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1. 发明授权

US5352491A Method for coating using molten organosiloxane compositions 失效
标题翻译：使用熔融的有机硅氧烷组合物涂覆的方法
公开(公告)号：US5352491A
公开(公告)日：1994-10-04
申请号：US75987
申请日：1993-06-11
申请人： Martin E. Cifuentes , Michael R. Strong , Bernard Vanwert
发明人： Martin E. Cifuentes , Michael R. Strong , Bernard Vanwert
IPC分类号： B05D3/02 , B05D3/04 , B05D7/24 , C09D183/04 , C09D183/10 , H05K3/28 , B05D3/10
CPC分类号： C09D183/10 , C09D183/04 , H05K3/285
摘要： Organosiloxane compositions comprising specified combinations of MQ resins and liquid polyorganosiloxanes can be applied as molten materials to form coatings that are non-flowable under ambient conditions and can initially be remelted by heating the coating above its flow transition temperature. In the presence of moisture, the flow transition temperature of the coating gradually increases due to the reaction of hydrolyzable groups on the polyorganosiloxane ingredient until the coating is converted to a non-flowable resin reinforced elastomer. Preferred coatings are non-transferable at 25.degree. C. within ten minutes following application.
摘要翻译：包含MQ树脂和液体聚有机硅氧烷的特定组合的有机硅氧烷组合物可以作为熔融材料施加以形成在环境条件下不可流动的涂层，并且最初可以通过将涂层加热到高于其流动转变温度来重新熔化。在存在水分的情况下，涂层的流动转变温度由于聚有机硅氧烷成分上的可水解基团的反应而逐渐增加，直到涂层转化为不可流动的树脂增强弹性体。优选的涂层在施用后10分钟内不能在25℃下转移。

2. 发明授权

US5302671A Moisture-curable compositions containing aminoalkoxy-functional silicone 失效
标题翻译：含有氨基烷氧基官能的硅氧烷的水溶性组合物
公开(公告)号：US5302671A
公开(公告)日：1994-04-12
申请号：US76619
申请日：1993-06-11
申请人： Martin E. Cifuentes , William P. Brady , William N. Fenton , Randall G. Schmidt , Michael R. Strong , David L. Stickles , Bernard VanWert
发明人： Martin E. Cifuentes , William P. Brady , William N. Fenton , Randall G. Schmidt , Michael R. Strong , David L. Stickles , Bernard VanWert
IPC分类号： C08K5/5465 , C08K5/54 , C08K5/5419 , C08L83/04 , C08L83/06 , C08L83/08 , C09D183/08 , C09J183/00 , C09J183/06 , C09J183/08 , C08G77/38
CPC分类号： C09D183/08 , C09J183/08
摘要： A moisture-curable silicone composition, suitable for use as a coating or pressure-sensitive adhesive, is disclosed, said composition comprising (i) a hydroxyl-functional organopolysiloxane resin comprising R.sub.3 SiO.sub.1/2 siloxane units and SiO.sub.4/2 siloxane units in a molar ratio of 0.5/1 to 1.2/1. respectively, wherein R is a hydrocarbon or halogenated hydrocarbon radical: (ii) a diorganopolysiloxane polymer having at least two silicon-bonded alkoxy groups and at least one carbon-bonded amine group in its molecule, said polymer having a viscosity at 25.degree. C. of 20 to 100,000 centipoise, the weight ratio of said resin to said polymer being in the range 20:80 to 80:20; (iii) optionally, a hydrolyzable silane in sufficient amount to provide stability to said composition; and (iv) optionally, sufficient catalyst to accelerate the cure of said composition.
摘要翻译：公开了适合用作涂层或压敏粘合剂的可湿气固化的硅氧烷组合物，所述组合物包含（i）含有摩尔比的R3SiO1 / 2硅氧烷单元和SiO4 / 2硅氧烷单元的羟基官能的有机聚硅氧烷树脂为0.5 / 1〜1.2 / 1。其中R是烃或卤代烃基：（ii）在其分子中具有至少两个与硅键合的烷氧基和至少一个与碳键合的胺基的二有机聚硅氧烷聚合物，所述聚合物在25℃下具有粘度。 20至100,000厘泊，所述树脂与所述聚合物的重量比在20:80至80:20的范围内; （iii）任选地，足够量的可水解硅烷以提供对所述组合物的稳定性; 和（iv）任选的足以催化所述组合物固化的催化剂。

