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1. 发明授权

US08002970B2 Zeolitic catalyst with a controlled doping element content, and improved process for processing hydrocarbon feeds 有权
标题翻译：具有受控掺杂元素含量的沸石催化剂，以及用于处理烃进料的改进方法
公开(公告)号：US08002970B2
公开(公告)日：2011-08-23
申请号：US11722610
申请日：2005-12-13
申请人： Patrick Euzen , Patrick Bourges , Christophe Gueret , Carole Bobin , Alexandra Chaumonnot , Hugues Dulot
发明人： Patrick Euzen , Patrick Bourges , Christophe Gueret , Carole Bobin , Alexandra Chaumonnot , Hugues Dulot
IPC分类号： C10G47/00
CPC分类号： B01J37/0009 , B01J21/12 , B01J29/146 , B01J29/166 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1061 , B01J35/108 , B01J2229/20 , B01J2229/42 , C10G47/14 , C10G47/20 , C10G65/12 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018
摘要： The present invention concerns doped catalysts on a mixed zeolite/alumino-silicate support with a low macropore content, and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table and a doping element in a controlled quantity selected from phosphorus, boron and silicon, and a support based on zeolite Y defined by a lattice parameter a of the unit cell in the range 24.40×10−10 m to 24.15×10−10 m and silica-alumina containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).
摘要翻译：本发明涉及具有低大孔含量的混合沸石/铝硅酸盐载体上的掺杂催化剂，以及使用它们的加氢裂化/加氢转化和加氢处理方法。该催化剂包含至少一种选自由元素周期表第ⅥB族和第Ⅷ族元素形成的基团和选自磷，硼和硅的受控量的掺杂元素和基于沸石Y的载体的脱氢元素，在24.40×10-10 m至24.15×10-10m范围内的晶胞的晶格参数a和含有多于5重量％和95重量％以下的二氧化硅（SiO 2）的二氧化硅 - 氧化铝，。

2. 发明授权

US07655136B2 Process for producing middle distillates by hydroisomerizing and hydrocracking feeds from the Fischer-Tropsch process using a doped catalyst based on mesoporous alumina-silica with a controlled macropore content 有权
标题翻译：通过使用基于具有受控大孔含量的介孔氧化铝 - 二氧化硅的掺杂催化剂从费 - 托方法加氢异构化和加氢裂化原料来生产中间馏分的方法
公开(公告)号：US07655136B2
公开(公告)日：2010-02-02
申请号：US11475259
申请日：2006-06-27
申请人： Patrick Euzen , Christophe Gueret , Vincenzo Calemma
发明人： Patrick Euzen , Christophe Gueret , Vincenzo Calemma
IPC分类号： C10G11/02
CPC分类号： B01J21/12 , B01J23/24 , B01J23/40 , B01J23/42 , B01J23/74 , B01J23/85 , B01J27/1856 , B01J35/0066 , B01J35/0093 , B01J35/10 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/108 , C10G47/18 , C10G65/12 , C10G65/14 , C10G2400/04 , C10G2400/06
摘要： The invention concerns a process for producing middle distillates from a paraffinic feed produced by Fischer-Tropsch synthesis, using a hydrocracking/hydroisomerization catalyst which comprises: at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table; 0.01% to 6% of phosphorus as a doping element; and a non-zeolitic support based on mesoporous alumina-silica.
摘要翻译：本发明涉及一种使用加氢裂化/加氢异构化催化剂由费 - 托合成生产的链烷烃进料生产中间馏分的方法，所述加氢裂化/加氢异构化催化剂包括：至少一种选自由周期性的VIB族和VIII族的元素形成的加氢元素表; 0.01〜6％的磷作为掺杂元素; 和基于介孔氧化铝 - 二氧化硅的非沸石载体。

