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    • 4. 发明授权
    • Continuous polymerization and direct fiber spinning and apparatus for accomplishing same
    • 连续聚合和直接纺丝纺丝及其设备
    • US06441109B1
    • 2002-08-27
    • US09475675
    • 1999-12-30
    • Dominick A. BurloneMatthew B. HoytCharles F. Helms, Jr.John A. HodanRichard KotekCarol W. MorganRandall A. SferrazzaFang A. WangOtto M. IlgTerry D. RobertsRonald G. Morrow
    • Dominick A. BurloneMatthew B. HoytCharles F. Helms, Jr.John A. HodanRichard KotekCarol W. MorganRandall A. SferrazzaFang A. WangOtto M. IlgTerry D. RobertsRonald G. Morrow
    • C08F201
    • C08G69/18D01D1/06D01F6/60
    • Continuous anionic polymerization and melt-spinning of a polycaprolactam includes forming a reaction mixture by bringing at least two streams of liquid caprolactam respectively containing a polymerization initiator and co-initiator into contact with one another, and then subjecting the reaction mixture to anionic polymerization reaction conditions to obtain a molten polycaprolactam. The molten polycaprolactam is the directly (i.e., without intermediate solidification) transferred to, and extruded through, a fiber-forming orifice of a spinneret to form a fiber thereof. One exemplary system to achieve such continuous anionic polymerization and melt-spinning of polycaprolactam includes a mixer for receiving and mixing at least two streams of liquid caprolactam respectively containing a polymerization initiator and co-initiator, and a reactor and melt-spinning apparatus downstream of the mixer. The reactor and melt-spinning apparatus most preferably is formed of multiple plates which establish a reactor zone having a flow path for the reaction mixture which is sized and configured to achieve a predetermined residence time of the reaction mixture therein, and a temperature control zone in thermal communication with the reactor plate for controlling the temperature of the reaction plate to achieve anionic polymerization reaction conditions while the reaction mixture is flowing along the defined flow path therein to obtain the molten polycaprolactam. A spinneret zone downstream of the reactor zone thus receives the molten polycaprolactam directly and forms a fiber therefrom by extruding it through the spinneret's fiber-spinning orifice.
    • 聚己内酰胺的连续阴离子聚合和熔融纺丝包括通过使至少两股分别含有聚合引发剂和共引发剂的液体己内酰胺流彼此接触形成反应混合物,然后将反应混合物进行阴离子聚合反应条件 得到熔融的聚己内酰胺。 熔融的聚己内酰胺直接(即没有中间凝固)转移到喷丝板的纤维形成孔中并被挤出,以形成其纤维。 实现这种连续阴离子聚合和聚己内酰胺的熔融纺丝的一个示例性系统包括用于接收和混合分别含有聚合引发剂和共引发剂的至少两种液体己内酰胺流的混合器,以及在聚合引发剂和共引发剂下游的反应器和熔融纺丝装置 混合器。 反应器和熔体纺丝装置最优选地由多个板形成,该板形成具有反应混合物流动路径的反应器区,该反应器区的尺寸和构造被设计成达到其中反应混合物的预定停留时间,以及温度控制区 与反应器板的热连通,用于控制反应板的温度以实现阴离子聚合反应条件,同时反应混合物沿其中限定的流动路径流动以获得熔融的聚己内酰胺。 因此,反应器区域下游的喷丝头区域直接接收熔融的聚己内酰胺并通过将其通过喷丝头的纤维纺丝孔口挤出而形成纤维。
    • 5. 发明授权
    • Process for modifying synthetic bicomponent fiber cross-sections
    • 改性合成双组分纤维截面的方法
    • US6153138A
    • 2000-11-28
    • US288185
    • 1999-04-08
    • Charles F. Helms, Jr.Otto M. IlgDiane R. KentMatthew B. HoytJohn A. Hodan
    • Charles F. Helms, Jr.Otto M. IlgDiane R. KentMatthew B. HoytJohn A. Hodan
    • D01D5/253D01F8/12B29D31/00D01D5/24D01D8/04D01D8/12
    • D01F8/12D01D5/253Y10T428/2929Y10T428/2931Y10T428/2973Y10T428/2975
    • Bicomponent fibers of different cross-sections may be formed without changing the geometry of the spinneret orifices. More specifically, at least two polymers are co-melt-spun through an orifice of fixed geometry so as to achieve a bicomponent fiber having a desired cross-section. In order to change to a bicomponent fiber having a cross-section which is different, therefore, at least one of (1) the differential relative viscosity, (2) the relative proportions of the first and/or second polymers, and (3) the cross-sectional bicomponent distribution of the first and second polymers, is changed. In such a manner, therefore, a wide variety of bicomponent fibers having different cross-sectional geometries may be produced without changing the fixed geometry orifice through which the polymers are co-melt-spun. Thus, bicomponent fiber cross-sections may be "engineered" to suit a variety of needs without necessarily shutting down production equipment in order to change spinnerets. The bicomponent fibers are most preferably multilobal (e.g., trilobal) in which the core component is generally triangularly shaped.