3. 发明授权

US5505997A Method and apparatus for applying coatings of molten moisture curable organosiloxane compositions 失效
标题翻译：用于涂覆熔融可湿气固化的有机硅氧烷组合物的方法和设备
公开(公告)号：US5505997A
公开(公告)日：1996-04-09
申请号：US235739
申请日：1994-04-29
申请人： Michael R. Strong , Bernard VanWert , Martin E. Cifuentes
发明人： Michael R. Strong , Bernard VanWert , Martin E. Cifuentes
IPC分类号： B05D3/02 , B05C5/00 , B05C5/02 , B05C5/04 , B05D1/26 , B05D3/04 , B05D7/24 , C09D183/04 , B05D3/12
CPC分类号： C09D183/04 , B05C5/02 , B05D1/265 , B05D3/042 , B05C5/001
摘要： A stream of a molten moisture curable organosiloxane composition is entrained in a current of a heated gas containing a concentration of water vapor below the saturation level of the gas at 25.degree. C. The gas current directs the organosiloxane composition toward the surface to be coated and provides an environment adjacent to the surface of the coated substrate that causes at least the surface layer of the composition to cure at a rate that is substantially constant and independent of the temperature and humidity in the macroscopic environment of the substrate.
摘要翻译：熔融可湿气固化的有机硅氧烷组合物流被夹带在含有低于25℃气体饱和水平的水蒸气浓度的加热气体的电流中。气流导向有机硅氧烷组合物朝向待涂覆的表面，提供了邻近涂覆基材表面的环境，使得至少组合物的表面层以基本恒定的速率固化，并且与基材的宏观环境中的温度和湿度无关。

4. 发明授权

US5561203A Silicone pressure sensitive adhesive composition 失效
标题翻译：硅胶压敏胶组成
公开(公告)号：US5561203A
公开(公告)日：1996-10-01
申请号：US479202
申请日：1995-04-13
申请人： Michael R. Strong , Bernard VanWert , Martin E. Cifuentes
发明人： Michael R. Strong , Bernard VanWert , Martin E. Cifuentes
IPC分类号： C08K3/00 , C08K5/5419 , C08L83/04 , C09J183/00 , C09J183/04 , C08F283/00
CPC分类号： C09J183/04
摘要： Silicone pressure sensitive compositions that combine high ultimate strength in a cured network with a lower modulus and have improved adhesive strength at elevated temperatures are disclosed. The pressure sensitive adhesive compositions are comprised of (A) a soluble, capped, organopolysiloxane resin containing less than 1.2 weight percent silicon-bonded hydroxyl groups based on the total weight of (A); (B) a diorganopolysiloxane polymer, each terminal group thereof containing at least two silicon-bonded hydrolyzable radicals said polymer having a viscosity at 25.degree. C. of 20 to 100,000 mm.sup.2 /s; and (C) a hydrolyzable silane.
摘要翻译：公开了在固化网络中具有较低模量并且在升高的温度下具有改善的粘合强度的高极限强度的硅酮压敏组合物。压敏粘合剂组合物由（A）基于（A）的总重量含有小于1.2重量％的硅键合的羟基的可溶性封端的有机聚硅氧烷树脂构成; （B）二有机聚硅氧烷聚合物，其每个端基含有至少两个硅键合的可水解基团，所述聚合物在25℃下的粘度为20至100,000mm 2 / s; 和（C）可水解硅烷。

