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1. 发明授权

US5651995A Highly saturated nitrile rubber, process for producing same, vulcanizable rubber composition, aqueous emulsion and adhesive composition 失效
标题翻译：高饱和丁腈橡胶，其制备方法，可硫化橡胶组合物，水性乳液和粘合剂组合物
公开(公告)号：US5651995A
公开(公告)日：1997-07-29
申请号：US476329
申请日：1995-06-07
申请人： Motofumi Oyama , Yoshiaki Aimura , Kazuyoshi Nakajima , Osamu Mori , Mitsugu Ishihara
发明人： Motofumi Oyama , Yoshiaki Aimura , Kazuyoshi Nakajima , Osamu Mori , Mitsugu Ishihara
IPC分类号： C08C19/02 , C08F2/38 , C08F236/12 , C08L15/00 , C08F8/02
CPC分类号： C08L15/005 , C08C19/02 , C08F236/12
摘要： A nitrile group-containing highly saturated copolymer rubber which is a product obtained by hydrogenating the conjugated diene portion of an unsaturated nitrile-conjugated diene copolymer. The highly saturated copolymer rubber has an alkylthio group having 12 to 16 carbon atoms, which include at least three tertiary carbon atoms, and having a sulfur atom which is directly bound to at least one of the tertiary carbon atom, and the highly saturated copolymer rubber further has a Mooney viscosity of 15 to 200 and an iodine value not larger than 80. The highly saturated copolymer rubber is produced copolymerizing an unsaturated nitrile, a conjugated diene and an optional copolymerizable monomer by using as a molecular weight modifier an alkylthiol compound having 12 to 16 carbon atoms, which include at least three tertiary carbon atoms, and having a sulfur atom which is directly bound to at least one of the tertiary carbon atoms; and then, hydrogenating the thus-obtained copolymer. The highly saturated copolymer rubber exhibits a high-rate vulcanizability when vulcanized with a sulfur-containing vulcanizer.
摘要翻译：作为通过使不饱和腈共轭二烯共聚物的共轭二烯部分氢化得到的产物的含腈基高饱和共聚物橡胶。高度饱和的共聚物橡胶具有碳原子数为12〜16的烷硫基，其包含至少三个叔碳原子，并且具有与叔碳原子中的至少一个直接结合的硫原子，高饱和共聚物橡胶进一步具有15至200的门尼粘度和不大于80的碘值。通过使用具有12个碳原子的烷基硫醇化合物作为分子量调节剂，制备高度饱和的共聚物橡胶，使不饱和腈，共轭二烯和任选的可共聚单体共聚至少16个碳原子，其包括至少三个叔碳原子，并且具有与至少一个叔碳原子直接结合的硫原子; 然后氢化由此得到的共聚物。当用含硫硫化剂硫化时，高度饱和的共聚物橡胶表现出高速硫化性。

2. 发明授权

US5683819A Composite of highly saturated nitrile rubber with fiber, and belt composed thereof 失效
标题翻译：高度饱和的丁腈橡胶与纤维的复合物，以及由其组成的带
公开(公告)号：US5683819A
公开(公告)日：1997-11-04
申请号：US469868
申请日：1995-06-06
申请人： Osamu Mori , Mitsugu Ishihara , Motofumi Oyama
发明人： Osamu Mori , Mitsugu Ishihara , Motofumi Oyama
IPC分类号： F16G1/08 , B29D29/00 , B29K9/00 , C08J5/04 , C08J5/06 , C08L9/02 , C08L15/00 , C08L21/00 , C08L33/18 , C08L33/20 , C08L33/22
CPC分类号： C08J5/06 , C08L15/005 , C08J2315/00 , Y10T428/31855
摘要： A composite comprised of a nitrile group-containing highly saturated copolymer rubber and a fibrous material, which copolymer rubber is a product obtained by hydrogenating the conjugated diene portion of an unsaturated nitrile-conjugated diene copolymer. The highly saturated copolymer rubber has an alkylthio group having 12 to 16 carbon atoms, which include at least three tertiary carbon atoms, and having a sulfur atom which is directly bound to at least one of the tertiary carbon atoms; and the copolymer rubber further has a Mooney viscosity of 15 to 200 and an iodine value not larger than 80. This composite is useful for a belt.
摘要翻译：由含腈基的高度饱和的共聚物橡胶和纤维材料组成的复合体，该共聚物橡胶是通过使不饱和腈共轭二烯共聚物的共轭二烯部分氢化获得的产物。高度饱和的共聚物橡胶具有碳原子数为12〜16的烷硫基，其包含至少三个叔碳原子，并具有与至少一个叔碳原子直接结合的硫原子; 共聚物橡胶的门尼粘度进一步为15〜200，碘值不大于80.这种复合材料可用于皮带。

