acid to form a reaction product, optionally dissolved in a solvent, characterized in that the multifunctional acrylate has a molecular weight of from about 100 to about 3000. The composition can be coated on a substrate, then optionally exposed to moisture and treated to initiate a free radical reaction. The invention can be applied to a variety of substrates used in packaging applications. The reaction mixture can further be cured by heating in the presence of moisture. The free radical reaction can be initiated by electron beam irradiation, ultraviolet radiation, gamma radiation, and/or heat and chemical free radical initiators.
摘要翻译：本发明是通过将多官能丙烯酸酯与氨基官能硅烷和烯属不饱和酸混合以形成任选溶解在溶剂中的反应产物而制得的组合物，其特征在于所述多官能丙烯酸酯具有约100至约3000的分子量。组合物可以涂覆在基材上，然后任选地暴露于水分并进行处理以引发自由基反应。本发明可应用于包装应用中使用的各种基材。反应混合物可以通过在水分存在下加热而进一步固化。自由基反应可以由电子束照射，紫外线辐射，γ辐射和/或热和化学自由基引发剂引发。

4. 发明授权

US06514584B1 Silicone containing laminate adhesive 有权
标题翻译：含硅胶层压胶粘剂
公开(公告)号：US06514584B1
公开(公告)日：2003-02-04
申请号：US09341255
申请日：1999-07-15
申请人： Patrick J. Merlin , Daniel Futter , John E. Wyman , Imtiaz Rangwalla , Gary Power , Karen Branch
发明人： Patrick J. Merlin , Daniel Futter , John E. Wyman , Imtiaz Rangwalla , Gary Power , Karen Branch
IPC分类号： B29D2200
CPC分类号： C09D4/00 , C08F290/14 , C08L51/003 , C09D4/06 , Y10T428/1383 , C08L2666/02 , C08F220/00
摘要： The invention is a laminate structure made by coating at least one side of a substrate with a laminating adhesive, bringing a coated side of said substrate into contact with a second substrate to form a multi-layer film, and treating said multi-layer film with a free radical initiator, wherein said laminating adhesive is the reaction product of a multifunctional acrylate, an aminofunctional silane, and an ethylenically unsaturated acid, optionally dissolved in a solvent, wherein the multifunctional acrylate has a molecular weight of from 100 to 3000.
摘要翻译：本发明是通过用层压粘合剂涂布基板的至少一侧而形成的层压结构体，使所述基板的涂布面与第二基板接触以形成多层膜，并且将所述多层膜用自由基引发剂，其中所述层压粘合剂是任选溶解在溶剂中的多官能丙烯酸酯，氨基官能硅烷和烯属不饱和酸的反应产物，其中所述多官能丙烯酸酯的分子量为100至3000。

5. 发明授权

US5215822A Method of imbuing organic polymer films with improved gas impermeability characteristics and improved barrier coatings therefor 失效
标题翻译：有机聚合物薄膜与改进的气体不可逆性特性及其改进的阻挡涂层的方法
公开(公告)号：US5215822A
公开(公告)日：1993-06-01
申请号：US663666
申请日：1991-03-01
申请人： John E. Wyman , Imtiaz Rangwalla
发明人： John E. Wyman , Imtiaz Rangwalla
IPC分类号： C07C57/13 , C07F7/04 , C08J7/04 , C08J7/18 , C09D4/00 , C09D183/04
CPC分类号： C08J7/047 , C09D183/04 , C09D4/00 , C08J2483/00 , Y10T428/31663
摘要： This invention embraces a method of controlling the impermeability of an organic polymer film to gases such as oxygen, aroma, flavor and fragrance and the like to produce gas impermeable organic polymer films by coating with a mixture of a siloxane monomer with carboxylic acid in an alcohol solvent and evaporating the solvent to complete the formation of Si--O--Si bonds; and then polymerizing and grafting the coating, preferably by electron beam radiation, to the polymer film. Improved coated polymer films and formulation products therefor are also provided.

