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1. 发明授权

US4891465A Process for producting alkyl group-substituted aromatic hydrocarbons 失效
标题翻译：制备烷基取代芳烃的方法
公开(公告)号：US4891465A
公开(公告)日：1990-01-02
申请号：US221246
申请日：1988-07-06
申请人： Katsuo Taniguchi , Michio Tanaka , Kazunori Takahata , Naoya Sakamoto , Toshihiro Takai , Yoshito Kurano , Masayasu Ishibashi
发明人： Katsuo Taniguchi , Michio Tanaka , Kazunori Takahata , Naoya Sakamoto , Toshihiro Takai , Yoshito Kurano , Masayasu Ishibashi
IPC分类号： B01J29/18 , B01J29/00 , C07B61/00 , C07C1/00 , C07C2/66 , C07C2/86 , C07C15/00 , C07C15/02 , C07C15/14 , C07C15/16 , C07C15/24 , C07C37/08 , C07C39/15 , C07C43/263 , C07C67/00 , C07C67/08
CPC分类号： C07C39/15 , C07C2/66 , C07C2/861 , C07C2/864 , C07C2529/18
摘要： In a process for producing an alkyl group-substituted aromatic hydrocarbon according to the present invention, (i) an aromatic hydrocarbon is reacted with (ii) an alkylating agent selected from the group consisting of olefins, lower aliphatic alcohols and alkyl halides in the presence of a mordenite-type zeolite catalyst treated with a fluorine-containing compound, and therefore the conversion of the aromatic compound can be increased and further it is possible to introduce the specific number of alkyl groups into the specific position of the aromatic compound.In particular, when biphenyl is used as the aromatic hydrocarbon and propylene is used as the alkylating agent, p,p'-diisopropylbiphenyl can be obtained in a high yield and high selectivity.

2. 发明授权

US5003113A Process of producing isopropylnaphthols 失效
标题翻译：生产异丙基萘酚的方法
公开(公告)号：US5003113A
公开(公告)日：1991-03-26
申请号：US440212
申请日：1989-11-22
申请人： Michio Tanaka , Masayasu Ishibashi , Katsuo Taniguchi
发明人： Michio Tanaka , Masayasu Ishibashi , Katsuo Taniguchi
IPC分类号： C07C37/08 , C07C37/84 , C07C39/14 , C07C409/12
CPC分类号： C07C409/12 , C07C37/08 , C07C37/84 , C07C407/00
摘要： In a process of producing isopropylnaphthols by oxidizing diisopropylnaphthalenes with molecular oxygen in a liquid phase to provide a reaction mixture which contains therein diisopropylnaphthalene monohydroperoxides and then acid decomposing the monohydroperoxides to isopropylnaphthols, the improvement comprising separating an organic layer from the reaction mixture, adding lower aliphatic alcohols of 1-4 carbons to the organic layer, crystallizing the diisopropylnaphthalenes while allowing the diisopropylnaphthalene monohydroperoxides to remain dissolved in the lower aliphatic alcohols, thereby to separate the monohydroperoxides from the diisopropylnaphthalenes.A further improvement in the process comprises crystallizing the isopropylnaphthols from aromatic hydrocarbons of 6-12 carbons.

