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1. 发明申请

US20130289189A1 Thermoprocessable per(halo)fluoropolymer composition 审中-公开
标题翻译：（卤）氟聚合物组合物的热可加工性
公开(公告)号：US20130289189A1
公开(公告)日：2013-10-31
申请号：US13993941
申请日：2011-12-16
申请人： Pasqua Colaianna , Marco Avataneo , Emanuele Di Nicolo , Giambattista Besana , Giuseppe Marchionni
发明人： Pasqua Colaianna , Marco Avataneo , Emanuele Di Nicolo , Giambattista Besana , Giuseppe Marchionni
IPC分类号： C08L53/00
CPC分类号： C08L53/00 , C08G65/007 , C08G2650/48 , C08K3/04 , C08K2003/3045 , C08L27/00 , C08L27/18 , C08L71/02 , C08L2666/04
摘要： The invention pertains to a thermoprocessable composition comprising: at least one thermoprocessable per(halo)fluoropolymer [polymer (A)]; at least one inorganic filler [filler (I)]; and at least one perfluoropolyether block copolymer [polymer (E)] comprising: A) one or more (per)fluoropolyoxyalkylene segment (chain Rf), that is to say a segment comprising recurring units having at least one catenary ether bond and at least one fluorocarbon moiety, and B) one or more polyalkylene segment (chain Ra) comprising recurring units of formula: —(CR1R2—CR3R4)— wherein R1, R2, R3, R4, equal to or different from each other, are selected from the group consisting of H, halogens (preferably F, Cl); C1-C6 (hydro)carbon groups, optionally containing fluorine or other heteroatoms, preferably perfluoroalkyl or (per)fluorooxyalkyl.
摘要翻译：本发明涉及一种热可加工组合物，其包含：至少一种热可加工的每（卤）含氟聚合物[聚合物（A）]; 至少一种无机填料[填料（I）]; 和至少一种全氟聚醚嵌段共聚物[聚合物（E）]，其包含：A）一种或多种（全）氟聚氧化烯链段（链Rf），也就是说，包含具有至少一个链烯键的重复单元的链段和至少一个氟化烃部分，和B）包含式： - （CR 1 R 2 -CR 3 R 4） - 的重复单元的一个或多个聚亚烷基链段（链Ra） - 其中R1，R2，R3，R4彼此相同或不同，选自由H，卤素（优选F，Cl）组成; 任选地含有氟或其它杂原子的C 1 -C 6（氢）碳基团，优选全氟烷基或（全）氟氧基烷基。

2. 发明申请

US20130059961A1 PVDF coating composition 有权
标题翻译： PVDF涂料组合物
公开(公告)号：US20130059961A1
公开(公告)日：2013-03-07
申请号：US13697744
申请日：2011-05-19
申请人： Vincenzo Arcella , Eliana Ieva , Shiow-Ching Lin , Marco Avataneo , Giuseppe Marchionni
发明人： Vincenzo Arcella , Eliana Ieva , Shiow-Ching Lin , Marco Avataneo , Giuseppe Marchionni
IPC分类号： C09D127/16 , B05D7/24 , C09D153/00 , C08K9/10 , C08K9/06
CPC分类号： C09D127/16 , B82Y30/00 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C08K3/32 , C08K9/08 , C08L33/00 , C09C1/3063 , C09C1/3072 , C09C1/3081 , C09C1/3669 , C09C1/3676 , C09C1/3684 , C09C3/08 , C09C3/10 , C09C3/12 , C08L2666/04
摘要： A composition comprising at least one vinylidene fluoride (VDF) polymer [polymer (F)]; and inorganic particles at least partially coated with at least one perfluoropolyether block copolymer [polymer (E)] comprising: A) one or more (per)fluoropolyoxyalkylene segment (chain Rf), comprising recurring units having at least one catenary ether bond and at least one fluorocarbon moiety, and B) one or more polyalkylene segment (chain Ra) comprising recurring units of formula: —(CR1R2—CR3R4)—, wherein R1, R2, R3, R4, equal to or different from each other, are selected from the group consisting of H, halogens (preferably F, Cl); C1-C6 (hydro)carbon groups, optionally containing fluorine or other heteroatoms, preferably perfluoroalkyl or (per)fluorooxyalkyl. The invention also discloses a method of coating various substrates using said composition.
摘要翻译：包含至少一种偏二氟乙烯（VDF）聚合物[聚合物（F）]的组合物; 至少部分涂覆有至少一种全氟聚醚嵌段共聚物[聚合物（E）]的无机颗粒，其包含：A）一种或多种（全）氟聚氧亚烷基链段（链Rf），其包含具有至少一个链烯键的重复单元，并且至少一个碳氟部分，和B）一个或多个包含式： - （CR 1 R 2 -CR 3 R 4） - 的重复单元的聚亚烷基链段（链Ra），其中彼此等于或不同的R 1，R 2，R 3，R 4，由H，卤素（优选F，Cl）组成的组; 任选地含有氟或其它杂原子的C 1 -C 6（氢）碳基团，优选全氟烷基或（全）氟氧基烷基。本发明还公开了使用所述组合物涂覆各种底物的方法。