6. 发明授权

US08784945B2 Materials treatable by particle beam processing apparatus and methods of making the same 有权
标题翻译：可通过粒子束处理装置处理的材料及其制造方法
公开(公告)号：US08784945B2
公开(公告)日：2014-07-22
申请号：US12249231
申请日：2008-10-10
申请人： Imtiaz Rangwalla
发明人： Imtiaz Rangwalla
IPC分类号： C08F2/54
CPC分类号： B41M7/0081 , Y10T428/1486 , Y10T428/216 , Y10T428/24851 , Y10T428/24876 , Y10T428/24901 , Y10T428/24942
摘要： The present invention is directed to methods for making materials treatable by electron beam (EB) processing, such as materials for flexible packaging, comprising: providing a substrate; applying an ink formulation on at least a portion of the substrate, the ink formulation comprising ink and at least one monomer selected from acrylates, vinyl ethers, cycloaliphatic diepoxides, and polyols; and applying a lacquer on at least a portion of the ink formulation, the lacquer comprising at least one monomer selected from acrylates, vinyl ethers, cycloaliphatic diepoxides, and polyols. The processing apparatus for EB treating the material operates at a low voltage, such as 110 kVolts or below.
摘要翻译：本发明涉及用于制造可通过电子束（EB）处理的材料的方法，例如用于软包装的材料，包括：提供基底; 在油墨配方的至少一部分上施用油墨配方，所述油墨配方包括油墨和至少一种选自丙烯酸酯，乙烯基醚，脂环族二环氧化物和多元醇的单体; 以及在油墨配方的至少一部分上施加漆，所述漆包含至少一种选自丙烯酸酯，乙烯基醚，脂环族二环氧化物和多元醇的单体。用于处理材料的EB的处理装置在110kV或更低的低电压下操作。

7. 发明授权

US06610376B1 Particle beam processing apparatus 有权
公开(公告)号：US06610376B1
公开(公告)日：2003-08-26
申请号：US09725471
申请日：2000-11-30
申请人： Imtiaz Rangwalla , Harvey Clough , George Hannafin
发明人： Imtiaz Rangwalla , Harvey Clough , George Hannafin
IPC分类号： C08F252
CPC分类号： H01J33/00 , B05D3/068
摘要： The present invention is directed to a particle beam processing apparatus that is smaller in size and operates at a higher efficiency. The processing apparatus includes a particle beam generating assembly, a foil support assembly, and a processing assembly. In the particle beam generating assembly, a cloud of particles, for example, electrons, are generated by heating at least one tungsten filament. The electrons are then extracted to travel at a high speed to the foil support assembly which is set at a much lower voltage than the particle beam generating assembly. A substrate is fed to the processing apparatus through the processing zone and is exposed to the electrons exiting the particle beam generating assembly and entering the processing zone. The electrons penetrate and cure the substrate causing a chemical reaction, such as polymerization, cross-linking, or sterilization.

8. 发明授权

US06426507B1 Particle beam processing apparatus 有权
标题翻译：粒子束处理装置
公开(公告)号：US06426507B1
公开(公告)日：2002-07-30
申请号：US09434380
申请日：1999-11-05
申请人： Imtiaz Rangwalla , Harvey Clough , George Hannafin
发明人： Imtiaz Rangwalla , Harvey Clough , George Hannafin
IPC分类号： A61N500
CPC分类号： H01J33/00 , B05D3/068
摘要： The present invention is directed to a particle beam processing apparatus that is smaller in size and operates at a higher efficiency. The processing apparatus includes a particle beam generating assembly, a foil support assembly, and a processing assembly. In the particle beam generating assembly, a cloud of particles, for example, electrons, are generated by heating at least one tungsten filament. The electrons are then extracted to travel at a high speed to the foil support assembly which is set at a much lower voltage than the particle beam generating assembly. A substrate is fed to the processing apparatus through the processing zone and is exposed to the electrons exiting the particle beam generating assembly and entering the processing zone. The electrons penetrate and cure the substrate causing a chemical reaction, such as polymerization, cross-linking, or sterilization.
摘要翻译：本发明涉及一种尺寸更小并以更高效率工作的粒子束处理装置。处理装置包括粒子束产生组件，箔支撑组件和处理组件。在粒子束产生组件中，通过加热至少一根钨丝来产生颗粒云，例如电子。然后提取电子以高速行进到箔片支撑组件，箔片支撑组件设置在比颗粒束产生组件低得多的电压下。衬底通过处理区被馈送到处理装置，并暴露于离开粒子束产生组件并进入处理区的电子。电子穿透和固化基板，导致化学反应，如聚合，交联或灭菌。

