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1. 发明申请

US20090176979A1 PROCESS FOR PRODUCTION OF POLYSACCHARIDE AND/OR MONOSACCHARIDE BY HYDROLYSIS OF DIFFERENT POLYSACCHARIDE 失效
标题翻译：通过不同多糖的水解生产多糖和/或单糖的方法
公开(公告)号：US20090176979A1
公开(公告)日：2009-07-09
申请号：US12304916
申请日：2007-06-22
申请人： Michikazu Hara , Shinichiro Yanagawa , Akira Matsuo , Hidesato Kondo
发明人： Michikazu Hara , Shinichiro Yanagawa , Akira Matsuo , Hidesato Kondo
IPC分类号： C07H1/00 , C08B1/00
CPC分类号： C07H3/02 , B01J21/18 , B01J27/02 , B01J31/10 , C10B53/02 , C13K1/02 , Y02E50/14
摘要： The object is to produce a polysaccharide and/or a monosaccharide efficiently by hydrolyzing a different polysaccharide efficiently. The hydrolysis of a polysaccharide is an important means for producing a monosaccharide that can be used as a starting material for the production of ethanol, the solubilization of a water-insoluble polysaccharide, and the production of a useful water-soluble low-polymeric saccharide or the like. For achieving the object, a polysaccharide to be hydrolyzed is reacted with water in the presence of a carbonaceous material having sulfonic acid group therein to cause the hydrolysis of the polysaccharide to be hydrolyzed, thereby producing a other polysaccharide and/or a monosaccharide.
摘要翻译：目的是通过有效地水解不同的多糖来有效地生成多糖和/或单糖。多糖的水解是生产可以用作生产乙醇的起始原料，水不溶性多糖的溶解和生产有用的水溶性低聚糖的单糖的重要手段，或者类似。为了达到上述目的，在其中含有磺酸基的碳质材料的存在下，将要水解的多糖与水反应，导致多糖的水解被水解，从而产生另一种多糖和/或单糖。

2. 发明授权

US08765938B2 Process for production of polysaccharide and/or monosaccharide by hydrolysis of different polysaccharide 失效
标题翻译：通过不同多糖的水解生产多糖和/或单糖的方法
公开(公告)号：US08765938B2
公开(公告)日：2014-07-01
申请号：US12304916
申请日：2007-06-22
申请人： Michikazu Hara , Shinichiro Yanagawa , Akira Matsuo , Hidesato Kondo
发明人： Michikazu Hara , Shinichiro Yanagawa , Akira Matsuo , Hidesato Kondo
IPC分类号： C07H1/08
CPC分类号： C07H3/02 , B01J21/18 , B01J27/02 , B01J31/10 , C10B53/02 , C13K1/02 , Y02E50/14
摘要： The object is to produce a polysaccharide and/or a monosaccharide efficiently by hydrolyzing a different polysaccharide efficiently. The hydrolysis of a polysaccharide is an important means for producing a monosaccharide that can be used as a starting material for the production of ethanol, the solubilization of a water-insoluble polysaccharide, and the production of a useful water-soluble low-polymeric saccharide or the like. For achieving the object, a polysaccharide to be hydrolyzed is reacted with water in the presence of a carbonaceous material having sulfonic acid group therein to cause the hydrolysis of the polysaccharide to be hydrolyzed, thereby producing a other polysaccharide and/or a monosaccharide.
摘要翻译：目的是通过有效地水解不同的多糖来有效地生成多糖和/或单糖。多糖的水解是生产可以用作生产乙醇的起始原料，水不溶性多糖的溶解和生产有用的水溶性低聚糖的单糖的重要手段，或者类似。为了达到上述目的，在其中含有磺酸基的碳质材料的存在下，将要水解的多糖与水反应，导致多糖的水解被水解，从而产生另一种多糖和/或单糖。

