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1. 发明申请

US20130289189A1 Thermoprocessable per(halo)fluoropolymer composition 审中-公开
标题翻译：（卤）氟聚合物组合物的热可加工性
公开(公告)号：US20130289189A1
公开(公告)日：2013-10-31
申请号：US13993941
申请日：2011-12-16
申请人： Pasqua Colaianna , Marco Avataneo , Emanuele Di Nicolo , Giambattista Besana , Giuseppe Marchionni
发明人： Pasqua Colaianna , Marco Avataneo , Emanuele Di Nicolo , Giambattista Besana , Giuseppe Marchionni
IPC分类号： C08L53/00
CPC分类号： C08L53/00 , C08G65/007 , C08G2650/48 , C08K3/04 , C08K2003/3045 , C08L27/00 , C08L27/18 , C08L71/02 , C08L2666/04
摘要： The invention pertains to a thermoprocessable composition comprising: at least one thermoprocessable per(halo)fluoropolymer [polymer (A)]; at least one inorganic filler [filler (I)]; and at least one perfluoropolyether block copolymer [polymer (E)] comprising: A) one or more (per)fluoropolyoxyalkylene segment (chain Rf), that is to say a segment comprising recurring units having at least one catenary ether bond and at least one fluorocarbon moiety, and B) one or more polyalkylene segment (chain Ra) comprising recurring units of formula: —(CR1R2—CR3R4)— wherein R1, R2, R3, R4, equal to or different from each other, are selected from the group consisting of H, halogens (preferably F, Cl); C1-C6 (hydro)carbon groups, optionally containing fluorine or other heteroatoms, preferably perfluoroalkyl or (per)fluorooxyalkyl.
摘要翻译：本发明涉及一种热可加工组合物，其包含：至少一种热可加工的每（卤）含氟聚合物[聚合物（A）]; 至少一种无机填料[填料（I）]; 和至少一种全氟聚醚嵌段共聚物[聚合物（E）]，其包含：A）一种或多种（全）氟聚氧化烯链段（链Rf），也就是说，包含具有至少一个链烯键的重复单元的链段和至少一个氟化烃部分，和B）包含式： - （CR 1 R 2 -CR 3 R 4） - 的重复单元的一个或多个聚亚烷基链段（链Ra） - 其中R1，R2，R3，R4彼此相同或不同，选自由H，卤素（优选F，Cl）组成; 任选地含有氟或其它杂原子的C 1 -C 6（氢）碳基团，优选全氟烷基或（全）氟氧基烷基。

2. 发明授权

US10246572B2 Foamable fluoropolymer compositions 有权
公开(公告)号：US10246572B2
公开(公告)日：2019-04-02
申请号：US13993331
申请日：2011-12-09
申请人： Pasqua Colaianna , Giambattista Besana , Emanuele Di Nicolo , Letanzio Bragante , Giuseppe Marchionni , Giulio Brinati
发明人： Pasqua Colaianna , Giambattista Besana , Emanuele Di Nicolo , Letanzio Bragante , Giuseppe Marchionni , Giulio Brinati
IPC分类号： C08K5/42 , C08J9/00
摘要： The invention pertains to foamable thermoplastic fluoropolymer composition comprising: at least one fluoropolymer [polymer (A)]; and at least one perfluoroalkoxysulphonic derivative of either of formulae: (Xn+)1/n−O3S—CF2CF2O—Rdf—OCF2CF2—SO3−(Xn+)1/n and Rmf—OCF2CF2—SO3−(Xn+)1/n wherein Rdf is a divalent C1-C12 perfluorocarbon group, possibly comprising one or more ethereal oxygen atom; Rmf is a monovalent C1-C12 perfluorocarbon group, possibly comprising one or more ethereal oxygen atom, optionally comprising heteroatoms, generally selected from S, N, P; X=H, a metal cation, or an ammonium group; n is the valence of the cation X, preferably 1 or 2.