9. 发明申请

US20090035479A1 MATERIALS TREATABLE BY PARTICLE BEAM PROCESSING APPARATUS 有权
标题翻译：材料可通过颗粒束加工设备进行处理
公开(公告)号：US20090035479A1
公开(公告)日：2009-02-05
申请号：US12249231
申请日：2008-10-10
申请人： Imtiaz Rangwalla
发明人： Imtiaz Rangwalla
IPC分类号： B05D5/00 , B05D3/06 , B41F7/00
CPC分类号： B41M7/0081 , Y10T428/1486 , Y10T428/216 , Y10T428/24851 , Y10T428/24876 , Y10T428/24901 , Y10T428/24942
摘要： The present invention is directed to materials treatable by electron beam (EB) processing, such as materials for flexible packaging. The material comprises a substrate; an ink formulation on at least a portion of the substrate, the ink formulation comprising ink and at least one monomer selected from acrylate esters, vinyl ethers, cycloaliphatic diepoxides, and polyols; and a lacquer on at least a portion of the ink formulation, the lacquer comprising at least one monomer selected from acrylate esters, vinyl ethers, cycloaliphatic diepoxides, and polyols. The processing apparatus for EB treating the material operates at a low voltage, such as 125 kVolts or less.
摘要翻译：本发明涉及可通过电子束（EB）处理的材料，例如用于软包装的材料。该材料包括基材; 所述油墨配方包含油墨和至少一种选自丙烯酸酯，乙烯基醚，脂环族二环氧化物和多元醇的单体; 和至少一部分油墨配方上的漆，所述漆包含至少一种选自丙烯酸酯，乙烯基醚，脂环族二环氧化物和多元醇的单体。用于EB处理的处理装置在低电压下操作，例如125kVol或更小。

10. 发明授权

US07449232B2 Materials treatable by particle beam processing apparatus 有权
标题翻译：可用粒子束处理装置处理的材料
公开(公告)号：US07449232B2
公开(公告)日：2008-11-11
申请号：US10823920
申请日：2004-04-14
申请人： Imtiaz Rangwalla
发明人： Imtiaz Rangwalla
IPC分类号： B32B3/00 , B32B7/06
CPC分类号： B41M7/0081 , Y10T428/1486 , Y10T428/216 , Y10T428/24851 , Y10T428/24876 , Y10T428/24901 , Y10T428/24942
摘要： The present invention is directed to materials treatable by electron beam (EB) processing, such as materials for flexible packaging. The material comprises a substrate; an ink formulation on at least a portion of the substrate, the ink formulation comprising ink and at least one monomer selected from acrylate esters, vinyl ethers, cycloaliphatic diepoxides, and polyols; and a lacquer on at least a portion of the ink formulation, the lacquer comprising at least one monomer selected from acrylate esters, vinyl ethers, cycloaliphatic diepoxides, and polyols. The processing apparatus for EB treating the material operates at a low voltage, such as 125 kVolts or less.
摘要翻译：本发明涉及可通过电子束（EB）处理的材料，例如用于软包装的材料。该材料包括基材; 在所述基材的至少一部分上的油墨制剂，所述油墨制剂包含油墨和至少一种选自丙烯酸酯，乙烯基醚，脂环族二环氧化物和多元醇的单体; 和至少一部分油墨配方上的漆，所述漆包含至少一种选自丙烯酸酯，乙烯基醚，脂环族二环氧化物和多元醇的单体。用于EB处理的处理装置在低电压下操作，例如125kVol或更小。

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