3. 发明授权

US07220349B2 Process for the production of middle distillates by two-step hydroisomerisation and hydrocracking of feeds from the Fischer-Tropsch process 有权
标题翻译：通过费 - 托方法的进料的两步加氢异构化和加氢裂化生产中间馏分的方法
公开(公告)号：US07220349B2
公开(公告)日：2007-05-22
申请号：US10189759
申请日：2002-07-08
申请人： Eric Benazzi , Christophe Gueret
发明人： Eric Benazzi , Christophe Gueret
IPC分类号： C10G65/12
CPC分类号： C10G65/12 , C10G2300/1022 , C10G2300/301 , C10G2300/4081 , C10G2400/06 , C10G2400/08
摘要： The invention concerns a process for producing middle distillates from an effluent produced by a Fischer-Tropsch unit, comprising optional fractionation to obtain at least one heavy fraction with an initial boiling point in the range 120-200° C., said heavy fraction or said effluent optionally being hydrotreated, then bringing it into contact with a first amorphous hydrocracking/hydroisomerization catalyst that contains at least one noble group VIII metal, the effluent obtained is distilled, then the residual fraction boiling above the middle distillates and/or a portion of the middle distillates is brought into contact with a second amorphous hydrocracking/hydroisomerization catalyst containing at least one noble group VIII metal. The invention also concerns a unit.
摘要翻译：本发明涉及从由费 - 托单元产生的流出物中生产中间馏分的方法，该方法包括任选的分馏以获得至少一种初馏点在120-200℃范围内的重馏分，所述重馏分或所述流出物任选地进行加氢处理，然后使其与含有至少一种贵金属VIII族金属的第一无定形加氢裂化/加氢异构化催化剂接触，将所得流出物蒸馏，然后在中间馏分沸腾的残余馏分和/或部分使中间馏分与含有至少一种贵金属VIII族金属的第二无定形加氢裂化/加氢异构化催化剂接触。本发明还涉及一个单元。

4. 发明授权

US07160436B2 Method for two-step hydrocracking of hydrocarbon feedstocks 有权
标题翻译：碳氢化合物原料两步加氢裂化方法
公开(公告)号：US07160436B2
公开(公告)日：2007-01-09
申请号：US10343218
申请日：2001-07-26
申请人： Eric Benazzi , Jean-Marie Deves , Pierre Marion , Christophe Gueret , Alain Billon , Patrick Bourges
发明人： Eric Benazzi , Jean-Marie Deves , Pierre Marion , Christophe Gueret , Alain Billon , Patrick Bourges
IPC分类号： C10G65/12 , C10G37/02
CPC分类号： C10G47/20 , C10G65/12 , C10G2300/207 , C10G2300/301 , C10G2300/4018 , C10G2300/4081 , C10G2400/04 , C10G2400/06 , C10G2400/08
摘要： An improved hydrocracking process of hydrocarbon charges, in two stages with an intermediate separation, in which the second-stage of hydrocracking is carried out in the presence of an added nitrogen content which is greater than 150 ppm by weight, preferably about 500 ppm by weight, and preferably in the presence of a Y zeolite catalyst, produces high yields of middle distillate.
摘要翻译：改进的烃电荷的加氢裂化方法，分两个阶段进行中间分离，其中第二阶段的加氢裂化在加入的氮含量大于150重量ppm，优选约500重量ppm的条件下进行，并且优选在Y沸石催化剂的存在下，产生高产率的中间馏分。