3. 发明申请

US20130267618A1 Foamable fluoropolymer compositions 审中-公开
标题翻译：可发泡含氟聚合物组合物
公开(公告)号：US20130267618A1
公开(公告)日：2013-10-10
申请号：US13993331
申请日：2011-12-09
申请人： Pasqua Colaianna , Giambattista Besana , Emanuele Di Nicolo , Letanzio Bragante , Giuseppe Marchionni , Giulio Brinati
发明人： Pasqua Colaianna , Giambattista Besana , Emanuele Di Nicolo , Letanzio Bragante , Giuseppe Marchionni , Giulio Brinati
IPC分类号： C08K5/42
CPC分类号： C08K5/42 , C08J9/0019 , C08J2327/12
摘要： The invention pertains to foamable thermoplastic fluoropolymer composition comprising: at least one fluoropolymer [polymer (A)]; and at least one perfluoroalkoxysulphonic derivative of either of formulae: (Xn+)1/n−O3S—CF2CF2O—Rdf—OCF2CF2—SO3−(Xn+)1/n and Rmf—OCF2CF2—SO3−(Xn+)1/n wherein Rdf is a divalent C1-C12 perfluorocarbon group, possibly comprising one or more ethereal oxygen atom; Rmf is a monovalent C1-C12 perfluorocarbon group, possibly comprising one or more ethereal oxygen atom, optionally comprising heteroatoms, generally selected from S, N, P; X═H, a metal cation, or an ammonium group; n is the valence of the cation X, preferably 1 or 2.
摘要翻译：本发明涉及可发泡热塑性含氟聚合物组合物，其包含：至少一种含氟聚合物[聚合物（A）]; 和（Xn +）1 / n-O3S-CF2CF2O-Rdf-OCF2CF2-SO3-（Xn +）1 / n和Rmf-OCF2CF2-SO3-（Xn +）1 / n的至少一种全氟代烷氧基磺酸衍生物，其中Rdf为可能包含一个或多个醚类氧原子的二价C1-C12全氟化碳基团; Rmf是单价C1-C12全氟化碳基团，可能包含一个或多个醚性氧原子，任选地包含杂原子，通常选自S，N，P; X = H，金属阳离子或铵基; n是阳离子X的化合价，优选1或2。

4. 发明授权

US06939495B2 Thermoprocessable copolymers of TFE 失效
标题翻译： TFE的热可加工共聚物
公开(公告)号：US06939495B2
公开(公告)日：2005-09-06
申请号：US10384243
申请日：2003-03-10
申请人： Pasqua Colaianna , Giulio Brinati , Giambattista Besana
发明人： Pasqua Colaianna , Giulio Brinati , Giambattista Besana
IPC分类号： C08J5/00 , B29C47/00 , B29K27/12 , B29K105/16 , B29L23/00 , C08F2/22 , C08F4/30 , C08F4/38 , C08F4/46 , C08F214/26
CPC分类号： C08F214/262
摘要： A thermoprocessable copolymer of TFE essentially formed by: (a) from 4.5 to 8.5% by weight of perfluoromethylvinylether (PMVE); (b) from 0.3 to 1.6% by weight of a perfluorodioxole of formula: wherein: Y=F, ORf, Rf wherein Rf is a perfluoroalkyl having from 1 to 5 carbon atoms; X1 and X2, equal to or diferent from each other, are —F or —CF3; (c) TFE, forming the remaining part to 100%.
摘要翻译： TFE的热可加工共聚物基本上由以下组成：（a）4.5至8.5重量％的全氟甲基乙烯基醚（PMVE）; （b）0.3至1.6重量％的下式所示的全氟二氧杂环戊烯：其中：Y = F，或其中R 1 f / >是具有1至5个碳原子的全氟烷基; X 1和X 2 2彼此相同或不同，为-F或-CF 3 3; （c）TFE，剩余部分形成100％。

5. 发明授权

US06730761B2 Thermoprocessable copolymers of TFE 有权
标题翻译： TFE的热可加工共聚物
公开(公告)号：US06730761B2
公开(公告)日：2004-05-04
申请号：US10322631
申请日：2002-12-19
申请人： Pasqua Colaianna , Giulio Brinati , Giambattista Besana
发明人： Pasqua Colaianna , Giulio Brinati , Giambattista Besana
IPC分类号： C08F11612
CPC分类号： C08F214/26
摘要： Thermoprocessable copolymers of TFE essentially formed by the following monomers: (a) FMVE; ((b) a perfluorodioxole of formula: the complement to 100% by weight being TFE.
摘要翻译：基本上由以下单体形成的TFE的热可加工共聚物：（a）FMVE;（b）式中的全氟二恶唑烷：100重量％的补体为TFE。