3. 发明授权

US07622618B2 Method for hydrating olefins 失效
标题翻译：烯烃水合方法
公开(公告)号：US07622618B2
公开(公告)日：2009-11-24
申请号：US12085853
申请日：2006-11-30
申请人： Shinichiro Yanagawa , Michikazu Hara
发明人： Shinichiro Yanagawa , Michikazu Hara
IPC分类号： C07C29/04
CPC分类号： C07C29/04 , C07B61/00 , C07C31/10 , C07C31/12
摘要： A novel olefin hydration method is provided for efficiently producing alcohols by hydration of olefins containing 2 to 5 carbon atoms in the presence of a catalyst. Thus, alcohols are produced by hydrating olefins containing 2 to 5 carbon atoms at reaction temperature of 100 to 250° C. in the presence of a solid acid catalyst consisting of carbonaceous materials containing sulfonic acid groups obtained from an organic matter by carbonization and sulfonation. In carrying out this method, the organic matter is preferably an aromatic hydrocarbon or a saccharide, the olefin is preferably propylene or a butenes, and the hydration reaction temperature is not lower than 120° C., more preferably not lower than 150° C.
摘要翻译：提供了一种新型的烯烃水合方法，用于在催化剂存在下，通过水合含2-5个碳原子的烯烃来有效生产醇。因此，在含有2-5个碳原子的烯烃的反应温度为100-250℃的存在下，通过碳酸化和磺化从含有有机物质的磺酸基的含碳材料组成的固体酸催化剂存在下，制备醇。在实施该方法时，有机物优选为芳香族烃或糖类，烯烃优选为丙烯或丁烯，水合反应温度为120℃以上，更优选为150℃以上。

4. 发明申请

US20090137850A1 Method for Hydrating Olefins 失效
标题翻译：保温烯烃的方法
公开(公告)号：US20090137850A1
公开(公告)日：2009-05-28
申请号：US12085853
申请日：2006-11-30
申请人： Shinichiro Yanagawa , Michikazu Hara
发明人： Shinichiro Yanagawa , Michikazu Hara
IPC分类号： C07C29/04
CPC分类号： C07C29/04 , C07B61/00 , C07C31/10 , C07C31/12
摘要： A novel olefin hydration method is provided for efficiently producing alcohols by hydration of olefins containing 2 to 5 carbon atoms in the presence of a catalyst. Thus, alcohols are produced by hydrating olefins containing 2 to 5 carbon atoms at reaction temperature of 100 to 250° C. in the presence of a solid acid catalyst consisting of carbonaceous materials containing sulfonic acid groups obtained from an organic matter by carbonization and sulfonation. In carrying out this method, the organic matter is preferably an aromatic hydrocarbon or a saccharide, the olefin is preferably propylene or a butenes, and the hydration reaction temperature is not lower than 120° C., more preferably not lower than 150° C.
摘要翻译：提供了一种新型的烯烃水合方法，用于在催化剂存在下，通过水合含2-5个碳原子的烯烃来有效生产醇。因此，在含有2-5个碳原子的烯烃的反应温度为100-250℃的存在下，通过碳酸化和磺化从含有有机物质的磺酸基的含碳材料组成的固体酸催化剂存在下，制备醇。在实施该方法时，有机物优选为芳香族烃或糖类，烯烃优选为丙烯或丁烯，水合反应温度为120℃以上，更优选为150℃以上。