5. 发明授权

US07156978B2 Process for the production of middle distillates by hydroisomerisation and hydrocracking of two fractions from feeds originating from the fischer-tropsch process 有权
$Process for the production of middle distillates by hydroisomerisation and hydrocracking of two fractions from feeds originating from the fischer-tropsch process$
标题翻译：通过加氢异构化和加氢裂化来自费 - 托方法的原料的两种馏分生产中间馏分的方法
公开(公告)号：US07156978B2
公开(公告)日：2007-01-02
申请号：US10189793
申请日：2002-07-08
申请人： Eric Benazzi , Christophe Gueret
发明人： Eric Benazzi , Christophe Gueret
IPC分类号： C10G49/02 , C10G47/02 , C10G69/14
CPC分类号： C10G65/00 , C10G45/62 , C10G47/14 , C10G65/14 , C10G69/14 , C10G2300/1022 , C10G2300/301 , C10G2300/4018 , C10G2300/4081 , C10G2400/04 , C10G2400/06 , C10G2400/08 , Y10S208/95
摘要： A system comprising: a paraffin feed produced by the Fischer-Tropsch process is fractionable into at least three fractions: an intermediate fraction boiling between T1 and T2, T1 being in the range 120–200° C. and T2 being more than 300° C. and less than 410° C., a light fraction boiling below it and a heavy fraction boiling above it; at least a portion of the intermediate fraction is hydrotreated then at least a portion thereof is passed over an amorphous hydroisomerisation/hydrocracking catalyst; the heavy fraction is passed over an amorphous hydroisomerisation/hydrocracking catalyst with a conversion of 370° C.+ products into 370° C.− products of more than 80% by weight; the hydrocracked/hydroisomerised fractions are distilled to obtain middle distillates (kerosine, gas oil).
摘要翻译：一种系统，包括：通过费 - 托法生产的链烷烃进料可分馏成至少三个馏分：在T 1和T 2之间沸腾的中间馏分，T 1在120-200℃范围内，T 2更多低于300℃，低于410℃，在其下方沸腾的轻馏分和在其上沸腾的重馏分; 将至少一部分中间馏分进行加氢处理，然后将其至少一部分通过无定形加氢异构化/加氢裂化催化剂; 将重馏分通过无定形加氢异构化/加氢裂化催化剂，转化率为370℃+产物至370℃，产率大于80％; 将加氢裂化/加氢异构化馏分蒸馏得到中间馏分（煤油，瓦斯油）。

6. 发明申请

US20060070915A1 Doped catalyst and improved process for treatment of hydrocarbon feedstocks 有权
标题翻译：掺杂催化剂和用于处理烃原料的改进方法
公开(公告)号：US20060070915A1
公开(公告)日：2006-04-06
申请号：US11221416
申请日：2005-09-08
申请人： Patrick Euzen , Alexandra Chaumonnot , Carole Bobin , Patrick Bourges , Christophe Gueret , Hugues Dulot
发明人： Patrick Euzen , Alexandra Chaumonnot , Carole Bobin , Patrick Bourges , Christophe Gueret , Hugues Dulot
IPC分类号： B01J21/12 , B01J27/187 , B01J21/02 , B01J27/182 , C10G47/02
CPC分类号： B01J37/28 , B01J21/02 , B01J21/12 , B01J23/74 , B01J23/85 , B01J23/883 , B01J23/8877 , B01J23/888 , B01J23/8885 , B01J23/8993 , B01J27/188 , B01J35/0006 , B01J35/002 , B01J35/10 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J35/108 , B01J37/0201 , B01J37/03 , B01J37/10 , B01J37/20 , B01J37/30 , C10G49/04 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018
摘要： This invention relates to doped catalysts on an aluminosilicate substrate with a low content of macropores and the hydrocracking/hydroconversion and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by the elements of group VIB and group VIII of the periodic table and a dopant in a controlled quantity that is selected from among phosphorus, boron, and silicon and a non-zeolitic substrate with a silica-alumina base that contains a quantity of more than 15% by weight and of less than or equal to 95% by weight of silica (SiO2).
摘要翻译：本发明涉及具有低含量大孔的铝硅酸盐底物上的掺杂催化剂和使用它们的加氢裂化/加氢转化和加氢处理方法。催化剂包含至少一种选自由元素周期表VIB族和VIII族的元素形成的基团和选自磷，硼和硅中的受控量的掺杂剂的氢脱氢元素以及含有大于15重量％且小于或等于95重量％的二氧化硅（SiO 2）的量的二氧化硅 - 氧化铝基底的非沸石基材。