3. 发明授权

US5017639A Adhesive for bonding rubber to fibers 失效
标题翻译：用于将橡胶粘合到纤维上的粘合剂
公开(公告)号：US5017639A
公开(公告)日：1991-05-21
申请号：US174866
申请日：1988-03-29
申请人： Osamu Mori , Motofumi Oyama , Hiroshi Hisaki , Masato Sekiguchi , Akinobu Okamura , Haruhiro Tanabe
发明人： Osamu Mori , Motofumi Oyama , Hiroshi Hisaki , Masato Sekiguchi , Akinobu Okamura , Haruhiro Tanabe
IPC分类号： C08J5/06 , C08K3/20
CPC分类号： C08J5/06 , C08J2321/00
摘要： An adhesive for bonding a nitrile group-containing highly saturated rubber to glass fibers or organic synthetic fibers, which comprises a nitrile group-containing highly saturated rubber latex having an iodine number of not more than 120 and a resorcinol-formaldehyde resin.

4. 发明授权

US5244943A Nitrile group-containing highly saturated polymer rubber latex and process for production thereof 失效
标题翻译：含腈基的高饱和聚合物橡胶胶乳及其生产方法
公开(公告)号：US5244943A
公开(公告)日：1993-09-14
申请号：US879140
申请日：1992-05-06
申请人： Motofumi Oyama , Osamu Mori , Nagatoshi Sugi
发明人： Motofumi Oyama , Osamu Mori , Nagatoshi Sugi
IPC分类号： C08C19/02 , C08J3/07
CPC分类号： C08J3/07 , C08C19/02 , C08J2315/00
摘要： A nitrile group-containing rubber latex comprising an aqueous dispersion of a nitrile group-containing highly saturated rubber having an iodine value of not more than 120. The said rubber latex can be produced by converting a solution of a nitrile group-containing highly saturated polymer rubber having an iodine value of not more than 120 in an inert solvent into an oil-in-water emulsion using water and an emulsifier, and removing the solvent from the resulting emulsion.
摘要翻译：含有腈基的橡胶胶乳，其包含碘值不超过120的含腈基的高饱和橡胶的水分散体。所述橡胶胶乳可以通过将含腈基的高饱和聚合物在惰性溶剂中碘值不超过120的橡胶，使用水和乳化剂将水包油乳液除去，并从所得乳液中除去溶剂。

5. 发明授权

US5122397A Method of treating polyester fibers, polyester fibers treated by said method, and composite composed of said polyester fibers and nitrile group-containing highly saturated copolymer rubber 失效
标题翻译：处理聚酯纤维的方法，通过方法处理的聚酯纤维和由聚酯纤维组成的复合组合物和含有高分子量的高饱和共聚物橡胶
公开(公告)号：US5122397A
公开(公告)日：1992-06-16
申请号：US471270
申请日：1990-01-26
申请人： Hiroshi Hisaki , Osamu Mori , Motofumi Oyama
发明人： Hiroshi Hisaki , Osamu Mori , Motofumi Oyama
IPC分类号： C08J5/06 , D06M15/41 , D06M15/693 , D06M101/00 , D06M101/16 , D06M101/30 , D06M101/32
CPC分类号： C08J5/06 , C08J2321/00
摘要： A method of treating polyester fibers, which comprises(1) treating the polyester fibers with an adhesive composition (AR) comprising a latex (A) of a vinylpyridine/conjugated diene copolymer having a vinylpyridine unit content of at least 20% by weight but not more than 70% by weight and a resorcinol-formaldehyde resin as main components, and(2) further treating it with an adhesive composition (BR) comprising a latex (B) of a ntirile group-containing highly saturated copolymer rubber having an iodine number of not more than 120 and a resorcinol-formaldehyde resin as main components. A composite obtained by bonding the treated polyester fibers to a nitrile group-containing highly saturated copolymer rubber by vulcanization has high initial and heat-resistant adhesion strength, and is useful for production of timing belts and polyribbed belts.