5. 发明授权

US09815047B2 Catalyst for producing monocyclic aromatic hydrocarbon and production method of monocyclic aromatic hydrocarbon 有权
公开(公告)号：US09815047B2
公开(公告)日：2017-11-14
申请号：US13976655
申请日：2011-12-28
申请人： Shinichiro Yanagawa , Masahide Kobayashi , Yasuyuki Iwasa , Ryoji Ida
发明人： Shinichiro Yanagawa , Masahide Kobayashi , Yasuyuki Iwasa , Ryoji Ida
IPC分类号： C07C4/06 , B01J29/70 , C10G11/18 , C10G47/16 , C10G11/05 , B01J29/85 , B01J37/00 , C01B39/48 , C01B39/10
CPC分类号： B01J29/70 , B01J29/85 , B01J37/0009 , B01J37/0036 , B01J2229/186 , C01B39/10 , C01B39/48 , C07C4/06 , C07C2529/06 , C07C2529/40 , C10G11/05 , C10G11/18 , C10G47/16 , C10G2300/1033 , C10G2300/1048 , C10G2300/1051 , C10G2300/1055 , C10G2300/1059 , C10G2300/107 , C10G2300/301 , C10G2400/30
摘要： The catalyst for producing aromatic hydrocarbon is for producing monocyclic aromatic hydrocarbon having 6 to 8 carbon number from oil feedstock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower and contains crystalline aluminosilicate and phosphorus. A molar ratio (P/Al ratio) between phosphorus contained in the crystalline aluminosilicate and aluminum of the crystalline aluminosilicate is from 0.1 to 1.0. The production method of monocyclic aromatic hydrocarbon is a method of bringing oil feedstock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower into contact with the catalyst for producing monocyclic aromatic hydrocarbon.

6. 发明授权

US09656232B2 Method for producing aromatic hydrocarbons and aromatic hydrocarbon production plant 有权
公开(公告)号：US09656232B2
公开(公告)日：2017-05-23
申请号：US13637238
申请日：2011-03-25
申请人： Hideki Minami , Yoshishige Sugi , Atsushi Fukui , Atsuro Nagumo , Susumu Yasui , Shinichiro Yanagawa
发明人： Hideki Minami , Yoshishige Sugi , Atsushi Fukui , Atsuro Nagumo , Susumu Yasui , Shinichiro Yanagawa
IPC分类号： C07C4/06 , C07C15/02 , C07C15/04 , C07C15/06 , B01J8/20 , B01J29/40 , C10G35/04 , C10G69/10 , B01J35/02 , B01J21/04 , B01J23/882 , B01J23/883 , B01J23/885 , B01J23/888 , B01J29/068 , B01D3/14
CPC分类号： B01J8/20 , B01D3/143 , B01J21/04 , B01J23/882 , B01J23/883 , B01J23/885 , B01J23/888 , B01J23/8885 , B01J29/068 , B01J29/405 , B01J35/023 , B01J2229/183 , C07C4/06 , C10G35/04 , C10G69/10 , C10G2300/1044 , C10G2300/1059 , C10G2300/42 , C10G2400/28 , C10G2400/30
摘要： A method for producing aromatic hydrocarbons, the method including: (a) bringing a feedstock oil such as an LCO into contact with an aromatic production catalyst to obtain a reaction product containing aromatic hydrocarbons, (b) separating the reaction product into a tower top fraction and a tower bottom fraction using a distillation tower, (c) separating the tower top fraction into a crude aromatic fraction containing an LPG fraction, and an off-gas containing hydrogen, (d) separating the crude aromatic fraction containing an LPG fraction into an LPG fraction and a crude aromatic fraction, (e) separating the off-gas containing hydrogen into hydrogen and an off-gas, and (f) using the hydrogen obtained in step (e) to hydrotreat the crude aromatic fraction, thereby obtaining an aromatic fraction.

