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1. 发明授权

US5981610A Injection molding silicone rubber compositions 失效
标题翻译：注塑硅橡胶组合物
公开(公告)号：US5981610A
公开(公告)日：1999-11-09
申请号：US192235
申请日：1998-11-16
申请人： Noriyuki Meguriya , Shinichi Ide , Takeo Yoshida
发明人： Noriyuki Meguriya , Shinichi Ide , Takeo Yoshida
IPC分类号： C08J9/32 , C08K7/22
CPC分类号： C08J9/32 , C08K7/22 , B29K2083/005 , C08J2383/04
摘要： A thixotropic agent is blended in a silicone rubber composition comprising an alkenyl radical-containing organopolysiloxane, an organohydrogenpolysiloxane, an addition reaction catalyst, and filler balloons having a specific gravity of 0.01-0.40 and a mean particle size of 1-300 .mu.m. The resulting composition effectively restrains floating and separation of the filler, remains stable and is thus suitable for injection molding.
摘要翻译：触变剂在含有含链烯基的有机聚硅氧烷，有机氢聚硅氧烷，加成反应催化剂和比重为0.01-0.40，平均粒径为1-300μm的填充气球的硅橡胶组合物中共混。所得组合物有效地抑制填料的漂浮和分离，保持稳定，因此适合于注射成型。

2. 发明授权

US06106954A Silicone rubber compositions for high-voltage electrical insulators and polymeric bushings 有权
标题翻译：用于高压绝缘子和聚合物衬套的硅橡胶组合物
公开(公告)号：US06106954A
公开(公告)日：2000-08-22
申请号：US222932
申请日：1998-12-30
申请人： Noriyuki Meguriya , Syuuichi Azechi , Susumu Sekiguchi , Takeo Yoshida
发明人： Noriyuki Meguriya , Syuuichi Azechi , Susumu Sekiguchi , Takeo Yoshida
IPC分类号： C08K9/06 , C08L83/07 , B29D22/00 , C08K3/22
CPC分类号： C08K9/06 , C08K2003/2227 , Y10T428/1386
摘要： A silicone rubber composition is obtained by blending (A) 100 parts by weight of an organopolysiloxane composition of the addition reaction curing type with (B) about 30-400 parts by weight of aluminum hydroxide which has been surface treated with an organosilane or organosilazane substantially free of an aliphatic unsaturated group or a partial hydrolyzate thereof so that the aluminum hydroxide has 0.01-2% by weight of carbon affixed thereto. The composition maintains silicone rubber properties even though it is loaded with large amounts of aluminum hydroxide. It cures into a silicone rubber having improved high-voltage electrical insulating properties and thus suited for use as high-voltage electrical insulators.
摘要翻译：通过将（A）100重量份的加成反应固化型的有机聚硅氧烷组合物与（B）约30-400重量份的氢氧化铝共混（A），其基本上与有机硅烷或有机硅氮烷进行了表面处理不含脂肪族不饱和基团或其部分水解物，因此氢氧化铝的固形物含有0.01〜2重量％的碳。该组合物即使装载有大量氢氧化铝也能保持硅橡胶性能。它固化成具有改进的高电压电绝缘性能的硅橡胶，因此适合用作高压电绝缘体。

3. 发明授权

US5618631A Silicone rubber/epoxy resin integral composite and method for making 失效
标题翻译：硅橡胶/环氧树脂整体复合材料及其制造方法
公开(公告)号：US5618631A
公开(公告)日：1997-04-08
申请号：US409591
申请日：1995-03-24
申请人： Noriyuki Meguriya , Takeo Yoshida
发明人： Noriyuki Meguriya , Takeo Yoshida
IPC分类号： B32B25/08 , C08G59/68 , C08J5/12 , C08L63/00 , B32B27/38
CPC分类号： C08J5/12 , B32B25/08 , C08G59/68 , C08L63/00 , C08J2321/00 , C08J2363/00 , Y10T428/31902
摘要： A cured product of an epoxy resin composition is integrally and firmly joined to a cured product of an organic peroxide--or addition reaction-curable silicone rubber composition to form an integral composite. The integral composite having practically acceptable adhesion force can be simply and briefly produced without using a primer.
摘要翻译：环氧树脂组合物的固化物与有机过氧化物或加成反应固化性硅橡胶组合物的固化物一体地牢固地接合，形成整体复合体。具有实际可接受的粘合力的整体复合材料可以简单且简单地生产而不使用底漆。