6. 发明授权

US06545111B2 Thermoprocessable copolymers of TFE 有权
标题翻译： TFE的热可加工共聚物
公开(公告)号：US06545111B2
公开(公告)日：2003-04-08
申请号：US09885930
申请日：2001-06-22
申请人： Pasqua Colaianna , Giulio Brinati , Giambattista Besana
发明人： Pasqua Colaianna , Giulio Brinati , Giambattista Besana
IPC分类号： C08F21426
CPC分类号： C08F214/262
摘要： A thermoprocessable copolymer of TFE essentially formed by: (a) from 4.5 to 8.5% by weight of perfluoromethylvinylether (PMVE); (b) from 0.3 to 1.6% by weight of a perfluorodioxole of formula: wherein: Y═F, ORf, Rf wherein Rf is a perfluoroalkyl having from 1 to 5 carbon atoms; X1 and X2, equal to or diferent from each other, are —F or —CF3; (c) TFE, forming the remaining part to 100%.
摘要翻译： TFE的热可加工共聚物基本上由以下组成：（a）4.5至8.5重量％的全氟甲基乙烯基醚（PMVE）;（b）0.3至1.6重量％的全氟二恶烷，其中：Y = F，OR f，Rf 其中Rf是具有1至5个碳原子的全氟烷基; X 1和X 2彼此相同或不同，是-F或-CF 3;（c）TFE，剩余部分形成100％。

7. 发明授权

US08461448B2 Solar cell module 有权
标题翻译：太阳能电池组件
公开(公告)号：US08461448B2
公开(公告)日：2013-06-11
申请号：US12594525
申请日：2008-04-04
申请人： Paolo Toniolo , Padmanabhan Srinivasan , Alessio Marrani , Giambattista Besana , Vincenzo Arcella
发明人： Paolo Toniolo , Padmanabhan Srinivasan , Alessio Marrani , Giambattista Besana , Vincenzo Arcella
IPC分类号： H01L31/042
CPC分类号： H02S50/15 , B32B27/322 , H01L31/048 , H01L31/0481 , Y02E10/50
摘要： The present invention pertains to a solar cell module comprising at least one photovoltaic element encapsulated between a front layer on its light receiving surface side and a back layer, said front layer comprising at least one layer comprising a tetrafluoroethylene (TFE) polymer [polymer (F)], said polymer (F) comprising: recurring units derived from TFE; and from 15 to 25% wt of recurring units derived from at least one perfluoromonomer [monomer (CM)] chosen among: (i) perfluoroalkylvinylethers complying with formula CF2═CFORf1, in which Rf1 is a C1-C6 perfluoroalkyl, e.g. —CF3, —C2F5, —C3F7; and/or (ii) perfluoro-oxyalkylvinylethers complying with formula CF2═CFOX0, in which X0 is a C1-C12 perfluorooxyalkyl having one or more ether groups, like perfluoro-2-propoxy-propyl; and (iii) mixtures thereof. Still objects of the invention are a process for the manufacture of the solar cell module as above defined and its use for producing current to external sources, e.g. for powering a fixed-wing aircraft.
摘要翻译：本发明涉及太阳能电池模块，其包括封装在其光接收表面侧的前层和背层之间的至少一个光伏元件，所述前层包括至少一层包含四氟乙烯（TFE）聚合物[聚合物（F ）]，所述聚合物（F）包含：衍生自TFE的重复单元; 和15至25重量％的衍生自至少一种全氟单体[单体（CM）]的重复单元，其选自：（i）符合式CF2 = CFORf1的全氟烷基乙烯基醚，其中Rf1为C1-C6全氟烷基，例如 -CF 3，-C 2 F 5，-C 3 F 7; 和/或（ii）符合式CF 2 = CFOX 0的全氟烷氧基乙烯基醚，其中X 0是具有一个或多个醚基的C 1 -C 12全氟氧烷基，如全氟-2-丙氧基丙基; 和（iii）它们的混合物。本发明的另一目的是制造如上所述的太阳能电池组件的方法及其用于产生电流至外部源的用途，例如，为固定翼飞机提供动力。

8. 发明申请

US20080161481A1 Thermoplastic Fluoropolymer Composition 有权
标题翻译：热塑性氟聚合物组合物
公开(公告)号：US20080161481A1
公开(公告)日：2008-07-03
申请号：US11912250
申请日：2006-04-25
申请人： Julio A. Abusleme , Claudia Manzoni , Giambattista Besana
发明人： Julio A. Abusleme , Claudia Manzoni , Giambattista Besana
IPC分类号： C08L27/12 , C08L27/16 , C08L27/18
CPC分类号： C08L27/12 , C08L27/16 , C08L27/18 , C08L2205/02 , C08L2666/04
摘要： The invention pertains to a multi-phase thermoplastic fluoropolymer composition, comprising a thermoplastic fluoropolymer and discrete domains of melt-processable perfluoropolymer, to the articles therefrom and to a process for manufacturing thermoplastic fluoropolymer compositions. The multi-phase thermoplastic fluoropolymer composition comprises: —at least one thermoplastic fluoropolymer (A); and —from 0.1 to 10% by weight of (A) of at least one melt-processible perfluoropolymer (B), and is characterized in that the polymer (B) is present in the composition in phase-separated domains in a continuous phase mainly comprising (A), at least 75% by volume of said domains having maximal dimension not exceeding 1 μm. The process of the invention comprises mixing: (i) a thermoplastic fluoropolymer (A); (ii) a melt-processible perfluoropolymer (B) under the form of particles having an average primary particle size not exceeding 300 nm; (iii) and optionally other additives or filling materials.
摘要翻译：本发明涉及一种多相热塑性含氟聚合物组合物，其包含热塑性氟聚合物和可熔融加工的全氟聚合物的离散区域，以及其制备方法以及制造热塑性含氟聚合物组合物的方法。多相热塑性含氟聚合物组合物包含： - 至少一种热塑性含氟聚合物（A）; 和（A）0.1至10重量％的至少一种可熔融加工的全氟聚合物（B），其特征在于聚合物（B）主要以连续相存在于相分离区域中的组合物中包含（A），至少75体积％的所述结构域的最大尺寸不超过1μm。本发明的方法包括混合：（i）热塑性含氟聚合物（A）; （ii）具有平均一次粒径不超过300nm的颗粒形式的可熔融加工的全氟聚合物（B）; （iii）和任选的其它添加剂或填充材料。