7. 发明申请

US20140018585A1 METHOD FOR PRODUCING MONOCYCLIC AROMATIC HYDROCARBONS 有权
标题翻译：生产单环芳香烃的方法
公开(公告)号：US20140018585A1
公开(公告)日：2014-01-16
申请号：US14007166
申请日：2012-03-23
申请人： Shinichiro Yanagawa , Masahide Kobayashi , Ryoji Ida , Susumu Yasui , Yoshishige Sugi , Atsushi Fukui , Atsuro Nagumo
发明人： Shinichiro Yanagawa , Masahide Kobayashi , Ryoji Ida , Susumu Yasui , Yoshishige Sugi , Atsushi Fukui , Atsuro Nagumo
IPC分类号： C07C4/06
CPC分类号： C07C4/06 , C10G69/04 , C10G69/10 , C10G2300/4081 , C10G2400/30 , Y02P20/582
摘要： A method for producing monocyclic aromatic hydrocarbons includes a step of introducing a feedstock oil into a cracking/reforming reactor, bringing the feedstock oil into contact with a catalyst, and causing the feedstock oil to react, a step of purifying and recovering the monocyclic aromatic hydrocarbons separated from the product produced in the reaction step, a step of hydrogenating a heavy fraction separated from the product, and a recycling step of returning a hydrogenation reactant of the heavy fraction to the cracking/reforming reaction step. In the recycling step, the hydrogenation reactant is introduced at a location different from an introduction location of the feedstock oil into the reactor so that a time during which the hydrogenation reactant is in contact with the catalyst in the reactor becomes shorter than a time during which the feedstock oil is in contact with the catalyst in the reactor.
摘要翻译：一种制备单环芳烃的方法包括将原料油引入裂解/重整反应器中，使原料油与催化剂接触并使原料油反应的步骤，纯化和回收单环芳烃与在反应步骤中产生的产物分离，氢化从产物分离的重馏分的步骤和将重馏分的氢化反应物返回到裂化/重整反应步骤的再循环步骤。在回收步骤中，将氢化反应物引入到不同于原料油的引入位置到反应器中的位置，使得氢化反应物与反应器中的催化剂接触的时间变得比其中原料油与反应器中的催化剂接触。

8. 发明申请

US20130281756A1 PRODUCTION METHOD OF MONOCYCLIC AROMATIC HYDROCARBONS 有权
标题翻译：单环芳烃的生产方法
公开(公告)号：US20130281756A1
公开(公告)日：2013-10-24
申请号：US13976701
申请日：2011-12-28
申请人： Shinichiro Yanagawa , Masahide Kobayashi , Yasuyuki Iwasa , Ryoji Ida
发明人： Shinichiro Yanagawa , Masahide Kobayashi , Yasuyuki Iwasa , Ryoji Ida
IPC分类号： C10G11/05
CPC分类号： C10G11/05 , B01J29/40 , B01J29/65 , B01J29/703 , B01J29/7042 , B01J29/7046 , B01J29/80 , B01J29/82 , B01J29/87 , B01J35/10 , B01J37/0009 , B01J37/04 , B01J2229/18 , B01J2229/20 , B01J2229/42 , C10G11/18 , C10G45/68 , C10G69/04 , C10G2300/1037 , C10G2300/301 , C10G2400/30
摘要： In the production method of monocyclic aromatic hydrocarbons, oil feedstock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower is brought into contact with a catalyst for producing monocyclic aromatic hydrocarbons that includes a mixture containing a first catalyst which contains crystalline aluminosilicate containing gallium and/or zinc and phosphorus and a second catalyst which contains crystalline aluminosilicate containing phosphorus.
摘要翻译：在单环芳烃的制造方法中，使具有140℃或更高的10体积％蒸馏温度和380℃或更低的90体积％蒸馏温度的油原料与用于制备单环芳族化合物的催化剂接触包括含有含有含有镓和/或锌和磷的结晶硅铝酸盐的第一催化剂和含有含磷结晶硅铝酸盐的第二催化剂的混合物的烃。