4. 发明授权

US5714265A Composite body of silicone rubber and silicone-epoxy resin and method for the preparation thereof 失效
标题翻译：硅橡胶复合体和硅氧烷环氧树脂及其制备方法
公开(公告)号：US5714265A
公开(公告)日：1998-02-03
申请号：US559535
申请日：1995-11-16
申请人： Noriyuki Meguriya , Takeo Yoshida , Yoshiteru Kobayashi
发明人： Noriyuki Meguriya , Takeo Yoshida , Yoshiteru Kobayashi
IPC分类号： B32B25/20 , B32B27/26 , B32B1/10 , B32B27/38
CPC分类号： B32B25/20 , B32B27/26 , Y10S264/42 , Y10T428/31511 , Y10T428/31663
摘要： Proposed is a method for the preparation of a monolithically integrated composite cured body consisting of a part of cured silicone rubber composition and a part of a silicone-epoxy resin composition firmly bonded together without using any primer or adhesive by first curing either one of the compositions in a metal mold and then bringing the other of the compositions into direct contact with the already cured part in the metal mold to be cured thereon. Firm bonding between the parts can be obtained when the silicone rubber composition is of the peroxide-curable or the hydrosilation-curable type and the silicone-epoxy resin composition comprises: (a) a curable epoxy resin; (b) an alkenyl group-containing organopolysiloxane; (c) an organohydrogenpolysiloxane; (d) an organosilicon compound having at least one silanol group in a molecule; (e) an organic aluminum compound such as aluminum benzoate; and (f) a compound of a platinum group metal such as chloroplatinic acid, each in a specified weight proportion.
摘要翻译：提出了一种制备整体式复合固化体的方法，该复合固化体由一部分固化的硅橡胶组合物和一部分硅氧烷 - 环氧树脂组合物组成，该硅氧烷环氧树脂组合物通过首先固化组合物中的任何一种而不使用任何底漆或粘合剂而牢固地结合在一起在金属模具中，然后使另一个组合物与待固化的金属模具中的已固化部分直接接触。当硅橡胶组合物为可过氧化物固化或氢化硅烷化固化型且硅氧烷 - 环氧树脂组合物包含：（a）可固化环氧树脂; （b）含链烯基的有机聚硅氧烷; （c）有机氢聚硅氧烷; （d）分子中具有至少一个硅烷醇基的有机硅化合物; （e）有机铝化合物，例如苯甲酸铝; 和（f）铂族金属如氯铂酸的化合物，各自以规定的重量比例。

5. 发明授权

US06232387B1 Silicone rubber compositions for high-voltage electrical insulators 有权
标题翻译：硅橡胶组合物用于高压绝缘子
公开(公告)号：US06232387B1
公开(公告)日：2001-05-15
申请号：US09312696
申请日：1999-05-17
申请人： Susumu Sekiguchi , Noriyuki Meguriya , Syuuichi Azechi , Takeo Yoshida
发明人： Susumu Sekiguchi , Noriyuki Meguriya , Syuuichi Azechi , Takeo Yoshida
IPC分类号： C08K320
CPC分类号： C08K3/36 , C08G77/20 , C08K9/04 , C08K2201/014 , C08L83/04 , C08L2666/54
摘要： A mixture of a first aluminum hydroxide surface treated with a silicon-containing compound and having a mean particle size of 5-20 &mgr;m and a second aluminum hydroxide surface treated with a silicon-containing compound and having a mean particle size of 0.1-2.5 &mgr;m is blended in a silicone rubber composition comprising an organopolysiloxane, finely divided silica, and an organic peroxide. The silicone rubber composition cures into silicone rubber having sufficiently improved properties to serve as high-voltage electrical insulators, even when exposed to air polluted conditions or rigorous weather conditions.
摘要翻译：用含硅化合物处理的平均粒径为5-20μm的第一氢氧化铝表面和用含硅化合物处理的平均粒度为0.1-2.5μm的第二氢氧化铝表面的混合物在包含有机聚硅氧烷，细分二氧化硅和有机过氧化物的硅橡胶组合物中共混。即使暴露在空气污染条件或严格的天气条件下，硅橡胶组合物固化成具有足够改进性能的硅橡胶用作高压电绝缘体。