    • 可以在不改变喷丝孔的几何形状的情况下形成不同横截面的双组分纤维。 更具体地说,至少两种聚合物通过固定几何形状的孔进行共熔纺丝,以达到具有所需横截面的双组分纤维。 因此,为了改变具有不同截面的双组分纤维,因此,(1)差分相对粘度,(2)第一和/或第二聚合物的相对比例和(3)中的至少一个, 改变第一和第二聚合物的横截面双组分分布。 因此,以这种方式,可以生产具有不同横截面几何形状的各种各样的双组分纤维,而不改变聚合物共熔共纺的固定几何孔。 因此,双组分纤维横截面可以“工程化”以适应各种需要,而不必关闭生产设备以改变喷丝头。 双组分纤维最优选为多叶形(例如三叶形),其中芯部分通常为三角形。
    • 7. 发明授权
    • Plate-type sheath/core-switching device and method of use
    • 板式护套/铁芯开关装置及其使用方法
    • US5750063A
    • 1998-05-12
    • US872130
    • 1997-06-10
    • Matthew B. Hoyt
    • Matthew B. Hoyt
    • D01D5/34D01D4/06D01F8/04
    • D01D5/34
    • A sheath/core-switching device contains a first plate(s) having a first flow path and a second plate(s) having a second flow path. The first flow path contains a first chamber, a first central-port, and multiple first channels with multiple first outer-ports radially disposed around the first central-port. The second flow path contains a second chamber, multiple second channels having multiple second outer-ports, and multiple third channels having multiple second central-ports which are radially disposed around the second central-ports. The sheath and core phases of a sheath/core fluid stream can be switched by means of the device by directing the stream axially to the first chamber where the stream is split into a core-stream and multiple sheath-substreams. The core-stream flows through the first central-port to the second chamber. The sheath-substreams flow through the first channels and first outer-ports to the third channels. In the second chamber, the core-stream splits into multiple core-substreams which flow through the second channels and second outer-ports. The sheath-substreams flow through the third channels and second central-ports. The core-substreams exiting the second outer-ports and the sheath-substreams exiting the second central-ports are disposed in a sheath/core configuration, the sheath-substreams forming the core and the core-substreams forming the sheath.
    • 鞘/芯开关装置包含具有第一流路的第一板和具有第二流路的第二板。 第一流路包括第一腔室,第一中心口和多个第一通道,多个第一外口径向设置在第一中心口周围。 第二流路包括第二室,具有多个第二外端口的多个第二通道,以及具有多个第二中心端口的多个第三通道,所述多个第二中心端口围绕第二中心端口径向设置。 鞘/芯流体流的鞘层和芯层可以通过将流体轴向引导到第一室,其中流被分成芯流和多个鞘 - 子流的方式来切换。 核心流通过第一中心端口流到第二室。 护套子流流过第一通道和第一外部端口流到第三通道。 在第二室中,核心流分离成多个流经第二通道和第二外部端口的核心子流。 护套子流流过第三通道和第二中心端口。 离开第二外部端口的核心子流和离开第二中心端口的鞘子流以鞘/核心构型设置,鞘 - 子流形成核心,核 - 子流形成鞘。
    • 8. 发明授权
    • Process for melt mixing and spinning synthetic polymer
    • 熔融混合和纺丝合成聚合物的方法
    • US5651928A
    • 1997-07-29
    • US624211
    • 1996-03-29
    • John A. HodanMatthew B. HoytOtto M. Ilg
    • John A. HodanMatthew B. HoytOtto M. Ilg
    • D01D5/28D01D4/06D01F8/04
    • D01D5/28B29B7/88Y10T137/2076Y10T137/212Y10T137/2147Y10T137/2158Y10T137/2218
    • Synthetic polymers are melt-mixed and spun from a mixture of respective first and second polymer melt flows. Specifically, the mixture of first and second polymer melt flows are mixed at a fluidic mixing device having a mixing intersection which receives the first and second polymer melt flows and discharges the mixture thereof respectively into at least one or another of multiple discharge ports fluid-connected with a respective spinning nozzle. The mixed flow of first and second polymer melt flows is controlled by diverting the first polymer melt so that it (i) entirely flows along a first flow path to responsively merge with the second polymer melt flow at the mixing intersection of the mixing device and thereby cause the mixed polymer flow to be discharged through the one discharge port, or (ii) entirely flow along a second flow path to responsively merge with the second polymer melt at the mixing intersection of the mixing device and thereby cause the mixed polymer flow to be discharged through the other discharge port. The mixed polymer flow thereby diverted is thus spun by one or another of the spinning nozzles, respectively.
    • 将合成聚合物熔融混合并从各自的第一和第二聚合物熔体流的混合物纺丝。 具体地说,第一和第二聚合物熔体流动的混合物在具有接收第一和第二聚合物熔体流动的混合交叉点的流体混合装置中混合,并将其混合物分别排放到流体连接的多个排放口中的至少一个或另一个 与相应的纺丝喷嘴。 通过转移第一聚合物熔体来控制第一和第二聚合物熔体流的混合流,使得其(i)完全沿着第一流动路径流动以在混合装置的混合交叉处与第二聚合物熔体流反应地合并,从而 导致混合聚合物流通过一个排出口排出,或(ii)沿着第二流动路径全部流动,以在混合装置的混合交叉处与第二聚合物熔体反应地合并,从而使混合的聚合物流为 通过另一个排放口排出。 由此分流的混合聚合物流分别由一个或另一个纺丝喷嘴纺出。