7. 发明申请

US20050029161A1 Process for improving the cetane number of a gas oil cut 审中-公开
标题翻译：改进瓦斯油切割十六烷值的方法
公开(公告)号：US20050029161A1
公开(公告)日：2005-02-10
申请号：US10916537
申请日：2004-08-12
申请人： Marcel Aussillous , Alain Billon , Patrick Briot , Christophe Gueret , Slavik Kasztelan , Nathalie Marchal , Pierre Marion
发明人： Marcel Aussillous , Alain Billon , Patrick Briot , Christophe Gueret , Slavik Kasztelan , Nathalie Marchal , Pierre Marion
IPC分类号： C10G35/06 , C10G45/08 , C10G45/50 , C10G47/18 , C10G65/12 , C10L1/08
CPC分类号： C10G65/12 , C10G2400/04
摘要： A process for transforming a gas oil cut from a conversion process or from an aromatic crude is described, the aim of the process being to improve the cetane number of said cut. The process comprises at least one hydrogenation step in which said gas oil cut is passed, in the presence of hydrogen, over a catalyst comprising an amorphous mineral support, at least one compound of a group VIB metal, at least one compound of a non noble group VIII metal and at least phosphorous or a compound of phosphorous, the process then comprising a hydrocracking step in which the hydrogenated feed is passed, in the presence of hydrogen, over a catalyst comprising an acidic support, at least one compound of a group VIB metal and at least one compound of a non noble group VIII metal.
摘要翻译：描述了从转化过程或芳族原油转化瓦斯油切割的方法，该方法的目的是改进所述切割的十六烷值。该方法包括至少一个氢化步骤，其中所述瓦斯油馏分在氢存在下通过催化剂，所述催化剂包含无定形矿物载体，至少一种VIB族金属化合物，至少一种非贵金属化合物 VIII族金属和至少磷或磷化合物，然后该方法包括加氢裂化步骤，其中氢化进料在氢的存在下通过包含酸性载体的催化剂，至少一种VIB族化合物金属和至少一种非贵金属VIII族金属的化合物。

8. 发明授权

US06783661B1 Process for producing oils with a high viscosity index 失效
标题翻译：生产具有高粘度指数的油的方法
公开(公告)号：US06783661B1
公开(公告)日：2004-08-31
申请号：US09644605
申请日：2000-08-24
申请人： Patrick Briot , Christophe Gueret , Jean-Claude Hipeaux , Eric Benazzi , Pierre Marion , Alain Billon
发明人： Patrick Briot , Christophe Gueret , Jean-Claude Hipeaux , Eric Benazzi , Pierre Marion , Alain Billon
IPC分类号： C01G4702
CPC分类号： C10G67/02
摘要： A process for producing oils with high viscosity indices from oil distillates or effluents from a conversion unit comprises the following steps: a) catalytic hydrotreatment of the feed in the presence of hydrogen and a non zeolitic catalyst; b) fractionation of at least a portion of the effluent from step a) or step d) described below to an oil residue; c) fractionation by thermal diffusion of at least a portion of the oil residue obtained from step b) into oil fractions with different compositions and viscosity indices. Step b) can be preceded by a step d) for hydrocracking the effluent obtained from step a) in the presence of hydrogen and a zeolitic catalyst.
摘要翻译：用于生产来自转化单元的油馏出物或流出物的具有高粘度指数的油的方法包括以下步骤：a）在氢气和非沸石催化剂存在下催化加氢处理进料; b）将至少一部分来自下述步骤a）或步骤d）的流出物至油残余物; c）通过将从步骤b）获得的至少一部分油残余物的热扩散分馏成具有不同组成和粘度指数的油馏分。步骤b）可以在步骤d）之前，在氢气和沸石催化剂的存在下加氢裂化从步骤a）获得的流出物。