3. 发明授权

US4891453A Process for producing p,p'-biphenol 失效
标题翻译：生产p，p'-联苯酚的方法
公开(公告)号：US4891453A
公开(公告)日：1990-01-02
申请号：US247333
申请日：1988-09-21
申请人： Michio Tanaka , Yoshito Kurano , Katsuo Taniguchi , Masayasu Ishibashi
发明人： Michio Tanaka , Yoshito Kurano , Katsuo Taniguchi , Masayasu Ishibashi
IPC分类号： C07C37/07 , C07C37/50 , C07C39/15
CPC分类号： C07C37/07 , C07C37/50
摘要： A process is disclosed which is capable of producing p,p'-biphenol of high purity by the dealkylation reaction of 3,3',5,5'-tetra-t-butyl-4,4'-dihydroxybiphenyl and which yet allows isobutene to be recovered in high yield. The process performs the dealkylation reaction of 3,3',5,5'-tetra-t-butyl-4,4'-dihydroxybiphenyl in the presence of an acid catalyst using as a solvent a saturated hydrocarbon having a boiling point of 190.degree. C. or above, an alicyclic hydrocarbon having a boiling point of 190.degree. C. or above, a hydrocarbon with an iodine value of no more than 1, sulfolane, or a mixture of these solvents. Also disclosed is a process for producing p,p'-biphenol from a mixture of 2,6-di-t-butyl-phenol and 3,3',5,5'-tetra-t-butyl-4,4'-diphenoquinone or from a mixture of 2,6-di-t-butylphenol, 3,3',5,5'-tetra-t-butyl-4,4'-diphenoquinone and 3,3',5,5'-tetra-t-butyl-4,4'-dihydroxybiphenyl. In this process, the synthesis of 3,3',5,5'-tetra-t-butyl-4,4'-dihydroxybiphenyl by the redox reaction between 2,6-di-t-butylphenol and 3,3',5,5'-tetra-t-butyl-4,4'-diphenoquinone and the production of p,p'-biphenol by the dealkylation reaction of 3,3',5,5'-tetra-t-butyl-4,4'-dihydroxybiphenyl are performed at one stage in the presence of both an acid catalyst and a solvent at a temperature of 120.degree.-280.degree. C.

4. 发明授权

US4902837A Process for preparing Biphenols 失效
标题翻译：制备双酚的方法
公开(公告)号：US4902837A
公开(公告)日：1990-02-20
申请号：US219151
申请日：1988-06-13
申请人： Michio Tanaka , Yoshito Kurano , Katsuo Taniguchi
发明人： Michio Tanaka , Yoshito Kurano , Katsuo Taniguchi
IPC分类号： C07B61/00 , B01J23/02 , B01J31/00 , C07C27/00 , C07C37/11 , C07C39/15 , C07C41/00 , C07C43/295 , C07C67/00
CPC分类号： C07C37/11 , C07C37/07
摘要： Processes for preparing biphenols by oxidation coupling of phenols, to which the present invention is directed, are characterized in that said oxidation coupling reaction is carried out under such conditions that the same diphenoquinones as those produced as by-products at the time when said oxidation coupling is effected are added to the reaction system. According to a preferred embodiment of the invention, moreover, the yield of biphenols can be enhanced by the reuse in the abovementioned reaction of diphenoquinones recovered from the reaction mixture containing the same.

5. 发明授权

US4351958A Process for producing orthoalkylated aromatic amine 失效
标题翻译：生产原烷基芳香胺的方法
公开(公告)号：US4351958A
公开(公告)日：1982-09-28
申请号：US297166
申请日：1981-08-28
申请人： Kazunori Takahata , Katsuo Taniguchi
发明人： Kazunori Takahata , Katsuo Taniguchi
IPC分类号： C07C209/68 , C07C85/24
CPC分类号： C07C209/68
摘要： An orthoalkylated aromatic amine is produced at a high selectivity from the reaction of an aromatic amine having at least one hydrogen atom at the ortho-positions and a primary or secondary alcohol under heating in the presence of a catalyst containing, as a main constituent, iron oxides.
摘要翻译：在邻位上具有至少一个氢原子的芳族胺与原醇或仲醇在加热下，在含有作为主要成分的铁的催化剂存在下，以高选择性制备原烷基化芳族胺氧化物。

6. 发明授权

US4900861A Method of producing polysilane compounds 失效
标题翻译：生产聚硅烷化合物的方法
公开(公告)号：US4900861A
公开(公告)日：1990-02-13
申请号：US254838
申请日：1988-10-07
申请人： Keiichi Yokoyama , Katsuo Taniguchi , Yoshihisa Kiso
发明人： Keiichi Yokoyama , Katsuo Taniguchi , Yoshihisa Kiso
IPC分类号： C08G77/60
CPC分类号： C08G77/60
摘要： A method of producing polysilane compounds which comprises: polymerizing a monomeric silane compound represented by the general formula of ##STR1## wherein R independently represents hydrogen or hydrocarbon group, but not both R's are hydrogen at the same time, in the presence of an organometallic complex of Ni, Co, Ru, Pd or Ir.

