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1. 发明授权

US4711710A Process for making improved lubricating oils from heavy feedstock 失效
标题翻译：从重质原料制备改进的润滑油的方法
公开(公告)号：US4711710A
公开(公告)日：1987-12-08
申请号：US938214
申请日：1986-12-05
申请人： Nai Y. Chen , Thomas F. Degnan, Jr. , Susan M. Leiby , Stephen M. Oleck , Bruce P. Pelrine
发明人： Nai Y. Chen , Thomas F. Degnan, Jr. , Susan M. Leiby , Stephen M. Oleck , Bruce P. Pelrine
IPC分类号： B01J29/46 , C10G11/05 , C10G45/64 , C10G11/10 , C10G47/16
CPC分类号： C10G45/64 , B01J29/46 , B01J2229/26 , B01J2229/42
摘要： There is disclosed an improved dewaxing process which will operate for longer periods of time involving contacting a feedstock having a 50 volume percent boiling point greater than 900.degree. F. with a crystalline aluminosilicate zeolite having a Constraint Index of from 1 to 12 and a silica-to-alumina ratio of at least 12. The crystalline aluminosilicate zeolite is composited with an inorganic oxide, such as alumina. The composite also containing a hydrogenation metal and the catalyst composite has a maximum diffusion distance of less than 0.025 inch.
摘要翻译：公开了一种改进的脱蜡方法，该方法操作更长的时间段，包括使具有大于900°F的50体积％沸点的原料与约1至12的约束指数的结晶硅铝酸盐沸石接触，氧化铝比至少为12.结晶硅铝酸盐沸石与无机氧化物如氧化铝复合。还含有氢化金属和催化剂复合材料的复合材料具有小于0.025英寸的最大扩散距离。

2. 发明授权

US4737263A Process and apparatus for catalytic dewaxing of paraffinic stocks and the simultaneous removal of cracked products 失效
标题翻译：用于石蜡原料的催化脱蜡的方法和装置以及同时除去裂化产物
公开(公告)号：US4737263A
公开(公告)日：1988-04-12
申请号：US884466
申请日：1986-07-11
申请人： Nai Y. Chen , Thomas F. Degnan, Jr. , Bruce P. Pelrine , Richard F. Socha
发明人： Nai Y. Chen , Thomas F. Degnan, Jr. , Bruce P. Pelrine , Richard F. Socha
IPC分类号： C10G45/58 , C10G45/64 , C10G23/00
CPC分类号： C10G45/64 , C10G45/58
摘要： Dewaxing a waxy feedstock is achieved by submerging the dewaxing catalyst bed in the waxy feedstock and removing gaseous products out of contact with the catalyst by agitating the bed to prevent further cracking or polymerization. Catalyst aging during dewaxing is significantly reduced by operating the dewaxing reactor within a narrow low temperature range.
摘要翻译：脱蜡蜡质原料通过将脱蜡催化剂床浸没在蜡质原料中并通过搅拌床除去与催化剂接触的气态产物以防止进一步的开裂或聚合来实现。脱蜡过程中的催化剂老化通过在较低的低温范围内操作脱蜡反应器而显着降低。

3. 发明授权

US5271920A Activation of zeolites 失效
标题翻译：活化沸石
公开(公告)号：US5271920A
公开(公告)日：1993-12-21
申请号：US818722
申请日：1992-01-07
申请人： Clarence D. Chang , Nai Y. Chen , Cynthis T. Chu , Bruce P. Pelrine
发明人： Clarence D. Chang , Nai Y. Chen , Cynthis T. Chu , Bruce P. Pelrine
IPC分类号： B01J20/18 , B01J29/40 , B01J37/06 , C01B33/34
CPC分类号： B01J37/06 , B01J20/186 , B01J29/40 , Y10S423/22
摘要： The invention includes a ZSM-5 composition and the preparation thereof which comprises treating ZSM-5 with solutions of salts of weak acids. The resulting ultrasmall crystal size ZSM-5 component has a sorption capacity for 2,2-dimethylbutane of at least 10 mg/g zeolite and a sorption time for 30% capacity zeolitic sorption at 60.degree. C. and P(2,2-dimethylbutane) of 60 torr, of less than about 4 minutes.
摘要翻译：本发明包括ZSM-5组合物及其制备方法，其包括用弱酸盐溶液处理ZSM-5。所得到的超小晶体尺寸ZSM-5组分对于至少10mg / g沸石的2,2-二甲基丁烷具有吸附能力，在60℃具有30％容量沸石吸附的吸附时间和P（2,2-二甲基丁烷）为60托，小于约4分钟。

