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1. 发明授权

US07655136B2 Process for producing middle distillates by hydroisomerizing and hydrocracking feeds from the Fischer-Tropsch process using a doped catalyst based on mesoporous alumina-silica with a controlled macropore content 有权
标题翻译：通过使用基于具有受控大孔含量的介孔氧化铝 - 二氧化硅的掺杂催化剂从费 - 托方法加氢异构化和加氢裂化原料来生产中间馏分的方法
公开(公告)号：US07655136B2
公开(公告)日：2010-02-02
申请号：US11475259
申请日：2006-06-27
申请人： Patrick Euzen , Christophe Gueret , Vincenzo Calemma
发明人： Patrick Euzen , Christophe Gueret , Vincenzo Calemma
IPC分类号： C10G11/02
CPC分类号： B01J21/12 , B01J23/24 , B01J23/40 , B01J23/42 , B01J23/74 , B01J23/85 , B01J27/1856 , B01J35/0066 , B01J35/0093 , B01J35/10 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/108 , C10G47/18 , C10G65/12 , C10G65/14 , C10G2400/04 , C10G2400/06
摘要： The invention concerns a process for producing middle distillates from a paraffinic feed produced by Fischer-Tropsch synthesis, using a hydrocracking/hydroisomerization catalyst which comprises: at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table; 0.01% to 6% of phosphorus as a doping element; and a non-zeolitic support based on mesoporous alumina-silica.
摘要翻译：本发明涉及一种使用加氢裂化/加氢异构化催化剂由费 - 托合成生产的链烷烃进料生产中间馏分的方法，所述加氢裂化/加氢异构化催化剂包括：至少一种选自由周期性的VIB族和VIII族的元素形成的加氢元素表; 0.01〜6％的磷作为掺杂元素; 和基于介孔氧化铝 - 二氧化硅的非沸石载体。

2. 发明授权

US07658836B2 Process for producing middle distillates by hydroisomerizing and hydrocracking feeds from the Fischer-Tropsch process using a multifunctional guard bed 有权
标题翻译：通过使用多功能保护床从费 - 托方法加氢异构化和加氢裂化原料生产中间馏分的方法
公开(公告)号：US07658836B2
公开(公告)日：2010-02-09
申请号：US11487591
申请日：2006-07-17
申请人： Patrick Euzen , Vincenzo Calemma
发明人： Patrick Euzen , Vincenzo Calemma
IPC分类号： C10G65/00 , C10G69/00 , C10G47/00
CPC分类号： B01J23/883 , B01J8/0207 , B01J21/12 , B01J23/40 , B01J27/19 , B01J35/0006 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J2208/025 , B01J2219/00038 , C10G2/32 , C10G45/38 , C10G47/14 , C10G65/12 , Y10S208/95
摘要： The process of producing middle distillates from effluents obtained by a Fischer-Tropsch synthesis, comprises a step for hydro-treatment and purification and/or decontamination by passage over a multi-functional guard bed prior to a step of hydrocracking/hydroisomerization. The guard bed reduces the amount of unsaturated compounds, oxygen-containing compounds, particulate mineral solids, and organometallic compounds.
摘要翻译：通过费 - 托合成获得的流出物生产中间馏分的方法包括在加氢裂化/加氢异构化步骤之前通过多功能保护床进行加氢处理和净化和/或去污的步骤。防护床减少了不饱和化合物，含氧化合物，微粒矿物固体和有机金属化合物的量。

3. 发明申请

US20070017850A1 Process for producing middle distillates by hydroisomerizing and hydrocracking feeds from the Fischer-Tropsch process using a multifunctional guard bed 有权
标题翻译：通过使用多功能保护床从费 - 托方法加氢异构化和加氢裂化原料生产中间馏分的方法
公开(公告)号：US20070017850A1
公开(公告)日：2007-01-25
申请号：US11487591
申请日：2006-07-17
申请人： Patrick Euzen , Vincenzo Calemma
发明人： Patrick Euzen , Vincenzo Calemma
IPC分类号： C10G65/00 , C10G69/00 , C10G47/00
CPC分类号： B01J23/883 , B01J8/0207 , B01J21/12 , B01J23/40 , B01J27/19 , B01J35/0006 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J2208/025 , B01J2219/00038 , C10G2/32 , C10G45/38 , C10G47/14 , C10G65/12 , Y10S208/95
摘要： The invention concerns a process for producing middle distillates from effluents obtained by Fischer-Tropsch synthesis, comprising a step for hydrotreatment and purification and/or decontamination by passage over a multifunctional guard bed. The invention also concerns a facility.
摘要翻译：本发明涉及一种通过费 - 托合成得到的流出物生产中间馏分的方法，包括通过多功能保护床通过加氢处理和净化和/或去污的步骤。本发明还涉及一种设施。

