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    • 7. 发明授权
    • Electrically conductive steel-ceramic composite and process to manufacture it
    • 导电钢 - 陶瓷复合材料及其制造工艺
    • US08349395B2
    • 2013-01-08
    • US10592752
    • 2005-03-16
    • Joachim LaatschFrank TietzNiels ChristiansenPetru GordesGijsbertus RietveldNicolaas J. J. Dekker
    • Joachim LaatschFrank TietzNiels ChristiansenPetru GordesGijsbertus RietveldNicolaas J. J. Dekker
    • B05D5/12
    • H01M8/0228H01M8/021H01M8/0217Y02P70/56
    • The invention relates to a electrically conductive steel-ceramic connection comprising a steel interconnector and an electrically conductive ceramic joining layer arranged thereon. The interconnector comprises a ferritic steel containing Cr in a quantity ranging from 18 to 24% by weight. The ceramic layer contains perovskite of a formula Ln1-xSrxMn1-yCoyO3-δ or Ln1-xSrxFe1-yCoyO3-δ, wherein 0.1≦x≦0.4, 0.1≦y≦0.6, 0≦δ≦x/2 and Ln=La—Lu. The inventive steel-ceramic connection is usable for a high-temperature fuel cell and regularly exhibits good adhesive properties and a low transition resistance (initial transition resistance R approximately equal to 0.01 Ωcm2). Said steel-ceramic connection makes it possible to advantageously introduce a ferritic steel into high-temperature fuel cells. The inventive method for producing said steel-ceramic connection consists in pre-treating an inserted ceramic powder exhibiting good sinterability during an assembly process and during the fuel cell operation.
    • 本发明涉及一种导电钢 - 陶瓷连接件,其包括钢互连器和布置在其上的导电陶瓷接合层。 互连器包括含有18至24重量%的Cr的铁素体钢。 陶瓷层含有式Ln1-xSrxMn1-yCoyO3-δ或Ln1-xSrxFe1-yCoyO3-δ的钙钛矿,其中0.1≦̸ x≦̸ 0.4,0.1≦̸ y≦̸ 0.6,0和nlE;δ≦̸ x / 2和Ln = La -鲁。 本发明的钢 - 陶瓷连接可用于高温燃料电池,并且经常表现出良好的粘合性能和低的过渡电阻(初始转变电阻R大约等于0.01和OHgr·cm 2)。 所述钢 - 陶瓷连接使得有可能有​​利地将铁素体钢引入高温燃料电池中。 用于生产所述钢 - 陶瓷连接的本发明的方法在于预处理在组装过程期间和在燃料电池操作期间表现出良好烧结性的插入陶瓷粉末。
    • 8. 发明申请
    • Electrically conductive steel-ceramic composite and process to manufacture it
    • 导电钢 - 陶瓷复合材料及其制造工艺
    • US20070178004A1
    • 2007-08-02
    • US10592752
    • 2005-03-16
    • Joachim LaatschFrank TietzNiels ChristiansenPetru GordesGijsbertus RietveldNicolaas Dekker
    • Joachim LaatschFrank TietzNiels ChristiansenPetru GordesGijsbertus RietveldNicolaas Dekker
    • B22F7/00
    • H01M8/0228H01M8/021H01M8/0217Y02P70/56
    • The invention relates to a electrically conductive steel-ceramic connection comprising a steel interconnector and an electrically conductive ceramic joining layer arranged thereon. The interconnector comprises a ferritic steel containing Cr in a quantity ranging from 18 to 24% by weight. The ceramic layer contains perovskite of a formula Ln1-xSrxMn1-yCoyO3-δ or Ln1-xSrxFe1-yCOyO3-δ, wherein 0.1≦x≦0.4, 0.1≦y≦0.6, 0≦δ≦x/2 and Ln=La—Lu. The inventive steel-ceramic connection is usable for a high-temperature fuel cell and regularly exhibits good adhesive properties and a low transition resistance (initial transition resistance R approximately equal to 0.01 Ωcm2). Said steel-ceramic connection makes it possible to advantageously introduce a ferritic steel into high-temperature fuel cells. The inventive method for producing said steel-ceramic connection consists in pre-treating an inserted ceramic powder exhibiting good sinterability during an assembly process and during the fuel cell operation.
    • 本发明涉及一种导电钢 - 陶瓷连接件,其包括钢互连器和布置在其上的导电陶瓷接合层。 互连器包括含有18至24重量%的Cr的铁素体钢。 陶瓷层含有下式的钙钛矿:Ln 1-x Sr x x Mn 1-y Co y O y O 3-δ或Ln 1-x Sr x x Fe 1-y CO 2, 其中0.1≤x≤0.4,0.1≤y≤0.6,0≤δ≤x/ 2和Ln = La-Lu。 本发明的钢 - 陶瓷连接件可用于高温燃料电池,并且经常表现出良好的粘合性能和低的过渡电阻(初始转变电阻R大约等于0.01Ω·cm 2)。 所述钢 - 陶瓷连接使得有可能有​​利地将铁素体钢引入高温燃料电池中。 用于生产所述钢 - 陶瓷连接的本发明的方法在于预处理在组装过程期间和在燃料电池操作期间表现出良好烧结性的插入陶瓷粉末。