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1. 发明授权

US5013423A Reforming and dehydrocyclization 失效
标题翻译：改革和脱水循环
公开(公告)号：US5013423A
公开(公告)日：1991-05-07
申请号：US295959
申请日：1989-01-11
申请人： Nai Y. Chen , Ralph M. Dessau , Randall D. Partride , Ernest W. Valyocsik
发明人： Nai Y. Chen , Ralph M. Dessau , Randall D. Partride , Ernest W. Valyocsik
IPC分类号： B01J29/44 , B01J29/74 , C07C5/41 , C10G35/085 , C10G35/095
CPC分类号： C10G35/095 , B01J29/04 , B01J29/068 , B01J29/44 , B01J29/7415 , B01J29/7438 , B01J29/84 , B01J29/86 , C07C5/417
摘要： Improved, dehydrocyclization and low-pressure reforming processes based on a non-acidic metal containing crystalline microporous indium catalyst, in which the feed is rich in C.sub.6 -C.sub.7 low octane hydrocarbons, such as paraffins, and in which the reformate has increased aromatic content and increased octane value over that of the feed are disclosed.
摘要翻译：基于非酸性金属结晶微孔铟催化剂的改进的脱氢环化和低压重整方法，其中进料富含C6-C7低辛烷值烃，如链烷烃，其中重整油具有增加的芳族含量，公开了比饲料中辛烷值增加的值。

2. 发明授权

US5037529A Integrated low pressure aromatization process 失效
标题翻译：集成低压芳构化工艺
公开(公告)号：US5037529A
公开(公告)日：1991-08-06
申请号：US459403
申请日：1989-12-29
申请人： Ralph M. Dessau , Randall D. Partridge , Sharon B. McCullen , Nai Y. Chen
发明人： Ralph M. Dessau , Randall D. Partridge , Sharon B. McCullen , Nai Y. Chen
IPC分类号： C10G59/02
CPC分类号： C10G59/02
摘要： High purity benzene and high octane alkylaromatic gasoline can be obtained via a dual stage reforming process utilizing a non-acidic Group VIII metal containing microporous crystalline silicate catalyst in the first stage followed by first stage effluent treatment over acidic zeolite catalyst operating under conditions in the second stage to upgrade the first stage effluent in RON, in aromatic content or both.
摘要翻译：高纯度苯和高辛烷值的烷基芳烃汽油可以通过双阶段重整方法获得，该方法利用在第一阶段中使用含非极性Ⅷ族金属的微孔结晶硅酸盐催化剂，然后在第二阶段的条件下在酸性沸石催化剂上进行第一阶段流出物处理在RON，芳香含量或两者都升级第一阶段流出物的阶段。

3. 发明授权

US4971766A Apparatus for FCC process with catalyst separation 失效
标题翻译： FCC催化分离装置
公开(公告)号：US4971766A
公开(公告)日：1990-11-20
申请号：US437064
申请日：1989-11-16
申请人： Nai Y. Chen , Billy K. Huh , Thomas E. Degnan
发明人： Nai Y. Chen , Billy K. Huh , Thomas E. Degnan
IPC分类号： C10G11/18
CPC分类号： C10G11/18
摘要： An FCC or fluidized catalytic cracking process and apparatus for converting heavy metals laden crudes is disclosed. The heavy feed, conventional catalyst and an additive or vanadium getter contact the feed in a riser reactor. The additive is segregated from conventional FCC catalyst upstream of the conventional FCC regenerator. An elutriating, upflow riser reactor may be used with a coarse, rapidly settling getter. A fine, slowly settling getter may be used, with getter segregation achieved by using an elutriating cyclone on the riser outlet, an elutriating catalyst stripper, a sieve, or the like. The spent getter may be used once through, regenerated in a separate getter regenerator, or used as a source of fuel. Alumina and sponge coke are preferred getters.
摘要翻译：公开了一种FCC或流化催化裂化方法和用于转化重金属负载原油的装置。重料，常规催化剂和添加剂或钒吸附剂在提升管反应器中接触进料。该添加剂与常规FCC再生器上游的常规FCC催化剂分离。淘汰式上升式提升管式反应器可与粗，快速沉降的吸气剂一起使用。可以使用细的缓慢沉降的吸气剂，通过在提升管出口，淘洗催化剂汽提器，筛子等上使用淘洗旋风来实现吸气剂分离。废吸气剂可以一次使用，在单独的吸气剂再生器中再生，或用作燃料来源。氧化铝和海绵焦炭是优选的吸气剂。

