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    • 4. 发明授权
    • Interconnects with improved barrier layer adhesion
    • 互连具有改进的阻隔层附着力
    • US07071562B2
    • 2006-07-04
    • US10662525
    • 2003-09-16
    • Minh Van NgoDawn Hopper
    • Minh Van NgoDawn Hopper
    • H01L23/48H01L23/52H01L29/40
    • H01L21/76846C23C16/56H01L21/76807H01L21/76814H01L21/76825H01L21/76831H01L23/5226H01L23/53238H01L2924/0002H01L2924/3011H01L2924/00
    • Semiconductor devices comprising interconnect with improved adhesion of barrier layers to dielectric layers are formed by laser thermal annealing exposed surfaces of a dielectric layer in an atmosphere of NH3 and N2, and subsequently depositing Ta to form a composite barrier layer. Embodiments include forming a dual damascene opening in an interlayer dielectric comprising F-containing silicon oxide, such as F-containing silicon oxide derived from F-TEOS, laser thermal annealing the exposed silicon oxide surface in NH3 and N2, depositing Ta and then filling the opening with Cu. Laser thermal annealing in NH3 and N2 depletes the exposed silicon oxide surface of F while forming an N2-rich surface region. Deposited Ta reacts with the N2 in the N2-rich surface region to form a composite barrier layer comprising a graded layer of tantalum nitride and a layer of α-Ta thereon.
    • 包括具有改善的阻挡层与电介质层的粘附性的互连的半导体器件通过激光热退火在NH 3和N 2的气氛中的电介质层的暴露表面而形成,以及 随后沉积Ta以形成复合阻挡层。 实施例包括在包含含F的氧化硅的层间电介质中形成双镶嵌开口,例如衍生自F-TEOS的含F的氧化硅,在NH 3中对暴露的氧化硅表面进行激光热退火,以及 N 2,沉积Ta,然后用Cu填充开口。 NH 3和N 2 N中的激光热退火在形成富含N 2的富含表面区域的同时消耗了暴露的F氧化硅表面。 沉积的Ta与富含N 2的表面区域中的N 2 N反应形成复合阻挡层,该复合势垒层包括氮化钽的梯度层和其上的α-Ta层 。
    • 5. 发明授权
    • Interconnects with improved barrier layer adhesion
    • 互连具有改进的阻隔层附着力
    • US06645853B1
    • 2003-11-11
    • US10001805
    • 2001-12-05
    • Minh Van NgoDawn Hopper
    • Minh Van NgoDawn Hopper
    • H01L214763
    • H01L21/76846C23C16/56H01L21/76807H01L21/76814H01L21/76825H01L21/76831H01L23/5226H01L23/53238H01L2924/0002H01L2924/3011H01L2924/00
    • Semiconductor devices comprising interconnect with improved adhesion of barrier layers to dielectric layers are formed by laser thermal annealing exposed surfaces of a dielectric layer in an atmosphere of NH3 and N2, and subsequently depositing Ta to form a composite barrier layer. Embodiments include forming a dual damascene opening in an interlayer dielectric comprising F-containing silicon oxide, such as F-containing silicon oxide derived from F-TEOS, laser thermal annealing the exposed silicon oxide surface in NH3 and N2, depositing Ta and then filling the opening with Cu. Laser thermal annealing in NH3 and N2 depletes the exposed silicon oxide surface of F while forming an N2-rich surface region. Deposited Ta reacts with the N2 in the N2-rich surface region to form a composite barrier layer comprising a graded layer of tantalum nitride and a layer of &agr;-Ta thereon.
    • 通过在NH 3和N 2的气氛中通过激光热退火介电层的暴露表面,随后沉积Ta形成复合阻挡层,形成包括具有改善的阻挡层与电介质层的粘合性的互连的半导体器件。 实施例包括在包含含F的氧化硅的层间电介质中形成双镶嵌开口,例如衍生自F-TEOS的含F的氧化硅,在NH 3和N 2中对暴露的氧化硅表面进行激光热退火,沉积Ta然后填充 用Cu打开。 NH3和N2中的激光热退火消耗了暴露的F氧化硅表面,同时形成富氮表面区域。 沉积的Ta在富氮的表面区域中与N 2反应以形成包含梯度氮化钽层和其上的α-Ta层的复合势垒层。