4. 发明授权

US4668377A Catalytic process for dewaxing 失效
标题翻译：催化脱蜡工艺
公开(公告)号：US4668377A
公开(公告)日：1987-05-26
申请号：US789608
申请日：1985-10-21
申请人： Nai Y. Chen , Bruce P. Pelrine
发明人： Nai Y. Chen , Bruce P. Pelrine
IPC分类号： C10G45/64 , C10G11/05 , C10G47/16
CPC分类号： C10G45/64
摘要： A process for dewaxing lube basestocks over low acidity dewaxing catalysts can be undertaken at steady state temperature. In a preferred embodiment, the feedstock is subjected to catalytic dewaxing with concommident removal of gaseous product. When high boiling feed with end points above 1000.degree. F., such as heavy neutrals and bright stocks, and waxy feeds containing more than 20 wt % wax are subject of the process, it is preferred to use continuously stirred tank reactors.
摘要翻译：在低酸度脱蜡催化剂上脱蜡润滑油基础油的方法可以在稳态温度下进行。在优选的实施方案中，原料经过催化脱蜡，同时除去气体产物。当终点高于1000°F的高沸点饲料（如重质中性粒子和光亮的油料）和含有20％（重量）以上蜡的蜡质进料时，最好使用连续搅拌釜式反应器。

5. 发明授权

US4363717A Conversion of heavy hydrocarbon oils 失效
标题翻译：重质烃油的转化
公开(公告)号：US4363717A
公开(公告)日：1982-12-14
申请号：US225284
申请日：1981-01-15
申请人： Bruce P. Pelrine , Nai Y. Chen , Tsoung Y. Yan
发明人： Bruce P. Pelrine , Nai Y. Chen , Tsoung Y. Yan
IPC分类号： B01D11/04 , C10G11/08 , C10G21/00 , C10G47/08 , C10G47/32
CPC分类号： C10G21/003 , B01D11/0407 , C10G11/08 , C10G47/08
摘要： This invention provides a process for upgrading a heavy hydrocarbon oil to motor fuel products.The heavy hydrocarbon oil is admixed with a metal halide catalyst and a solvent component under supercritical conditions to form (1) a dense-gas solvent phase which contains refined hydrocarbon crackate, and which is substantially free of metal halide catalyst content; and (2) a residual asphaltic phase.
摘要翻译：本发明提供了一种将重质烃油升级为机动车燃料产品的方法。在超临界条件下将重质烃油与金属卤化物催化剂和溶剂组分混合以形成（1）含有精炼烃裂化物的致密气体溶剂相，其基本上不含金属卤化物催化剂含量; 和（2）残留沥青相。

6. 发明授权

US4222855A Production of high viscosity index lubricating oil stock 失效
标题翻译：生产高粘度指数润滑油原料
公开(公告)号：US4222855A
公开(公告)日：1980-09-16
申请号：US23855
申请日：1979-03-26
申请人： Bruce P. Pelrine , Nai Y. Chen
发明人： Bruce P. Pelrine , Nai Y. Chen
IPC分类号： B01J29/46 , B01J29/70 , C10G45/64 , C10G11/05 , C10G47/16
CPC分类号： B01J29/7049 , B01J29/46 , B01J29/70 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C10G2400/10
摘要： Waxy hydrocarbon oils, e.g., of petroleum origin, boiling within the approximate range of 450.degree. to 1050.degree. F. are catalytically dewaxed utilizing a catalyst comprising a crystalline aluminosilicate zeolite possessing particularly characterized pore openings, such as, for example, ZSM-23 or ZSM-35, which may be associated with a hydrogenation metal.
摘要翻译：使用包含具有特别表征的孔开口的结晶铝硅酸盐沸石的催化剂，在450至1050°F的近似范围内沸腾的石油来源的蜡质烃油进行催化脱蜡，所述结晶硅铝酸盐沸石包括例如ZSM-23或 ZSM-35，其可与氢化金属缔合。