3. 发明授权

US07132051B2 Liquid-liquid extraction of polar organic substances from their aqueous solutions with fluorinated extracting liquids 有权
公开(公告)号：US07132051B2
公开(公告)日：2006-11-07
申请号：US10384665
申请日：2003-03-11
申请人： Giuseppe Marchionni , Ugo De Patto , Marco Avataneo
发明人： Giuseppe Marchionni , Ugo De Patto , Marco Avataneo
IPC分类号： B01D11/00
CPC分类号： C07C209/86 , C07B63/00 , C07C29/86 , C07C41/38 , C07C45/80 , C07C51/48 , C07C67/58 , C07C53/08 , C07C53/02 , C07C69/14 , C07C211/05 , C07C43/126 , C07C43/123 , C07C31/08 , C07C31/10
摘要： A liquid-liquid extraction process of ketones, alcohols, aldehydes, alkyl esters of carboxylic acids, carboxylic acids, ethers, amines and heterocyclic compounds, from their aqueous solutions, comprising the addition under stirring to said aqueous solutions of a fluorinated extracting liquid selected from A) hydrofluoropolyethers, B) hydrofluorocarbons, C) hydrofluoroethers, or mixtures thereof, with formation of an aqueous phase and of an organic phase; the separation of the organic phase from the aqueous phase; the fractional distillation of the organic phase to separate the polar organic substance from the extractant.

4. 发明授权

US09090794B2 PVDF coating composition 有权
标题翻译： PVDF涂料组合物
公开(公告)号：US09090794B2
公开(公告)日：2015-07-28
申请号：US13697744
申请日：2011-05-19
申请人： Vincenzo Arcella , Eliana Ieva , Shiow-Ching Lin , Marco Avataneo , Giuseppe Marchionni
发明人： Vincenzo Arcella , Eliana Ieva , Shiow-Ching Lin , Marco Avataneo , Giuseppe Marchionni
IPC分类号： C08K9/10 , C08K9/06 , C08K3/04 , C09D127/16 , C09C1/30 , C09C1/36 , C09C3/08 , C09C3/10 , C09C3/12 , B82Y30/00 , C08K9/08 , C08L33/00 , C08K3/32
CPC分类号： C09D127/16 , B82Y30/00 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C08K3/32 , C08K9/08 , C08L33/00 , C09C1/3063 , C09C1/3072 , C09C1/3081 , C09C1/3669 , C09C1/3676 , C09C1/3684 , C09C3/08 , C09C3/10 , C09C3/12 , C08L2666/04
摘要： A composition comprising at least one vinylidene fluoride (VDF) polymer [polymer (F)]; and inorganic particles at least partially coated with at least one perfluoropolyether block copolymer [polymer (E)] comprising: A) one or more (per)fluoropolyoxyalkylene segment (chain Rf), comprising recurring units having at least one catenary ether bond and at least one fluorocarbon moiety, and B) one or more polyalkylene segment (chain Ra) comprising recurring units of formula: —(CR1R2—CR3R4)—, wherein R1, R2, R3, R4, equal to or different from each other, are selected from the group consisting of H, halogens (preferably F, Cl); C1-C6 (hydro)carbon groups, optionally containing fluorine or other heteroatoms, referably perfluoroalkyl or (per)fluorooxyalkyl. The invention also discloses a method of coating various substrates using said composition.
摘要翻译：包含至少一种偏二氟乙烯（VDF）聚合物[聚合物（F）]的组合物; 至少部分涂覆有至少一种全氟聚醚嵌段共聚物[聚合物（E）]的无机颗粒，其包含：A）一种或多种（全）氟聚氧亚烷基链段（链Rf），其包含具有至少一个链烯键的重复单元，并且至少一个碳氟部分，和B）一个或多个包含式： - （CR 1 R 2 -CR 3 R 4） - 的重复单元的聚亚烷基链段（链Ra），其中彼此等于或不同的R 1，R 2，R 3，R 4，由H组成的组，卤素（优选F，Cl）; 任选地含有氟或其它杂原子的C 1 -C 6（氢）碳基团是指全氟烷基或（全）氟氧基烷基。本发明还公开了使用所述组合物涂覆各种底物的方法。