9. 发明申请

US20110062055A1 METHOD FOR THE VALORIZATION OF HEAVY CHARGES BY BUBBLING-BED DEASPHALTING AND HYDROCRACKING 有权
标题翻译：通过泡沫床除磷和水解加工重金属的方法
公开(公告)号：US20110062055A1
公开(公告)日：2011-03-17
申请号：US12900987
申请日：2010-10-08
申请人： Christophe GUERET , Stéphane Kressmann , Jan Verstraete
发明人： Christophe GUERET , Stéphane Kressmann , Jan Verstraete
IPC分类号： C10G69/04
CPC分类号： C10G69/04 , C10G2300/107
摘要： The invention relates to a method for treating a hydrocarbons charge comprising the following stages, in which: a) the charge is brought into contact with a solvent in order to obtain a deasphalted effluent having a content of asphaltenes below 3000 ppm by weight, b) the deasphalted effluent is cracked in the presence of hydrogen and a hydrocracking catalyst, in a bubbling-bed reactor, so as to convert at least 50 wt. % of the fraction of the deasphalted effluent boiling above 500° C. to compounds having a boiling point below 500° C., c) the effluent from stage b) is fractionated to recover gasolines, kerosene, gas oils and a first residue, and d) at least a portion of this first residue is cracked so as to obtain an effluent comprising gasolines, kerosene, gas oils and a second residue.
摘要翻译：本发明涉及一种用于处理包括以下阶段的烃装料的方法，其中：a）使电荷与溶剂接触，以获得沥青质含量低于3000重量ppm的脱沥青流出物，b）在氢气和加氢裂化催化剂的存在下，在鼓泡床反应器中将脱沥青的流出物裂化，以便将至少50wt。沸点高于500℃的脱沥青流出物的百分比达到沸点低于500℃的化合物，c）将来自阶段b）的流出物分馏以回收汽油，煤油，瓦斯油和第一残渣，以及 d）该第一残留物的至少一部分被裂化，以获得包含汽油，煤油，瓦斯油和第二残余物的流出物。

10. 发明申请

US20100065475A1 PROCESS FOR FCC PRETREATMENT BY MILD HYDROCRACKING INCLUDING DILUTING THE FEEDSTOCK WITH A FEEDSTOCK OF BIOLOGICAL ORIGIN 审中-公开
标题翻译：通过微生物加氢处理FCC预处理方法，包括用生物原料的饲料稀释饲料
公开(公告)号：US20100065475A1
公开(公告)日：2010-03-18
申请号：US12558968
申请日：2009-09-14
申请人： Christophe Gueret , Vincent Mayeur
发明人： Christophe Gueret , Vincent Mayeur
IPC分类号： C10G69/04 , B01J8/18
CPC分类号： C10G47/02 , C10G3/46 , C10G3/50 , C10G69/04 , C10G2300/1014 , C10G2300/1018 , C10G2300/1074 , C10G2300/202 , C10G2300/301 , C10G2300/4081 , C10G2400/04 , Y02E50/13 , Y02P30/20
摘要： Process for FCC pretreatment by mild hydrocracking including diluting the feedstock with a feedstock of biological origin The invention relates to a process which comprises the stages consisting in carrying out a mild hydrocracking, implemented under a pressure of 20 to 120 bar and at a temperature of between 300 and 500° C., on a hydrocarbon feedstock comprising or consisting of a feedstock of petroleum origin, comprising or consisting of a vacuum distillate fraction and/or a deasphalted oil, at least 85% by weight of which boils above 370° C., and a feedstock of biological origin comprising components of vegetable oil and/or animal fat type, in order to produce gas oil and an effluent having an initial boiling point of greater than 330° C. within the meaning of the simulated distillation according to standard ASTM D2287, and carrying out a catalytic cracking (FCC) of a composition comprising or consisting of said effluent, and to a plant which makes it possible to carry out this process.
摘要翻译：通过轻度加氢裂化进行FCC预处理的方法，包括用原料原料稀释原料本发明涉及一种方法，其包括在20至120巴的压力下和在20至120巴之间的温度下进行的温和加氢裂化 300和500℃，包含或由石油来源的原料组成的烃原料，其包含或由其中至少85重量％沸腾至370℃以上的真空馏分馏分和/或脱沥青油组成。，以及包含植物油和/或动物脂肪型成分的生物来源的原料，以便产生瓦斯油和根据标准的模拟蒸馏含义的初始沸点大于330℃的流出物 ASTM D2287，并且进行包含或由所述流出物组成的组合物的催化裂化（FCC），以及使得可以执行该p 加油

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