7. 发明授权

US4582944A Process for producing hydroxydiphenyl ethers 失效
标题翻译：生产羟基二苯醚的方法
公开(公告)号：US4582944A
公开(公告)日：1986-04-15
申请号：US606611
申请日：1984-05-03
申请人： Katsuo Taniguchi , Hideo Nakamura , Terunori Fujita
发明人： Katsuo Taniguchi , Hideo Nakamura , Terunori Fujita
IPC分类号： B01J27/00 , B01J27/12 , C07B61/00 , C07C41/00 , C07C41/09 , C07C43/295 , C07C67/00
CPC分类号： C07C41/09
摘要： A process for producing a hydroxydiphenyl ether, which comprises reacting at least one hydroquinone compound with itself or with a monohydric phenol compound in the presence of a catalyst composed essentially of a synthetic mica in which at least 10 mole % of cation-exchangeable interlayer cations are made up of a metal ion other than alkali metal ions, and/or a proton.
摘要翻译：一种生产羟基二苯醚的方法，其包括使至少一种氢醌化合物与其自身或与一元酚化合物在催化剂存在下反应，所述催化剂基本上由合成云母组成，其中至少10摩尔％的可阳离子交换的层间阳离子是由除金属离子以外的金属离子和/或质子组成。

8. 发明授权

US5475183A Process for producing lower olefins 失效
标题翻译：低级烯烃的制备方法
公开(公告)号：US5475183A
公开(公告)日：1995-12-12
申请号：US161061
申请日：1993-12-03
申请人： Shintaro Araki , Katsuo Taniguchi , Toshiyuki Isaka
发明人： Shintaro Araki , Katsuo Taniguchi , Toshiyuki Isaka
IPC分类号： B01J21/04 , C07C1/24 , C07C1/20
CPC分类号： B01J21/04 , C07C1/24 , C07C2521/04 , C07C2521/12 , Y02P20/52
摘要： A process for the production of lower olefins by dehydrating lower alcohols having 2 to 4 carbon atoms which comprises using a .gamma.-alumina catalyst containing 0.3% by weight or less of impurities in total excluding SiO.sub.2, the impurities including 0.2% by weight or less of sulfur content calculated in terms of SO.sub.4 - and 0.05% by weight or less of sodium content calculated in terms of Na.sub.2 O, and/or a process for the production of lower olefins by dehydrating lower alcohols having 2 to 4 carbon atoms that comprises using a .gamma.-alumina catalyst which contains 0.5 to 5% by weight of SiO.sub.2.According to the process of the present invention, lower olefins can be produced from lower alcohols with high yield and high selectivity for a prolonged period of time without reducing the catalytic activity.
摘要翻译：通过使具有2至4个碳原子的低级醇脱水生产低级烯烃的方法，该方法包括使用含有0.3重量％以下除了SiO 2以外的杂质总量为0.3重量％以下的γ-氧化铝催化剂，包含0.2重量％以下的杂质根据SO 4计算的硫含量和以Na 2 O计算的0.05重量％以下的钠含量，和/或通过使具有2至4个碳原子的低级醇脱水生产低级烯烃的方法，包括使用γ 含有0.5〜5重量％的SiO 2的氧化铝催化剂。根据本发明的方法，低级烯烃可以从高产率和高选择性的低级醇生产较长时间，而不降低催化活性。