5. 发明授权

US09267012B2 Fluoroelastomer composition 有权
标题翻译：氟弹性体组合物
公开(公告)号：US09267012B2
公开(公告)日：2016-02-23
申请号：US13809421
申请日：2011-07-08
申请人： Matteo Fantoni , Marco Apostolo , Marco Avataneo , Giuseppe Marchionni
发明人： Matteo Fantoni , Marco Apostolo , Marco Avataneo , Giuseppe Marchionni
IPC分类号： C08L27/18 , C08K5/06 , C08L51/08 , C08L53/00
CPC分类号： C08K5/06 , C08L27/18 , C08L51/08 , C08L53/00
摘要： The invention pertains to a (per)fluoroelastomer composition comprising: at least one (per)fluoroelastomer [fluoroelastomer (A)]; and from 0.1 to 30 weight parts, per hundred parts of fluoroelastomer (A), of at least one perfluoropolyether block copolymer [polymer (E)] comprising: A) one or more (per)fluoropolyoxyalkylene segment (chain Rf), that is to say a segment comprising recurring units having at least one catenary ether bond and at least one fluorocarbon moiety, and B) one or more polyalkylene segment (chain Ra) comprising recurring units of formula: —(CR1R2—CR3R4)— wherein R1, R2, R3, R4, equal to or different from each other, are selected from the group consisting of H, halogens (preferably F, Cl); C1-C6 (hydro)carbon groups, optionally containing fluorine or other heteroatoms, preferably perfluoroalkyl or (per)fluorooxyalkyl.
摘要翻译：本发明涉及一种（全）含氟弹性体组合物，其包含：至少一种（全）含氟弹性体[含氟弹性体（A）]; 和每100份含氟弹性体（A）0.1至30重量份的至少一种全氟聚醚嵌段共聚物[聚合物（E）]，其包含：A）一种或多种（全）氟聚氧亚烷基链段（链Rf），即例如包括具有至少一个链烯键和至少一个氟碳部分的重复单元的链段，以及B）包含式： - （CR 1 R 2 -CR 3 R 4） - 的重复单元的一个或多个聚亚烷基链段（链Ra） - 其中R1，R2， R 3，R 4彼此相同或不同，选自H，卤素（优选F，Cl）; 任选地含有氟或其它杂原子的C 1 -C 6（氢）碳基团，优选全氟烷基或（全）氟氧基烷基。