5. 发明授权

US5508360A Moisture-curable hot melt silicone pressure-sensitive adhesives 失效
标题翻译：水溶性热熔硅胶压敏粘合剂
公开(公告)号：US5508360A
公开(公告)日：1996-04-16
申请号：US414465
申请日：1995-03-31
申请人： Martin E. Cifuentes , Michael R. Strong , Bernard VanWert , Michael A. Lutz , Randall G. Schmidt
发明人： Martin E. Cifuentes , Michael R. Strong , Bernard VanWert , Michael A. Lutz , Randall G. Schmidt
IPC分类号： C09J183/08 , C09J183/00 , C09J183/04 , C09J183/14 , C08F283/12
CPC分类号： C09J183/04 , C09J183/14
摘要： The present invention relates to a silicone pressure-sensitive adhesive composition which cure upon exposure to ambient moisture. The moisture-curable silicone pressure-sensitive adhesive composition of the instant invention comprise:(A) an organopolysiloxane resin containing curing radicals of the formula --SiY.sub.2 ZNY'ZSiR.sup.1.sub.x Y".sub.3-x wherein R.sup.1 is a monovalent hydrocarbon radical, each Z is a divalent linking group, each Y is independently selected from the group consisting of a monovalent organic radical, an enoloxy radical, an alkoxy radical, and an oximo radical; Y' is selected from the group consisting of a monovalent organic radical, a hydrogen atom, and --ZSiR.sup.1.sub.x Y".sub.3-x ; Y" is selected from the group consisting of an enoloxy radical, an alkoxy radical, and an oximo radical; and the subscript x has a value of 0 or 1; (B) a diorganopolysiloxane polymer, each terminal group thereof containing at least one silicon-bonded hydrolyzable functional radicals selected from the group consisting of hydroxyl radicals, alkoxy radicals having 1 to 4 carbon atoms, ketoxime radicals, enoloxy radicals, aminoxy radicals, acetamido radicals, N-methylacetamido radicals and acetoxy radicals; said polymer having a viscosity at 25.degree. C. of 20 to
摘要翻译：本发明涉及在暴露于环境水分时固化的硅氧烷压敏粘合剂组合物。本发明的湿气固化型硅氧烷粘合剂组合物包含：（A）含有式-SiY 2 ZNY'ZSiR1 x Y'3-x固化基团的有机聚硅氧烷树脂，其中R 1为单价烃基，Z为二价每个Y独立地选自一价有机基团，烯氧基，烷氧基和肟基; Y'选自单价有机基团，氢原子和-ZSiR1xY'3-x; Y“选自烯氧基，烷氧基和肟基; 下标x的值为0或1; （B）二有机聚硅氧烷聚合物，其每个末端基团含有至少一个选自羟基，具有1至4个碳原子的烷氧基，酮肟基，烯氧基，氨氧基，乙酰氨基的硅键合的可水解官能团，N-甲基乙酰氨基和乙酰氧基; 所述聚合物在25℃下的粘度为20至<100,000mm 2 / s，所述树脂与所述聚合物的重量比在5:95至90:10的范围内; （C）任选的足以加速所述组合物固化的催化剂; （D）任选的式R 24 -ySiXy的硅烷或其低聚反应产物，其中R 2选自烃基和具有1至6个碳原子的取代烃基，X是可水解基团，y是2 到4; 和（E）任选的填料。

