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1. 发明授权

US09422478B2 Char-handling processes in a pyrolysis system 有权
公开(公告)号：US09422478B2
公开(公告)日：2016-08-23
申请号：US13810405
申请日：2011-07-08
申请人： Paolo Palmas , Paul A. Sechrist , Sid Kulprathipanja , Stanley J. Frey , Barry Freel , Daniel N. Myers , Vincenza Myers
发明人： Paolo Palmas , Paul A. Sechrist , Sid Kulprathipanja , Stanley J. Frey , Barry Freel , Daniel N. Myers
IPC分类号： F23B90/00 , C10B23/00 , C10B49/22 , C10B53/02 , C10C5/00 , C10K1/02 , F23G5/027 , F23G5/30 , F23G5/46 , F23G5/50 , F23G7/10
CPC分类号： C10B23/00 , C10B49/22 , C10B53/02 , C10C5/00 , C10K1/026 , F23G5/0273 , F23G5/30 , F23G5/46 , F23G5/50 , F23G7/10 , F23G2201/303 , F23G2201/304 , F23G2201/601 , F23G2206/10 , F23G2900/50205 , Y02E50/14 , Y02P20/133 , Y02P20/145 , Y02P30/20
摘要： Char-handling processes for controlling overall heat balance, ash accumulation, and afterburn in a reheater are provided. Carbonaceous biomass feedstock is pyrolyzed using a heat transfer medium forming pyrolysis products and a spent heat transfer medium. The spent heat transfer medium is separated into segregated char and char-depleted spent heat transfer medium. The char-depleted spent heat transfer medium is introduced into a dense bed of heat transfer medium fluidized by a stream of oxygen-containing regeneration gas. All or a portion of the segregated char is combusted in the dense bed using the stream of oxygen-containing regeneration gas. A portion of the segregated char may be exported out of the pyrolysis system to control the overall heat balance and ash accumulation.

2. 发明申请

US20130327629A1 Char-Handling Processes in a Pyrolysis System 有权
标题翻译：热解系统中的焦炭处理过程
公开(公告)号：US20130327629A1
公开(公告)日：2013-12-12
申请号：US13810405
申请日：2011-07-08
申请人： Paolo Palmas , Paul A. Sechrist , Sid Kulprathipanja , Stanley J. Frey , Barry Freel , Daniel N. Myers
发明人： Paolo Palmas , Paul A. Sechrist , Sid Kulprathipanja , Stanley J. Frey , Barry Freel , Daniel N. Myers
IPC分类号： C10B23/00
CPC分类号： C10B23/00 , C10B49/22 , C10B53/02 , C10C5/00 , C10K1/026 , F23G5/0273 , F23G5/30 , F23G5/46 , F23G5/50 , F23G7/10 , F23G2201/303 , F23G2201/304 , F23G2201/601 , F23G2206/10 , F23G2900/50205 , Y02E50/14 , Y02P20/133 , Y02P20/145 , Y02P30/20
摘要： Char-handling processes for controlling overall heat balance, ash accumulation, and afterburn in a reheater are provided. Carbonaceous biomass feedstock is pyrolyzed using a heat transfer medium forming pyrolysis products and a spent heat transfer medium. The spent heat transfer medium is separated into segregated char and char-depleted spent heat transfer medium. The char-depleted spent heat transfer medium is introduced into a dense bed of heat transfer medium fluidized by a stream of oxygen-containing regeneration gas. All or a portion of the segregated char is combusted in the dense bed using the stream of oxygen-containing regeneration gas. A portion of the segregated char may be exported out of the pyrolysis system to control the overall heat balance and ash accumulation.
摘要翻译：提供了用于控制再热器中总体热平衡，灰分积累和再燃烧的焦炭处理过程。碳质生物质原料使用形成热解产物和废热转移介质的传热介质进行热解。废弃的传热介质被分离成分离的炭和贫乏的传热介质。将贫乏的废热转移介质引入通过含氧再生气体流流化的传热介质的致密层中。所有或部分分离的炭在密实床中使用含氧再生气体气流燃烧。分离的焦炭的一部分可以从热解系统输出以控制总体热平衡和灰分积累。