4. 发明申请

US20070056879A1 Process for producing middle distillates by hydroisomerizing and hydrocracking feeds from the fischer-tropsch process using a doped catalyst based on mesoporous alumina-silica with a controlled macropore content 有权
标题翻译：通过使用基于具有受控大孔含量的介孔氧化铝 - 二氧化硅的掺杂催化剂从费托方法加氢异构化和加氢裂化原料来生产中间馏分的方法
公开(公告)号：US20070056879A1
公开(公告)日：2007-03-15
申请号：US11475259
申请日：2006-06-27
申请人： Patrick Euzen , Christophe Gueret , Vincenzo Calemma
发明人： Patrick Euzen , Christophe Gueret , Vincenzo Calemma
IPC分类号： C10G47/24 , C10G47/02
CPC分类号： B01J21/12 , B01J23/24 , B01J23/40 , B01J23/42 , B01J23/74 , B01J23/85 , B01J27/1856 , B01J35/0066 , B01J35/0093 , B01J35/10 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/108 , C10G47/18 , C10G65/12 , C10G65/14 , C10G2400/04 , C10G2400/06
摘要： The invention concerns a process for producing middle distillates from a paraffinic feed produced by Fischer-Tropsch synthesis, using a hydrocracking/hydroisomerization catalyst which comprises: at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table; 0.01% to 6% of phosphorus as a doping element; and a non-zeolitic support based on mesoporous alumina-silica.
摘要翻译：本发明涉及一种使用加氢裂化/加氢异构化催化剂由费 - 托合成生产的链烷烃进料生产中间馏分的方法，所述加氢裂化/加氢异构化催化剂包括：至少一种选自由周期性的VIB族和VIII族的元素形成的加氢元素表; 0.01〜6％的磷作为掺杂元素; 和基于介孔氧化铝 - 二氧化硅的非沸石载体。

5. 发明申请

US20090232720A1 MESOSTRUCTURED ALUMINOSILICATE MATERIAL 有权
标题翻译：结构化铝氧化物材料
公开(公告)号：US20090232720A1
公开(公告)日：2009-09-17
申请号：US12408437
申请日：2009-03-20
申请人： Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Patrick Euzen , Cedric Boissiere , David Grosso
发明人： Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Patrick Euzen , Cedric Boissiere , David Grosso
IPC分类号： C01B33/26
CPC分类号： B01J35/0013 , B01J29/041 , B01J35/023 , B01J35/10 , B01J35/1023 , B01J37/0045 , C01B39/02
摘要： A mesostructured aluminosilicate material is described, constituted by at least two spherical elementary particles, each of said spherical particles being constituted by a matrix based on silicon oxide and aluminium oxide, having a pore size in the range 1.5 to 30 nm, a Si/Al molar ratio of at least 1, having amorphous walls with a thickness in the range 1 to 20 nm, said spherical elementary particles having a maximum diameter of 10 μm. A process for preparing said material and its application in the fields of refining and petrochemistry are also described.
摘要翻译：描述了由至少两个球形基本粒子构成的介孔结构的硅铝酸盐材料，每个所述球形颗粒由基于氧化硅和氧化铝的基体构成，孔径在1.5至30nm的范围内，Si / Al 摩尔比至少为1，具有厚度在1至20nm范围内的非晶壁，所述球形基本颗粒的最大直径为10μm。还描述了制备所述材料的方法及其在精炼和石油化学领域的应用。