6. 发明授权

US5032454A Method for bonding rubbers to fibers 失效
标题翻译：将橡胶粘合到纤维上的方法
公开(公告)号：US5032454A
公开(公告)日：1991-07-16
申请号：US443826
申请日：1989-12-01
申请人： Motofumi Oyama , Osamu Mori , Nagatoshi Sugi
发明人： Motofumi Oyama , Osamu Mori , Nagatoshi Sugi
IPC分类号： C08J5/06 , C09J161/06 , C09J161/12
CPC分类号： C08J5/06 , C08J2315/00 , Y10S156/91 , Y10T428/2964 , Y10T428/2971
摘要： In a method for bonding a nitrile group-containing highly saturated polymer rubber having an iodine value of 120 or less to fibers on vulcanization, the improvement wherein fibers treated with an aqueous dispersion comprising a halogen-containing polymer latex and a resorcinol-formaldehyde resin are used.
摘要翻译：在将含有碘值为120以下的含腈基的高饱和聚合物橡胶与硫化时的纤维接合的方法中，将含有含卤聚合物胶乳和间苯二酚 - 甲醛树脂的水分散体处理的纤维用过的。

7. 发明授权

US5176781A Process for producing fiber-rubber composite 失效
标题翻译：生产纤维橡胶复合材料的方法
公开(公告)号：US5176781A
公开(公告)日：1993-01-05
申请号：US647342
申请日：1991-01-29
申请人： Osamu Mori , Hiroshi Hisaki , Motofumi Oyama , Kiyomori Ohura
发明人： Osamu Mori , Hiroshi Hisaki , Motofumi Oyama , Kiyomori Ohura
IPC分类号： C08J5/06 , C08J5/18 , C08L9/00 , D06M15/41 , D06M15/693 , D06M101/00 , D06M101/16 , D06M101/30 , D06M101/32
CPC分类号： C08J5/06 , C08J2321/00 , Y10S156/91 , Y10T428/2969
摘要： A process for producing a fiber-rubber composite comprising:a polyester fiber treated with (1) an adhesive composition (AR) consisting mainly of a latex (A) of a vinylpyridine-conjugated diene type copolymer containing a vinylpyridine unit in an amount of not less than 20% by weight but not more than 70% by weight and a resorcinol-formaldehyde resin and then with (2) an adhesive composition (BR) consisting mainly of a latex (B) of a nitrile group-containing highly saturated copolymer rubber having an iodine value of 120 or less obtained by emulsion polymerization or by emulsion polymerization followed by hydrogenation in the emulsion state and a resorcinol-formaldehyde resin, anda nitrile group-containing highly saturated copolymer rubber having an iodine value of 20 or less, which process comprises bonding said polyester filber and said nitrile group-containing highly saturated copolymer rubber having an iodine value of 20 or less, by vulcanizing by a peroxide vulcanizing system.