6. 发明申请

US20110136713A1 Hydrofluoroalcohols with improved thermal and chemical stability 有权
标题翻译：具有改善的热和化学稳定性的氢氟醇
公开(公告)号：US20110136713A1
公开(公告)日：2011-06-09
申请号：US13058297
申请日：2009-08-07
申请人： Giuseppe Marchionni , Ugo De Patto , Marco Avataneo
发明人： Giuseppe Marchionni , Ugo De Patto , Marco Avataneo
IPC分类号： C10M169/04 , C07C43/13 , C07C41/01 , C08K5/06
CPC分类号： C07C43/137 , C07C41/01 , C07C41/42 , C07C43/313 , C07C69/653 , C07C319/08 , C08G65/007 , C10M147/04 , C10M2213/04 , C10M2213/0606 , C10N2230/06 , C10N2230/12 , C10N2240/205 , C10N2250/10 , C07C321/04
摘要： Hydrofluoro alcohols of formula (I): A—(Rf)a—CFX—O—RhO—(CFX—(Rf)a*—CFX—O—RhO—)nH in which: Rh is a hydrocarbon-based chain; X is F or a C1-C6 (per)fluoroalkyl; a or a* is 0 or 1; Rf is a (per)fluoro(poly)oxyalkylene chain or a (per)fluoroalkyl chain; A is selected from the group consisting of —F, —Cl, and —H (possible only when a=1) or is HO—Rh—O—CFX—; n is an integer from 0 to 200, with the condition that n=0 when A is selected from the group consisting of —F, —Cl, and —H.
摘要翻译：式（I）的氟氟醇：A-（Rf）a-CFX-O-RhO-（CFX-（Rf）a * -CFX-O-RhO-）nH其中：Rh是烃类链; X是F或C 1 -C 6（全）氟代烷基; a或a *为0或1; Rf是（全）氟（聚）氧化烯链或（全）氟烷基链; A选自-F，-Cl和-H（仅当a = 1时可能）或是HO-Rh-O-CFX-; n为0〜200的整数，条件是当A选自-F，-Cl和-H时，n = 0。

7. 发明申请

US20100069275A1 Fluorinated lubricants 有权
标题翻译：氟化润滑剂
公开(公告)号：US20100069275A1
公开(公告)日：2010-03-18
申请号：US12516158
申请日：2007-11-29
申请人： Giuseppe Marchionni , Pier Antonio Guarda , Marco Avataneo
发明人： Giuseppe Marchionni , Pier Antonio Guarda , Marco Avataneo
IPC分类号： C10M147/04 , C08L27/12
CPC分类号： C08G65/007 , C08L27/12 , C08L71/02 , C08L2205/05 , C10M107/38 , C10M2213/043 , C10M2213/0606 , C10N2230/06 , C10N2230/74 , C10N2250/10 , C08L2666/04
摘要： Polymers of formula Q-O-[A-B]z-[A-B′]z-A-Q′ (I) wherein: A=-(X)a—O-A′-(X′)b— with A′=perfluoropolyether chain and X, X′=—CF2—, —CF2CF2—; a, b=0.1 with the proviso that a=1 if A is linked to Q-O—; b=0 when A is linked to Q′; B derives from homopolymerizable olefins by radical route, of formula: —[(CR1R2—CR3R4)j(CR5R6—CR7R8)j′]— (Ia) wherein j is an integer from 1 to 30, j′ is an integer from 0 to 29 with the proviso that (j+j′) is higher than 2 and lower than 30; R1-R8 are halogen; H; C1-C6 (per)haloalkyl; C1-C6 alkyl; or C1-C6 oxy(per)fluoroalkyl; B′=B but at least one among R1-R8 has a meaning different from that in B; z, z′ are such that the number average molecular weight of the polymer of formula (I) is between 500 and 150,000; Q, Q′=C1-C3 (per)fluoroalkyl or functional end group —(CFW)-Dq-Tk; W=F, CF3; k and q are integers, k ranges from 1 to 4, q is an integer and is equal to 0 or 1; with the proviso that at least one of Q, Q′ is functional end group.
摘要翻译：具有式QO- [AB] z- [AB'] zAQ'（I）的聚合物其中：A = - （X）a-OA' - （X'）b-，其中A'=全氟聚醚链，X，X'= -CF 2 - ， - C 2 CF 2 - ; a，b = 0.1，条件是如果A连接到Q-O-，则a = 1; 当A连接到Q'时，b = 0; B通过自由基途径衍生自均聚烯烃，式为： - [（CR1R2-CR3R4）j（CR5R6-CR7R8）j'] - （Ia）其中j为1至30的整数，j'为0至 29，条件是（j + j'）高于2且低于30; R1-R8是卤素; H; C1-C6（全）卤代烷基; C1-C6烷基; 或C 1 -C 6氧基（全）氟代烷基; B'= B，但R1-R8中至少有一个与B不同; z，z'使得式（I）的聚合物的数均分子量在500和150,000之间; Q，Q'= C1-C3（全）氟烷基或官能端基 - （CFW）-Dq-Tk; W = F，CF3; k和q是整数，k的范围是1到4，q是整数，等于0或1; 条件是Q，Q'中的至少一个是官能端基。