6. 发明授权

US6162854A Silicone rubber compositions for high-voltage electrical insulators 失效
标题翻译：硅橡胶组合物用于高压绝缘子
公开(公告)号：US6162854A
公开(公告)日：2000-12-19
申请号：US31691
申请日：1998-02-27
申请人： Noriyuki Meguriya , Susumu Sekiguchi , Syuuichi Azechi , Takeo Yoshida
发明人： Noriyuki Meguriya , Susumu Sekiguchi , Syuuichi Azechi , Takeo Yoshida
IPC分类号： C08K3/22 , C08F130/08 , C08F283/12 , C08F290/06 , C08K5/5419 , C08L51/08 , C08L83/04 , C08L83/05 , C08L83/07 , H01B3/46 , C08K5/24
CPC分类号： C08K5/5419 , C08F130/08 , C08F283/12 , C08F290/068 , C08G77/12 , C08G77/16 , C08G77/18 , C08G77/20 , C08G77/70 , C08K2003/2227 , C08L51/085 , C08L83/04 , C08L83/00 , C08L2666/54 , C08L2666/34
摘要： A silicone rubber composition contains (A) 100 parts by weight of an organopolysiloxane composition of the organic peroxide or addition reaction curing type, (B) 20-400 parts by weight of aluminum hydroxide, and (C) 1-20 parts by weight of an organopolysiloxane of formula (I): R.sup.1.sub.a (OX).sub.b SiO.sub.(4-a-b)/2 wherein R.sup.1 is a monovalent hydrocarbon group, at least 10 mol % of the R.sup.1 groups being phenyl, X is hydrogen or a monovalent hydrocarbon group, a and b are positive numbers satisfying the range: 1.0.ltoreq.a
摘要翻译：硅橡胶组合物含有（A）100重量份的有机过氧化物或加成反应固化型的有机基聚硅氧烷组合物，（B）20-400重量份的氢氧化铝，和（C）1-20重量份的式（I）的有机聚硅氧烷：R1a（OX）bSiO（4-ab）/ 2其中R1是一价烃基，R 1基团的至少10摩尔％为苯基，X为氢或一价烃基，和b是满足以下范围的正数：1.0

7. 发明授权

US6063487A Silicone rubber compositions for high-voltage electrical insulators and polymer insulators 失效
标题翻译：用于高压绝缘子和聚合物绝缘子的硅橡胶组合物
公开(公告)号：US6063487A
公开(公告)日：2000-05-16
申请号：US17317
申请日：1998-02-02
申请人： Syuuichi Azechi , Noriyuki Meguriya , Susumu Sekiguchi , Takeo Yoshida
发明人： Syuuichi Azechi , Noriyuki Meguriya , Susumu Sekiguchi , Takeo Yoshida
IPC分类号： C08K3/22 , C08K3/36 , C08L83/04 , C08L83/07 , H01B3/46 , B32B25/20 , B32B18/00
CPC分类号： H01B3/46 , C08K3/22 , C08K3/36 , C08L83/04 , C08G77/12 , C08G77/20 , C08G77/24 , C08G77/26 , C08G77/70 , Y10T428/252 , Y10T428/256 , Y10T428/259 , Y10T428/31663 , Y10T428/31667
摘要： A silicone rubber composition comprising (A) 100 parts by weight of an organopolysiloxane composition of the organic peroxide or addition curing type, (B) 1-100 parts by weight of finely divided silica, and (C) 30-500 parts by weight of aluminum hydroxide is suitable for use as a high-voltage electrical insulator. The aluminum hydroxide (C) has a water-soluble sodium ion content of up to 0.01% by weight and exhibits pH 6.5-8.0 and an electrical conductivity of up to 50 .mu.s/cm when measured as a 30 wt % water slurry and preferably has been treated to be hydrophobic. The composition cures into a silicone rubber having improved high-voltage electrical insulating properties even under rigorous conditions.
摘要翻译：一种硅橡胶组合物，其包含（A）100重量份的有机过氧化物或加成固化型的有机聚硅氧烷组合物，（B）1-100重量份的细分二氧化硅，和（C）30-500重量份的氢氧化铝适合用作高压电绝缘体。氢氧化铝（C）的水溶性钠离子含量高达0.01重量％，当以30重量％的水浆测定时，其pH值为6.5-8.0，电导率高达50μs/ cm 2，优选已被处理为疏水性。组合物即使在严格条件下也固化成具有改进的高电压电绝缘性能的硅橡胶。