6. 发明授权

US5473026A Moisture-curable hot melt silicone pressure-sensitive adhesives 失效
标题翻译：水溶性热熔硅胶压敏粘合剂
公开(公告)号：US5473026A
公开(公告)日：1995-12-05
申请号：US262791
申请日：1994-06-20
申请人： Michael R. Strong , Martin E. Cifuentes , Bernard VanWert , William J. Schoenherr
发明人： Michael R. Strong , Martin E. Cifuentes , Bernard VanWert , William J. Schoenherr
IPC分类号： C09J183/00 , C09J183/04 , C09J183/14 , C08L83/06
CPC分类号： C09J183/04 , C09J183/14
摘要： A moisture-curable silicone hot melt pressure sensitive adhesive composition is disclosed, said composition comprising: (A) a solid alkoxy functional organopolysiloxane resin containing curing radicals of the formula --ZSiR.sup.1.sub.x (OR.sup.2).sub.3-x ; wherein R.sup.1 is a monovalent hydrocarbon radical, R.sup.2 is selected from the group consisting of a alkyl radical and alkoxyalkyl radical, Z is a divalent linking radical, and the subscript x has a value of 0 or 1; (B) a diorganopolysiloxane polymer, each terminal group thereof containing at least one silicon-bonded hydrolyzable functional radical selected from the group consisting of alkoxy radicals having 1 to 4 carbon atoms, ketoxime radicals, aminoxy radicals, acetamido radicals, N-methylacetamido radicals and acetoxy radicals; said polymer having a viscosity at 25.degree. C. of 20 to
摘要翻译：公开了一种可湿气固化的硅氧烷热熔压敏粘合剂组合物，所述组合物包含：（A）含有式-ZSiR1x（OR2）3-x固化基团的固体烷氧基官能的有机聚硅氧烷树脂; 其中R1是一价烃基，R2选自烷基和烷氧基烷基，Z是二价连接基团，下标x具有0或1的值; （B）二有机聚硅氧烷聚合物，其每个末端基团含有至少一个选自具有1至4个碳原子的烷氧基，酮肟基，氨氧基，乙酰氨基，N-甲基乙酰胺基的硅键合的可水解的官能团，乙酰氧基; 所述聚合物在25℃下的粘度为20至<100,000mm 2 / s，所述树脂与所述聚合物的重量比在40:60至80:20的范围内; 和（C）足够的催化剂以加速所述组合物的固化; 所述组合物在室温下是基本上无溶剂的非坍落度固体，其在暴露于水分时可固化成基本上非粘性的弹性体。

7. 发明授权

US5389170A Method for bonding substrates using molten moisture reactive organosiloxane compositions 失效
标题翻译：使用熔融水分反应性有机硅氧烷组合物粘结基材的方法
公开(公告)号：US5389170A
公开(公告)日：1995-02-14
申请号：US75989
申请日：1993-06-11
申请人： William P. Brady , Martin E. Cifuentes , William J. Schoenherr , David L. Stickles , Michael R. Strong , Bernard Vanwert , Gary A. Vincent , Randall G. Schmidt
发明人： William P. Brady , Martin E. Cifuentes , William J. Schoenherr , David L. Stickles , Michael R. Strong , Bernard Vanwert , Gary A. Vincent , Randall G. Schmidt
IPC分类号： C09J5/00 , C09J183/04 , C03C27/00
CPC分类号： C09J183/04
摘要： Curable adhesive compositions comprise combinations of organosiloxane MQ resins and liquid polyorganosiloxanes of specified viscosity and functionality. The compositions are substantially free of unreactive materials and are applied in the molten state. Depending upon the concentration of reactive groups on the resin and polyorganosiloxane, the compositions may also include a silane containing an average of more than two hydrolyzable groups per molecule. Preferred compositions develop excellent adhesion to a variety of organic and metallic substrates during curing under ambient conditions.
摘要翻译：可固化的粘合剂组合物包括具有特定粘度和功能性的有机硅氧烷MQ树脂和液体聚有机硅氧烷的组合。组合物基本上不含非反应性材料，并以熔融状态施加。根据树脂和聚有机硅氧烷上的反应性基团的浓度，组合物还可以包括每分子平均含有多于两个可水解基团的硅烷。优选的组合物在环境条件下固化期间对各种有机和金属基底形成良好的粘合性。

8. 发明授权

US5246972A Polish containing highly adsorptive polymer 失效
标题翻译：含高分子吸收聚合物的POLISH
公开(公告)号：US5246972A
公开(公告)日：1993-09-21
申请号：US506032
申请日：1990-04-06
申请人： Martin E. Cifuentes , Kenneth A. Kasprzak , Janet M. Smith
发明人： Martin E. Cifuentes , Kenneth A. Kasprzak , Janet M. Smith
IPC分类号： C08K9/10 , C08K5/544 , C08K9/08 , C08L83/04 , C08L101/00 , C09G1/12 , C09G1/16
CPC分类号： C09G1/16
摘要： A polish composition which includes discrete particles of a highly cross-linked macroporous hydrophobic polymer. The particles are of a first predetermined average diameter, and the polymer particles have entrapped therein and dispersed uniformly throughout an active organosilicon ingredient. The composition also includes a coacervating agent mixed with the polymer particles in an amount sufficient to cause the polymer particles to collect forming dense clusters of coacervated particles of a second predetermined average diameter, the second predetermined average diameter being substantially in excess of the first predetermined average diameter.
摘要翻译：一种抛光组合物，其包含高度交联的大孔疏水性聚合物的离散颗粒。颗粒具有第一预定平均直径，并且聚合物颗粒被捕获并均匀分散在活性有机硅成分中。组合物还包括与聚合物颗粒混合的凝聚剂，其量足以使聚合物颗粒收集形成具有第二预定平均直径的凝聚颗粒的致密簇，第二预定平均直径基本上超过第一预定平均值直径。