8. 发明授权

US08735510B2 Polymer composition 有权
标题翻译：聚合物组成
公开(公告)号：US08735510B2
公开(公告)日：2014-05-27
申请号：US13202550
申请日：2010-02-22
申请人： Theodore Moore , Mark G. Reichmann , Marco Avataneo , Giuseppe Marchionni
发明人： Theodore Moore , Mark G. Reichmann , Marco Avataneo , Giuseppe Marchionni
IPC分类号： C08L71/02
CPC分类号： C08G65/007 , C08G2650/40 , C08G2650/48 , C08L71/00 , C08L71/02 , C08L79/08 , C08L81/06 , C08L2205/05 , C08L2666/22 , C08L81/00 , C08L2666/14
摘要： A polymer composition comprising: at least one polycondensation polymer having a heat deflection temperature (HDT) of above 80° C. under a load of 1.82 MPa when measured according to ASTM D648 [polymer (P)]; at least one perfluoropolyether block copolymer [polymer (F)] comprising: A) one or more (per)fluoropolyoxyalkylene segment (chain Rf) comprising recurring units having at least one catenary ether bond and at least one fluorocarbon moiety, and B) one or more polyalkylene segment (chain Ra) comprising recurring units of formula: —(CR1R2—CR3R4)—; wherein R1, R2, R3, R4, equal to or different from each other, are selected from the group consisting of H, halogens; C1-C6 (hydro)carbon groups, optionally containing fluorine or other heteroatoms, to a process for its manufacture and to its use for manufacturing shaped articles, in particular by extrusion molding or injection molding techniques.
摘要翻译：一种聚合物组合物，其包含：当根据ASTM D648 [聚合物（P）]测量时，在1.82MPa的载荷下，至少一种具有高于80℃的热变形温度（HDT）的缩聚聚合物; 至少一种全氟聚醚嵌段共聚物[聚合物（F）]，其包含：A）一个或多个（全）氟聚氧亚烷基链段（链Rf），其包含具有至少一个链烯键和至少一个氟碳部分的重复单元，以及B）一个或多个更多的聚亚烷基链（链Ra）包含式： - （CR 1 R 2 -CR 3 R 4） - 的重复单元; 其中R1，R2，R3，R4彼此相同或不同，选自H，卤素; 任选地含有氟或其它杂原子的C 1 -C 6（氢）碳基团，其制备方法及其用于制造成型制品，特别是通过挤出成型或注射成型技术。

9. 发明申请

US20130109797A1 Fluoroelastomer composition 有权
标题翻译：氟弹性体组合物
公开(公告)号：US20130109797A1
公开(公告)日：2013-05-02
申请号：US13809421
申请日：2011-07-08
申请人： Matteo Fantoni , Marco Apostolo , Marco Avataneo , Giuseppe Marchionni
发明人： Matteo Fantoni , Marco Apostolo , Marco Avataneo , Giuseppe Marchionni
IPC分类号： C08K5/06
CPC分类号： C08K5/06 , C08L27/18 , C08L51/08 , C08L53/00
摘要： The invention pertains to a (per)fluoroelastomer composition comprising: at least one (per)fluoroelastomer [fluoroelastomer (A)]; and from 0.1 to 30 weight parts, per hundred parts of fluoroelastomer (A), of at least one perfluoropolyether block copolymer [polymer (E)] comprising: A) one or more (per)fluoropolyoxyalkylene segment (chain Rt), that is to say a segment comprising recurring units having at least one catenary ether bond and at least one fluorocarbon moiety, and B) one or more polyalkylene segment (chain Ra) comprising recurring units of formula: —(CR1R2—CR3R4)— wherein R1, R2, R3, R4, equal to or different from each other, are selected from the group consisting of H, halogens (preferably F, Cl); C1-C6 (hydro)carbon groups, optionally containing fluorine or other heteroatoms, preferably perfluoroalkyl or (per)fluorooxyalkyl.
摘要翻译：本发明涉及一种（全）含氟弹性体组合物，其包含：至少一种（全）含氟弹性体[含氟弹性体（A）]; 和每100份含氟弹性体（A）0.1至30重量份的至少一种全氟聚醚嵌段共聚物[聚合物（E）]，其包含：A）一个或多个（全）氟聚氧亚烷基链段（链Rt），即例如包括具有至少一个链烯键和至少一个氟碳部分的重复单元的链段，以及B）包含式： - （CR 1 R 2 -CR 3 R 4） - 的重复单元的一个或多个聚亚烷基链段（链Ra） - 其中R1，R2， R 3，R 4彼此相同或不同，选自H，卤素（优选F，Cl）; 任选地含有氟或其它杂原子的C 1 -C 6（氢）碳基团，优选全氟烷基或（全）氟氧基烷基。

