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    • 1. 发明授权
    • Electrically conductive steel-ceramic composite and process to manufacture it
    • 导电钢 - 陶瓷复合材料及其制造工艺
    • US08349395B2
    • 2013-01-08
    • US10592752
    • 2005-03-16
    • Joachim LaatschFrank TietzNiels ChristiansenPetru GordesGijsbertus RietveldNicolaas J. J. Dekker
    • Joachim LaatschFrank TietzNiels ChristiansenPetru GordesGijsbertus RietveldNicolaas J. J. Dekker
    • B05D5/12
    • H01M8/0228H01M8/021H01M8/0217Y02P70/56
    • The invention relates to a electrically conductive steel-ceramic connection comprising a steel interconnector and an electrically conductive ceramic joining layer arranged thereon. The interconnector comprises a ferritic steel containing Cr in a quantity ranging from 18 to 24% by weight. The ceramic layer contains perovskite of a formula Ln1-xSrxMn1-yCoyO3-δ or Ln1-xSrxFe1-yCoyO3-δ, wherein 0.1≦x≦0.4, 0.1≦y≦0.6, 0≦δ≦x/2 and Ln=La—Lu. The inventive steel-ceramic connection is usable for a high-temperature fuel cell and regularly exhibits good adhesive properties and a low transition resistance (initial transition resistance R approximately equal to 0.01 Ωcm2). Said steel-ceramic connection makes it possible to advantageously introduce a ferritic steel into high-temperature fuel cells. The inventive method for producing said steel-ceramic connection consists in pre-treating an inserted ceramic powder exhibiting good sinterability during an assembly process and during the fuel cell operation.
    • 本发明涉及一种导电钢 - 陶瓷连接件,其包括钢互连器和布置在其上的导电陶瓷接合层。 互连器包括含有18至24重量%的Cr的铁素体钢。 陶瓷层含有式Ln1-xSrxMn1-yCoyO3-δ或Ln1-xSrxFe1-yCoyO3-δ的钙钛矿,其中0.1≦̸ x≦̸ 0.4,0.1≦̸ y≦̸ 0.6,0和nlE;δ≦̸ x / 2和Ln = La -鲁。 本发明的钢 - 陶瓷连接可用于高温燃料电池,并且经常表现出良好的粘合性能和低的过渡电阻(初始转变电阻R大约等于0.01和OHgr·cm 2)。 所述钢 - 陶瓷连接使得有可能有​​利地将铁素体钢引入高温燃料电池中。 用于生产所述钢 - 陶瓷连接的本发明的方法在于预处理在组装过程期间和在燃料电池操作期间表现出良好烧结性的插入陶瓷粉末。
    • 2. 发明申请
    • Electrically conductive steel-ceramic composite and process to manufacture it
    • 导电钢 - 陶瓷复合材料及其制造工艺
    • US20070178004A1
    • 2007-08-02
    • US10592752
    • 2005-03-16
    • Joachim LaatschFrank TietzNiels ChristiansenPetru GordesGijsbertus RietveldNicolaas Dekker
    • Joachim LaatschFrank TietzNiels ChristiansenPetru GordesGijsbertus RietveldNicolaas Dekker
    • B22F7/00
    • H01M8/0228H01M8/021H01M8/0217Y02P70/56
    • The invention relates to a electrically conductive steel-ceramic connection comprising a steel interconnector and an electrically conductive ceramic joining layer arranged thereon. The interconnector comprises a ferritic steel containing Cr in a quantity ranging from 18 to 24% by weight. The ceramic layer contains perovskite of a formula Ln1-xSrxMn1-yCoyO3-δ or Ln1-xSrxFe1-yCOyO3-δ, wherein 0.1≦x≦0.4, 0.1≦y≦0.6, 0≦δ≦x/2 and Ln=La—Lu. The inventive steel-ceramic connection is usable for a high-temperature fuel cell and regularly exhibits good adhesive properties and a low transition resistance (initial transition resistance R approximately equal to 0.01 Ωcm2). Said steel-ceramic connection makes it possible to advantageously introduce a ferritic steel into high-temperature fuel cells. The inventive method for producing said steel-ceramic connection consists in pre-treating an inserted ceramic powder exhibiting good sinterability during an assembly process and during the fuel cell operation.
