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    • 4. 发明授权
    • Dip coating process for producing electrophotographic composition layer having controlled thickness
    • US07544382B2
    • 2009-06-09
    • US11022210
    • 2004-12-21
    • Michel F. Molaire
    • Michel F. Molaire
    • C23C14/54B05D1/18
    • B05D1/18G03G5/047G03G5/05G03G5/051G03G5/0525
    • A method for controlling the thickness and uniformity of a dip coated layer, using a coating apparatus in a normal coating environment, includes the following steps: forming under normal coating conditions of ambient temperature and relative humidity a series of coated layers on a metal substrate having a thickness of at least about 500 microns, using variations in coating solution viscosity m, coating substrate withdrawal speed v, capillary number Ca, coating solution surface tension S, and boiling point bp (a correlative of evaporation rate)of the coating solution solvent, a coated layer including at least a portion of uniform thickness T(even) and, optionally, a portion of non-uniform thickness L (uneven); statistically analyzing measurements carried out on the series of coated layers and generating the constants, a, b, c, d, and e for Equations 2, 3, and 4: T(even)=a+b(m*v)   (Equation 2) L(uneven)=c+d*(v*bp)+e*(Ca*bp)   (Equation 3) v(even)=−c/bp*(d+e*m/S)   (Equation 4) using Equation 4, determining the coating speed v(even) producing the maximum thickness of a coated layer having a completely uniform thickness for a given set of coating solution characteristics; and using Equation 2, determining the thickness T(even) of the portion of the coated layer having uniform thickness for a given set of coating solution characteristics and the coating speed determined in step (c).
    • 5. 发明申请
    • Encapsulated toner compositions incorporating organic monomeric glasses
    • 包含有机单体玻璃的包封调色剂组合物
    • US20070292799A1
    • 2007-12-20
    • US11453408
    • 2006-06-15
    • Michel F. Molaire
    • Michel F. Molaire
    • G03G9/093
    • G03G9/09335G03G9/09307G03G9/09364G03G9/09385
    • The present invention is an electrostatographic core shell toner which includes as a core material of at least two nonpolymeric compounds each independently corresponding to the structure (R1Y1)p[(Z1Y2)mR2Y3]nZ2Y4R3. M is zero or one, n is zero up to an integer at which said compound starts to become a polymer and p is an integer of from one to eight. Each of R1 and R3 is independently a monovalent aliphatic or cycloaliphatic hydrocarbon group an aromatic group or a multicyclic aromatic nucleus. Each of R2, Z1 and Z2 independently represent multivalent aliphatic or cycloaliphatic hydrocarbon groups or an aromatic group. Y1, Y2, Y3 and Y4 each independently represent one or more linking groups. The core material is surrounded by a shell that includes an amorphous matrix.
    • 本发明是一种静电核心壳调色剂,其包含作为至少两种非聚合化合物的核心材料,每种非聚合化合物各自独立地对应于结构(R 1,Y 1, [(Z 1)2 2 Y 4 3 3 3 M为0或1,n为0,直至所述化合物开始变成聚合物并且p为1至8的整数的整数。 R 1和R 3各自独立地是一价脂族或脂环族烃基,芳基或多环芳族核。 R 2,Z 1和Z 2各自独立地表示多价脂族或脂环族烃基或芳族基团。 Y 1,Y 2,Y 3和Y 4各自独立地表示一个或多个连接基团。 核心材料被包含无定形基质的壳包围。
    • 8. 发明授权
    • Photoconductive elements having a polymeric barrier layer
    • 具有聚合物阻挡层的光导元件
    • US06593046B2
    • 2003-07-15
    • US09954907
    • 2001-09-18
    • Louis J. SorrieroMichel F. MolaireMarie B. O'ReganWayne T. FerrarDavid S. WeissJane Robin Cowdery
    • Louis J. SorrieroMichel F. MolaireMarie B. O'ReganWayne T. FerrarDavid S. WeissJane Robin Cowdery
    • G03G510
    • C08G73/1082C08G73/14C08G73/16G03G5/142
    • Disclosed are photoconductive elements including a conductive support, e.g., an electrically conductive film, drum, or belt, on which a negatively chargeable photoconductive layer is disposed. An electrical barrier layer is disposed between the conductive support and the photoconductive layer. The barrier layer provides a high energy barrier to the injection of positive charges, but transports electrons under an applied electric field. In embodiments, the barrier layer can transport charge by electronic, or both electronic and ionic mechanisms, and, is not substantially affected by humidity changes. The barrier layer includes a polyester-co-imides, polyesterionomer-co-imides, or polyamide-co-imides having covalently bonded as repeat units in the polymer chain, aromatic tetracarbonylbisimide groups of the formula: wherein Ar1 and Ar2 respectively represent tetravalent or trivalent aromatic groups of 6 to about 20 carbon atoms, and X is O, C(CF3)2, S═O or SO2.
    • 公开了包括导电性支持体(例如,导电膜,鼓或带)的光电导元件,其上设置有带负电的光导电层。 电阻挡层设置在导电支撑体和光电导层之间。 阻挡层为注入正电荷提供了高能量势垒,但在施加的电场下传输电子。 在实施例中,阻挡层可以通过电子或电子和离子机制两者传输电荷,并且基本上不受湿度变化的影响。 阻挡层包括在聚合物链中共价键合作为重复单元的聚酯 - 共 - 酰亚胺,聚酯型聚异氰酸酯 - 共 - 酰亚胺或聚酰胺 - 共 - 酰亚胺,其中Ar 1和Ar 2分别表示四价或三价的芳族四羰基二酰亚胺基团 6至约20个碳原子的芳基,X是O,C(CF 3)2,S = O或SO 2。