6. 发明申请

US20090188834A1 Doped alumino-silicate catalyst and improved process for treatment of hydrocarbon feeds 有权
标题翻译：掺杂铝硅酸盐催化剂和改进的烃类进料处理方法
公开(公告)号：US20090188834A1
公开(公告)日：2009-07-30
申请号：US11663497
申请日：2005-09-20
申请人： Patrick Euzen , Alexandra Chaumonnot , Magalie Roy-Auberger , Partick Bourges , Tivadar Cseri , Maryline Delage , Nathalie Lett
发明人： Patrick Euzen , Alexandra Chaumonnot , Magalie Roy-Auberger , Partick Bourges , Tivadar Cseri , Maryline Delage , Nathalie Lett
IPC分类号： C10G47/20 , B01J27/19 , B01J27/188 , B01J27/185 , B01J21/12 , B01J21/02
CPC分类号： B01J21/12 , B01J21/02 , B01J23/883 , B01J23/888 , B01J27/1853 , B01J27/188 , B01J35/0006 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/1066 , B01J35/108 , B01J37/0201 , B01J37/20 , B01J37/28 , C10G49/02 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018
摘要： The present invention concerns doped catalysts on an alumino-silicate support with an adapted macropore content and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table, a controlled quantity of phosphorus (optionally in combination with boron and/or silicon) as a doping element, and a non-zeolitic support based on alumina-silica containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).
摘要翻译：本发明涉及具有适用的大孔含量和加氢裂化/加氢转化和使用它们的加氢处理方法的铝硅酸盐载体上的掺杂催化剂。该催化剂包含至少一种选自元素周期表第VIB族和第VIII族的元素形成的氢化脱氢元素，受控量的磷（任选与硼和/或硅组合）作为掺杂元素， - 基于含有大于5重量％和95重量％或更少的二氧化硅（SiO 2）的量的氧化铝 - 二氧化硅的硅铝石载体。

7. 发明申请

US20090029847A1 Mesostructured material with a high aluminium content 有权
标题翻译：具有高铝含量的中等结构材料
公开(公告)号：US20090029847A1
公开(公告)日：2009-01-29
申请号：US11889891
申请日：2007-08-17
申请人： Patrick Euzen , Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Cedric Boissiere , David Grosso
发明人： Patrick Euzen , Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Cedric Boissiere , David Grosso
IPC分类号： B01J29/06
CPC分类号： C01B39/04 , B01J20/08 , B01J20/16 , B01J20/18 , B01J20/28007 , B01J20/28083 , B01J29/041 , B01J29/08 , B01J29/40 , B01J29/60 , B01J29/7007 , B01J29/80 , B01J2229/62 , B82Y30/00 , C01B39/48
摘要： A mesostructured material that consists of at least two elementary spherical particles, each of said particles comprising a mesostructured matrix based on aluminum oxide and having a pore size of between 1.5 and 30 nm, an aluminum oxide content that represents more than 46% by weight relative to the mass of said matrix, which has amorphous walls with a thickness of between 1 and 30 nm and whereby said elementary spherical particles have a maximum diameter of 10 μm, is described. Said mesostructured matrix can also contain silicon oxide. Each of the spherical particles of the mesostructured material can also contain zeolitic nanocrystals so as to form a material with a mixed porosity that is both mesostructured and zeolitic in nature. The preparation of said material is also described.
摘要翻译：由至少两个基本球形颗粒组成的介孔结构材料，每个所述颗粒包含基于氧化铝的孔结构基质，孔径在1.5至30nm之间，氧化铝含量相对于46重量％涉及具有1至30nm厚度的非晶壁的所述基体的质量，并且由此所述基本球形颗粒的最大直径为10um。所述介孔结构的基质也可以含有氧化硅。介孔结构材料的每个球形颗粒也可以含有沸石纳米晶体，以便形成具有混合孔隙率的材料，其本质上是介孔结构和沸石。还描述了所述材料的制备。

8. 发明授权

US07262333B2 Process for the production of phenylalkanes that use a catalyst based on silicated alumina 有权
标题翻译：制备使用基于硅酸铝的催化剂的苯基烷烃的方法
公开(公告)号：US07262333B2
公开(公告)日：2007-08-28
申请号：US10981740
申请日：2004-11-05
申请人： Patrick Euzen , Emmanuelle Guillon
发明人： Patrick Euzen , Emmanuelle Guillon
IPC分类号： C07C2/68
CPC分类号： B01J21/12 , B01J23/42 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J35/108 , B01J37/0009 , C07C2/66 , C07C15/107
摘要： The invention relates to a process for the production of at least one compound that is selected from among the 2-, 3-, 4-, 5-, and 6-phenylalkanes by alkylation of an aromatic compound by means of at least one olefin that comprises at least 9 carbon atoms per molecule, in the presence of a catalyst that comprises at least one non-zeolitic substrate with a silicated alumina base that contains an amount of more than 6% by weight and less than or equal to 50% by weight of silica (SiO2) and that exhibits particular characteristics, whereby said process is carried out at a temperature of between 30 and 400° C., a pressure of between 0.1 and 10 MPa, an hourly volumetric flow rate of 0.50 to 200 h−1, and an aromatic compound/olefin molar ratio of between 1:1 and 50:1.
摘要翻译：本发明涉及一种通过至少一种烯烃将芳族化合物烷基化制备至少一种选自2-，3-，4-，5-和6-苯基烷烃的化合物的方法，在每个分子中包含至少9个碳原子的催化剂存在下，所述催化剂包含至少一种非沸石基质，其中硅烷氧化铝基质含量超过6重量％且小于或等于50重量％的二氧化硅（SiO 2），并且其表现出特定的特性，由此所述方法在30至400℃的温度下进行，压力为0.1至10MPa，小时体积流速为0.50至200h -1 ，芳香族化合物/烯烃的摩尔比为1：1〜50：1。

