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    • 4. 发明授权
    • Polymeric strands with high surface area or altered surface properties
    • 具有高表面积或改变的表面性质的聚合物链
    • US5801106A
    • 1998-09-01
    • US644511
    • 1996-05-10
    • Lee Kirby Jameson
    • Lee Kirby Jameson
    • D01D5/098D01D5/28B32B3/00
    • D01D5/28D01D5/098Y10T428/2978Y10T428/31Y10T442/608
    • A melt-extrudable polymeric strand with altered physical properties formed by extruding an emulsion comprising a melt-extrudable polymer and an immiscible component while subjecting the emulsion to ultrasonic energy. In one embodiment, a melt-extrudable polymeric strand has a plurality of fissures in the surface of the strand such that the strand has a B.E.T. surface area to six times the B.E.T. surface area of an otherwise identical strand lacking the plurality of fissures. Desirably, the strand of this embodiment has a B.E.T. surface area of within a range from about 0.10 to about 0.18 m.sup.2 /g. In a method for making such a strand, the immiscible component of the extrudable emulsion comprises a substance that is an expandable gas upon extrusion. The expandable gas forms the fissures in the strand. According to another aspect, a polymeric strand has a continuous phase which is a melt-extrudable polymer and a disperse phase which is immiscible with the continuous phase. The disperse phase forms discrete pockets of material in the extruded strand and can include a variety of components which alter the physical properties of the strand. Suitable components of the disperse phase include water, aqueous solutions, oils, low melting point metals, and other physical property altering materials.
    • 具有改变的物理性质的可熔融挤出的聚合物链通过挤出包含可熔融挤出的聚合物和不混溶组分的乳液形成,同时使乳液受到超声能量。 在一个实施方案中,可熔融挤出的聚合物链在链的表面中具有多个裂缝,使得该链具有B.E.T. 表面积为B.E.T.的六倍。 缺少多个裂缝的另外相同的链的表面积。 理想地,本实施例的股线具有B.E.T. 表面积在约0.10至约0.18m 2 / g的范围内。 在制造这种线材的方法中,可挤出乳液的不混溶组分包括在挤出时是可膨胀气体的物质。 可膨胀气体在股线中形成裂缝。 根据另一方面,聚合物线具有连续相,其是可熔融挤出的聚合物和与连续相不混溶的分散相。 分散相在挤出的链中形成分散的材料袋,并且可以包括改变链的物理性质的各种成分。 分散相的合适组分包括水,水溶液,油,低熔点金属和其它物理性能改变材料。