4. 发明授权

US4877581A Catalyst for dewaxing hydrocarbon feedstock 失效
标题翻译：用于脱蜡烃原料的催化剂
公开(公告)号：US4877581A
公开(公告)日：1989-10-31
申请号：US239257
申请日：1988-09-01
申请人： Nai Y. Chen , Dennis E. Walsh
发明人： Nai Y. Chen , Dennis E. Walsh
IPC分类号： B01J29/44 , B01J29/74 , C10G45/64
CPC分类号： C10G45/64 , B01J29/44
摘要： A paraffin conversion process for hydroisomerizing a nitrogen and wax-containing hydrocarbon feedstock comprising contacting the feedstock with a catalyst including a ZSM-11 zeolite characterized by an alpha value from about 10 to 50, in combination with a Group VIII metal hydrogenation-dehydrogenation component of platinum or palladium at a temperature of about 400.degree. F. to about 850.degree. F. and at a pressure of from about 200 to about 2000 psig.
摘要翻译：一种用于使含氮和含蜡的烃原料加氢异构化的链烷烃转化方法，包括使原料与包含Z值为约10至50的α值的ZSM-11沸石的催化剂结合，与第VIII族金属加氢脱氢组分铂或钯，温度为约400°F至约850°F，压力为约200至约2000psig。

5. 发明授权

US4827068A Aromatization with catalyst comprising noble-metal containing titanosilicate having the structure of zeolite beta 失效
标题翻译：用含有β沸石结构的含有钛酸硅酸的贵金属的催化剂进行芳构化
公开(公告)号：US4827068A
公开(公告)日：1989-05-02
申请号：US138974
申请日：1987-12-29
申请人： Nai Y. Chen , Sharon B. McCullen
发明人： Nai Y. Chen , Sharon B. McCullen
IPC分类号： B01J29/89 , C07C1/20 , C07C5/41 , C07C11/20 , C07C2/52
CPC分类号： C07C5/417 , B01J29/89 , C07C1/20 , C07C2529/89 , Y02P30/42
摘要： Aromatization of non-aromatics is carried out by contacting with a titanosilicate having the structure of zeolite beta which contains noble metal.
摘要翻译：通过与含有贵金属的β沸石结构的钛硅酸盐接触来进行非芳族化合物的芳构化。

6. 发明授权

US4789656A Crystalline silicate zeolite beta of improved stability 失效
标题翻译：结晶硅酸盐沸石β具有改善的稳定性
公开(公告)号：US4789656A
公开(公告)日：1988-12-06
申请号：US070170
申请日：1987-07-02
申请人： Nai Y. Chen , Sharon B. McCullen
发明人： Nai Y. Chen , Sharon B. McCullen
IPC分类号： B01J29/74 , C10G45/64 , B01J29/32
CPC分类号： C10G45/64 , B01J29/7415
摘要： A process is described for preparing a binder-free Zeolite Beta containing catalyst which has a highly dispersed noble metal incorporated into the framework. The process comprises steaming Zeolite Beta, followed by noble metal incorporation and calcination. The present invention is also directed to an improved calcination process.
摘要翻译：描述了一种制备不含无粘结剂的含沸石沸石的催化剂的方法，该催化剂具有掺入框架中的高度分散的贵金属。该方法包括蒸煮沸石β，然后进行贵金属掺入和煅烧。本发明还涉及一种改进的煅烧方法。

7. 发明授权

US4756822A Hydroprocessing catalyst and process 失效
标题翻译：加氢催化剂和工艺
公开(公告)号：US4756822A
公开(公告)日：1988-07-12
申请号：US31807
申请日：1987-03-30
申请人： Nai Y. Chen , Tracy J. Huang
发明人： Nai Y. Chen , Tracy J. Huang
IPC分类号： B01J29/86 , C10G47/16
CPC分类号： B01J29/86 , C10G47/16
摘要： This invention provides a novel hydrocracking catalyst composition that contains Zeolite Beta having a framework boron content, a solid source of alumina, and a hydrogenation component. It further provides a low-pressure hydrocracking process that uses such composition.
摘要翻译：本发明提供一种新型加氢裂化催化剂组合物，其包含具有骨架硼含量的沸石β，氧化铝的固体源和氢化组分。它还提供了使用这种组合物的低压加氢裂化方法。