3. 发明授权

US08283509B2 Thermal-separation process with absorption heat pump 有权
标题翻译：吸热式热分离工艺
公开(公告)号：US08283509B2
公开(公告)日：2012-10-09
申请号：US12630195
申请日：2009-12-03
申请人： Paul A. Sechrist , Stanley J. Frey
发明人： Paul A. Sechrist , Stanley J. Frey
IPC分类号： C07C7/04
CPC分类号： B01D3/007 , B01D3/143 , Y02B30/52
摘要： The invention comprises an absorption heat pump to supply energy to a distillation process or an outside process. The streams used to effect the absorption heat pump are to be combined in any case as a feedstream to a conversion process, and energy thus is conserved by avoiding the necessity of reseparating the streams.
摘要翻译：本发明包括一个用于向蒸馏过程或外部过程供应能量的吸收式热泵。用于影响吸收式热泵的流在任何情况下都将作为进料流组合到转化过程中，因此通过避免重新分离流的需要来节省能量。

4. 发明授权

US07914673B2 Fluid distribution apparatus 有权
标题翻译：流体分配装置
公开(公告)号：US07914673B2
公开(公告)日：2011-03-29
申请号：US11924157
申请日：2007-10-25
申请人： Stanley J. Frey , Paul A. Sechrist , Daniel A. Kauff
发明人： Stanley J. Frey , Paul A. Sechrist , Daniel A. Kauff
IPC分类号： B01D15/08
CPC分类号： B01D15/1821 , B01D15/14 , B01D24/008 , B01D24/14 , B01D2201/44
摘要： Disclosed is a mixer-distributor-collector apparatus for use between beds of solid particles in a fluid-solid contacting vessel. The apparatus includes a solids retaining screen, fluid deflector, passageway, fluid distributor, and flow manipulator. The flow manipulator is a device such as a honeycomb, porous solid, perforated plate, screen, or grid having an open area greater than the open area of the fluid distributor and is located below and spaced apart from the fluid distributor. The apparatus improves the fluid flow characteristics by minimizing or eliminating fluid velocity jets and/or other turbulence which can disturb the downstream particle bed. In an exemplary application, the invention finds use in simulated moving bed (SMB) adsorptive separation processes.
摘要翻译：公开了一种在流体 - 固体接触容器中用于固体颗粒床之间的混合器 - 分配器 - 收集器装置。该装置包括固体挡板，流体偏转器，通道，流体分配器和流动操纵器。流动操纵器是诸如蜂窝状，多孔固体，多孔板，筛网或格栅的装置，其开口面积大于流体分配器的开口面积，并且位于流体分配器的下方并与其间隔开。该装置通过最小化或消除可能干扰下游颗粒床的流体速度射流和/或其它紊流来改善流体流动特性。在示例性应用中，本发明用于模拟移动床（SMB）吸附分离过程。

5. 发明授权

US07314551B2 Flow distribution apparatus 有权
标题翻译：流量分配装置
公开(公告)号：US07314551B2
公开(公告)日：2008-01-01
申请号：US10993470
申请日：2004-11-19
申请人： Stanley J. Frey , Paul A. Sechrist , Daniel A. Kauff
发明人： Stanley J. Frey , Paul A. Sechrist , Daniel A. Kauff
IPC分类号： B01D15/08
CPC分类号： B01D15/1821 , B01D15/14 , B01D24/008 , B01D24/14 , B01D2201/44
摘要： Disclosed is a mixer-distributor-collector apparatus for use between beds of solid particles in a fluid-solid contacting vessel. The apparatus includes a solids retaining screen, fluid deflector, passageway, fluid distributor, and flow manipulator. The flow manipulator is a device such as a honeycomb, porous solid, perforated plate, screen, or grid having an open area greater than the open area of the fluid distributor and is located below and spaced apart from the fluid distributor. The apparatus improves the fluid flow characteristics by minimizing or eliminating fluid velocity jets and/or other turbulence which can disturb the downstream particle bed. In an exemplary application, the invention finds use in simulated moving bed (SMB) adsorptive separation processes.
摘要翻译：公开了一种在流体 - 固体接触容器中用于固体颗粒床之间的混合器 - 分配器 - 收集器装置。该装置包括固体挡板，流体偏转器，通道，流体分配器和流动操纵器。流动操纵器是诸如蜂窝状，多孔固体，多孔板，筛网或格栅的装置，其开口面积大于流体分配器的开口面积，并且位于流体分配器的下方并与其间隔开。该装置通过最小化或消除可能干扰下游颗粒床的流体速度射流和/或其它紊流来改善流体流动特性。在示例性应用中，本发明用于模拟移动床（SMB）吸附分离过程。