9. 发明授权

US07282267B2 Multilayers of fluoropolymers with chlorinated polyvinylchloride 有权
标题翻译：含氟聚合物的多层与氯化聚氯乙烯
公开(公告)号：US07282267B2
公开(公告)日：2007-10-16
申请号：US11357030
申请日：2006-02-21
申请人： Julio Abusleme , Claudia Manzoni , Giambattista Besana
发明人： Julio Abusleme , Claudia Manzoni , Giambattista Besana
IPC分类号： B32B27/08 , B32B27/18 , B32B27/30 , B32B27/34
CPC分类号： B32B27/08 , Y10T428/3154 , Y10T428/31725 , Y10T428/31739 , Y10T428/31743 , Y10T428/3175 , Y10T428/31935
摘要： Multilayers comprising at least one laminate formed in sequence by the following layers: A) one thermoprocessable fluoropolymer layer comprising units deriving from vinylidenfluoride (VDF); B) one polyamide layer blended with 0.01%-5% by weight of a diamine or one polyamide layer having at least 20 μeq/g of —NH2 groups, or one thermoprocessable polymer layer containing (—COO—) units and/or —CN groups; and C) one layer based on chlorinated polyvinylchloride (CPVC) containing from 58% to 75% by weight of chlorine.
摘要翻译：多层包含至少一层由以下层顺序形成的层压材料：A）一个热可加工含氟聚合物层，其包含衍生自偏氟乙烯（VDF）的单元; B）一种聚酰胺层，其与0.01％-5％重量的二胺或一种聚酰胺层共混，所述二胺或一个聚酰胺层具有至少20个mueq / g的-NH 2基团，或一个含有（-COO）的热可加工聚合物层 - ）单元和/或-CN基团; 和C）基于含有58重量％至75重量％氯的氯化聚氯乙烯（CPVC）的一层。

10. 发明授权

US06329481B1 Ethylene fluoro-containing copolymers 有权
标题翻译：含乙烯含氟共聚物
公开(公告)号：US06329481B1
公开(公告)日：2001-12-11
申请号：US09354158
申请日：1999-07-16
申请人： Julio A. Abusleme , Vincenzo Arcella , Giambattista Besana
发明人： Julio A. Abusleme , Vincenzo Arcella , Giambattista Besana
IPC分类号： C08F21424
CPC分类号： C08F214/186 , C08F210/02
摘要： Ethylene fluoro-containing copolymers of the ECTFE and ETFE type, optionally in the presence of a third comonomer in amount comprised between 0.1 and 10% by moles, having a viscosity between 102 and 105 Pa.sec with shear rates of 1 sec−1 measured at the temperature of about 30° C. higher than the second melting temperature, and having a rheologic curve in the diagram shear viscosity/shear-rate with a slope higher than 200, calculated as ratio between the viscosity in Pa.sec and the shear-rate in sec−1 in the shear-rate range comprised between 1 and 10 sec−1, and having a processability zone with shear-rate values higher than 10 s−1.
摘要翻译： ECTFE和ETFE型的含乙烯基氟的共聚物，任选地在第三共聚单体存在下，其量为0.1至10摩尔％，其粘度为102至105Pa·s，剪切速率为1秒-1 在比第二熔融温度高约30℃的温度下，并且在图中具有斜率高于200的剪切粘度/剪切速率的流变曲线，以Pa.sec中的粘度与剪切比之间的比计算 - 在剪切速率范围为1至10秒-1的sec-1范围内，并具有剪切速率值高于10s-1的加工性区域。

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