9. 发明申请

US20070108102A1 Method for treating a hydrocarbon feedstock including resin removal 有权
标题翻译：用于处理包括树脂去除的烃原料的方法
公开(公告)号：US20070108102A1
公开(公告)日：2007-05-17
申请号：US10584048
申请日：2004-12-13
申请人： Christophe Gueret , Raphael Huyghe , Hugues Dulot , Patrick Euzen
发明人： Christophe Gueret , Raphael Huyghe , Hugues Dulot , Patrick Euzen
IPC分类号： C10G7/00 , B01D3/00
CPC分类号： C10G21/14 , C10G47/00 , C10G67/049 , C10G2300/107 , C10G2300/1077 , C10G2300/301 , C10G2300/44
摘要： The invention relates to a process, including removal of resins, for the treatment of a hydrocarbon charge, at least 80% of the compounds of which have a boiling point which is above or equal to 340° C., in which process: the charge is sent to a fractionation stage during which the recovery takes place of at least one heavy fraction and at least one light fraction, at least some of the heavy fraction is sent to an extraction stage during which resins contained in said heavy fraction are extracted, and a purified fraction is recovered, a mixture is made which comprises at least part of the purified fraction which was obtained in the extraction stage and at least one light fraction which was obtained in the fractionation stage, and the mixture thus obtained is sent to a cracking stage. Drawing to be published.
摘要翻译：本发明涉及一种方法，包括除去树脂，用于处理烃装料，其中至少80％的化合物具有高于或等于340℃的沸点，其中所述装料送入分馏阶段，在此阶段，回收发生至少一个重馏分和至少一个轻馏分，至少部分重馏分被送至萃取阶段，在此阶段萃取所述重馏分中所含的树脂，以及回收纯化的馏分，制备包含在萃取阶段获得的至少一部分纯化级分和在分馏阶段获得的至少一种轻馏分的混合物，将得到的混合物送入裂化阶段。绘图出版。

10. 发明授权

US06284210B1 Combustion catalyst and combustion process using such a catalyst 失效
标题翻译：燃烧催化剂和使用这种催化剂的燃烧过程
公开(公告)号：US06284210B1
公开(公告)日：2001-09-04
申请号：US08857072
申请日：1997-05-15
申请人： Patrick Euzen , Eric Tocque , Stephane Rebours , Gil Mabilon
发明人： Patrick Euzen , Eric Tocque , Stephane Rebours , Gil Mabilon
IPC分类号： B01J802
CPC分类号： F23C13/00 , B01J23/894
摘要： A combustion catalyst comprising a monolithic substrate, a porous support based on refractory inorganic oxide and an active phase formed by cerium, iron and at least one metal selected from the group formed by palladium and platinum, the content of porous support being between 100 and 400 g per liter of catalyst; the content of cerium being between 0.3 and 20% by weight with respect to the porous support; the content of iron being between 0.01 and 3.5% of iron by weight with respect to the porous support; and the content of palladium and/or platinum being between 3 and 20 g per liter of catalyst. The catalyst of the invention is used in particular in processes for the catalytic combustion of hydrocarbons, carbon monoxide, hydrogen or mixtures thereof, in processes involving one or more catalytic stages.
摘要翻译：一种燃烧催化剂，其包含整体式基体，基于耐火无机氧化物的多孔载体和由铈，铁和选自钯和铂形成的基团中的至少一种金属形成的活性相，多孔载体的含量为100-400 g每升催化剂; 相对于多孔载体，铈的含量为0.3〜20重量％铁的含量相对于多孔载体为铁的重量的0.01％至3.5％; 钯和/或铂的含量为3至20克/升催化剂。本发明的催化剂特别用于烃，一氧化碳，氢气或其混合物的催化燃烧方法中，涉及一种或更多的催化阶段。

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