6. 发明授权

US07271303B1 Multi-zone process for the production of diesel and aromatic compounds 有权
标题翻译：用于生产柴油和芳香族化合物的多区过程
公开(公告)号：US07271303B1
公开(公告)日：2007-09-18
申请号：US10946928
申请日：2004-09-22
申请人： Paul A. Sechrist , Stanley J. Frey
发明人： Paul A. Sechrist , Stanley J. Frey
IPC分类号： C07C4/02 , C07C6/00 , C10G47/00
CPC分类号： C07C6/126 , C07C15/08 , C10G69/10 , C10G2400/02 , C10G2400/04
摘要： A multi-zone process for the production of low sulfur diesel and aromatic compounds wherein C9+ hydrocarbons are hydrocracked to produce low sulfur diesel and a naphtha boiling range stream which is reformed and transalkylated within reforming and transalkylation zones to produce an aromatics-rich high-octane stream containing xylene and to balance hydrogen needs.
摘要翻译：用于生产低硫柴油和芳香族化合物的多区域方法，其中C 9 S 9+ C 20烃被加氢裂化以产生低硫柴油和重整的石脑油沸程流并在重整和烷基转移区内转烷基化，以产生富含芳烃的含有二甲苯的高辛烷值并平衡氢气需求。

7. 发明申请

US20110132741A1 Thermal-Separation Process With Absorption Heat Pump 有权
标题翻译：吸热热分离工艺
公开(公告)号：US20110132741A1
公开(公告)日：2011-06-09
申请号：US12630195
申请日：2009-12-03
申请人： Paul A. Sechrist , Stanley J. Frey
发明人： Paul A. Sechrist , Stanley J. Frey
IPC分类号： B01D3/14
CPC分类号： B01D3/007 , B01D3/143 , Y02B30/52
摘要： The invention comprises an absorption heat pump to supply energy to a distillation process or an outside process. The streams used to effect the absorption heat pump are to be combined in any case as a feedstream to a conversion process, and energy thus is conserved by avoiding the necessity of reseparating the streams.
摘要翻译：本发明包括一个用于向蒸馏过程或外部过程供应能量的吸收式热泵。用于影响吸收式热泵的流在任何情况下都将作为进料流组合到转化过程中，因此通过避免重新分离流的需要来节省能量。

8. 发明申请

US20130116495A1 ENERGY EFFICIENCY IN ADSORPTIVE SEPARATION 有权
标题翻译：吸收分离能量效率
公开(公告)号：US20130116495A1
公开(公告)日：2013-05-09
申请号：US13292713
申请日：2011-11-09
申请人： Stanley J. Frey , Lewis H. Pettengill , Michael R. Van de Cotte
发明人： Stanley J. Frey , Lewis H. Pettengill , Michael R. Van de Cotte
IPC分类号： C07C7/12
CPC分类号： C07C7/12 , B01D15/1828 , Y02P20/123 , Y02P20/57 , C07C15/08
摘要： The present process comprises a means for energy savings in one or more process pumps by driving the one or more pumps with a variable-speed driving means. The invention is particularly useful in the separation of an adsorbed product from a mixture of components using simulated-moving-bed adsorption associated with a large circulating stream pumped with variable-speed driving means for conservation of energy relative to the known art. The improvement is particularly applicable to a process for the separation of para-xylene from mixed C8 aromatics.
摘要翻译：本方法包括通过用变速驱动装置驱动一个或多个泵来在一个或多个处理泵中节能的装置。本发明特别可用于使用与用已知技术节约能源的可变速度驱动装置泵送的大循环流相关联的模拟移动床吸附分离吸附产物与组分混合物。该改进特别适用于从混合的C8芳族化合物中分离对二甲苯的方法。