8. 发明授权

US5645941A Silicone resin/silicone rubber composite material 失效
标题翻译：硅树脂/硅橡胶复合材料
公开(公告)号：US5645941A
公开(公告)日：1997-07-08
申请号：US440056
申请日：1995-05-12
申请人： Noriyuki Meguriya , Takeo Yoshida
发明人： Noriyuki Meguriya , Takeo Yoshida
IPC分类号： C08J3/24 , C08J5/12 , B32B9/04 , C08F283/12 , C08L83/04
CPC分类号： C08J3/244 , C08J5/12 , C08J2383/04 , Y10T428/31663
摘要： By curing or semi-curing an addition curable silicone resin composition comprising a phenyl-containing organopolysiloxane, placing an addition or peroxide curable silicone rubber composition in close contact with the cured or semi-cured resin, and heat curing the silicone rubber composition, there is prepared a composite material in which silicone resin and silicone rubber are firmly joined together.
摘要翻译：通过固化或半固化包含含苯基的有机聚硅氧烷的可加成固化的有机硅树脂组合物，将加成或过氧化物可固化的硅橡胶组合物与固化或半固化树脂紧密接触，并加热固化硅橡胶组合物，制备其中硅树脂和硅橡胶牢固地接合在一起的复合材料。

9. 发明授权

US5977216A Silicone rubber compositions for high-voltage electrical insulators and polymeric bushings 有权
标题翻译：用于高压绝缘子和聚合物衬套的硅橡胶组合物
公开(公告)号：US5977216A
公开(公告)日：1999-11-02
申请号：US156046
申请日：1998-09-17
申请人： Noriyuki Meguriya , Susumu Sekiguchi , Syuuichi Azechi , Takeo Yoshida
发明人： Noriyuki Meguriya , Susumu Sekiguchi , Syuuichi Azechi , Takeo Yoshida
IPC分类号： C08K9/06 , C08L83/04 , C08L83/05 , C08L83/07 , H01L21/00
CPC分类号： C08K9/06 , C08L83/04 , H01L21/00
摘要： A silicone rubber composition is obtained by blending (A) 100 parts by weight of an organopolysiloxane composition of the organic peroxide or addition reaction curing type, with (B) 30-400 parts by weight of aluminum hydroxide which has been surface treated so as to bear 1.0.times.10.sup.-6 to 2.0.times.10.sup.-4 mol/gram of vinyl groups. The composition does not lose rubber strength even though it is loaded with large amounts of aluminum hydroxide. It cures into a silicone rubber having satisfactory physical properties and improved high-voltage electrical insulating properties and thus suited for use as high-voltage electrical insulators.
摘要翻译：通过将（A）100重量份的有机过氧化物或加成反应固化型的有机基聚硅氧烷组合物与（B）30-400重量份已经表面处理的氢氧化铝共混以获得硅橡胶组合物，承担1.0×10 -6至2.0×10 -4 mol / g的乙烯基。即使装载有大量的氢氧化铝，组合物也不会失去橡胶强度。它固化成具有令人满意的物理性能和改进的高压电绝缘性能的硅橡胶，因此适合用作高压电绝缘体。

10. 发明授权

US5585445A Hydrosilation 失效
标题翻译：水解
公开(公告)号：US5585445A
公开(公告)日：1996-12-17
申请号：US513558
申请日：1995-08-10
申请人： Noriyuki Meguriya , Takeo Yoshida , Yoshiteru Kobayashi
发明人： Noriyuki Meguriya , Takeo Yoshida , Yoshiteru Kobayashi
IPC分类号： C08G59/22 , C08G59/24 , C08G59/68 , C08G59/70 , C08L63/00 , C08L83/04 , C08K5/24 , C08G77/04
CPC分类号： C08L63/00 , C08G59/226 , C08G59/24 , C08G59/68 , C08G59/70 , C08L83/04 , C08G77/12 , C08G77/16 , C08G77/20 , C08G77/70
摘要： A novel curable organopolysiloxane-epoxy resin composition, which is capable of giving a cured body having excellent mechanical properties without the problem of adhesion to the metal mold, is proposed. The composition comprises: (a) an epoxy resin; (b) an organopolysiloxane containing vinyl groups; (c) an organohydrogenpolysiloxane as the crosslinking agent of the component (b); (d) a platinum compound as a catalyst for the hydrosilation reaction; and (e) a specific organic aluminum compound, such as tris(acetylacetonato) aluminum, each in a specified proportion.
摘要翻译：提出了能够赋予具有优异的机械性能的固化体而不会粘附到金属模具的问题的新型可固化的有机聚硅氧烷 - 环氧树脂组合物。该组合物包括：（a）环氧树脂; （b）含乙烯基的有机聚硅氧烷; （c）作为（b）成分的交联剂的有机氢聚硅氧烷; （d）作为硅氢化反应的催化剂的铂化合物; 和（e）特定的有机铝化合物，例如三（乙酰丙酮）铝，各自以规定的比例。

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