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    • 2. 发明授权
    • Method of application and device for application
    • 应用方法和应用设备
    • US5206056A
    • 1993-04-27
    • US770005
    • 1991-10-02
    • Norio ShibataNaoyoshi Chino
    • Norio ShibataNaoyoshi Chino
    • B05C5/02B05D1/26D21H23/46G03C1/74G11B5/842
    • G11B5/842B05C5/0254D21H23/46G03C1/74G03C2001/7459G03C2001/7466
    • An application device capable of very rapidly applying a liquid in the form of a thin film to a continuously moving flexible carrier in such a manner as to avoid corrosion and wear to the surface of the doctor edge portion of the application device to thus avoid the formation of streaks on the surface of the applied liquid. A clearance between the surface of the carrier and the surface of the doctor edge portion is made larger at the downstream end of the surface of the doctor edge portion than at the upstream part thereof. For this purpose, a support roller is provided near the downstream end of the surface of the doctor edge portion so that the clearance between the surface of the doctor edge portion and the surface of the carrier can be appropriately controlled along substantially the entire width of the doctor edge portion by adjustably displacing the roller. Application is performed while the clearance between the surface of the carrier and the doctor edge portion is set larger at the downstream end of the surface of the doctor edge portion than at the upstream part of the surface thereof.
    • 一种能够非常快速地将薄膜形式的液体施加到连续移动的柔性载体的应用装置,以避免腐蚀和磨损到施加装置的刮刀边缘部分的表面,从而避免形成 在所施加的液体的表面上的条纹。 在刮刀边缘部分的表面的下游端比在其上游部分处使载体表面与刮刀边缘部分表面之间的间隙更大。 为此,在刮刀边缘部分的表面的下游端附近设置有支撑辊,使得刮刀边缘部分的表面与载体表面之间的间隙可以基本上沿着 刮刀边缘部分通过可调地移动辊子。 当在刮刀边缘部分的表面的下游端比在其表面的上游部分处设置载体表面和刮刀边缘部分之间的间隙更大的应用。
    • 5. 发明授权
    • Process for producing multi-layered magnetic recording media
    • 多层磁记录介质的制造方法
    • US5069934A
    • 1991-12-03
    • US623637
    • 1990-12-06
    • Naoyoshi ChinoNorio ShibataHiroshi Chikamasa
    • Naoyoshi ChinoNorio ShibataHiroshi Chikamasa
    • B05C5/02B05C9/06G11B5/716G11B5/848
    • B05C5/0254B05C9/06G11B5/716G11B5/848Y10S428/90
    • A multi-layer coating method by which multi-layered magnetic recording media having good recording characteristics can be produced consistently at high speed with multiple thin layers being coated simultaneously while insuring effective prevention of unwanted phenomena such as color unevenness and longitudinal streaks. A plurality of organic solvent based dispersions that are non-Newtonian fluids having fine particles dispersed therein are simultaneously applied in superposition onto a continuously running nonmagnetic support using an extrusion type applicator head. The coating operation is performed in such a manner that the Reynolds number as determined by the average of the kinetic viscosity coefficients of the dispersions, the coating speed and the equivalent diameter during coating is adjusted to 400 or below, and that, at the same time, the yield stress of at least the dispersion for the topmost layer is adjusted to 10 dyne/cm.sup.2 or more. Further, the coating operation is performed in such a way that the ratio of .eta..sub.T to .eta..sub.H is adjusted to 50 or above, where .eta..sub.H is the viscosity of the dispersions at the rate of shear that is exerted upon the dispersions when they are applied using an extrusion type applicator head, and .eta..sub.T is the viscosity of the dispersions at the shear rate for the time period defined by the end of application and the entrance into the subsequent drying zone.
    • 可以通过同时涂覆多个薄层,同时高效率地一致地制造具有良好记录特性的多层磁记录介质的多层涂布方法,同时确保有效防止诸如颜色不均匀性和纵向条纹的不期望的现象。 使用挤出型涂布头,将多个分散有细颗粒的非牛顿流体的有机溶剂基分散体同时施加到连续运行的非磁性载体上。 涂布操作以这样的方式进行,即通过将分散体的动力粘度系数,涂布速度和涂布期间的当量直径的平均值确定的雷诺数调整到400或以下,并且同时 至少将最上层的色散的屈服应力调节至10达因/ cm2以上。 此外,涂布操作是这样进行的,即将ηa与eta H的比值调节至50或更高,其中η是当分散体在分散体时施加的剪切速率时分散体的粘度 使用挤出式涂布头施加,eta T是在施用结束和进入后续干燥区限定的时间段内在剪切速率下的分散体的粘度。
    • 10. 发明申请
    • 2-FLUORO-1,3-BENZODITHIOL 1,1,3,3-TETRAOXIDE DERIVATIVE, PRODUCTION METHOD THEREOF, AND PRODUCTION METHOD OF MONOFLUOROMETHYL GROUP-CONTAINING COMPOUND USING THE SAME
    • 二氟-1,3-二苯并咪唑1,1,3,3-四氧化硫衍生物及其制备方法,以及使用该单体的含氟单体组的化合物的制造方法
    • US20110319637A1
    • 2011-12-29
    • US13254260
    • 2010-02-12
    • Norio Shibata
    • Norio Shibata
    • C07D339/06C07C29/147C07C29/132
    • C07B53/00C07B2200/07C07C29/32C07D339/06C07C33/48
    • A 2-fluoro-1,3-benzodithiol 1,1,3,3-tetraoxide derivative as a monofluoromethyl group introduction agent that is effective as an intermediate in pharmaceutical and agrochemical synthesis, a production method thereof, and a production method of a monofluoromethyl group-containing compound using this 2-fluoro-1,3-benzodithiol 1,1,3,3-tetraoxide derivative are provided. The 2-fluoro-1,3-benzodithiol 1,1,3,3-tetraoxide derivative represented by the following general formula (1) (wherein R1, R2, R3, and R4 each independently represent a hydrogen atom, a straight-chain or branched alkyl group having 1 to 4 carbon atoms, a straight-chain or branched alkyloxy group having 1 to 4 carbon atoms, a halogen atom, a nitro group, or a cyano group), the production method thereof, and various monofluoromethyl group-containing compounds are manufactured using this 2-fluoro-1,3-benzodithiol 1,1,3,3-tetraoxide derivative as a monofluoromethylating agent.
    • 作为药物和农药合成中的中间体的作为单氟甲基导入剂的2-氟-1,3-苯并二硫醇1,1,3,3-四氧化物衍生物,其制造方法和单氟甲基的制造方法 提供了使用该2-氟-1,3-苯并二硫醇1,1,3,3-四氧化物衍生物的含有基团的化合物。 由以下通式(1)表示的2-氟-1,3-苯并二硫醇1,1,3,3-四氧化物衍生物(其中R 1,R 2,R 3和R 4各自独立地表示氢原子,直链 或具有1〜4个碳原子的支链烷基,具有1〜4个碳原子的直链或支链烷氧基,卤原子,硝基或氰基),其制备方法和各种单氟甲基 - 使用该2-氟-1,3-苯并二硫醇1,1,3,3-四氧化物衍生物作为单氟甲基化剂制造含氟化合物。