9. 发明授权

US4349419A Process for separation of alkyl phenols by azeotropic distillation 失效
标题翻译：通过共沸蒸馏分离烷基酚的方法
公开(公告)号：US4349419A
公开(公告)日：1982-09-14
申请号：US231022
申请日：1981-02-03
申请人： Kazunori Takahata , Katsuo Taniguchi , Tadaaki Fujimoto
发明人： Kazunori Takahata , Katsuo Taniguchi , Tadaaki Fujimoto
IPC分类号： C07C27/00 , C07C37/78 , C07C39/07 , C07C67/00 , B01D3/40
CPC分类号： C07C37/78
摘要： In a process for separating at least two alkyl phenols having close boiling points by azeotropic distillation of a mixture composed of the alkyl phenols with a hydrocarbon azeotroping agent, the improvement wherein said hydrocarbon azeotroping agent is selected from saturated aliphatic hydrocarbons of 9 to 13 carbon atoms having a boiling point of 150.degree. to 190.degree. C. at 760 mmHg.
摘要翻译：在通过由烃共沸剂组成的烷基酚组成的混合物共沸蒸馏来分离具有接近沸点的至少两种烷基酚的方法中，所述烃共沸剂选自9至13个碳原子的饱和脂族烃在760mmHg下沸点为150〜190℃。

10. 发明授权

US4978789A Process for production of alkenyl substituted aromatic compound 失效
标题翻译：烯基取代芳族化合物的制备方法
公开(公告)号：US4978789A
公开(公告)日：1990-12-18
申请号：US376929
申请日：1989-07-10
申请人： Katsuo Taniguchi , Shigeki Fujikawa , Yoshito Kurano
发明人： Katsuo Taniguchi , Shigeki Fujikawa , Yoshito Kurano
IPC分类号： C07C37/00 , C07C209/68
CPC分类号： B01J23/862 , B01J23/825 , B01J23/835 , B01J23/8472 , B01J37/031 , C07C209/68 , C07C37/001 , B01J2523/00
摘要： A process for producing an alkenyl substituted aromatic compound having the general formula (I): ##STR1## wherein Ar represents an aromatic ring, R.sup.1 represents an alkenyl group having 2 to 8 carbon atoms, p is 1, 2, or 3 provided that R.sup.1 may be the same or different when p is 2 or 3, R.sup.2 represents an alkyl group having 1 to 8 carbon atoms, q is 0, 1, or 2 provided that R.sup.2 may be the same or different when q is 2, X represents --OH or --NR.sup.3 R.sup.4 wherein R.sup.3 and R.sup.4 independently represent hydrogen or an alkyl group having 1 to 2 carbon atoms, n is 1 or 2, provided that the sum of p and q is 1, 2, or 3 comprising the step of catalytically dehydrogenating an alkyl substituted aromatic compound having the general formula (III): ##STR2## wherein R.sup.5 represents an alkyl group having 2 to 8 carbon atoms and Ar, R.sup.2, X, p, q, and n are the same as defined above, n is 1 or 2, provided that R.sup.5 may be the same or different when p is 2 or 3 in the presence of a catalyst comprising (a) at least one iron oxide as a main component and (b) at least one oxide of metals belonging to the group III, IV or V of the periodic table of atoms.This catalyst can produce an alkenyl substituted aromatic compound having a hydroxyl or amino group in the aromatic ring thereof from the dehydrogenation of the corresponding alkyl substituted aromatic compound at a high yield and high selectivity and has a prolonged catalyst life.
摘要翻译：一种制备具有通式（I）的烯基取代的芳族化合物的方法：其中Ar表示芳族环，R 1表示具有2至8个碳原子的链烯基，p是1,2或3 条件是当p为2或3时，R 1可以相同或不同，R 2表示具有1至8个碳原子的烷基，q为0,1或2，条件是当q为2时，R 2可以相同或不同， X表示-OH或-NR 3 R 4，其中R 3和R 4独立地表示氢或具有1至2个碳原子的烷基，n为1或2，条件是p和q之和为1,2或3，包括步骤催化脱氢具有通式（III）的烷基取代的芳族化合物：其中R 5表示具有2至8个碳原子的烷基，Ar，R 2，X，p，q和n与 n为1或2，条件是当催化剂存在时p为2或3时，R 5可以相同或不同，所述催化剂包含（a）至少一种i 氧化物作为主要成分，和（b）属于元素周期表第III，IV或V族的金属的至少一种氧化物。该催化剂可以以高产率和高选择性从相应的烷基取代的芳族化合物的脱氢产生其芳环中具有羟基或氨基的烯基取代的芳族化合物，并具有延长的催化剂寿命。

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