8. 发明授权

US4749467A Lube dewaxing method for extension of cycle length 失效
标题翻译：润滑油脱蜡方法延长循环长度
公开(公告)号：US4749467A
公开(公告)日：1988-06-07
申请号：US054115
申请日：1987-05-22
申请人： Nai Y. Chen , Bruce P. Pelrine
发明人： Nai Y. Chen , Bruce P. Pelrine
IPC分类号： C10G45/64 , C10G73/38
CPC分类号： C10G45/64
摘要： An improved method which provides for an extended cycle length in catalytic lube dewaxing of residual lube oil feedstocks and easier catalyst regeneration. The method may incorporate catalytically dewaxing a feedstock in a fixed bed reactor with or without product recycle, or a series of reactors with interreactor separation of vapors from liquids. Improved performance is achieved by operating the reactor at a temperature between about 490.degree. and about 620.degree. F., employing a high activity crystalline zeolite catalyst having an alpha value between about 50 and about 900 based on the zeolite and a space velocity sufficiently low to produce a dewaxed effluent of desired pour point and to maintain an average catalyst aging rate of less than about 2.degree. F. per day. This relatively low temperature operation allows catalyst performance to be restored by simple hydrogen reactivation.
摘要翻译：一种改进的方法，其提供了在残余润滑油原料的催化润滑油脱蜡中延长的循环长度并且更容易的催化剂再生。该方法可以将原料催化脱蜡在具有或不具有产物再循环的固定床反应器中，或者一系列具有蒸发器与液体的反应器分离的反应器。通过使用基于沸石的α值在约50至约900之间的高活性结晶沸石催化剂，在约490℃至约620℃的温度下操作反应器来实现改进的性能，空间速度足够低至产生所需倾点的脱蜡流出物，并保持每天平均催化剂老化速率小于约2°F。这种相对较低的温度操作允许通过简单的氢再活化来恢复催化剂性能。

9. 发明授权

US4711710A Process for making improved lubricating oils from heavy feedstock 失效
标题翻译：从重质原料制备改进的润滑油的方法
公开(公告)号：US4711710A
公开(公告)日：1987-12-08
申请号：US938214
申请日：1986-12-05
申请人： Nai Y. Chen , Thomas F. Degnan, Jr. , Susan M. Leiby , Stephen M. Oleck , Bruce P. Pelrine
发明人： Nai Y. Chen , Thomas F. Degnan, Jr. , Susan M. Leiby , Stephen M. Oleck , Bruce P. Pelrine
IPC分类号： B01J29/46 , C10G11/05 , C10G45/64 , C10G11/10 , C10G47/16
CPC分类号： C10G45/64 , B01J29/46 , B01J2229/26 , B01J2229/42
摘要： There is disclosed an improved dewaxing process which will operate for longer periods of time involving contacting a feedstock having a 50 volume percent boiling point greater than 900.degree. F. with a crystalline aluminosilicate zeolite having a Constraint Index of from 1 to 12 and a silica-to-alumina ratio of at least 12. The crystalline aluminosilicate zeolite is composited with an inorganic oxide, such as alumina. The composite also containing a hydrogenation metal and the catalyst composite has a maximum diffusion distance of less than 0.025 inch.
摘要翻译：公开了一种改进的脱蜡方法，该方法操作更长的时间段，包括使具有大于900°F的50体积％沸点的原料与约1至12的约束指数的结晶硅铝酸盐沸石接触，氧化铝比至少为12.结晶硅铝酸盐沸石与无机氧化物如氧化铝复合。还含有氢化金属和催化剂复合材料的复合材料具有小于0.025英寸的最大扩散距离。

10. 发明授权

US4500417A Conversion of Fischer-Tropsch products 失效
标题翻译：费托产品的转化
公开(公告)号：US4500417A
公开(公告)日：1985-02-19
申请号：US453970
申请日：1982-12-28
申请人： Nai Y. Chen , Werner O. Haag , Tracy J. Huang , Stephen S. Wong
发明人： Nai Y. Chen , Werner O. Haag , Tracy J. Huang , Stephen S. Wong
IPC分类号： C10G45/64 , B01J29/00 , B01J29/74 , B01J29/78 , C07C1/00 , C07C1/04 , C07C9/00 , C07C67/00 , C10G47/16 , C10G49/08 , C10G47/20
CPC分类号： C10G47/16 , B01J2229/37 , B01J29/7415 , B01J29/7815 , Y10S208/95
摘要： The high boiling fraction of Fischer-Tropsch synthesis is upgraded by contact with a catalyst comprising a high-silica, large pore zeolite and a hydrogenation component. The products are a distillate fraction characterized by low sulfur and nitrogen content, high isoparaffin content and low pour point and a lube fraction characterized by its high viscosity index and low pour point.
摘要翻译：通过与包含高二氧化硅，大孔沸石和氢化组分的催化剂接触来提高费 - 托合成的高沸点馏分。该产品是以低硫和氮含量，高异链烷烃含量和低倾点为特征的馏出物部分，其特征在于其高粘度指数和低倾点。

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