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1. 发明授权

US3590066A Hydrocarbyl borate production using ozone 失效
标题翻译：使用臭氧的石油硼酸盐生产
公开(公告)号：US3590066A
公开(公告)日：1971-06-29
申请号：US3590066D
申请日：1966-09-12
申请人： PHILLIPS PETROLEUM CO
发明人： HOLTZ HANS D
IPC分类号： C07C29/52 , C07F5/04
CPC分类号： C07F5/04 , C07C29/52 , Y10S585/931 , C07C31/125
摘要： HYDROCARBYL BORATES ARE PRODUCED BY REACTING SATURATED HYDROCARBONS WITH OXYGEN AND A BORON-CONTAINING COMPOUND IN THE PRESENCE OF OZONE AND IN SOLVENT MEDIUM.

2. 发明授权

US3899537A Producing benzophenone and related products 失效
标题翻译：生产二苯甲酮及相关产品
公开(公告)号：US3899537A
公开(公告)日：1975-08-12
申请号：US27103172
申请日：1972-07-12
申请人： PHILLIPS PETROLEUM CO
发明人： HOLTZ HANS D
IPC分类号： C07C45/36 , C07C45/54 , C07C45/67 , C07C49/76 , C07C45/04
CPC分类号： C07C45/54 , C07C45/36 , C07C45/67 , C07C49/786 , C07C47/565
摘要： A stilbene, e.g., cis- and/or trans-stilbene or a substituted stilbene, is oxidized at an elevated temperature to produce benzophenone and a related product. Diphenylacetaldehyde, also produced, can be converted under the conditions of the invention to produce additional benzophenone. The reaction is effected at a temperature in the approximate range 50*-600*F, preferably 200*-400*F under a pressure of oxygen of from about 1 to 500 psig, preferably 20 to about 200 psig. A solvent, e.g., a carboxylic acid for example acetic acid or a halogenated compound for example chlorobenzene is employed. Also, a catalyst, e.g., trifluoroacetic acid and/or trichloroacetic acid can be employed. Further a cocatalyst which is an organic compound of a transition metal, e.g., cobalt acetylacetonate or vanadium naphthenate can also be employed. New compounds, e.g., hydrobenzoin monotrifluoroacetate, hydrobenzoin bistrifluoroacetate, benzoin trifluoroacetate are produced by the process of the invention.
摘要翻译：二苯乙烯，例如顺式和/或反式二苯乙烯或取代的1,2-二苯乙烯，在升高的温度下被氧化，产生二苯甲酮和相关产物。也可以在本发明的条件下转化也产生的二苯基乙醛以产生额外的二苯甲酮。

3. 发明授权

US3527815A Olefinic alcohols 失效
标题翻译： OLEFINIC酒精
公开(公告)号：US3527815A
公开(公告)日：1970-09-08
申请号：US3527815D
申请日：1965-11-08
申请人： PHILLIPS PETROLEUM CO
发明人： HOLTZ HANS D
IPC分类号： C07F5/04 , C07C35/00 , C07C69/54
CPC分类号： C07F5/04

4. 发明授权

US3639436A Omega omega-dinitroalkanoic acids esters and ester-salts 失效
标题翻译：欧米茄 - 欧米茄 - 酸菜酸和甜菜
公开(公告)号：US3639436A
公开(公告)日：1972-02-01
申请号：US3639436D
申请日：1967-12-11
申请人： PHILLIPS PETROLEUM CO
发明人： HOLTZ HANS D
IPC分类号： C07C205/51 , C07F1/00 , C09F7/00
CPC分类号： C07C205/51 , C07F1/00
摘要： NOVEL COMPOUNDS, OMEGA,OMEGA-DINITROALKANOIC ACIDS ARE PREPARED BY INITIALLY REACTING CERTAIN OXYGEN-CONTAINING CYCLOALKANE DERIVATIVES WITH AQUEOUS NITRIC ACID IN THE PRESENCE OF A CATALYST COMPOSITION, SUCH AS AMMONIUM VANADATE (V), HAVING ONE OR MORE METALLIC ELEMENTS SELECTED FROM SC, TI, V, CR, MN, FE, CO, NI, CU, Y, LA, CE, PR, ND, AND SM, PREFERABLY V AND CU, AND RECOVERING THE DESIRED NOVEL ACIDS FROM THE REACTION PRODUCT. NOVEL ESTERS AND ALKALI METAL SALTS OF THESE ESTERS CAN BE PREPARED FROM THE NOVEL ACIDS BY SUITABLE REACTIONS. THE NOVEL ACIDS AND DERIVATIVES THEREOF ARE USEFUL INTERMEDIATES FOR THE PRODUCTION OF OMEGA-AMINO ACIDS WHICH ARE USEFUL IN THE SYNTHESIS OF POLYAMIDE POLYMERS, SUCH AS NYLON 12.

5. 发明授权

US3600384A Reaction of 1,2-bis(3-cyclohexen-1-yl) ethylenes with certain unsaturated compounds and product obtained thereby 失效
标题翻译： 1-BIS（3-环己烯-1-基）乙烯与某些不饱和化合物的反应及其产物
公开(公告)号：US3600384A
公开(公告)日：1971-08-17
申请号：US3600384D
申请日：1968-11-15
申请人： PHILLIPS PETROLEUM CO
发明人： HOLTZ HANS D
IPC分类号： C07D307/60 , C07C53/28
CPC分类号： C07D307/60
摘要： 1,2-BIS(3-CYCLOHEXEN-1-YL)ETHYLENES ARE REACTED WITH UNSATURATED COMPOUNDS SUCH AS MALEIC ANHYDRIDE TO PRODUCE NOVEL COMPOUNDS WHICH ARE USEFUL AS CURING AGENTS FOR EPOXY RESINS, AS COMPONENTS OF ALKYL RESINS AND THE LIKE, AND AS STARTING MATERIALS FOR THE PRODUCTION OF POLYIMIDE RESINS.

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