    • 本发明涉及一种导电钢 - 陶瓷连接件,其包括钢互连器和布置在其上的导电陶瓷接合层。 互连器包括含有18至24重量%的Cr的铁素体钢。 陶瓷层含有下式的钙钛矿:Ln 1-x Sr x x Mn 1-y Co y O y O 3-δ或Ln 1-x Sr x x Fe 1-y CO 2, 其中0.1≤x≤0.4,0.1≤y≤0.6,0≤δ≤x/ 2和Ln = La-Lu。 本发明的钢 - 陶瓷连接件可用于高温燃料电池,并且经常表现出良好的粘合性能和低的过渡电阻(初始转变电阻R大约等于0.01Ω·cm 2)。 所述钢 - 陶瓷连接使得有可能有​​利地将铁素体钢引入高温燃料电池中。 用于生产所述钢 - 陶瓷连接的本发明的方法在于预处理在组装过程期间和在燃料电池操作期间表现出良好烧结性的插入陶瓷粉末。
    • 3. 发明申请
    • PROCESS AND APPARATUS FOR HARDENING THE SURFACE LAYER OF COMPONENTS HAVING A COMPLICATED SHAPE
    • 用于硬化具有复合形状的部件的表面层的工艺和装置
    • US20100126642A1
    • 2010-05-27
    • US12312115
    • 2007-10-10
    • Berndt BrennerSteffen BonssFrank TietzMarko SeifertJan HannweberStefan KuehnUdo Karsunke
    • Berndt BrennerSteffen BonssFrank TietzMarko SeifertJan HannweberStefan KuehnUdo Karsunke
    • C21D1/42C21D1/34C21D9/00B23K26/00C21D11/00H05B6/04
    • C21D1/09C21D10/00C21D10/005C21D11/00
    • The invention relates to the hardening of the surface layer of parts of machines, plants and apparatuses and also tools. Objects for which the application is possible and advantageous are components which are subjected to severe fatigue or wear stresses and are composed of hardenable steels and have a complicated shape and whose surface has to be hardened selectively on the functional surfaces or whose functional surface has a multidimensional shape. The process for hardening the surface layer of components having a complicated shape is carried out by means of a plurality of energy input zones. According to the invention, it is characterized in that the energy input zones are conducted on different curved parts separately in space and time and by means of cooperatively working transport systems so that superposition of the individual temperature fields forms a uniform temperature field which completely covers the functional surface of the component and within which each surface element of the later hardening zone of the component attains the selected austenite formation temperature interval ΔTa at least once and the time interval Δt between the maximum temperatures Tmaxn of the individual temperature fields is from 3.1 to 3.n smaller than the time ΔtmS which is required to go below the martensite start temperature MS during the cooling phase. The apparatus by means of which the process of the invention can be carried out is, according to the invention, characterized in that the energy configuring units are connected to one or more energy sources for optical or electromagnetic radiation and are each fixed to separate but cooperatively operating transport systems.
    • 本发明涉及机器,设备和设备的部件表面层的硬化以及工具。 应用可能和有利的对象是遭受严重疲劳或磨损应力的部件,并且由可硬化钢组成并且具有复杂的形状并且其表面必须在功能表面上选择性地硬化,或者其功能表面具有多维度 形状。 用于硬化具有复杂形状的部件的表面层的工艺通过多个能量输入区域进行。 根据本发明,其特征在于,能量输入区域在空间和时间上分别在不同的弯曲部件上进行,并且通过协同工作的输送系统,使得各个温度场的叠加形成均匀的温度场,其完全覆盖 组分的功能表面,并且其中组分的后期硬化区的每个表面元素至少达到所选奥氏体形成温度间隔&Dgr; Ta,并且各个温度场的最高温度Tmaxn之间的时间间隔&Dgr; t 从3.1到3.n小于在冷却阶段要求低于马氏体起始温度MS的时间&Dgr; tmS。 根据本发明,可以实现本发明的方法的装置是,其特征在于,能量构成单元连接到一个或多个用于光学或电磁辐射的能量源,并且各自固定为分离但协作地 操作运输系统。
    • 4. 发明申请
    • Method for Producing Wear-Resistant and Fatigue-Resistant Edge Layers in Titanium Alloys, and Components Produced Therewith
    • 在钛合金中生产耐磨和耐疲劳边缘层的方法及其生产的部件
    • US20080011391A1
    • 2008-01-17
    • US11571818
    • 2005-07-08
    • Berndt BrennerSteffen BonssFrank TietzJoerg KasparDavid Walter
    • Berndt BrennerSteffen BonssFrank TietzJoerg KasparDavid Walter
    • C21D1/09
    • C23C8/06B23K26/32B23K26/34B23K31/025B23K35/325B23K2101/001B23K2103/14C23C8/24C23C24/08Y02T50/67Y02T50/6765