9. 发明授权

US5389364A Conditioning hair with aminosilane reaction products with lactones or carbonates 失效
标题翻译：用氨基硅烷反应产物调理头发与内酯或碳酸酯
公开(公告)号：US5389364A
公开(公告)日：1995-02-14
申请号：US102927
申请日：1993-08-06
申请人： Martin E. Cifuentes , Patricia A. Giwa-Agbomeirele
发明人： Martin E. Cifuentes , Patricia A. Giwa-Agbomeirele
IPC分类号： A61K8/00 , A61K8/58 , A61K8/89 , A61K8/895 , A61K8/898 , A61Q5/00 , A61Q5/02 , A61Q5/12 , C08L83/08 , A61K7/06 , A61K7/09
CPC分类号： A61Q5/02 , A61K8/898
摘要： Hair is conditioned by applying to the hair an effective amount of a composition which includes as the hair conditioning agent, from 0.5 to 5.0 percent by weight of a derivatized amine functional organosilicon compound which is one of (i) a reaction product of an amine functional polysiloxane and a derivative of carbonic acid; (ii) a reaction product of an amine functional polysiloxane and a lactone; (iii) a reaction product of an amine functional silane and a derivative of carbonic acid; or (iv) a reaction product of an amine functional silane and a lactone.
摘要翻译：头发通过向头发施用有效量的组合物，其包含作为头发调理剂的0.5至5.0重量％的衍生的胺官能的有机硅化合物，其为（i）胺官能团的反应产物之一聚硅氧烷和碳酸衍生物; （ii）胺官能聚硅氧烷和内酯的反应产物; （iii）胺官能硅烷与碳酸衍生物的反应产物; 或（iv）胺官能硅烷与内酯的反应产物。

10. 发明授权

US5217758A Silicone containing automotive vinyl protectant 失效
标题翻译：含硅氧烷的汽车乙烯基保护剂
公开(公告)号：US5217758A
公开(公告)日：1993-06-08
申请号：US883976
申请日：1992-05-15
申请人： Suzanne M. Greenleaf , Martin E. Cifuentes
发明人： Suzanne M. Greenleaf , Martin E. Cifuentes
IPC分类号： B05D7/02 , C08J7/04 , C09D183/04
CPC分类号： C08J7/047 , B05D7/02 , C09D183/04 , C08J2483/00
摘要： A method is described for providing a protective finish to a vinyl substrate by applying to the vinyl substrate a vinyl protectant composition. In one embodiment the composition is an abrasive free mixture of a film forming polysiloxane; a diluent; and a wax in the form of micronized particles having an average diameter of 3-12 microns. In another embodiment, the composition is a hydrocarbon solvent free mixture of a film forming polysiloxane; water; and an amorphous silica in the form of fumed silica particles having an average diameter of 7-30 nanometers.
摘要翻译：描述了一种通过向乙烯基底物施加乙烯基保护剂组合物来向乙烯基底物提供保护整理剂的方法。在一个实施方案中，组合物是成膜聚硅氧烷的无磨料混合物; 稀释剂和具有平均直径为3-12微米的微粉化颗粒形式的蜡。在另一个实施方案中，组合物是成膜聚硅氧烷的无烃溶剂混合物; 水; 以及平均直径为7-30纳米的热解二氧化硅颗粒形式的无定形二氧化硅。

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