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    • 1. 再颁专利
    • Radiation sensitive resin composition
    • 辐射敏感树脂组合物
    • USRE37179E1
    • 2001-05-15
    • US09420604
    • 1999-10-21
    • Mikio YamachikaEiichi KobayashiAkira TsujiToshiyuki Ota
    • Mikio YamachikaEiichi KobayashiAkira TsujiToshiyuki Ota
    • G03F7023
    • G03F7/0045G03F7/039Y10S430/106Y10S430/11Y10S430/111
    • A radiation sensitive resin composition which comprises (A) a polymer which becomes alkali-soluble in the presence of an acid and (B) a radiation sensitive acid generator which generates an acid upon irradiation with a radiation, said polymer (A) comprising two recurring units represented by the general formulas (1) and (2) and a recurring unit which acts to reduce the solubility of the polymer is an alkali developer after the irradiation: wherein R1 represents a hydrogen atom or a methyl group and R2 represents a hydrogen atom or a methyl group. Said composition provides a chemically amplified positive resist which can give a fine pattern with a good pattern shape, and said resist is freed from volume shrinkage, peeling failure and adhesive failure, is excellent in dry etching resistance and effectively reacts with various radiations to give a good pattern shape which is excellent in photolithographic process stability, said pattern shape having no thinned portion at the upper part.
    • 一种辐射敏感性树脂组合物,其包含(A)在酸存在下变为碱溶性的聚合物和(B)辐射敏感的酸产生剂,其在辐射时产生酸,所述聚合物(A)包含两个重复 由通式(1)和(2)表示的单元和降低聚合物溶解度的重复单元是照射后的碱显影剂:其中R1表示氢原子或甲基,R2表示氢原子 或甲基。 所述组合物提供化学放大的正性抗蚀剂,其可以产生具有良好图案形状的精细图案,并且所述抗蚀剂没有体积收缩,剥离破坏和粘合剂破坏,具有优异的耐干蚀刻性,并且与各种辐射有效反应以产生 良好的图案形状,其光刻工艺稳定性优异,所述图案形状在上部没有变薄部分。
    • 3. 发明授权
    • Radiation sensitive resin composition
    • 辐射敏感树脂组合物
    • US5679495A
    • 1997-10-21
    • US352848
    • 1994-12-02
    • Mikio YamachikaEiichi KobayashiToshiyuki OtaAkira Tsuji
    • Mikio YamachikaEiichi KobayashiToshiyuki OtaAkira Tsuji
    • G03F7/004G03F7/028G03F7/039H01L21/027G03F7/023
    • G03F7/0045G03F7/039Y10S430/106Y10S430/11Y10S430/111
    • A radiation sensitive resin composition which comprises (A) a polymer which becomes alkali-soluble in the presence of an acid and (B) a radiation sensitive acid generator which generates an acid upon irradiation with a radiation, said polymer (A) comprising two recurring units represented by the general formulas (1) and (2) and a recurring unit which acts to reduce the solubility of the polymer in an alkali developer after the irradiation: ##STR1## wherein R.sup.1 represents a hydrogen atom or a methyl group and R.sup.2 represents a hydrogen atom or a methyl group. Said composition provides a chemically amplified positive resist which can give a fine pattern with a good pattern shape, and said resist is freed from volume shrinkage, peeling failure and adhesive failure, is excellent in dry etching resistance and effectively reacts with various radiations to give a good pattern shape which is excellent in photolithographic process stability, said pattern shape having no thinned portion at the upper part.