9. 发明申请

US20130012746A1 PRODUCTION OF PARAFFINIC FUEL FROM RENEWABLE FEEDSTOCKS 有权
标题翻译：从可再生原料生产配方燃料
公开(公告)号：US20130012746A1
公开(公告)日：2013-01-10
申请号：US13616915
申请日：2012-09-14
申请人： Charles P. Luebke , Stanley J. Frey
发明人： Charles P. Luebke , Stanley J. Frey
IPC分类号： C10G3/00 , C07C1/22
CPC分类号： C10G45/04 , C10G3/50 , C10G3/60 , C10G2300/1014 , C10G2300/1018 , C10G2300/4081 , C10G2400/02 , C10G2400/04 , C10G2400/08 , Y02P30/20
摘要： A process has been developed for producing fuel from renewable feedstocks such as plant and animal oils and greases. The process involves treating a first portion of a renewable feedstock by hydrogenating and deoxygenating in a first reaction zone and a second portion of a renewable feedstock by hydrogenating and deoxygenating in a second reaction zone to provide a diesel boiling point range fuel hydrocarbon product. If desired, the hydrocarbon product can be isomerized to improve cold flow properties. A portion of the hydrocarbon product is recycled to the first reaction zone to increase the hydrogen solubility of the reaction mixture.
摘要翻译：已经开发了用于从可再生原料如植物油和动物油和油脂生产燃料的方法。该方法包括通过在第二反应区中通过氢化和脱氧来在第一反应区和第二部分可再生原料中进行氢化和脱氧处理可再生原料的第一部分以提供柴油沸点范围的燃料烃产物。如果需要，烃产物可被异构化以改善冷流动性能。一部分烃产物再循环到第一反应区以提高反应混合物的氢溶解度。

10. 发明授权

US08198502B2 Process for separating para-xylene from a mixture of C8 and C9 aromatic hydrocarbons 有权
标题翻译：从C8和C9芳烃的混合物中分离对二甲苯的方法
公开(公告)号：US08198502B2
公开(公告)日：2012-06-12
申请号：US12719410
申请日：2010-03-08
申请人： Leonid Bresler , Stanley J. Frey
发明人： Leonid Bresler , Stanley J. Frey
IPC分类号： C07C7/13
CPC分类号： C07C7/005 , C07C7/13 , C07C15/08
摘要： The invention is an adsorptive separation process for producing a para-xylene product from a feed stream comprising para-xylene, at least one other C8 aromatic, and a C9 aromatic. An adsorbent comprising X or Y zeolite and a desorbent comprising para-diethylbenzene (p-DEB) are used in an adsorptive separation zone to produce an extract stream comprising para-xylene, p-DEB, and the C9 aromatic and a raffinate stream comprising the at least one other C8 aromatic, the C9 aromatic, and p-DEB. The extract stream is separated in an extract distillation zone to produce a second desorbent stream comprising the C9 aromatic and p-DEB and the raffinate stream is separated in a raffinate distillation zone to produce a third desorbent stream comprising the C9 aromatic and p-DEB. At least a portion of at least one of the second desorbent stream and the third desorbent stream is further separated in a desorbent distillation zone to produce a stream comprising the C9 aromatic.
摘要翻译：本发明是用于从包含对二甲苯，至少一种其它C 8芳族和C 9芳族的进料流产生对二甲苯产物的吸附分离方法。包含X或Y沸石的吸附剂和包含对二乙基苯（p-DEB）的解吸剂用于吸附分离区，以产生包含对二甲苯，p-DEB和C9芳族化合物的萃取物料流和含有至少一种其它C 8芳族，C 9芳族和p-DEB。萃取物流在提取蒸馏区中分离以产生包含C 9芳族和p-DEB的第二解吸流，并且萃余物流在萃余液蒸馏区中分离以产生包含C 9芳族和p-DEB的第三解吸流。第二解吸流和第三解吸流中的至少一个的至少一部分在解吸蒸馏区进一步分离以产生包含C 9芳族的物流。

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