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    • 10. 发明授权
    • Preparation of electrically conductive soluble heteropolyphenylenes
    • 导电性可溶性多聚苯乙烯的制备
    • US4395497A
    • 1983-07-26
    • US273688
    • 1981-06-15
    • Herbert NaarmannDieter NaegeleKlaus PenzienJohannes Schlag
    • Herbert NaarmannDieter NaegeleKlaus PenzienJohannes Schlag
    • C08G61/12C08L65/00H01B1/12H01L51/30C08L77/02
    • H01B1/128C08G61/123C08L65/00H01B1/127H01L51/0035C08G2261/312Y02E10/549
    • A process for the preparation of electrically conductive heteropolyphenylenes, wherein from 0.5 to 5 per cent by weight of an activating additive is introduced, in the absence of moisture and of oxygen, into a heteropolyphenylene of the general formula ##STR1## where X is O, S, Se, SO or SO.sub.2 and Y has one of the meanings given for X or is NH, CH.sub.2, CO or C.sub.6 H.sub.4, and n is from 2 to 250. The activating additive is preferably one of the compounds AsF.sub.5, SbF.sub.5, UF.sub.6, HClO.sub.4, NO.sup.+ SbF.sub.6.sup.-, NO.sub.2.sup.+ SbF.sub.6.sup.-, NO.sup.+ PF.sub.6.sup.-, SbCl.sub.5, NO.sub.2.sup.+ PF.sub.6.sup.-, NO.sup.+ BF.sub.4.sup.-, NO.sup.+ ClO.sub.4.sup.-, (CF.sub.3).sub.2 SO.sub.4, 2,4,6-trinitrophenol, 2,4,6-trinitrophenylsulfonic acid and 2,4,6-trinitrophenylcarboxylic acid, or is sodium, potassium, rubidium, cesium, calcium or barium or one of their amides, the latter being added, if appropriate, in tetrahydrofuran, dimethoxyglycol, anthracene, naphthalene or 2-methylstyrene. The conductive heteropolyphenylenes may be used in the electrical industry for the production of solar cells, for conversion and fixing of radiation and for the production of electrical and magnetic switches, or may be used for the antistatic treatment of plastics.
    • 一种用于制备导电杂多苯基苯的方法,其中将0.5-5重量%的活化添加剂在没有水分和氧气的情况下引入通式为“IMAGE”的杂多亚苯基,其中X为O, S,Se,SO或SO 2,Y具有对X给出的含义之一或为NH,CH 2,CO或C 6 H 4,n为2至250.活化添加剂优选为化合物AsF5,SbF5,UF6, HClO4,NO + SbF6-,NO2 + SbF6-,NO + PF6-,SbCl5,NO2 + PF6-,NO + BF4-,NO + ClO4-,(CF3)2SO4,2,4,6-三硝基苯酚 ,6-三硝基苯磺酸和2,4,6-三硝基苯基羧酸,或者是钠,钾,铷,铯,钙或钡或它们的酰胺之一,如果合适,将其加入四氢呋喃,二甲氧基乙二醇,蒽,萘 或2-甲基苯乙烯。 导电杂多亚苯基可用于电气工业中用于生产太阳能电池,用于辐射的转换和固定以及用于电气和磁性开关的生产,或可用于塑料的抗静电处理。