    • 一种辐射敏感性树脂组合物,其包含(A)在酸存在下变为碱溶性的聚合物和(B)辐射敏感的酸产生剂,其在辐射时产生酸,所述聚合物(A)包含两个重复 由通式(1)和(2)表示的单元和反应单元,其用于降低聚合物在照射后的碱显影剂中的溶解度:其中R1表示 氢原子或甲基,R 2表示氢原子或甲基。 所述组合物提供化学放大的正性抗蚀剂,其可以产生具有良好图案形状的精细图案,并且所述抗蚀剂没有体积收缩,剥离破坏和粘合剂破坏,具有优异的耐干蚀刻性,并且与各种辐射有效反应以产生 良好的图案形状,其光刻工艺稳定性优异,所述图案形状在上部没有变薄部分。
    • 7. 发明授权
    • Radiation-sensitive resin composition
    • 辐射敏感树脂组合物
    • US06506537B2
    • 2003-01-14
    • US09878274
    • 2001-06-12
    • Eiichi KobayashiJun NumataMikio YamachikaMasafumi Yamamoto
    • Eiichi KobayashiJun NumataMikio YamachikaMasafumi Yamamoto
    • G03F7004
    • G03F7/0758G03F7/0045G03F7/039Y10S430/106Y10S430/111
    • A positive-type radiation-sensitive resin composition is provided. The composition includes: (A) a low-molecular compound comprising a compound having at least one amino group having one or two hydrogen atom(s) bonded to the nitrogen atom; at least one hydrogen atom the amino group has having been substituted with a t-butoxycarbonyl group; (B) a radiation-sensitive acid generator; and (C) a silicon-atom-containing resin comprising an alkali-insoluble or alkali-slightly-soluble resin having been protected with an acid-cleavable group; the resin being capable of turning soluble in alkali upon cleavage of the acid-cleavable group. This radiation-sensitive resin composition is effectively responsive to radiations of various types, has superior sensitivity and resolution and also a superior long-term storage stability, and is useful as a positive-type chemically amplified resist.
    • 提供正型辐射敏感性树脂组合物。 该组合物包括:(A)包含具有至少一个具有与氮原子键合的一个或两个氢原子的氨基的化合物的低分子化合物; 至少一个氢原子已经被叔丁氧基羰基取代;(B)辐射敏感性酸产生剂; 和(C)含有硅原子的树脂,其包含用酸可裂解基团保护的碱不溶性或碱 - 微溶性树脂; 该树脂在切割酸可分解基团时能够转变为碱溶性。该辐射敏感性树脂组合物对各种辐射有效响应,具有优异的灵敏度和分辨率,并且还具有优异的长期储存稳定性,并且 可用作正型化学放大抗蚀剂。
    • 8. 发明授权
    • Chemically amplified resist
    • 化学放大抗蚀剂
    • US5580695A
    • 1996-12-03
    • US339289
    • 1994-11-10
    • Makoto MurataTakao MiuraYoshiji YumotoToshiyuki OtaEiichi Kobayashi
    • Makoto MurataTakao MiuraYoshiji YumotoToshiyuki OtaEiichi Kobayashi
    • G03F7/004G03C1/73G03F7/038
    • G03F7/0045Y10S430/118Y10S430/121
    • A chemically amplified resist comprising an alkali-soluble resin or a resin having at least one acid-dissociable group which is alkali-insoluble or -sprairingly soluble but becomes alkali-soluble upon dissociation of said acid dissociable group due to an acid; a radiation-sensitive, acid-generating agent; and an optional component in which resist, the radiation-sensitive, acid-generating agent generates an acid upon irradiation with a radiation in the irradiated portion and the solubility of the resin component and optional component in a developing solution is varied in the irradiated portion by a chemical reaction caused by the catalytic action of the acid, whereby a pattern is formed, characterized in that a compound having a nitrogen-containing basic group is contained in the resist. Said resist is superior in developability, pattern form, resolution, focus tolerance and yield of residual film thickness, has good process stability, and can be suitably used even in irradiation with, in particular, a radiation having a wavelength equal to or smaller than far ultraviolet rays, for example, an excimer laser or the like.
    • 一种化学放大抗蚀剂,其包含碱溶性树脂或具有至少一种酸解离基团的树脂,所述酸解离基团是由于酸而导致的所述酸解离基团的解离时为碱不溶性或易溶性但是变得碱溶性的; 辐射敏感的酸产生剂; 以及任选的组分,其中抗辐射敏感的酸产生剂在照射部分中的辐射照射时产生酸,并且树脂组分和任选组分在显影溶液中的溶解度在照射部分中变化 由酸的催化作用引起的化学反应,由此形成图案,其特征在于在抗蚀剂中含有具有含氮碱性基团的化合物。 所述抗蚀剂的显影性,图案形式,分辨率,聚焦容限和残留膜厚度的产率优异,具有良好的工艺稳定性,并且可以适用于特别是具有等于或小于远的波长的辐射 紫外线,例如准分子激光等。