7. 发明授权

US4749467A Lube dewaxing method for extension of cycle length 失效
标题翻译：润滑油脱蜡方法延长循环长度
公开(公告)号：US4749467A
公开(公告)日：1988-06-07
申请号：US054115
申请日：1987-05-22
申请人： Nai Y. Chen , Bruce P. Pelrine
发明人： Nai Y. Chen , Bruce P. Pelrine
IPC分类号： C10G45/64 , C10G73/38
CPC分类号： C10G45/64
摘要： An improved method which provides for an extended cycle length in catalytic lube dewaxing of residual lube oil feedstocks and easier catalyst regeneration. The method may incorporate catalytically dewaxing a feedstock in a fixed bed reactor with or without product recycle, or a series of reactors with interreactor separation of vapors from liquids. Improved performance is achieved by operating the reactor at a temperature between about 490.degree. and about 620.degree. F., employing a high activity crystalline zeolite catalyst having an alpha value between about 50 and about 900 based on the zeolite and a space velocity sufficiently low to produce a dewaxed effluent of desired pour point and to maintain an average catalyst aging rate of less than about 2.degree. F. per day. This relatively low temperature operation allows catalyst performance to be restored by simple hydrogen reactivation.
摘要翻译：一种改进的方法，其提供了在残余润滑油原料的催化润滑油脱蜡中延长的循环长度并且更容易的催化剂再生。该方法可以将原料催化脱蜡在具有或不具有产物再循环的固定床反应器中，或者一系列具有蒸发器与液体的反应器分离的反应器。通过使用基于沸石的α值在约50至约900之间的高活性结晶沸石催化剂，在约490℃至约620℃的温度下操作反应器来实现改进的性能，空间速度足够低至产生所需倾点的脱蜡流出物，并保持每天平均催化剂老化速率小于约2°F。这种相对较低的温度操作允许通过简单的氢再活化来恢复催化剂性能。

8. 发明授权

US5157177A VI enhancing compositions and newtonian lube blends 失效
标题翻译： VI增强组合物和牛顿润滑剂混合物
公开(公告)号：US5157177A
公开(公告)日：1992-10-20
申请号：US686639
申请日：1991-04-17
申请人： Bruce P. Pelrine , Margaret M. Wu
发明人： Bruce P. Pelrine , Margaret M. Wu
IPC分类号： C08F10/14 , C08F110/14 , C08F210/14 , C10G50/02 , C10M143/08
CPC分类号： C08F10/14 , C10G50/02 , C10M143/08 , C08F110/14 , C08F210/14 , C10M2205/00 , C10M2205/028 , C10N2220/02 , Y02P20/582
摘要： A novel composition is disclosed that is particularly useful as a lubricant viscosity index improver. The composition comprises branched C.sub.30 -C.sub.10000 hydrocarbons that have a branch ratio of less than 0.19 and viscosity at 100.degree. C. between 725 cS and 15,000 cS. The novel compositions comprise the product of the oligomerization of C.sub.6 to C.sub.20 alpha-olefin feedstock, or mixtures thereof, under oligomerization conditions at a temperature between -20.degree. C. and +90.degree. C. in contact with a reduced valence state Group VIB metal catalyst on porous support. The compositions have viscosities at 100.degree. C. between 725 cS and 15,000 cS. Using the foregoing compositions in admixture with mineral oil and synthetic lubricants provides novel lubricant blends that show an elevated viscosity index. The mixtures also show an increased stability to shear stress at high temperature with all blends notable by exhibiting Newtonian flow.
摘要翻译：公开了作为润滑剂粘度指数改进剂特别有用的新型组合物。该组合物包含分支比小于0.19且在100℃下的粘度在725cS和15,000cS之间的支链C30-C10000烃。该新型组合物包括C6-C20α-烯烃原料低聚的产物，或其混合物，在低温条件下，在-20℃至+ 90℃之间的温度下与还原的化合价VIB金属多孔载体上的催化剂。组合物在100℃下的粘度在725cS和15,000cS之间。使用与矿物油和合成润滑剂混合的上述组合物提供显示升高的粘度指数的新型润滑剂共混物。混合物还显示出在高温下对剪切应力的稳定性增加，所有共混物通过显示牛顿流动显着。