8. 发明授权

US5159010A Adhesive compositions for adhering organic synthetic fibers to nitrile group-containing highly saturated copolymer rubbers, method for treating organic synthetic fibers using same, and method for adhering organic synthetic fibers to rubbers using same 失效
标题翻译：用于将有机合成纤维粘附到含腈基的高饱和共聚物橡胶上的粘合剂组合物，使用它们的有机合成纤维的处理方法以及使用它们将有机合成纤维粘附到橡胶的方法
公开(公告)号：US5159010A
公开(公告)日：1992-10-27
申请号：US618969
申请日：1990-11-28
申请人： Osamu Mori , Hiroshi Hisaki , Motofumi Oyama , Kiyomori Ohura
发明人： Osamu Mori , Hiroshi Hisaki , Motofumi Oyama , Kiyomori Ohura
IPC分类号： C08L15/00 , C08C19/02 , C08F8/04 , C08G8/20 , C08G8/22 , C08L21/00 , C09J115/00 , C09J121/00 , C09J161/04 , D01F8/08 , D06M15/41 , D06M15/693 , D06M101/00 , D06M101/16
CPC分类号： C09J115/005 , C08C19/02 , C09J161/04
摘要： An adhesive composition for adhering an organic synthetic fiber to a nitrile group-containing highly saturated copolymer rubber, said composition comprising a nitrile group-containing highly saturated copolymer rubber latex having an iodine value of not more than 120 and a resorcinol-formaldehyde resin, characterized in that the nitrile group-containing highly saturated copolymer rubber latex is obtained by treating a nitrile group-containing unsaturated copolymer rubber latex resulting from emulsion polymerization with hydrogen in the presence of a hydrogenation catalyst to selectively hydrogenate a carbon-carbon double bond of the nitrile group-containing unsaturated copolymer constituting said latex.
摘要翻译：一种用于将有机合成纤维粘附到含腈基的高度饱和的共聚物橡胶上的粘合剂组合物，所述组合物包含具有不超过120的碘值的含腈基的高度饱和的共聚物橡胶胶乳和间苯二酚 - 甲醛树脂，其特征在于因为含腈基的高度饱和的共聚物橡胶胶乳是通过在氢化催化剂的存在下用氢气将由乳液聚合得到的含腈基的不饱和共聚物橡胶胶乳处理以选择性氢化腈的碳 - 碳双键来获得的含有基团的不饱和共聚物构成所述胶乳。

9. 发明授权

US5077127A Adhesive for bonding rubber to fibers 失效
标题翻译：胶粘剂用于将橡胶粘合到纤维上
公开(公告)号：US5077127A
公开(公告)日：1991-12-31
申请号：US643929
申请日：1991-01-22
申请人： Osamu Mori , Motofumi Oyama , Hiroshi Hisaki , Masato Sekiguchi , Akinobu Okamura , Haruhiro Tanabe
发明人： Osamu Mori , Motofumi Oyama , Hiroshi Hisaki , Masato Sekiguchi , Akinobu Okamura , Haruhiro Tanabe
IPC分类号： C08J5/06 , B32B9/00
CPC分类号： C08J5/06 , C08J2321/00 , Y10T428/2933 , Y10T428/2938 , Y10T428/296 , Y10T428/2964
摘要： An adhesive for bonding a nitrile group-containing highly saturated rubber to glass fibers or organic synthetic fibers, which comprises a nitrile group-containing highly saturated rubber latex having an iodine number of not more than 120 and a resoncinol/formaldehyde resin.

10. 发明授权

US5569719A Vulcanizable partially hydrogenated nitrile rubber composition containing partially hydrogenated unsaturated nitrile-conjugated diene copolymer sulfur vulcanizer and tellurium dithiocarbamate vulcanization promotor 失效
标题翻译：含有部分氢化不饱和腈共轭二烯共聚物硫硫化剂和二硫代氨基甲酸碲硫化促进剂的可硫化部分氢化丁腈橡胶组合物
公开(公告)号：US5569719A
公开(公告)日：1996-10-29
申请号：US359336
申请日：1994-12-19
申请人： Sachio Hayashi , Isamu Miyauchi , Motofumi Oyama
发明人： Sachio Hayashi , Isamu Miyauchi , Motofumi Oyama
IPC分类号： C08K5/39 , C09K3/10 , F16G1/06 , F16G5/04 , C08C19/20
CPC分类号： F16G5/04 , C08K5/39 , C09K3/10 , F16G1/06 , C09K2200/0488 , C09K2200/0612
摘要： A vulcanizable rubber composition including a partially hydrogenated unsaturated nitrile-conjugated diene copolymer having an iodine value of smaller than 25, a sulfur vulcanizer and a tellurium dithiocarbamate compound as a vulcanization promotor. This rubber composition provides a vulcanizate having reduced heat build-up, reduced compression set and high mechanical strength.
摘要翻译：包含碘值小于25的部分氢化不饱和腈共轭二烯共聚物，硫硫化剂和二硫代氨基甲酸碲化合物作为硫化促进剂的可硫化橡胶组合物。该橡胶组合物提供了具有减少的热积聚，降低的压缩永久变形和高机械强度的硫化橡胶。

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