    • The invention relates to edge layer finishing of functional components, and thereby in particular to a method for producing wear-resistant and fatigue-resistant edge layers in titanium alloys, and components produced therewith. The method according to the invention for producing wear-resistant and fatigue-resistant edge layers in titanium alloys by means of laser gas alloying is essentially characterized in that the laser gas alloying is carried out with a reaction gas that contains or releases interstitially soluble elements in the titanium alloy used, whereby the partial pressure of the reaction gas is selected such that the partial pressure remains below the threshold value above which nitride, carbide, or boride titanium phases are produced. The features according to the invention of the wear-resistant and fatigue-resistant component made of a titanium alloy with a gas-alloyed edge layer essentially are that the wear-resistant edge layer is composed of a fine-grain mixture of α- and β-titanium grains with an interstitially dissolved reaction gas, has a surface hardness Hs, measured on the ground surface, of 360 HV0.5≦Hs≦500 HV0.5, or an edge layer microhardness HR, measured on a polished cross section at 0.1 mm below the surface, of 360 HV0.1≦HR≦560 HV0.1, extends over a depth tR of 0.1 mm≦tR
    • 本发明涉及功能部件的边缘层整理,特别涉及一种在钛合金中生产耐磨和耐疲劳边缘层的方法,以及由其制造的部件。 根据本发明的用于通过激光气体合金化在钛合金中生产耐磨和耐疲劳边缘层的方法的基本特征在于,激光气体合金化是用含有或释放空间溶解元素的反应气体进行的 使用钛合金,由此选择反应气体的分压使得分压保持低于阈值以上,在该阈值以上产生氮化物,碳化物或硼化物钛相。 根据本发明的由具有气体合金边缘层的钛合金制成的耐磨和耐疲劳部件的特征基本上是耐磨边缘层由α和β的细晶粒混合物组成 具有间质溶解的反应气体的钛颗粒在地表上测量的表面硬度H S为360HV0.5≤H≤500HV0 或在表面下方0.1mm的抛光横截面上测量的边缘层显微硬度H为360 HV0.1 <= H
    • 9. 发明授权
    • Process and apparatus for hardening the surface layer of components having a complicated shape
    • 用于硬化具有复杂形状的部件的表面层的方法和装置
    • US09187794B2
    • 2015-11-17
    • US12312115
    • 2007-10-10
    • Berndt BrennerSteffen BonssFrank TietzMarko SeifertJan HannweberStefan KuehnUdo Karsunke
    • Berndt BrennerSteffen BonssFrank TietzMarko SeifertJan HannweberStefan KuehnUdo Karsunke
    • C21D1/42C21D1/09C21D10/00C21D11/00C21D1/34C21D9/00
    • C21D1/09C21D10/00C21D10/005C21D11/00
    • The invention relates to the hardening of the surface layer of parts of machines, plants and apparatuses and also tools. Objects for which the application is possible and advantageous are components which are subjected to severe fatigue or wear stresses and are composed of hardenable steels and have a complicated shape and whose surface has to be hardened selectively on the functional surfaces or whose functional surface has a multidimensional shape. The process for hardening the surface layer of components having a complicated shape is carried out by means of a plurality of energy input zones. According to the invention, it is characterized in that the energy input zones are conducted on different curved parts separately in space and time and by means of cooperatively working transport systems so that superposition of the individual temperature fields forms a uniform temperature field which completely covers the functional surface of the component and within which each surface element of the later hardening zone of the component attains the selected austenite formation temperature interval ΔTa at least once and the time interval Δt between the maximum temperatures Tmaxn of the individual temperature fields is from 3.1 to 3.n smaller than the time ΔtmS which is required to go below the martensite start temperature MS during the cooling phase. The apparatus by means of which the process of the invention can be carried out is, according to the invention, characterized in that the energy configuring units are connected to one or more energy sources for optical or electromagnetic radiation and are each fixed to separate but cooperatively operating transport systems.
    • 本发明涉及机器,设备和设备的部件表面层的硬化以及工具。 应用可能和有利的对象是遭受严重疲劳或磨损应力的部件,并且由可硬化钢组成并且具有复杂的形状并且其表面必须在功能表面上选择性地硬化,或者其功能表面具有多维度 形状。 用于硬化具有复杂形状的部件的表面层的工艺通过多个能量输入区域进行。 根据本发明,其特征在于,能量输入区域在空间和时间上分别在不同的弯曲部件上进行,并且通过协同工作的输送系统,使得各个温度场的叠加形成均匀的温度场,其完全覆盖 组分的功能表面,并且其中组分的后期硬化区的每个表面元素至少达到所选奥氏体形成温度间隔&Dgr; Ta,并且各个温度场的最高温度Tmaxn之间的时间间隔&Dgr; t 从3.1到3.n小于在冷却阶段要求低于马氏体起始温度MS的时间&Dgr; tmS。 根据本发明,可以实现本发明的方法的装置是,其特征在于,能量构成单元连接到一个或多个用于光学或电磁辐射的能量源,并且各自固定为分离但协作地 操作运输系统。