9. 发明申请

US20130281755A1 CATALYST FOR PRODUCING MONOCYCLIC AROMATIC HYDROCARBONS AND PRODUCTION METHOD OF MONOCYCLIC AROMATIC HYDROCARBONS 审中-公开
标题翻译：生产单环芳烃的催化剂和单环芳烃的生产方法
公开(公告)号：US20130281755A1
公开(公告)日：2013-10-24
申请号：US13976581
申请日：2011-12-28
申请人： Shinichiro Yanagawa , Masahide Kobayashi , Yasuyuki Iwasa , Ryoji Ida
发明人： Shinichiro Yanagawa , Masahide Kobayashi , Yasuyuki Iwasa , Ryoji Ida
IPC分类号： B01J29/70 , C07C4/06
CPC分类号： B01J29/7049 , B01J23/10 , B01J29/061 , B01J29/40 , B01J29/405 , B01J35/023 , B01J37/0009 , B01J37/0036 , B01J37/0201 , B01J2229/186 , B01J2229/42 , C07C4/06 , C10G11/05 , C10G47/16 , C10G47/20 , C10G69/04 , C10G2300/301 , C10G2400/30
摘要： The catalyst for producing monocyclic aromatic hydrocarbons is for producing monocyclic aromatic hydrocarbons having 6 to 8 carbon number from oil feedstock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower. The catalyst contains crystalline aluminosilicate and a rare earth element, in which the amount of the rare earth element expressed in terms of the element is 0.1 to 10 mass % based on the crystalline aluminosilicate. In the production method of monocyclic aromatic hydrocarbons, oil feed stock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower is brought into contact with the catalyst for producing monocyclic aromatic hydrocarbons.
摘要翻译：用于生产单环芳烃的催化剂用于生产具有10体积％蒸馏温度为140℃或更高，90体积％蒸馏温度为380℃或更低的油原料具有6至8个碳数的单环芳烃。催化剂含有结晶硅铝酸盐和稀土元素，其中以元素表示的稀土元素的量相对于结晶铝硅酸盐为0.1〜10质量％。在单环芳香烃的制造方法中，将具有10体积％蒸馏温度为140℃以上，90体积％蒸馏温度为380℃以下的原料原料与用于制造单环芳烃的催化剂接触芳烃。

10. 发明申请

US20130184506A1 METHOD FOR PRODUCING AROMATIC HYDROCARBONS 审中-公开
标题翻译：生产芳香烃的方法
公开(公告)号：US20130184506A1
公开(公告)日：2013-07-18
申请号：US13822556
申请日：2011-09-14
申请人： Shinichiro Yanagawa , Ryoji Ida , Masahide Kobayashi , Yasuyuki Iwasa
发明人： Shinichiro Yanagawa , Ryoji Ida , Masahide Kobayashi , Yasuyuki Iwasa
IPC分类号： C10G11/05
CPC分类号： C10G11/05 , C10G35/095 , C10G45/44 , C10G63/02 , C10G69/00 , C10G69/08 , C10G2300/203 , C10G2300/301 , C10G2400/30
摘要： Disclosed is a method for producing aromatic hydrocarbons including a cracking reforming reaction step of bringing a feedstock having a 10 vol % distillation temperature of 140° C. or higher and a 90 vol % distillation temperature of 380° C. or lower, into contact with a catalyst for monocyclic aromatic hydrocarbon production containing a crystalline aluminosilicate to cause the feedstock to react with the catalyst, and thereby obtaining a product including monocyclic aromatic hydrocarbons having 6 to 8 carbon numbers and a heavy oil fraction having 9 or more carbon numbers; a step of separating the monocyclic aromatic hydrocarbons and the heavy oil fraction from the product obtained from the cracking reforming reaction step; a step of purifying the monocyclic aromatic hydrocarbons separated in the separating step, and collecting the hydrocarbons; and a step of separating naphthalene compounds from the heavy oil fraction separated in the separating step, and collecting the naphthalene compounds.
摘要翻译：本发明公开了一种芳烃化合物的制造方法，其特征在于，包括裂解重整反应步骤，使10vol％蒸馏温度为140℃以上，90体积％蒸馏温度为380℃以下的原料与含有结晶硅铝酸盐以使原料与催化剂反应的单环芳香烃生产催化剂，从而得到包括具有6至8个碳数的单环芳烃和具有9个或更多个碳数的重油馏分的产物; 从裂解重整反应步骤获得的产物中分离单环芳烃和重油馏分的步骤; 纯化在分离步骤中分离的单环芳烃并收集烃的步骤; 以及从分离步骤中分离的重油馏分中分离萘化合物的步骤，并收集萘化合物。

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