9. 发明授权

US5105051A Production of olefin oligomer lubricants 失效
标题翻译：生产烯烃低聚物润滑剂
公开(公告)号：US5105051A
公开(公告)日：1992-04-14
申请号：US693254
申请日：1991-04-29
申请人： Bruce P. Pelrine , Kirk D. Schmitt , James C. Vartuli
发明人： Bruce P. Pelrine , Kirk D. Schmitt , James C. Vartuli
IPC分类号： B01J29/04 , B01J39/10 , C07C2/12 , C08F10/14 , C10M107/02 , C10M143/00
CPC分类号： C10M143/00 , B01J29/04 , B01J39/10 , C07C2/12 , C08F10/14 , C10M107/02 , C07C2523/26 , C07C2529/78 , C10M2205/00 , C10M2205/028 , C10N2220/02
摘要： A process for oligomerizing alpha olefins to produce hydrocarbon oligomers useful as lubricants and lubricant additives uses a catalyst comprising a supported reduced group VIB metal, preferably chromium, in the form of its oxide. The support is a mesoporous, inorganic, crystalline solid of unique structure, of novel pore geometry. The preferred forms of these mesoporous materials are characterized by substantially uniform hexagonal honeycomb microstructure, with uniform pores having a cell diameter greater than 13 .ANG., preferably in the mesoporous range of about 20-100 .ANG.. The use of the catalysts made with the mesoporous support materials enables products of greater viscosity to be made as compared to the products from catalysts using amorphous supports. The catalyst is usually used under oligomerization conditions at a temperature of about 90.degree. to 250.degree. C. to produce liquid hydrocarbon oligomers in the lubricant range which have a branch ratio of less than 0.19 and high values of viscosity index.
摘要翻译：用于使α-烯烃低聚以制备用作润滑剂和润滑剂添加剂的烃低聚物的方法使用包含其氧化物形式的负载的还原族VIB金属，优选铬的催化剂。该支持体是具有独特结构，孔隙几何形状的介孔，无机，结晶固体。这些介孔材料的优选形式的特征在于基本上均匀的六边形蜂窝微结构，具有孔直径大于13的均匀孔，优选在约20-100的介孔范围内。与使用无定形载体的催化剂的产物相比，使用由介孔载体材料制成的催化剂能够制备更大粘度的产物。催化剂通常在低温条件下在约90℃至250℃的温度下使用，以在润滑剂范围内产生分支比小于0.19且粘度指数高的液态烃低聚物。

10. 发明授权

US4990718A Aromatic alkylation with alpha-olefin dimer 失效
标题翻译：芳族烷基化与α-烯烃二聚体
公开(公告)号：US4990718A
公开(公告)日：1991-02-05
申请号：US332146
申请日：1989-04-03
申请人： Bruce P. Pelrine
发明人： Bruce P. Pelrine
IPC分类号： B01J29/08 , C07B61/00 , C07C2/10 , C07C2/66 , C07C2/70 , C07C11/02 , C07C15/107
CPC分类号： C07C15/107 , C07C2/10 , C07C2/66 , C07C2521/08 , C07C2523/26 , C07C2529/08 , Y02P20/52
摘要： A process is disclosed for the production of novel monoalkylbenzenes or substituted benzenes by aromatics alkylation wherein the alkylation catalyst is an acidic shape selective metallosilicate catalyst and the alkylating agent is the olefins dimer by-product of the oligomerization of alpha-olefins in contact with reduced valence state solid chromium oxide catalyst on a porous support. The alkylated benzenes produced comprise those mono-alkylbenzenes wherein the alkyl group contains 12 to 28 carbon atoms and have high viscosity index, low pour point and low viscosity. They have a low degree of residual olefinic unsaturation and are useful as additives to thermally and oxidatively stabilize lubricant materials. The process comprises reacting benzene or substituted benzene with C.sub.6 -C.sub.14 alpha-olefin olefinic dimer having a branch ratio of less than 0.19, or mixture of said dimers, in contact with acidic shape selective zeolite catalyst having large pore size.
摘要翻译：公开了通过芳烃烷基化生产新的单烷基苯或取代的苯的方法，其中烷基化催化剂是酸性形状的选择性金属硅酸盐催化剂，烷基化剂是烯烃与低价接触的低聚烯烃的副产物状态的固体氧化铬催化剂在多孔载体上。所生产的烷基化苯包括其中烷基含有12至28个碳原子并具有高粘度指数，低倾点和低粘度的单烷基苯。它们具有低残余烯属不饱和度，并且可用作热和氧化稳定润滑剂材料的添加剂。该方法包括使苯或取代的苯与分支比小于0.19的C 6 -C 14α-烯烃烯属二聚体或所述二聚体的混合物与具有大孔径的酸性形状选择性沸石催化剂接触。

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