10. 发明授权

US08278256B2 Fluorinated lubricants 有权
标题翻译：氟化润滑剂
公开(公告)号：US08278256B2
公开(公告)日：2012-10-02
申请号：US12516158
申请日：2007-11-29
申请人： Giuseppe Marchionni , Pier Antonio Guarda , Marco Avataneo
发明人： Giuseppe Marchionni , Pier Antonio Guarda , Marco Avataneo
IPC分类号： C10M105/18
CPC分类号： C08G65/007 , C08L27/12 , C08L71/02 , C08L2205/05 , C10M107/38 , C10M2213/043 , C10M2213/0606 , C10N2230/06 , C10N2230/74 , C10N2250/10 , C08L2666/04
摘要： Polymers of formula Q-O-[A-B]z-[A-B′]z-A-Q′ (I) wherein: A=-(X)a—O-A′-(X′)b— with A′=perfluoropolyether chain and X, X′=—CF2—, —CF2CF2—; a, b=0.1 with the proviso that a=1 if A is linked to Q-O—; b=0 when A is linked to Q′; B derives from homopolymerizable olefins by radical route, of formula: —[(CR1R2—CR3R4)j(CR5R6—CR7R8)j′]— (Ia) wherein j is an integer from 1 to 30, j′ is an integer from 0 to 29 with the proviso that (j+j′) is higher than 2 and lower than 30; R1-R8 are halogen; H; C1-C6 (per)haloalkyl; C1-C6 alkyl; or C1-C6 oxy(per)fluoroalkyl; B′=B but at least one among R1-R8 has a meaning different from that in B; z, z′ are such that the number average molecular weight of the polymer of formula (I) is between 500 and 150,000; Q, Q′=C1-C3 (per)fluoroalkyl or functional end group —(CFW)-Dq-Tk; W=F, CF3; k and q are integers, k ranges from 1 to 4, q is an integer and is equal to 0 or 1; with the proviso that at least one of Q, Q′ is functional end group.
摘要翻译：具有式QO- [AB] z- [AB'] zAQ'（I）的聚合物其中：A = - （X）a-OA' - （X'）b-，其中A'=全氟聚醚链，X，X'= -CF 2 - ， - C 2 CF 2 - ; a，b = 0.1，条件是如果A连接到Q-O-，则a = 1; 当A连接到Q'时，b = 0; B通过自由基途径衍生自均聚烯烃，式为： - [（CR1R2-CR3R4）j（CR5R6-CR7R8）j'] - （Ia）其中j为1至30的整数，j'为0至 29，条件是（j + j'）高于2且低于30; R1-R8是卤素; H; C1-C6（全）卤代烷基; C1-C6烷基; 或C 1 -C 6氧基（全）氟代烷基; B'= B，但R1-R8中至少有一个与B不同; z，z'使得式（I）的聚合物的数均分子量在500和150,000之间; Q，Q'= C1-C3（全）氟烷基或官能端基 - （CFW）-Dq-Tk; W = F，CF3; k和q是整数，k的范围是1到4，q是整数，等于0或1; 条件是Q，Q'中的至少一个是官能端基。

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